{"type": "FeatureCollection", "features": [{"id": "10.1016/j.epsl.2017.04.002", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:22Z", "type": "Journal Article", "created": "2017-04-14", "title": "The origin of volatile element depletion in early solar system material: Clues from Zn isotopes in chondrules", "description": "Abstract   Volatile lithophile elements are depleted in the different planetary materials to various degrees, but the origin of these depletions is still debated. Stable isotopes of moderately volatile elements such as Zn can be used to understand the origin of volatile element depletions. Samples with significant volatile element depletions, including the Moon and terrestrial tektites, display heavy Zn isotope compositions (i.e. enrichment of 66Zn vs. 64Zn), consistent with kinetic Zn isotope fractionation during evaporation. However,  Luck et al. (2005)  found a negative correlation between      \u03b4    66     Zn and 1/[Zn] between CI, CM, CO, and CV chondrites, opposite to what would be expected if evaporation caused the Zn abundance variations among chondrite groups.  We have analyzed the Zn isotope composition of multiple samples of the major carbonaceous chondrite classes: CI (1), CM (4), CV (2), CO (4), CB (2), CH (2), CK (4), and CK/CR (1). The bulk chondrites define a negative correlation in a plot of      \u03b4    66     Zn vs 1/[Zn], confirming earlier results that Zn abundance variations among carbonaceous chondrites cannot be explained by evaporation. Exceptions are CB and CH chondrites, which display Zn systematics consistent with a collisional formation mechanism that created enrichment in heavy Zn isotopes relative to the trend defined by CI\u2013CK.  We further report Zn isotope analyses of chondrite components, including chondrules from Allende (CV3) and Mokoia (CV3), as well as an aliquot of Allende matrix. All chondrules are enriched in light Zn isotopes (\u223c500 ppm on 66Zn/64Zn) relative to the bulk, contrary to what would be expected if Zn were depleted during evaporation, on the other hand the matrix has a complementary heavy isotope composition. We report sequential leaching experiments in un-equilibrated ordinary chondrites, which show sulfides are isotopically heavy compared to silicates and the bulk meteorite by ca. +0.65 per mil on 66Zn/64Zn. We suggest isotopically heavy sulfides were removed from either chondrules or their precursors, thereby producing the light Zn isotope enrichments in chondrules.", "keywords": ["chondrules", "550", "protoplanetary disk", "551", "carbonaceous chondrites", "01 natural sciences", "volatiles", "[SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDU.STU.PL] Sciences of the Universe [physics]/Earth Sciences/Planetology", "zinc isotopes", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.epsl.2017.04.002"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Earth%20and%20Planetary%20Science%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.epsl.2017.04.002", "name": "item", "description": "10.1016/j.epsl.2017.04.002", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.epsl.2017.04.002"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-06-01T00:00:00Z"}}, {"id": "10.1007/s11368-022-03203-1", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:15:21Z", "type": "Journal Article", "created": "2022-04-23", "title": "Improving the design and implementation of sediment fingerprinting studies: summary and outcomes of the TRACING 2021 Scientific School", "description": "Identifying best practices for sediment fingerprinting or tracing is important to allow the quantification of sediment contributions from catchment sources. Although sediment fingerprinting has been applied with reasonable success, the deployment of this method remains associated with many issues and limitations.Seminars and debates were organised during a 4-day Thematic School in October 2021 to come up with concrete suggestions to improve the design and implementation of tracing methods.First, we suggest a better use of geomorphological information to improve study design. Researchers are invited to scrutinise all the knowledge available on the catchment of interest, and to obtain multiple lines of evidence regarding sediment source contributions. Second, we think that scientific knowledge could be improved with local knowledge and we propose a scale of participation describing different levels of involvement of locals in research. Third, we recommend the use of state-of-the-art sediment tracing protocols to conduct sampling, deal with particle size, and examine data before modelling and accounting for the hydro-meteorological context under investigation. Fourth, we promote best practices in modelling, including the importance of running multiple models, selecting appropriate tracers, and reporting on model errors and uncertainty. Fifth, we suggest best practices to share tracing data and samples, which will increase the visibility of the fingerprinting technique in geoscience. Sixth, we suggest that a better formulation of hypotheses could improve our knowledge about erosion and sediment transport processes in a more unified way.With the suggested improvements, sediment fingerprinting, which is interdisciplinary in nature, could play a major role to meet the current and future challenges associated with global change.The online version contains supplementary material available at 10.1007/s11368-022-03203-1.", "keywords": ["[SDE] Environmental Sciences", "DATA", "550", "[SDU.STU.GM] Sciences of the Universe [physics]/Earth Sciences/Geomorphology", "[SDV.SA.SDS]Life Sciences [q-bio]/Agricultural sciences/Soil study", "01 natural sciences", "333", "source-to-sink", "basin", "local knowledge", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "11. Sustainability", "[SDU.STU.GM]Sciences of the Universe [physics]/Earth Sciences/Geomorphology", "14. Life underwater", "[SDU.STU.HY]Sciences of the Universe [physics]/Earth Sciences/Hydrology", "catchment", "[SDV.SA.SDS] Life Sciences [q-bio]/Agricultural sciences/Soil study", "watershed", "FAIR", "0105 earth and related environmental sciences", "sediment tracing", "ddc:550", "Frontiers in Soils and Sediments \u2022 Research Article", "15. Life on land", "[SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces", " environment", "6. Clean water", "sediment fingerprinting", "Chemistry", "critical Zone", "13. Climate action", "Earth and Environmental Sciences", "[SDE]Environmental Sciences", "[SDU.STU.HY] Sciences of the Universe [physics]/Earth Sciences/Hydrology", "[SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces", "environment"]}, "links": [{"href": "https://link.springer.com/content/pdf/10.1007/s11368-022-03203-1.pdf"}, {"href": "https://doi.org/10.1007/s11368-022-03203-1"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Soils%20and%20Sediments", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s11368-022-03203-1", "name": "item", "description": "10.1007/s11368-022-03203-1", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s11368-022-03203-1"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-04-23T00:00:00Z"}}, {"id": "10.1007/s10021-013-9650-7", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:14:46Z", "type": "Journal Article", "created": "2013-02-21", "title": "Stimulation Of Different Functional Groups Of Bacteria By Various Plant Residues As A Driver Of Soil Priming Effect", "description": "The turnover of organic matter in soil depends on the activity of microbial decomposers. However, little is known about how modifications of the diversity of soil microbial communities induced by fresh organic matter (FOM) inputs can regulate carbon cycling. Here, we investigated the decomposition of two 13C labeled crop residues (wheat and alfalfa) and the dynamics of the genetic structure and taxonomic composition of the soil bacterial communities decomposing 13C labeled FOM and native unlabeled soil organic matter (SOM), respectively. It was achieved by combining the stable isotope probing method with molecular tools (DNA genotyping and pyrosequencing of 16S rDNA). Although a priming effect (PE) was always induced by residue addition, its intensity increased with the degradability of the plant residue. The input of both wheat and alfalfa residues induced a rapid dynamics of FOM-degrading communities, corresponding to the stimulation of bacterial phyla which have been previously described as copiotrophic organisms. However, the dynamics and the identity of the bacterial groups stimulated depended on the residue added, with Firmicutes dominating in the wheat treatment and Proteobacteria dominating in the alfalfa treatment after 3\u00a0days of incubation. In both treatments, SOM-degrading communities were dominated by Acidobacteria, Verrucomicrobia, and Gemmatimonadetes phyla which have been previously described as oligotrophic organisms. An early stimulation of SOM-degrading populations mainly belonging to Firmicutes and Bacteroidetes groups was observed in the alfalfa treatment whereas no change occurred in the wheat treatment. Our findings support the hypothesis that the succession of bacterial taxonomic groups occurring in SOM- and FOM-degrading communities during the degradation process may be an important driver of the PE, and consequently of carbon dynamics in soil.", "keywords": ["0301 basic medicine", "2. Zero hunger", "570", "0303 health sciences", "[SDE.MCG]Environmental Sciences/Global Changes", "bacterial diversity", "[SDV.SA.SDS]Life Sciences [q-bio]/Agricultural sciences/Soil study", "15. Life on land", "[SDV.MP.BAC]Life Sciences [q-bio]/Microbiology and Parasitology/Bacteriology", "630", "soil", "[SDE.MCG] Environmental Sciences/Global Changes", "03 medical and health sciences", "pyrosequencing", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "soil organic matter", "carbon cycle", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDV.MP.BAC] Life Sciences [q-bio]/Microbiology and Parasitology/Bacteriology", "[SDV.SA.SDS] Life Sciences [q-bio]/Agricultural sciences/Soil study", "stable isotope probing"]}, "links": [{"href": "https://doi.org/10.1007/s10021-013-9650-7"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Ecosystems", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10021-013-9650-7", "name": "item", "description": "10.1007/s10021-013-9650-7", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10021-013-9650-7"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2013-02-22T00:00:00Z"}}, {"id": "10.1007/s10533-013-9920-7", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:14:54Z", "type": "Journal Article", "created": "2013-10-29", "title": "Compound-Specific C-13 And C-14 Measurements Improve The Understanding Of Soil Organic Matter Dynamics", "description": "Compound-specific isotopic analyses were used to assess the dynamics and origin of organic matter in soils across a 30 year chronose- quence where native savanna (C4) had been replaced with eucalyptus (C3). Apolar lipid fractions were recovered from plants and soils planted with Eucalyptus 0, 7.5, 17 and 30 years ago. The molecular composition of lipids in plants and soils identified three major pentacyclic triterpene methyl esters (PTMEs) specific to savanna, and three odd n- alkanes common to both vegetation types. Savanna- derived PTMEs and \u03b4 13 C remained at similar levels in soils after 30 years of eucalyptus growth. 14 C", "keywords": ["<sup>13</sup>C", "570", "550", "Chronosequence C<sub>4</sub>/C<sub>3</sub>", "14 C", "<sup>14</sup>C", "13 C", "04 agricultural and veterinary sciences", "Molecular dynamics", "15. Life on land", "n-Alkanes", "Chronosequence C 4 /C 3", "PTMEs", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "0401 agriculture", " forestry", " and fisheries", "14. Life underwater"]}, "links": [{"href": "https://doi.org/10.1007/s10533-013-9920-7"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Biogeochemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10533-013-9920-7", "name": "item", "description": "10.1007/s10533-013-9920-7", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10533-013-9920-7"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2013-10-30T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2021.120283", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:04Z", "type": "Journal Article", "created": "2021-04-27", "title": "Imprint of chemical weathering and hydrothermalism on the Ge/Si ratio and Si isotope composition of rivers in a volcanic tropical island, Basse-Terre, Guadeloupe (French West Indies)", "description": "Abstract   A significant portion of the disproportionally high chemical weathering flux in volcanic island arcs may originate from hydrothermal fluid-rock interaction, thereby compromising the accurate estimate of atmospheric CO2 consumption rates. The objective of this study is to evaluate how the riverine Ge/Si ratio and Si isotopes, two well-established tracers of weathering, respond to hydrothermal inputs. The work took place in Basse-Terre, Guadeloupe, a tropical volcanic island with a dense river network, high chemical weathering fluxes and various hydrothermal surface manifestations. We characterized the Ge/Si ratio and \u03b430Si of 15 thermal springs, nine non-impacted (NI) rivers and 13 hydrothermally-impacted (HI) rivers. The soil solution from a highly weathered soil profile (Ferralsol) and a clayey-rock corresponding to the material exposed in an extinct hydrothermal system were also measured. A new purification method was successfully developed in order to allow the reliable measurement of Si isotopes in SO42\u2212- and Cl\u2212-rich thermal spring and HI river waters by mass spectrometry. Basse-Terre's thermal springs have variable Ge/Si ratios (0.05\u201321.03\u00a0\u03bcmol.mol\u22121) and \u03b430Si (0.71\u20131.50\u2030), but with no apparent relationship to the water compositional type. The Ge/Si ratio (0.15\u20132.57\u00a0\u03bcmol.mol\u22121) and Si isotope composition (0.26\u20131.21\u2030) values of the NI rivers reveal differences in the watersheds' weathering degree. Dissolution of Ge- and 28Si-rich secondary minerals explains the high Ge/Si and isotopically light composition of the northern NI rivers draining strongly weathered terranes. The Ge/Si ratio and \u03b430Si values measured for the NI and HI rivers overlap, implying that they cannot be used to diagnose hydrothermal contributions to river basins unambiguously. However, when combined with the Cl\u2212 and SO42\u2212 concentrations, the analysis of Ge and Si in the HI rivers suggests that water seeping through an extinct hydrothermal system produces SO4-rich drainages with distinctively lower Ge/Si ratios than those inferred for watersheds receiving thermal spring discharges associated with an active hydrothermal system. Overall, our results provide new constraints for applying and interpreting Ge/Si and Si isotope measurements to study weathering in volcanic environments.", "keywords": ["[SDE] Environmental Sciences", "Volcanic hydrothermal system", "Chemical weathering", "River geochemistry", "Si isotope", "Ge/Si ratio", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Guadeloupe", "01 natural sciences", "6. Clean water", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2021.120283"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2021.120283", "name": "item", "description": "10.1016/j.chemgeo.2021.120283", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2021.120283"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-09-01T00:00:00Z"}}, {"id": "10.1007/s10705-014-9650-9", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:15:00Z", "type": "Journal Article", "created": "2014-10-25", "title": "Nitrate Leaching From Organic And Conventional Arable Crop Farms In The Seine Basin (France)", "description": "In the Seine Basin, characterised by intensive arable crops, most of the surface and groundwater is contaminated by nitrate (NO3-). The goal of this study is to investigate nitrogen leaching on commercial arable crop farms in five organic and three conventional systems. In 2012-2013, a total of 37 fields are studied on eight arable crop rotations, for three different soil and climate conditions. Our results show a gradient of soil solution concentrations in function of crops, lower for alfalfa (mean 2.8 mg NO3-N l(-1)) and higher for crops fertilised after legumes (15 mg NO3-N l(-1)). Catch crops decrease nitrate soil solution concentrations, below 10 mg NO3-N l(-1). For a full rotation, the estimated mean concentrations is lower for organic farming, 12 +/- 5 mg NO3-N l(-1) than for conventional farming 24 +/- 11 mg NO3-N l(-1), with however a large range of variability. Overall, organic farming shows lower leaching rates (14-50 kg NO3-N ha(-1)) than conventional farms (32-77 kg NO3-N ha(-1)). Taking into account the slightly lower productivity of organic systems, we show that yield-scaled leaching values are also lower for organic (0.2 +/- 0.1 kg N kg(-1) N year(-1)) than for conventional systems (0.3 +/- 0.1 kg N kg(-1) N year(-1)). Overall, we show that organic farming systems have lower impact than conventional farming on N leaching, although there is still room for progress in both systems in commercial farms.", "keywords": ["[SDV.SA.AGRO] Life Sciences [q-bio]/Agricultural sciences/Agronomy", "2. Zero hunger", "Organic farming", "Soil Science", "04 agricultural and veterinary sciences", "15. Life on land", "6. Clean water", "Nitrate leaching", "Farmer-centred approach", "Arable crops", "13. Climate action", "Ceramic cups", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "0401 agriculture", " forestry", " and fisheries", "Agronomy and Crop Science"], "contacts": [{"organization": "Benoit, Marie, Garnier, Josette, Anglade, Juliette, Billen, Gilles,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1007/s10705-014-9650-9"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Nutrient%20Cycling%20in%20Agroecosystems", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10705-014-9650-9", "name": "item", "description": "10.1007/s10705-014-9650-9", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10705-014-9650-9"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2014-10-26T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2016.11.020", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:03Z", "type": "Journal Article", "created": "2016-11-17", "title": "The gallium isotopic composition of the bulk silicate Earth", "description": "AbstractWe report a new method for precise analysis of gallium (Ga) isotopic composition in geological samples. The purification of Ga is achieved by a three-step ion exchange chromatography to remove matrix and interfering elements. The 71Ga/69Ga ratios are analyzed by multi-collector inductively-coupled-plasma mass-spectrometer (MC-ICP-MS). The external reproducibility of the measurements (0.05\u2030, 2 s.d.) was assessed by replicate analyses of the USGS BCR-2 and BHVO-2 standards. This newly developed technique was then used to investigate the extent of Ga isotopic fractionation during igneous processes by analyzing well-characterized samples from the Kilauea Iki lava lake, USA. These samples were formed in a closed system and have MgO contents ranging from 26.9 to 2.4wt.%. We found that igneous processes do not fractionate Ga isotopes within the analytical uncertainty and that the Ga isotopic composition of mafic-ultramafic lavas can be used to estimate the composition of their mantle source. Twelve ocean island basalts, two mid-ocean-ridge basalts, one continental flood basalt and one komatiite have homogeneous and nearly identical Ga isotopic compositions within analytical uncertainties averaging 0.00\u00b10.06\u2030 (2s.d.). This value represents the best estimate for the Ga isotopic composition of the bulk silicate Earth", "keywords": ["Bulk Silicate Earth", "Komatiite", "Gallium", "Geology", "MORB", "01 natural sciences", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Geochemistry and Petrology", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "14. Life underwater", "OIB", "MC-ICP-MS", "Basalt", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2016.11.020"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2016.11.020", "name": "item", "description": "10.1016/j.chemgeo.2016.11.020", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2016.11.020"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2017.12.006", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:04Z", "type": "Journal Article", "created": "2017-12-13", "title": "Zinc isotope composition of the Earth and its behaviour during planetary accretion", "description": "Abstract   The terrestrial planets are depleted in volatile elements with respect to chondritic meteorites, their possible building blocks. However, the timing, extent and origin of volatile depletion is debated. Zinc is a moderately volatile element (MVE), whose stable isotopic composition can distinguish when and where this depletion took place. Here, we report data for 40 ultramafic rocks comprising pristine upper mantle peridotites from the Balmuccia orogenic lherzolite massif and Archean komatiites that together define the Zn isotope composition of the Earth's primitive mantle. Peridotites and komatiites are shown to have indistinguishable Zn isotopic compositions of \u03b466Zn\u00a0=\u00a0+\u00a00.16\u00a0\u00b1\u00a00.06\u2030 (2SD), (with \u03b466Zn the per mille deviation of 66Zn/64Zn from the JMC-Lyon standard), implying a constant Zn isotope composition for the silicate Earth since 3.5\u00a0Ga. After accounting for Zn sequestration during core formation, the Earth falls on the volatile-depleted end of a carbonaceous chondrite array in \u03b466Zn-Zn/Mg space, implying Earth avoided modification of its MVE budgets during late accretion (e.g. during a giant impact), in contrast to the Moon. The Moon deviates from the chondritic array in a manner consistent with evaporative loss of Zn, where its \u03b466Zn co-varies with Mn/Na, implying post-nebular volatile loss is more pronounced on smaller bodies. Should the giant impact deliver the Earth's volatile complement of Pb and Ag, it cannot account for the budget of lithophile MVEs (e.g. Zn, Rb, Mn), whose abundances reflect those of Earth's nebular building blocks. The Earth initially accreted from material that experienced chemical- and mass-dependent isotopic fractionation akin to carbonaceous chondrites, though volatile depletion was more pronounced on Earth.", "keywords": ["Zinc", "550", "Isotope", "13. Climate action", "Nebula", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Komatiite", "Mantle", "[SDU.STU.PL] Sciences of the Universe [physics]/Earth Sciences/Planetology", "Peridotite", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://openresearch-repository.anu.edu.au/bitstream/1885/139076/4/1-s2.0-S0009254117306782-main.pdf.jpg"}, {"href": "https://doi.org/10.1016/j.chemgeo.2017.12.006"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2017.12.006", "name": "item", "description": "10.1016/j.chemgeo.2017.12.006", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2017.12.006"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2018.03.030", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:04Z", "type": "Journal Article", "created": "2018-03-20", "title": "The stable strontium isotopic composition of ocean island basalts, mid-ocean ridge basalts, and komatiites", "description": "Ocean island basalts Mid-ocean ridge basalts Komatiites Kilauea Iki Bulk silicate earth A B S T R A C T The radiogenic 87 Rb-87 Sr system has been widely applied to the study of geological and planetary processes. In contrast, the stable Sr isotopic composition of the bulk silicate Earth (BSE) and the effects of igneous differentiation on stable Sr isotopes are not well-established. Here we report the stable Sr isotope (88 Sr/ 86 Sr, reported as \u03b4 88/86 Sr, in parts per mil relative to NIST SRM 987) compositions for ocean islands basalts (OIB), mid-ocean ridge basalts (MORB) and komatiites from a variety of locations. Stable Sr isotopes display limited fractionation in a OIB sample suite from the Kilauea Iki lava lake suggesting that igneous processes have limited effect on stable Sr isotope fractionation (\u00b1 0.12\u2030 over 20% MgO variation; 2sd). In addition, OIB (\u03b4 88/ 86 Sr = 0.16-0.46\u2030; average 0.28 \u00b1 0.17\u2030), MORB (\u03b4 88/86 Sr = 0.27-0.34\u2030; average 0.31 \u00b1 0.05\u2030) and komatiites (\u03b4 88/86 Sr = 0.20-0.97\u2030; average 0.41 \u00b1 0.16\u2030) from global localities exhibit broadly similar Sr stable isotopic compositions. Heavy stable Sr isotope compositions (\u03b4 88/86 Sr > 0.5\u2030) in some Barberton Greenstone belt komatiites may reflect Archean seawater alteration or metamorphic processes and preferential removal of the lighter isotopes of Sr. To first order, the similarity among OIBs from three different ocean basins suggests homogeneity of stable Sr isotopes in the mantle. Earth's mantle stable Sr isotopic composition is established from the data on OIB, MORB and komatiites to be \u03b4 88/86 Sr = 0.30 \u00b1 0.02\u2030 (2sd). The BSE \u03b4 88/86 Sr value is identical, within uncertainties, to the composition of carbonaceous chondrites (\u03b4 88/ 86 Sr = 0.29 \u00b1 0.06\u2030; 2sd) measured in this study.", "keywords": ["Ocean island basalts", "Bulk silicate earth", "Sr isotopes", "Mid-ocean ridge basalts", "Kilauea Iki", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "14. Life underwater", "Komatiites", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2018.03.030"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2018.03.030", "name": "item", "description": "10.1016/j.chemgeo.2018.03.030", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2018.03.030"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-04-01T00:00:00Z"}}, {"id": "10.1016/j.epsl.2016.12.008", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:22Z", "type": "Journal Article", "created": "2016-12-22", "title": "Chromium isotope evidence in ejecta deposits for the nature of Paleoproterozoic impactors", "description": "Non-mass dependent chromium isotopic signatures have been successfully used to determine the presence and identification of extra-terrestrial materials in terrestrial impact rocks. Paleoproterozoic spherule layers from Greenland (Graenseso) and Russia (Zaonega), as well as some distal ejecta deposits (Lake Superior region) from the Sudbury impact (1,849 +/- 0.3 Ma) event, have been analyzed for their Cr isotope compositions. Our results suggest that 1) these distal ejecta deposits are all of impact origin, 2) the Graenseso and Zaonega spherule layers contain a distinct carbonaceous chondrite component, and are possibly related to the same impact event, which could be Vredefort (2,023 +/- 4 Ma) or another not yet identified large impact event from that of similar age, and 3) the Sudbury ejecta record a complex meteoritic signature, which is different from the Graenseso and Zaonega spherule layers, and could indicate the impact of a heterogeneous chondritic body.", "keywords": ["TERRESTRIAL", "KARELIA", "impact ejecta", "FOS: Physical sciences", "01 natural sciences", "METEORITIC COMPONENTS", "SOLAR-SYSTEM", "[SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "SOUTH GREENLAND", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "GEOCHEMICAL EVIDENCE", "Vredefort", "Sudbury", "0105 earth and related environmental sciences", "Earth and Planetary Astrophysics (astro-ph.EP)", "crater", "KETILIDIAN OROGEN", "meteorite", "EARLY EARTH", "105105 Geochemistry", "EVENT", "13. Climate action", "chromium isotopes", "[SDU.STU.PL] Sciences of the Universe [physics]/Earth Sciences/Planetology", "105105 Geochemie", "SPHERULES", "Astrophysics - Earth and Planetary Astrophysics"]}, "links": [{"href": "https://doi.org/10.1016/j.epsl.2016.12.008"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Earth%20and%20Planetary%20Science%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.epsl.2016.12.008", "name": "item", "description": "10.1016/j.epsl.2016.12.008", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.epsl.2016.12.008"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-02-01T00:00:00Z"}}, {"id": "10.1016/j.epsl.2017.05.033", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:22Z", "type": "Journal Article", "created": "2017-06-16", "title": "Rubidium isotopic composition of the Earth, meteorites, and the Moon: Evidence for the origin of volatile loss during planetary accretion", "description": "Abstract   Understanding the origin of volatile element variations in the inner Solar System has long been a goal of cosmochemistry, but many early studies searching for the fingerprint of volatile loss using stable isotope systems failed to find any resolvable variations.  An improved method for the chemical purification of Rb for high-precision isotope ratio measurements by multi-collector inductively-coupled-plasma mass-spectrometry. This method has been used to measure the Rb isotopic composition for a suite of planetary materials, including carbonaceous, ordinary, and enstatite chondrites, as well as achondrites (eucrite, angrite), terrestrial igneous rocks (basalt, andesite, granite), and Apollo lunar samples (mare basalts, alkali suite). Volatile depleted bodies (e.g. HED parent body, thermally metamorphosed meteorites) are enriched in the heavy isotope of Rb by up to several per mil compared to chondrites, suggesting volatile loss by evaporation at the surface of planetesimals. In addition, the Moon is isotopically distinct from the Moon in Rb. The variations in Rb isotope compositions in the volatile-poor samples are attributed to volatile loss from planetesimals during accretion. This suggests that either the Rb (and other volatile elements) were lost during or following the giant impact or by evaporation earlier during the accretion history of Theia.", "keywords": ["volatile depletion", "[SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "the Moon", "[SDU.STU.PL] Sciences of the Universe [physics]/Earth Sciences/Planetology", "01 natural sciences", "chondrites", "rubidium isotopes", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.epsl.2017.05.033"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Earth%20and%20Planetary%20Science%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.epsl.2017.05.033", "name": "item", "description": "10.1016/j.epsl.2017.05.033", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.epsl.2017.05.033"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-09-01T00:00:00Z"}}, {"id": "10.1016/j.epsl.2017.10.018", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:22Z", "type": "Journal Article", "created": "2017-10-18", "title": "Chromium isotopic homogeneity between the Moon, the Earth, and enstatite chondrites", "description": "Among the elements exhibiting non-mass dependent isotopic variations in meteorites, chromium (Cr) has been central in arguing for an isotopic homogeneity between the Earth and the Moon. However, the 54Cr isotope composition of the Moon relies on 2 samples only, which define an average value that is slightly different from the terrestrial standard. Here, by determining the Cr isotopic composition of 17 lunar, 9 terrestrial and 5 enstatite chondrite samples, we re-assess the isotopic similarity between these different planetary bodies, and provide the first robust estimate for the Moon. In average, terrestrial and enstatite samples show similar eps_54Cr. On the other hand, lunar samples show variables excesses of 53Cr and 54Cr compared to terrestrial and enstatite chondrites samples with correlated eps_53Cr and eps_54Cr (per 10,000 deviation of the 53Cr/52Cr and 54Cr/52Cr ratios normalized to the 50Cr/52Cr ratio from Cr standard). Unlike previous suggestions, we show for the first time that cosmic irradiation can affect significantly the Cr isotopic composition of lunar materials. Moreover, we also suggest that rather than spallation reactions, neutron capture effects are the dominant process controlling the Cr isotope composition of lunar igneous rocks. This is supported by the correlation between eps_53Cr and eps_54Cr, and 150Sm/152Sm ratios. After correction of these effects, the average eps_54Cr of the Moon is indistinguishable from the terrestrial and enstatite chondrite materials reinforcing the idea of an Earth-Moon-Enstatite chondrite system homogeneity. This is compatible with the most recent scenarios of Moon formation suggesting an efficient physical homogenization after a high-energy impact on a fast spinning Earth, and/or with an impactor originating from the same reservoir in the inner proto-planetary disk as the Earth and enstatite chondrites and having similar composition.", "keywords": ["Earth and Planetary Astrophysics (astro-ph.EP)", "cosmogenic effects", "FOS: Physical sciences", "01 natural sciences", "3. Good health", "Moon formation", "13. Climate action", "chromium isotopes", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "0103 physical sciences", "enstatite chondrite", "neutron capture", "Astrophysics - Earth and Planetary Astrophysics", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Christa G\u00f6pel, Fr\u00e9d\u00e9ric Moynier, Fr\u00e9d\u00e9ric Moynier, B\u00e9reng\u00e8re Mougel,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.epsl.2017.10.018"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Earth%20and%20Planetary%20Science%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.epsl.2017.10.018", "name": "item", "description": "10.1016/j.epsl.2017.10.018", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.epsl.2017.10.018"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-01-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2015.10.009", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:36Z", "type": "Journal Article", "created": "2015-10-23", "title": "High-precision sulfur isotope composition of enstatite meteorites and implications of the formation and evolution of their parent bodies", "description": "Abstract   In order to better understand the formation and evolution of their parent bodies, the three isotope ratios of sulfur were analyzed in 33 enstatite meteorites (24 enstatite chondrites and 9 aubrites). The results show that on average all enstatite chondrite groups are enriched in the lightest isotopes compared to other chondrite groups, with means of \u03b4 34 S of \u22120.28\u00a0\u00b1\u00a00.22\u2030 for EH3/4, \u22120.16\u00a0\u00b1\u00a00.16\u2030 for EH5, \u22120.32\u00a0\u00b1\u00a00.15\u2030 for EL3, \u22120.67\u00a0\u00b1\u00a00.16\u2030 for EL6 and \u22120.64\u00a0\u00b1\u00a00.00\u2030 for EL7 (all 1 \u03c3 ). Aubrites show a larger isotope variability in their composition, with a \u03b4 34 S varying from \u22121.350\u2030 to +0.154\u2030. Contrary to previously published results, our data show a distinct composition for EL6 compared to other enstatite chondrites. This could be related to an impact-induced loss of isotopically heavy oldhamite (\u03b4 34 S\u00a0=\u00a0by 3.62\u00a0\u00b1\u00a03.02\u2030 (1 \u03c3 )) on the EL parent body. Although the bulk sulfur in both enstatite meteorites and aubrites does not show any significant \u0394 33 S and \u0394 36 S, the oldhamite fraction shows clear evidence of mass independent fractionation on the  36 S/ 32 S ratio (in 3 out of 9 analyzes, \u0394 36 S up to +2.2\u2030), a signal that is not correlated to any  33 S/ 32 S anomaly (in 1 out of 9 analyzes, \u0394 33 S down to \u22120.085\u2030). Though a nebular or photochemical origin cannot be ruled out, the most plausible mechanism to produce such isolated non-mass dependent  36 S/ 32 S anomalies would be a contribution of FeCl 2  containing excesses of  36 S due to the decay of  36 Cl to the leached oldhamite fraction. Even though the sulfur isotopic composition measured in enstatite meteorites is distinct from the Bulk Silicate Earth (BSE), the isotopically lightest samples of EL6, EL7 and aubrites are approaching the isotopic composition of the BSE and enstatite meteorites remain the meteorites with the sulfur isotopic composition the closest to the terrestrial one.", "keywords": ["550", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "549", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "10. No inequality", "01 natural sciences", "3. Good health", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2015.10.009"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2015.10.009", "name": "item", "description": "10.1016/j.gca.2015.10.009", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2015.10.009"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-01-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2016.06.008", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:36Z", "type": "Journal Article", "created": "2016-06-20", "title": "Silicon isotopes reveal recycled altered oceanic crust in the mantle sources of Ocean Island Basalts", "description": "Open Access23 pages, 5 figures, 2 tables", "keywords": ["Ocean Island Basalts", "Earth and Planetary Astrophysics (astro-ph.EP)", "GE", "550", "NDAS", "500", "Silicon isotopes", "FOS: Physical sciences", "7. Clean energy", "01 natural sciences", "12. Responsible consumption", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Recycling", "14. Life underwater", "BDC", "Mantle heterogeneity", "GE Environmental Sciences", "Astrophysics - Earth and Planetary Astrophysics", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2016.06.008"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2016.06.008", "name": "item", "description": "10.1016/j.gca.2016.06.008", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2016.06.008"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-09-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2016.03.006", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:36Z", "type": "Journal Article", "created": "2016-03-11", "title": "Cosmogenic effects on Cu isotopes in IVB iron meteorites", "description": "We measured Cu isotope compositions of 12 out of the 14 known IVB iron meteorites. Our results show that IVB iron meteorites display a very large range of \u03b465Cu values (\u22125.84\u2030\u00a0<\u00a0\u03b465Cu\u00a0<\u00a0\u22120.24\u2030; defined as per mil deviation of the 65Cu/63Cu ratio from the NIST-976 standard). These Cu isotopic data display clear correlations with W, Pt, and Os isotope ratios, which are very sensitive to secondary neutron capture due to galactic cosmic ray (GCR) irradiation. This demonstrates that \u03b465Cu in IVB irons is majorly modified by neutron capture by the reaction 62Ni(n,\u03b3)63Ni followed by beta decay to 63Cu. Using correlations with Pt and Os neutron dosimeters, we calculated a pre-exposure \u03b465Cu of \u22120.3\u00a0\u00b1\u00a00.8\u2030 (95% conf.) of IVB irons that agrees well with the Cu isotopic compositions of other iron meteorite groups and falls within the range of chondrites. This shows that the volatile depletion of the IVB parent body is not due to evaporation that should have enriched IVB irons in the heavy Cu isotopes.", "keywords": ["HF-W CHRONOMETRY", "COPPER", "01 natural sciences", "PROTRACTED CORE FORMATION", "COOLING RATES", "CHONDRITES", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Geochemistry and Petrology", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "RAY-PRODUCED NUCLIDES", "PARENT BODIES", "NEUTRON-CAPTURE", "HETEROGENEITY", "RAPID ACCRETION", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2016.03.006"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2016.03.006", "name": "item", "description": "10.1016/j.gca.2016.03.006", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2016.03.006"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-06-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2016.09.013", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:36Z", "type": "Journal Article", "created": "2016-09-22", "title": "Elemental partitioning and isotopic fractionation of Zn between metal and silicate and geochemical estimation of the S content of the Earth\u2019s core", "description": "Open AccessZinc metal-silicate fractionation provides experimental access to the conditions of core formation and Zn has been used to estimate the S contents of the Earth's core and of the bulk Earth, assuming that they share similar volatility and that Zn was not partitioned into the Earth's core. We have conducted a suite of partitioning experiments to characterize Zn metal-silicate elemental and isotopic fractionation as a function of time, temperature, and composition. Experiments were conducted at temperatures from 1473-2273K, with run durations from 5-240 minutes for four starting materials. Chemical and isotopic equilibrium is achieved within 10 minutes. Zinc metal-silicate isotopic fractionation displays no resolvable dependence on temperature, composition, or oxygen fugacity. Thus, the Zn isotopic composition of silicate phases can be used as a proxy for bulk telluric bodies. Results from this study and literature data were used to parameterize Zn metal-silicate partitioning as a function of temperature, pressure, and redox state. Using this parameterization and viable formation conditions, we have estimated a range of Zn contents in the cores of iron meteorite parent bodies (i.e. iron meteorites) of ~0.1-150 ppm, in good agreement with natural observations. We have calculated the first geochemical estimates for the Zn contents of the Earth's core and of the bulk Earth, at 242 +/-107 ppm and 114 +/-34 ppm (respectively), that consider the slightly siderophile behavior of Zn and are therefore significantly higher than previous estimates. Assuming similar volatility for S and Zn, a chondritic S/Zn ratio, and considering our new estimates, we have calculated a geochemical upper bound for the S content of the Earth's core of 6.3 +/-1.9 wt%. This indicates that S may be a major contributor to the density deficit of the Earth's core or that the S/Zn ratio for the Earth is non-chondritic.", "keywords": ["Earth and Planetary Astrophysics (astro-ph.EP)", "550", "[SDU.ASTR.EP] Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]", "FOS: Physical sciences", "01 natural sciences", "Iron meteorites", "13. Climate action", "Core formation", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Zinc metal-silicate partitioning", "Isotopic fractionation", "Sulfur", "Astrophysics - Earth and Planetary Astrophysics", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2016.09.013"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2016.09.013", "name": "item", "description": "10.1016/j.gca.2016.09.013", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2016.09.013"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-01-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2017.09.027", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:36Z", "type": "Journal Article", "created": "2017-09-20", "title": "A history of violence: Insights into post-accretionary heating in carbonaceous chondrites from volatile element abundances, Zn isotopes and water contents", "description": "Open AccessCarbonaceous chondrites (CCs) may have been the carriers of water, volatile and moderately volatile elements to Earth. Investigating the abundances of these elements, their relative volatility, and isotopes of state-change tracer elements such as Zn, and linking these observations to water contents, provide vital information on the processes that govern the abundances and isotopic signatures of these species in CCs and other planetary bodies. Here we report Zn isotopic data for 28 CCs (20 CM, 6 CR, 1 C2-ung, and 1 CV3), as well as trace element data for Zn, In, Sn, Tl, Pb, and Bi in 16 samples (8 CM, 6 CR, 1 C2-ung, and 1 CV3), that display a range of elemental abundances from case-normative to intensely depleted. We use these data, water content data from literature and Zn isotopes to investigate volatile depletions and to discern between closed and open system heating. Trace element data have been used to construct relative volatility scales among the elements for the CM and CR chondrites. From least volatile to most, the scale in CM chondrites is Pb-Sn-Bi-In-Zn-Tl, and for CR chondrites it is Tl-Zn-Sn-Pb-Bi-In. These observations suggest that heated CM and CR chondrites underwent volatile loss under different conditions to one another and to that of the solar nebula, e.g. differing oxygen fugacities. Furthermore, the most water and volatile depleted samples are highly enriched in the heavy isotopes of Zn. Taken together, these lines of evidence strongly indicate that heated CM and CR chondrites incurred open system heating, stripping them of water and volatiles concomitantly, during post-accretionary shock impact(s).", "keywords": ["Earth and Planetary Astrophysics (astro-ph.EP)", "550", "[SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]", "500", "[SDU.ASTR.EP] Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]", "FOS: Physical sciences", "01 natural sciences", "Moderately volatile elements", "Volatity", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Heated meteorites", "Shock impacts", "Carbonaceous chondrites", "Astrophysics - Earth and Planetary Astrophysics", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2017.09.027"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2017.09.027", "name": "item", "description": "10.1016/j.gca.2017.09.027", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2017.09.027"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-01-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2019.06.035", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:36Z", "type": "Journal Article", "created": "2019-07-02", "title": "Experimentally determined Si isotope fractionation between zircon and quartz", "description": "Abstract   The silicon isotope composition of detrital quartz and zircon have the potential to inform us about secular changes to the silica cycle and weathering reactions on Earth. However, inferring source melt Si isotope composition from out-of-context minerals is hampered by the fact that, to-date, there is limited Si isotope equilibrium fractionation data for minerals. Here, we report experimental data to constrain Si isotope equilibrium fractionation between zircon and quartz, using two fundamentally different strategies, but with the same experimental design. First, zircon and quartz were hydrothermally synthesized from Zr(OH)4 and SiO2 at 1.5\u202fGPa and temperatures of 725, 800, and 900\u202f\u00b0C. The second experimental strategy utilized the three-isotope method; the starting materials consisted of natural zircon and isotopically-labelled SiO2. Three sets of hydrothermal time-series experiments were conducted at the same pressure and temperatures as the direct synthesis experiments. For all experiments, quartz and zircon were separated and 30Si/28Si and 29Si/28Si ratios were measured by solution multi-collector inductively coupled plasma mass spectrometry. The three-isotope method, which provides the best indicator of equilibrium fractionations, yields the following relationship:        \u0394   30   S  i   (  q  t  z  -  z  r  c  )   =   (  0.53  \u00b1  0.14  )   \u00d7    10   6   /    T   2       where \u039430Si(qtz-zrc) is the relative difference in 30Si/28Si between quartz and zircon in permil, T is temperature in K, and the error is 2\u202fs.e. This relationship can be used to calculate the fractionation between zircon and other phases, and to estimate the Si isotope composition of the melt from which a zircon crystallized. The results may be used to assess equilibrium-disequilibrium isotope fractionations between quartz and zircon and co-existing phases in igneous rocks. These data can also be applied to out-of-context zircon (and quartz) to estimate the isotope composition of the host rock. Zircons crystallizing from a melt derived from purely igneous sources \u2013 i.e., without the involvement of \u201cweathered\u201d material \u2013 are expected to display a \u03b430SiNBS-28 (permil deviation of the 30Si/28Si from the NBS-28 standard) range from \u22120.7 to \u22120.35\u2030. Deviations from this range indicate assimilation of non-igneous (i.e., sedimentary) material in the melt source.", "keywords": ["Zircon", "GE", "550", "NDAS", "Quartz", "Si isotopes", "7. Clean energy", "01 natural sciences", "Three-istope", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "Igneous", "Three-isotope", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Fractionation", "GE Environmental Sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2019.06.035"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2019.06.035", "name": "item", "description": "10.1016/j.gca.2019.06.035", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2019.06.035"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-09-01T00:00:00Z"}}, {"id": "10.1016/j.scib.2018.01.018", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:17:03Z", "type": "Journal Article", "created": "2018-01-31", "title": "Barium isotope cosmochemistry and geochemistry", "description": "While the isotopic variations of barium were reported for the first time fourty years ago, the number of studies on barium isotopes significantly increased only after 2010. Barium isotope anomalies in meteorites have been successfully used to provide constraints about the origin of presolar SiC grains. In carbonaceous chondrites Ba isotope anomalies are indicative of the heterogeneity of the early solar system, possibly resulting from of a later injection of material after the cooling of solar system. Barium isotope fractionation in the same carbonaceous chondrites suggests that a strong magnetic field was present in the innermost part of the early solar system. Barium mass-dependent isotope fractionation has also been detected throughout Earth surface materials. While igneous rocks show limited Ba isotopic variations, relatively large isotopic variations are observed amongst and within soils, rivers, and biological materials. Indeed, plants seem to fractionate Ba isotopes during Ba uptake from soil solutions. Therefore, Ba isotope signatures have the potential to provide clues on the biological cycling of Ba at the Earth surface. In seawater, Ba isotopic variations have been mapped out, and are mainly related to barite precipitation, which is in turn related to organic matter remineralization in the water column. This makes Ba isotopes a potentially powerful tool to reconstruct past ocean productivity, although constraints are still lacking regarding the inputs of dissolved Ba to the oceans by rivers or hydrothermalism.", "keywords": ["13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDU.OTHER] Sciences of the Universe [physics]/Other", "01 natural sciences", "[SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces", " environment", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Fr\u00e9d\u00e9ric Moynier, Fr\u00e9d\u00e9ric Moynier, Julien Bouchez, Quentin Charbonnier,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.scib.2018.01.018"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20Bulletin", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.scib.2018.01.018", "name": "item", "description": "10.1016/j.scib.2018.01.018", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.scib.2018.01.018"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-03-01T00:00:00Z"}}, {"id": "10.1016/j.soilbio.2004.08.025", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:17:12Z", "type": "Journal Article", "created": "2004-12-15", "title": "Long-Term Effects Of Metal-Containing Farmyard Manure And Sewage Sludge On Soil Organic Matter In A Fluvisol", "description": "Abstract   Our aim was to establish the long-term effects of repeated applications after 20\u00a0y of organic amendments (farmyard manure at 10\u00a0t\u00a0ha \u22121 \u00a0y \u22121 , and urban sewage sludge at two different rates, 10\u00a0t\u00a0ha \u22121 \u00a0y \u22121  and 100\u00a0t\u00a0ha \u22121  every 2\u00a0y) on the quality of a sandy and poorly buffered soil (Fluvisol, pH 6). Chemical characteristics and biodegradability of the labile organic matter, which is mainly derived from microbial biomass and biodegradation products of organic residues, were chosen as indicators for soil quality. The organic C content had reached a maximal value (30.6\u00a0g\u00a0C\u00a0kg \u22121  in the 100\u00a0t sludge-treated soil), i.e. about 2.5 times that in the control. Six years after the last application, the organic C content and the microbial biomass content remained higher in sludge-treated soils than in the control. In contrast, the proportion of labile organic matter was significantly lower in sludge-treated soils than in manure-treated and control soils. The labile organic matter of sludge extracts appeared less humified than that of manure-treated and control soils.", "keywords": ["2. Zero hunger", "Sandy soils", "04 agricultural and veterinary sciences", "[SDV.SA.SDS]Life Sciences [q-bio]/Agricultural sciences/Soil study", "15. Life on land", "630", "Soil quality", "6. Clean water", "12. Responsible consumption", "[SDV.EE] Life Sciences [q-bio]/Ecology", " environment", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDV.EE]Life Sciences [q-bio]/Ecology", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "11. Sustainability", "Farmyard manure", "Zn", "0401 agriculture", " forestry", " and fisheries", "Labile organic matter", "[SDV.SA.SDS] Life Sciences [q-bio]/Agricultural sciences/Soil study", "Sewage sludge", "environment", "Cu", "Pb"]}, "links": [{"href": "https://doi.org/10.1016/j.soilbio.2004.08.025"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Soil%20Biology%20and%20Biochemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.soilbio.2004.08.025", "name": "item", "description": "10.1016/j.soilbio.2004.08.025", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.soilbio.2004.08.025"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2005-04-01T00:00:00Z"}}, {"id": "10.1021/acs.est.9b03735", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:17:50Z", "type": "Journal Article", "created": "2019-11-11", "title": "Contribution of Peatland Permafrost to Dissolved Organic Matter along a Thaw Gradient in North Siberia", "description": "Permafrost peatlands are important carbon stocks currently experiencing rapid evolution after permafrost thaw. Following thaw, dissolved organic matter (DOM) is a potentially important pathway for the release of permafrost carbon. This study investigates the origin and composition of DOM across sites at different stages of thaw in a discontinuous permafrost area of North Siberia. We determine the optical properties, molecular composition, and stable isotopic (\u03b413C) and radiocarbon (14C) contents of DOM. Early stages of thaw are characterized by high DOC concentrations, high aromaticity, contribution of vegetation-derived DOM, and a high contribution of permafrost carbon. In contrast, in later stages, the microbial contribution to DOM increases, and only modern carbon is detected. This work links DOM composition with its radiocarbon content in permafrost peatlands. It shows that DOM originating from previously frozen permafrost peatlands is highly aromatic and previously processed. It highlights the variability of post-thaw carbon dynamics in boreal and arctic ecosystems.", "keywords": ["570", "550", "Arctic Regions", "Permafrost", "15. Life on land", "GEOF", "01 natural sciences", "Panoply", "Carbon", "Siberia", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Ecosystem", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.9b03735"}, {"href": "https://doi.org/10.1021/acs.est.9b03735"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.9b03735", "name": "item", "description": "10.1021/acs.est.9b03735", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.9b03735"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-11-11T00:00:00Z"}}, {"id": "10.1038/ngeo2882", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:18:10Z", "type": "Journal Article", "created": "2017-01-30", "title": "Historical carbon dioxide emissions caused by land-use changes are possibly larger than assumed", "description": "The terrestrial biosphere absorbs about 20% of fossil-fuel CO2 emissions. The overall magnitude of this sink is constrained by the difference between emissions, the rate of increase in atmospheric CO2 concentrations, and the ocean sink. However, the land sink is actually composed of two largely counteracting fluxes that are poorly quantified: fluxes from land-use change and CO2 uptake by terrestrial ecosystems. Dynamic global vegetation model simulations suggest that CO2 emissions from land-use change have been substantially underestimated because processes such as tree harvesting and land clearing from shifting cultivation have not been considered. As the overall terrestrial sink is constrained, a larger net flux as a result of land-use change implies that terrestrial uptake of CO2 is also larger, and that terrestrial ecosystems might have greater potential to sequester carbon in the future. Consequently, reforestation projects and efforts to avoid further deforestation could represent important mitigation pathways, with co-benefits for biodiversity. It is unclear whether a larger land carbon sink can be reconciled with our current understanding of terrestrial carbon cycling. Our possible underestimation of the historical residual terrestrial carbon sink adds further uncertainty to our capacity to predict the future of terrestrial carbon uptake and losses.", "keywords": ["[SDE] Environmental Sciences", "Earth sciences", "info:eu-repo/classification/ddc/550", "550", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "ddc:550", "13. Climate action", "[SDE]Environmental Sciences", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "910", "15. Life on land", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "http://www.nature.com/articles/ngeo2882.pdf"}, {"href": "https://doi.org/10.1038/ngeo2882"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Nature%20Geoscience", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1038/ngeo2882", "name": "item", "description": "10.1038/ngeo2882", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1038/ngeo2882"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-01-30T00:00:00Z"}}, {"id": "10.1038/s41467-021-22748-2", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:18:12Z", "type": "Journal Article", "created": "2021-05-05", "title": "Calcium isotope evidence for early Archaean carbonates and subduction of oceanic crust", "description": "Abstract<p>Continents are unique to Earth and played a role in coevolution of the atmosphere, hydrosphere, and biosphere. Debate exists, however, regarding continent formation and the onset of subduction-driven plate tectonics. We present Ca isotope and trace-element data from modern and ancient (4.0 to 2.8 Ga) granitoids and phase equilibrium models indicating that Ca isotope fractionations are dominantly controlled by geothermal gradients. The results require gradients of 500\uffe2\uff80\uff93750\uffe2\uff80\uff89\uffc2\uffb0C/GPa, as found in modern (hot) subduction-zones and consistent with the operation of subduction throughout the Archaean. Two granitoids from the Nuvvuagittuq Supracrustal Belt, Canada, however, cannot be explained through magmatic processes. Their isotopic signatures were likely inherited from carbonate sediments. These samples (&gt; 3.8 Ga) predate the oldest known carbonates preserved in the rock record and confirm that carbonate precipitation in Eoarchaean oceans provided an important sink for atmospheric CO2. Our results suggest that subduction-driven plate tectonic processes started prior to ~3.8 Ga.</p>", "keywords": ["Geochemistry", "13. Climate action", "Science", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Q", "14. Life underwater", "01 natural sciences", "Article", "Petrology", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://www.nature.com/articles/s41467-021-22748-2.pdf"}, {"href": "https://doi.org/10.1038/s41467-021-22748-2"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Nature%20Communications", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1038/s41467-021-22748-2", "name": "item", "description": "10.1038/s41467-021-22748-2", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1038/s41467-021-22748-2"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-05-05T00:00:00Z"}}, {"id": "10.1038/s41561-021-00714-3", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:18:15Z", "type": "Journal Article", "created": "2021-04-07", "title": "Co-variation of silicate, carbonate and sulfide weathering drives CO2 release with erosion", "description": "Abstract<p>Global climate is thought to be modulated by the supply of minerals to Earth\uffe2\uff80\uff99s surface. Whereas silicate weathering removes carbon dioxide (CO2) from the atmosphere, weathering of accessory carbonate and sulfide minerals is a geologically relevant source of CO2. Although these weathering pathways commonly operate side by side, we lack quantitative constraints on their co-variation across erosion rate gradients. Here we use stream-water chemistry across an erosion rate gradient of three orders of magnitude in shales and sandstones of southern Taiwan, and find that sulfide and carbonate weathering rates rise with increasing erosion, while silicate weathering rates remain steady. As a result, on timescales shorter than marine sulfide compensation (approximately 106\uffe2\uff80\uff93107 years), weathering in rapidly eroding terrain leads to net CO2 emission rates that are about twice as fast as CO2 sequestration rates in slow-eroding terrain. We propose that these weathering reactions are linked and that sulfuric acid generated from sulfide oxidation boosts carbonate solubility, whereas silicate weathering kinetics remain unaffected, possibly due to efficient buffering of the pH. We expect that these patterns are broadly applicable to many Cenozoic mountain ranges that expose marine metasediments.</p>", "keywords": ["[SDU] Sciences of the Universe [physics]", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "15. Life on land", "01 natural sciences", "333", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://www.nature.com/articles/s41561-021-00714-3.pdf"}, {"href": "https://doi.org/10.1038/s41561-021-00714-3"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Nature%20Geoscience", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1038/s41561-021-00714-3", "name": "item", "description": "10.1038/s41561-021-00714-3", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1038/s41561-021-00714-3"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-04-01T00:00:00Z"}}, {"id": "10.1038/s41561-019-0407-6", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:18:14Z", "type": "Journal Article", "created": "2019-08-26", "title": "An oceanic subduction origin for Archaean granitoids revealed by silicon isotopes", "description": "Modern oceanic crust is constantly produced at oceanic ridges and recycled back into the mantle at subduction zones via plate tectonics. An outstanding question in geology is whether the Earth started in a non-plate tectonic regime, and if it did, when the transition to the modern regime occurred. This is a complicated question to address because Archaean rocks lack modern equivalents to anchor interpretations. Here, we present a silicon isotopic study of 4.0\u20132.8-Gyr-old tonalite\u2013trondhjemite\u2013granodiorites, as well as Palaeozoic granites and modern adakites. We show that Archaean granitoids have heavier silicon isotopic compositions than granites and adakites, regardless of melting pressure. This is best explained if Archaean granitoids were formed by melting of subducted basaltic crust enriched in sedimentary silica through interaction with seawater. Before the appearance of silica-forming organisms 0.5\u20130.6\u2009billion years ago, the oceans were close to silicon saturation, which led to extensive precipitation of cherts on the seafloor. This is in contrast to modern oceans, where silica biomineralization maintains dissolved silicon at low concentration. The unique heavy silicon isotope signature of cherts has been transferred to Archaean granitoids during an oceanic subduction process, which was probably responsible for the formation of felsic rocks on Archaean emerged lands. Archaean granitic rocks formed by melting of silica-enriched subducted basaltic crust through interaction with seawater, according to heavy silicon isotopes measured in Archaean samples.", "keywords": ["Geochemistry", "13. Climate action", "Precambrian geology", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "14. Life underwater", "Sedimentology", "Geodynamics", "01 natural sciences", "Petrology", "0105 earth and related environmental sciences"]}, "links": [{"href": "http://www.nature.com/articles/s41561-019-0407-6.pdf"}, {"href": "https://doi.org/10.1038/s41561-019-0407-6"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Nature%20Geoscience", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1038/s41561-019-0407-6", "name": "item", "description": "10.1038/s41561-019-0407-6", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1038/s41561-019-0407-6"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-08-26T00:00:00Z"}}, {"id": "10.1073/pnas.1807263115", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:18:38Z", "type": "Journal Article", "created": "2018-08-06", "title": "Volatile element evolution of chondrules through time", "description": "Significance<p>We present time-anchored elemental abundance data for some of the Solar System\uffe2\uff80\uff99s first solids by tracking Pb\uffe2\uff88\uff92Pb dated chondrule compositions. Volatile element contents generally rise, while redox conditions (based on chondrule Mn/Na ratios) decline beginning \uffe2\uff88\uffbc1 My after Solar System formation (\uffe2\uff88\uffbc4,567 Ma). These results reflect a continued rise in volatile element contents and their fugacities during chondrule recycling, and early water influx to the inner Solar System followed by its express removal. These observations support the early formation of Mars under oxidizing condition and Earth\uffe2\uff80\uff99s protracted growth under more reducing conditions in an environment increasing in volatile contents with time, while also calling into question the coupling of water and volatile elements during Solar System evolution.</p>", "keywords": ["550", "pebble accretion", "[SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]", "[SDU.ASTR.EP] Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]", "planetary formation", "01 natural sciences", "meteorites", "12. Responsible consumption", "Solar System evolution", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "cosmochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Physical Sciences", "10. No inequality", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pnas.org/doi/pdf/10.1073/pnas.1807263115"}, {"href": "https://researchonline.jcu.edu.au/62756/1/62756.pdf"}, {"href": "https://doi.org/10.1073/pnas.1807263115"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Proceedings%20of%20the%20National%20Academy%20of%20Sciences", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1073/pnas.1807263115", "name": "item", "description": "10.1073/pnas.1807263115", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1073/pnas.1807263115"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-08-06T00:00:00Z"}}, {"id": "10.1073/pnas.1809164116", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:18:38Z", "type": "Journal Article", "created": "2019-01-04", "title": "Titanium isotopes as a tracer for the plume or island arc affinity of felsic rocks", "description": "Significance           <p>             The debate on the onset of plate tectonics in the Earth\uffe2\uff80\uff99s history has partially originated from the controversial criteria of using felsic crust to trace plate tectonics in the past. Here, we demonstrate how Ti isotope ratios can be used as a proxy for the affinity of felsic rocks to plume or island arc settings. Our study shows that, contrary to what was previously assumed, Ti isotopes cannot serve as a direct evidence for plate tectonics from 3.5 billion years ago, and must be combined with other information on SiO             2             contents of crustal rocks to be reliable.           </p>", "keywords": ["Titanium isotopes", "Plume", "Magma differentiation", "magma differentiation", "GE", "550", "plume", "Plate tectonics", "[SDU.STU.TE] Sciences of the Universe [physics]/Earth Sciences/Tectonics", "DAS", "island arc", "7. Clean energy", "01 natural sciences", "13. Climate action", "plate tectonics", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Island arc", "titanium isotopes", "GE Environmental Sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pnas.org/doi/pdf/10.1073/pnas.1809164116"}, {"href": "https://doi.org/10.1073/pnas.1809164116"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Proceedings%20of%20the%20National%20Academy%20of%20Sciences", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1073/pnas.1809164116", "name": "item", "description": "10.1073/pnas.1809164116", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1073/pnas.1809164116"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-01-03T00:00:00Z"}}, {"id": "10.1088/1748-9326/abe25c", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:18:55Z", "type": "Journal Article", "created": "2021-02-03", "title": "Dominant contribution of nitrogen compounds in precipitation chemistry in the Lake Victoria catchment (East Africa)", "description": "Abstract                <p>This work provides a complete chemical characterization of rains collected in the tropical rural site of Mbita (Kenya) on the shores of Lake Victoria (annual rainfall 1259.3 mm). We present a wet nitrogen deposition budget including inorganic and organic dissolved nitrogen in relation with atmospheric sources of gases and particles, precipitation rate and air mass transport. A unique 2 yr monitoring data set (2017\uffe2\uff80\uff932019), providing 183 rain samples was collected and analyzed according to international standards (WMO/GAW). Considering that precipitation represents the largest contributor of water to the Lake Victoria (80%), this study gives new insights in the seasonality of nutrients wet deposition (WD) inputs in the unique natural resource represented by Lake Victoria and its catchment. Four main contributions to the chemical composition of precipitation, were identified: (a) a 28% terrigenous contribution related to crustal and biomass sources, (b) a 14% marine contribution related to Indian ocean air masses intrusion, (c) a 15% organic contribution due to volatile organic carbon emissions from biomass burning and vegetation and (d) a predominant nitrogenous contribution of 39% due to livestock and fertilizers, biomass burning and neighboring agricultural fires. Ammonium and nitrate volume weighed mean concentrations are 36.75 and 8.88 \uffce\uffbceq l\uffe2\uff88\uff921, respectively. Rain in Mbita is alkaline (pH = 5.8) highlighting neutralization by heterogeneous chemistry. Total nitrogen WD is 8.54 kgN ha\uffe2\uff88\uff921 yr\uffe2\uff88\uff921, 58\uffe2\uff80\uff89760 tN yr\uffe2\uff88\uff921 for the entire lake, with 26% attributed to dissolved organic nitrogen. A total atmospheric deposition of 15 kgN ha\uffe2\uff88\uff921 yr\uffe2\uff88\uff921 is estimated taking into account dry deposition estimate from literature, showing that the Lake Victoria ecosystem is exposed to eutrophication. An extensive and regular monitoring of wet and dry nitrogen deposition is highly recommended both in-shore and off-shore to help improving the efficiency of nitrogen use in agricultural areas and reduce nitrogen losses around Lake Victoria.</p>", "keywords": ["[SDE] Environmental Sciences", "Science", "Physics", "QC1-999", "Q", "15. Life on land", "Kenya", "Environmental technology. Sanitary engineering", "01 natural sciences", "6. Clean water", "Environmental sciences", "nitrogen wet deposition budget", "precipitation chemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "wet deposition", "GE1-350", "14. Life underwater", "TD1-1066", "Lake Victoria basin", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1088/1748-9326/abe25c"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Research%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1088/1748-9326/abe25c", "name": "item", "description": "10.1088/1748-9326/abe25c", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1088/1748-9326/abe25c"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-04-01T00:00:00Z"}}, {"id": "10.1126/sciadv.aba3269", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:19:53Z", "type": "Journal Article", "created": "2020-06-03", "title": "Calcium isotopic evidence for the mantle sources of carbonatites", "description": "<p>Melting of recycled carbonate in the mantle explains the origin of carbonatitic magmas.</p>", "keywords": ["SILICATE ROCKS", "550", "CA CYCLE", "ORIGIN", "FRACTIONATION", "500", "NOBLE-GAS", "OLDOINYO-LENGAI", "01 natural sciences", "EVOLUTION", "12. Responsible consumption", "SUBDUCTION", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "CLINOPYROXENE", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "SERPENTINITES", "14. Life underwater", "Research Articles", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1126/sciadv.aba3269"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20Advances", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1126/sciadv.aba3269", "name": "item", "description": "10.1126/sciadv.aba3269", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1126/sciadv.aba3269"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-06-05T00:00:00Z"}}, {"id": "10.1111/maps.12922", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:19:47Z", "type": "Journal Article", "created": "2017-07-27", "title": "Implications for behavior of volatile elements during impacts-Zinc and copper systematics in sediments from the Ries impact structure and central European tektites", "description": "Abstract<p>Moldavites are tektites genetically related to the Ries impact structure, located in Central Europe, but the source materials and the processes related to the chemical fractionation of moldavites are not fully constrained. To further understand moldavite genesis, the Cu and Zn abundances and isotope compositions were measured in a suite of tektites from four different substrewn fields (South Bohemia, Moravia, Cheb Basin, Lusatia) and chemically diverse sediments from the surroundings of the Ries impact structure. Moldavites are slightly depleted in Zn (~10\uffe2\uff80\uff9320%) and distinctly depleted in Cu (&gt;90%) relative to supposed sedimentary precursors. Moreover, the moldavites show a wide range in \uffce\uffb466Zn values between 1.7 and 3.7\uffe2\uff80\uffb0 (relative to JMC 3\uffe2\uff80\uff900749 Lyon) and \uffce\uffb465Cu values between 1.6 and 12.5\uffe2\uff80\uffb0 (relative to NIST SRM 976) and are thus enriched in heavy isotopes relative to their possible parent sedimentary sources (\uffce\uffb466Zn\uffc2\uffa0=\uffc2\uffa0\uffe2\uff88\uff920.07 to +0.64\uffe2\uff80\uffb0; \uffce\uffb465Cu\uffc2\uffa0=\uffc2\uffa0\uffe2\uff88\uff920.4 to +0.7\uffe2\uff80\uffb0). In particular, the Cheb Basin moldavites show some of the highest \uffce\uffb465Cu values (up to 12.5\uffe2\uff80\uffb0) ever observed in natural samples. The relative magnitude of isotope fractionation for Cu and Zn seen here is opposite to oxygen\uffe2\uff80\uff90poor environments such as the Moon where Zn is significantly more isotopically fractionated than Cu. One possibility is that monovalent Cu diffuses faster than divalent Zn in the reduced melt and diffusion will not affect the extent of Zn isotope fractionation. These observations imply that the capability of forming a redox environment may aid in volatilizing some elements, accompanied by isotope fractionation, during the impact process. The greater extent of elemental depletion, coupled with isotope fractionation of more refractory Cu relative to Zn, may also hinge on the presence of carbonyl species of transition metals and electromagnetic charge, which could exist in the impact\uffe2\uff80\uff90induced high\uffe2\uff80\uff90velocity jet of vapor and melts.</p>", "keywords": ["550", "GRANITES", "NDAS", "Ries crater", "01 natural sciences", "Tektites", "ZINC", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "QE", "14. Life underwater", "STABLE-ISOTOPE GEOCHEMISTRY", "QC", "0105 earth and related environmental sciences", "Copper isotopes", "ORIGIN", "AUSTRALASIAN TEKTITES", "FRACTIONATION", "IRON", "500", "LACHLAN FOLD BELT", "Ries area sediments", "QE Geology", "Impact", "QC Physics", "13. Climate action", "Volatile loss", "ZN", "Isotope fractionation", "Zinc isotopes", "CU"]}, "links": [{"href": "http://onlinelibrary.wiley.com/wol1/doi/10.1111/maps.12922/fullpdf"}, {"href": "https://doi.org/10.1111/maps.12922"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Meteoritics%20%26amp%3B%20Planetary%20Science", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1111/maps.12922", "name": "item", "description": "10.1111/maps.12922", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1111/maps.12922"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-07-27T00:00:00Z"}}, {"id": "10.5194/bg-2020-327", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:22:46Z", "type": "Journal Article", "created": "2021-02-17", "title": "Evaluating stream CO 2 outgassing via Drifting and Anchored flux chambers in a controlled flume experiment", "description": "<p>Abstract. Carbon dioxide (CO2) emissions from running waters represent a key component of the global carbon cycle. However, quantifying CO2 fluxes across air\uffe2\uff80\uff93water boundaries remains challenging due to practical difficulties in the estimation of reach-scale standardized gas exchange velocities (k600) and water equilibrium concentrations. Whereas craft-made floating chambers supplied by internal CO2 sensors represent a promising technique to estimate CO2 fluxes from rivers, the existing literature lacks rigorous comparisons among differently designed chambers and deployment techniques. Moreover, as of now the uncertainty of k600 estimates from chamber data has not been evaluated. Here, these issues were addressed by analysing the results of a flume experiment carried out in the Summer of 2019 in the Lunzer:::Rinnen \uffe2\uff80\uff93 Experimental Facility (Austria). During the experiment, 100 runs were performed using two different chamber designs (namely, a standard chamber and a flexible foil chamber with an external floating system and a flexible sealing) and two different deployment modes (drifting and anchored). The runs were performed using various combinations of discharge and channel slope, leading to variable turbulent kinetic energy dissipation rates (1.5\uffc3\uff9710-3&lt;\uffce\uffb5&lt;1\uffc3\uff9710-1\uffe2\uff80\uff89m2\uffe2\uff80\uff89s\uffe2\uff88\uff923). Estimates of gas exchange velocities were in line with the existing literature (4&lt;k600&lt;32\uffe2\uff80\uff89m2\uffe2\uff80\uff89s\uffe2\uff88\uff923), with a general increase in k600 for larger turbulent kinetic energy dissipation rates. The flexible foil chamber gave consistent k600 patterns in response to changes in the slope and/or the flow rate. Moreover, acoustic Doppler velocimeter measurements indicated a limited increase in the turbulence induced by the flexible foil chamber on the flow field (22\uffe2\uff80\uff89% increase in \uffce\uffb5, leading to a theoretical 5\uffe2\uff80\uff89% increase in k600). The uncertainty in the estimate of gas exchange velocities was then estimated using a generalized likelihood uncertainty estimation (GLUE) procedure. Overall, uncertainty in k600 was moderate to high, with enhanced uncertainty in high-energy set-ups. For the anchored mode, the standard deviations of k600 were between 1.6 and 8.2\uffe2\uff80\uff89m\uffe2\uff80\uff89d\uffe2\uff88\uff921, whereas significantly higher values were obtained in drifting mode. Interestingly, for the standard chamber the uncertainty was larger (+\uffe2\uff80\uff8920\uffe2\uff80\uff89%) as compared to the flexible foil chamber. Our study suggests that a flexible foil design and the anchored deployment might be useful techniques to enhance the robustness and the accuracy of CO2 measurements in low-order streams. Furthermore, the study demonstrates the value of analytical and numerical tools in the identification of accurate estimations for gas exchange velocities. These findings have important implications for improving estimates of greenhouse gas emissions and reaeration rates in running waters.                     </p>", "keywords": ["0106 biological sciences", "QE1-996.5", "550", "660", "Ecology", "Geology", "7. Clean energy", "01 natural sciences", "6. Clean water", "Life", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "QH501-531", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "11. Sustainability", "[SDU.STU.HY] Sciences of the Universe [physics]/Earth Sciences/Hydrology", "QH540-549.5", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pub.epsilon.slu.se/22849/1/vingiani_f_et_al_210329.pdf"}, {"href": "https://doi.org/10.5194/bg-2020-327"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Biogeosciences", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.5194/bg-2020-327", "name": "item", "description": "10.5194/bg-2020-327", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.5194/bg-2020-327"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-09-23T00:00:00Z"}}, {"id": "10.3389/fmicb.2016.01247", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:21:41Z", "type": "Journal Article", "created": "2016-08-08", "title": "Soil Fungal:Bacterial Ratios Are Linked to Altered Carbon Cycling", "description": "Despite several lines of observational evidence, there is a lack of consensus on whether higher fungal:bacterial (F:B) ratios directly cause higher soil carbon (C) storage. We employed RNA sequencing, protein profiling and isotope tracer techniques to evaluate whether differing F:B ratios are associated with differences in C storage. A mesocosm (13)C labeled foliar litter decomposition experiment was performed in two soils that were similar in their physico-chemical properties but differed in microbial community structure, specifically their F:B ratio (determined by PLFA analyses, RNA sequencing and protein profiling; all three corroborating each other). Following litter addition, we observed a consistent increase in abundance of fungal phyla; and greater increases in the fungal dominated soil; implicating the role of fungi in litter decomposition. Litter derived (13)C in respired CO2 was consistently lower, and residual (13)C in bulk SOM was higher in high F:B soil demonstrating greater C storage potential in the F:B dominated soil. We conclude that in this soil system, the increased abundance of fungi in both soils and the altered C cycling patterns in the F:B dominated soils highlight the significant role of fungi in litter decomposition and indicate that F:B ratios are linked to higher C storage potential.", "keywords": ["Microbiology (medical)", "Proteomics", "0301 basic medicine", "environment/Bioclimatology", "Supplementary Data", "[SDE.MCG]Environmental Sciences/Global Changes", "stable isotopes", "litter decomposition", "Microbiology", "03 medical and health sciences", "proteomics", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDV.EE]Life Sciences [q-bio]/Ecology", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "soil carbon", "European Commission", "bacteria", "Stable isotopes", "2. Zero hunger", "655240", "0303 health sciences", "Bacteria", "Litter decomposition", "Fungi", "RNA sequencing", "QR Microbiology", "15. Life on land", "Soil carbon", "[SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces", " environment", "QR1-502", "QR", "[SDE.BE] Environmental Sciences/Biodiversity and Ecology", "[SDE.MCG] Environmental Sciences/Global Changes", "[SDV.EE] Life Sciences [q-bio]/Ecology", " environment", "[SDV.EE.BIO] Life Sciences [q-bio]/Ecology", " environment/Bioclimatology", "[SDV.EE.BIO]Life Sciences [q-bio]/Ecology", "fungi", "[SDE.BE]Environmental Sciences/Biodiversity and Ecology", "[SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces", "environment"]}, "links": [{"href": "https://doi.org/10.3389/fmicb.2016.01247"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Frontiers%20in%20Microbiology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.3389/fmicb.2016.01247", "name": "item", "description": "10.3389/fmicb.2016.01247", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.3389/fmicb.2016.01247"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-08-09T00:00:00Z"}}, {"id": "10.5194/bg-15-3625-2018", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:22:44Z", "type": "Journal Article", "created": "2018-06-18", "title": "Reviews and syntheses: Carbonyl sulfide as a\u00a0multi-scale tracer for carbon and water cycles", "description": "<p>Abstract. For the past decade, observations of carbonyl sulfide (OCS or COS) have been investigated as a\uffc2\uffa0proxy for carbon uptake by plants. OCS is destroyed by enzymes that interact with CO2 during photosynthesis, namely carbonic anhydrase (CA) and RuBisCO, where CA is the more important one. The majority of sources of OCS to the atmosphere are geographically separated from this large plant sink, whereas the sources and sinks of CO2 are co-located in ecosystems. The drawdown of OCS can therefore be related to the uptake of CO2 without the added complication of co-located emissions comparable in magnitude. Here we review the state of our understanding of the global OCS cycle and its applications to ecosystem carbon cycle science. OCS uptake is correlated well to plant carbon uptake, especially at the regional scale. OCS can be used in conjunction with other independent measures of ecosystem function, like solar-induced fluorescence and carbon and water isotope studies. More work needs to be done to generate global coverage for OCS observations and to link this powerful atmospheric tracer to systems where fundamental questions concerning the carbon and water cycle remain.                     </p>", "keywords": ["570", "550", "GLOBAL BIOGEOCHEMICAL CYCLE", "isotope du carbone", "01 natural sciences", "[PHYS.PHYS.PHYS-AO-PH] Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph]", "ANTHROPOGENIC EMISSIONS INVENTORY", "Life", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "QH501-531", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Meteorology & Atmospheric Sciences", "REDUCED SULFUR GASES", "OH-INITIATED OXIDATION", "photosynth\u00e8se", "anhydrase carbonique", "QUANTUM CASCADE LASER", "SOUTHERN GREAT-PLAINS", "ORGANIC VOLATILE SULFUR", "QH540-549.5", "0105 earth and related environmental sciences", "[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph]", "QE1-996.5", "Ecology", "FT-IR PRODUCT", "GROSS PRIMARY PRODUCTION", "Geology", "Biological Sciences", "15. Life on land", "Climate Action", "Environmental sciences", "atmosph\u00e8re", "absorption racinaire", "sulfure de carbonyle", "13. Climate action", "NORTHEAST ATLANTIC-OCEAN", "Earth Sciences", "Environmental Sciences"]}, "links": [{"href": "http://oro.open.ac.uk/56080/1/Whelan%20etal%20%2718%20bgs_COS%20review.pdf"}, {"href": "http://oceanrep.geomar.de/43577/1/bg-15-3625-2018.pdf"}, {"href": "https://bg.copernicus.org/articles/15/3625/2018/bg-15-3625-2018.pdf"}, {"href": "https://escholarship.org/content/qt5ft9v0bw/qt5ft9v0bw.pdf"}, {"href": "https://escholarship.org/content/qt7b184769/qt7b184769.pdf"}, {"href": "https://doi.org/10.5194/bg-15-3625-2018"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Biogeosciences", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.5194/bg-15-3625-2018", "name": "item", "description": "10.5194/bg-15-3625-2018", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.5194/bg-15-3625-2018"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-10-24T00:00:00Z"}}, {"id": "10.5194/gmd-12-3503-2019", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:22:55Z", "type": "Journal Article", "created": "2019-08-12", "title": "ORCHIDEE MICT-LEAK (r5459), a global model for the production, transport, and transformation of dissolved organic carbon from Arctic permafrost regions \u2013 Part 1: Rationale, model description, and simulation protocol", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>Abstract. Few Earth system models adequately represent the unique permafrost soil biogeochemistry and its respective processes; this significantly contributes to uncertainty in estimating their responses, and that of the planet at large, to warming. Likewise, the riverine component of what is known as the \u201cboundless carbon cycle\u201d is seldom recognised in Earth system modelling. The hydrological mobilisation of organic material from a \u223c1330\u20131580\u2009PgC carbon stock to the river network results in either sedimentary settling or atmospheric \u201cevasion\u201d, processes widely expected to increase with amplified Arctic climate warming. Here, the production, transport, and atmospheric release of dissolved organic carbon (DOC) from high-latitude permafrost soils into inland waters and the ocean are explicitly represented for the first time in the land surface component (ORCHIDEE) of a CMIP6 global climate model (Institut Pierre Simon Laplace \u2013 IPSL). The model, ORCHIDEE MICT-LEAK, which represents the merger of previously described ORCHIDEE versions MICT and LEAK, mechanistically represents (a)\u00a0vegetation and soil physical processes for high-latitude snow, ice, and soil phenomena and (b)\u00a0the cycling of DOC and CO2, including atmospheric evasion, along the terrestrial\u2013aquatic continuum from soils through the river network to the coast at 0.5 to 2\u2218 resolution. This paper, the first in a two-part study, presents the rationale for including these processes in a high-latitude-specific land surface model, then describes the model with a focus on novel process implementations, followed by a summary of the model configuration and simulation protocol. The results of these simulation runs, conducted for the Lena River basin, are evaluated against observational data in the second part of this study.                     </p></article>", "keywords": ["QE1-996.5", "550", "Geology", "15. Life on land", "551", "01 natural sciences", "6. Clean water", "Sciences de la terre et du cosmos", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDU.STU.GL]Sciences of the Universe [physics]/Earth Sciences/Glaciology", "Sciences pharmaceutiques", "[SDU.STU.GL] Sciences of the Universe [physics]/Earth Sciences/Glaciology", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://dipot.ulb.ac.be/dspace/bitstream/2013/292778/1/doi_276405.pdf"}, {"href": "https://doi.org/10.5194/gmd-12-3503-2019"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geoscientific%20Model%20Development", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.5194/gmd-12-3503-2019", "name": "item", "description": "10.5194/gmd-12-3503-2019", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.5194/gmd-12-3503-2019"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-03-25T00:00:00Z"}}, {"id": "10.7185/geochemlet.1506", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:25:43Z", "type": "Journal Article", "created": "2015-06-04", "title": "Copper isotope evidence for large-scale sulphide fractionation during Earth\u2019s differentiation", "description": "The differentiation of Earth into a metallic core and silicate mantle left its signature on the chemical and isotopic composition of the bulk silicate Earth (BSE). This is seen in the depletion of siderophile (metal-loving) relative to lithophile (rock-loving) elements in Earth\u2019s mantle as well as the silicon isotope offset between primitive meteorites (i.e. bulk Earth) and BSE, which is generally interpreted as a proof that Si is present in Earth\u2019s core. Another putative light element in Earth\u2019s core is sulphur; however, estimates of core S abundance vary significantly and, due to its volatile nature, no unequivocal S isotopic signature for core fractionation has thus far been detected. Here we present new high precision isotopic data for Cu, a chalcophile (sulphur-loving) element, which shows that Earth\u2019s mantle is isotopically fractionated relative to bulk Earth. Results from high pressure equilibration experiments suggest that the sense of Cu isotopic fractionation between BSE and bulk Earth requires that a sulphide-rich liquid segregated from Earth\u2019s mantle during differentiation, which likely entered the core. Such an early-stage removal of a sulphide-rich phase from the mantle presents a possible solution to the long-standing 1st terrestrial lead paradox.", "keywords": ["S in the core", "Terrestrial Pb paradox", "GB", "550", "NDAS", "[SDU.ASTR.EP] Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]", "551", "01 natural sciences", "Planetary differentiation", "13. Climate action", "Core formation", "GB Physical geography", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Cu isotopes", "BDC", "Terrestrial Pb paradox.", "R2C", "0105 earth and related environmental sciences"]}, "links": [{"href": "http://dro.dur.ac.uk/15741/1/15741.pdf"}, {"href": "https://doi.org/10.7185/geochemlet.1506"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochemical%20Perspectives%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.7185/geochemlet.1506", "name": "item", "description": "10.7185/geochemlet.1506", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.7185/geochemlet.1506"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2015-01-01T00:00:00Z"}}, {"id": "10.7185/geochemlet.1831", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:25:43Z", "type": "Journal Article", "created": "2018-12-13", "title": "Bridging the depleted MORB mantle and the continental crust using titanium isotopes", "description": "The mechanisms driving the chemical complementarity between depleted MORB mantle (DMM) and continental crust (with an average 'andesitic' composition) remain unclear. By investigating Archean komatiites, and modern enriched (E) and normal (N) MORB samples, we demonstrate that partial melting of the mantle does not fractionate Ti isotopes, whereas intracrustal differentiation causes significant Ti isotopic fractionation between melts and minerals, specifically Fe-Ti oxides. Thus, Ti isotope ratios are tracers of these two magmatic regimes. N-MORB and late Archean (2.9-2.7 Ga) komatiites are depleted in the heavier Ti isotopes compared to E-MORB and middle Archean (3.5-3.3 Ga) komatiites. We show that the depletion in the heavier Ti isotopes of the DMM is due to mantle recycling of the isotopically light residues from the generation of felsic continental crust over 3.5-2.7 Ga. This process must have reached a steady state by \u2248 2.5 Ga, based on the uniform Ti isotopic composition of contemporary N-MORBs and late Archean komatiites. This change is likely due to a decrease in the mantle potential temperature related to the emergence of plate tectonics.", "keywords": ["13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "15. Life on land", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.7185/geochemlet.1831"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochemical%20Perspectives%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.7185/geochemlet.1831", "name": "item", "description": "10.7185/geochemlet.1831", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.7185/geochemlet.1831"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-12-01T00:00:00Z"}}, {"id": "10.7185/geochemlet.2014", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:25:43Z", "type": "Journal Article", "created": "2020-04-16", "title": "Moderately volatile element behaviour at high temperature determined from nuclear detonation", "description": "Open AccessThe first nuclear detonation, at the Trinity test site, is an analogue for high temperature volatile loss during planet formation processes. We report Cu isotope and abundance data, comparing them with Zn and K isotopes in trinitite glasses sampled with distance from the detonation centre. Copper concentrations drop, and isotopic compositions become ~0.3 \u2030 higher with proximity to the detonation. Relative sensitivity to high temperature evaporative isotopic fractionation processes occur in the order: Zn > Cu >> K. Lower volatility of K relative to Cu and Zn results from its low activity coefficient in silicate melts. Lunar mare basalt and some tektite Cu, Zn and K isotope compositions can be modelled using empirical fractionation factors (\u03b1) derived from trinitite. Combined with isotopic variations measured in mare basalts, the results support volatile loss during a magma ocean phase for the Moon.", "keywords": ["13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.7185/geochemlet.2014"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochemical%20Perspectives%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.7185/geochemlet.2014", "name": "item", "description": "10.7185/geochemlet.2014", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.7185/geochemlet.2014"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-04-01T00:00:00Z"}}, {"id": "2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/292778", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:26:54Z", "type": "Journal Article", "created": "2019-08-12", "title": "ORCHIDEE MICT-LEAK (r5459), a global model for the production, transport, and transformation of dissolved organic carbon from Arctic permafrost regions \u2013 Part 1: Rationale, model description, and simulation protocol", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>Abstract. Few Earth system models adequately represent the unique permafrost soil biogeochemistry and its respective processes; this significantly contributes to uncertainty in estimating their responses, and that of the planet at large, to warming. Likewise, the riverine component of what is known as the \u201cboundless carbon cycle\u201d is seldom recognised in Earth system modelling. The hydrological mobilisation of organic material from a \u223c1330\u20131580\u2009PgC carbon stock to the river network results in either sedimentary settling or atmospheric \u201cevasion\u201d, processes widely expected to increase with amplified Arctic climate warming. Here, the production, transport, and atmospheric release of dissolved organic carbon (DOC) from high-latitude permafrost soils into inland waters and the ocean are explicitly represented for the first time in the land surface component (ORCHIDEE) of a CMIP6 global climate model (Institut Pierre Simon Laplace \u2013 IPSL). The model, ORCHIDEE MICT-LEAK, which represents the merger of previously described ORCHIDEE versions MICT and LEAK, mechanistically represents (a)\u00a0vegetation and soil physical processes for high-latitude snow, ice, and soil phenomena and (b)\u00a0the cycling of DOC and CO2, including atmospheric evasion, along the terrestrial\u2013aquatic continuum from soils through the river network to the coast at 0.5 to 2\u2218 resolution. This paper, the first in a two-part study, presents the rationale for including these processes in a high-latitude-specific land surface model, then describes the model with a focus on novel process implementations, followed by a summary of the model configuration and simulation protocol. The results of these simulation runs, conducted for the Lena River basin, are evaluated against observational data in the second part of this study.</p></article>", "keywords": ["QE1-996.5", "550", "Geology", "15. Life on land", "551", "01 natural sciences", "6. Clean water", "Sciences de la terre et du cosmos", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDU.STU.GL]Sciences of the Universe [physics]/Earth Sciences/Glaciology", "Sciences pharmaceutiques", "[SDU.STU.GL] Sciences of the Universe [physics]/Earth Sciences/Glaciology", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://dipot.ulb.ac.be/dspace/bitstream/2013/292778/1/doi_276405.pdf"}, {"href": "https://doi.org/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/292778"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geoscientific%20Model%20Development", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/292778", "name": "item", "description": "2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/292778", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/292778"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-03-25T00:00:00Z"}}, {"id": "2078.1/246033", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:26:55Z", "type": "Journal Article", "created": "2021-04-27", "title": "Imprint of chemical weathering and hydrothermalism on the Ge/Si ratio and Si isotope composition of rivers in a volcanic tropical island, Basse-Terre, Guadeloupe (French West Indies)", "description": "Abstract   A significant portion of the disproportionally high chemical weathering flux in volcanic island arcs may originate from hydrothermal fluid-rock interaction, thereby compromising the accurate estimate of atmospheric CO2 consumption rates. The objective of this study is to evaluate how the riverine Ge/Si ratio and Si isotopes, two well-established tracers of weathering, respond to hydrothermal inputs. The work took place in Basse-Terre, Guadeloupe, a tropical volcanic island with a dense river network, high chemical weathering fluxes and various hydrothermal surface manifestations. We characterized the Ge/Si ratio and \u03b430Si of 15 thermal springs, nine non-impacted (NI) rivers and 13 hydrothermally-impacted (HI) rivers. The soil solution from a highly weathered soil profile (Ferralsol) and a clayey-rock corresponding to the material exposed in an extinct hydrothermal system were also measured. A new purification method was successfully developed in order to allow the reliable measurement of Si isotopes in SO42\u2212- and Cl\u2212-rich thermal spring and HI river waters by mass spectrometry. Basse-Terre's thermal springs have variable Ge/Si ratios (0.05\u201321.03\u00a0\u03bcmol.mol\u22121) and \u03b430Si (0.71\u20131.50\u2030), but with no apparent relationship to the water compositional type. The Ge/Si ratio (0.15\u20132.57\u00a0\u03bcmol.mol\u22121) and Si isotope composition (0.26\u20131.21\u2030) values of the NI rivers reveal differences in the watersheds' weathering degree. Dissolution of Ge- and 28Si-rich secondary minerals explains the high Ge/Si and isotopically light composition of the northern NI rivers draining strongly weathered terranes. The Ge/Si ratio and \u03b430Si values measured for the NI and HI rivers overlap, implying that they cannot be used to diagnose hydrothermal contributions to river basins unambiguously. However, when combined with the Cl\u2212 and SO42\u2212 concentrations, the analysis of Ge and Si in the HI rivers suggests that water seeping through an extinct hydrothermal system produces SO4-rich drainages with distinctively lower Ge/Si ratios than those inferred for watersheds receiving thermal spring discharges associated with an active hydrothermal system. Overall, our results provide new constraints for applying and interpreting Ge/Si and Si isotope measurements to study weathering in volcanic environments.", "keywords": ["[SDE] Environmental Sciences", "Volcanic hydrothermal system", "Chemical weathering", "River geochemistry", "Si isotope", "Ge/Si ratio", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Guadeloupe", "01 natural sciences", "6. Clean water", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/2078.1/246033"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2078.1/246033", "name": "item", "description": "2078.1/246033", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2078.1/246033"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-09-01T00:00:00Z"}}, {"id": "21.11116/0000-0005-7E8F-E", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:26:57Z", "type": "Journal Article", "created": "2019-11-11", "title": "Contribution of Peatland Permafrost to Dissolved Organic Matter along a Thaw Gradient in North Siberia", "description": "Permafrost peatlands are important carbon stocks currently experiencing rapid evolution after permafrost thaw. Following thaw, dissolved organic matter (DOM) is a potentially important pathway for the release of permafrost carbon. This study investigates the origin and composition of DOM across sites at different stages of thaw in a discontinuous permafrost area of North Siberia. We determine the optical properties, molecular composition, and stable isotopic (\u03b413C) and radiocarbon (14C) contents of DOM. Early stages of thaw are characterized by high DOC concentrations, high aromaticity, contribution of vegetation-derived DOM, and a high contribution of permafrost carbon. In contrast, in later stages, the microbial contribution to DOM increases, and only modern carbon is detected. This work links DOM composition with its radiocarbon content in permafrost peatlands. It shows that DOM originating from previously frozen permafrost peatlands is highly aromatic and previously processed. It highlights the variability of post-thaw carbon dynamics in boreal and arctic ecosystems.", "keywords": ["570", "550", "Arctic Regions", "Permafrost", "15. Life on land", "GEOF", "01 natural sciences", "Panoply", "Carbon", "Siberia", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Ecosystem", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.9b03735"}, {"href": "https://doi.org/21.11116/0000-0005-7E8F-E"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "21.11116/0000-0005-7E8F-E", "name": "item", "description": "21.11116/0000-0005-7E8F-E", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/21.11116/0000-0005-7E8F-E"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-11-11T00:00:00Z"}}, {"id": "2164/13228", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:27:02Z", "type": "Journal Article", "created": "2016-08-08", "title": "Soil Fungal:Bacterial Ratios Are Linked to Altered Carbon Cycling", "description": "Despite several lines of observational evidence, there is a lack of consensus on whether higher fungal:bacterial (F:B) ratios directly cause higher soil carbon (C) storage. We employed RNA sequencing, protein profiling and isotope tracer techniques to evaluate whether differing F:B ratios are associated with differences in C storage. A mesocosm (13)C labeled foliar litter decomposition experiment was performed in two soils that were similar in their physico-chemical properties but differed in microbial community structure, specifically their F:B ratio (determined by PLFA analyses, RNA sequencing and protein profiling; all three corroborating each other). Following litter addition, we observed a consistent increase in abundance of fungal phyla; and greater increases in the fungal dominated soil; implicating the role of fungi in litter decomposition. Litter derived (13)C in respired CO2 was consistently lower, and residual (13)C in bulk SOM was higher in high F:B soil demonstrating greater C storage potential in the F:B dominated soil. We conclude that in this soil system, the increased abundance of fungi in both soils and the altered C cycling patterns in the F:B dominated soils highlight the significant role of fungi in litter decomposition and indicate that F:B ratios are linked to higher C storage potential.", "keywords": ["Microbiology (medical)", "Proteomics", "0301 basic medicine", "environment/Bioclimatology", "Supplementary Data", "[SDE.MCG]Environmental Sciences/Global Changes", "stable isotopes", "litter decomposition", "Microbiology", "03 medical and health sciences", "proteomics", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDV.EE]Life Sciences [q-bio]/Ecology", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "soil carbon", "European Commission", "bacteria", "Stable isotopes", "2. Zero hunger", "655240", "0303 health sciences", "Bacteria", "Litter decomposition", "Fungi", "RNA sequencing", "QR Microbiology", "15. Life on land", "Soil carbon", "[SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces", " environment", "QR1-502", "6. Clean water", "QR", "[SDE.BE] Environmental Sciences/Biodiversity and Ecology", "[SDE.MCG] Environmental Sciences/Global Changes", "[SDV.EE] Life Sciences [q-bio]/Ecology", " environment", "[SDV.EE.BIO] Life Sciences [q-bio]/Ecology", " environment/Bioclimatology", "[SDV.EE.BIO]Life Sciences [q-bio]/Ecology", "fungi", "[SDE.BE]Environmental Sciences/Biodiversity and Ecology", "[SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces", "environment"]}, "links": [{"href": "https://doi.org/2164/13228"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Frontiers%20in%20Microbiology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2164/13228", "name": "item", "description": "2164/13228", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2164/13228"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-08-09T00:00:00Z"}}, {"id": "2984123384", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:27:25Z", "type": "Journal Article", "created": "2019-11-11", "title": "Contribution of Peatland Permafrost to Dissolved Organic Matter along a Thaw Gradient in North Siberia", "description": "Permafrost peatlands are important carbon stocks currently experiencing rapid evolution after permafrost thaw. Following thaw, dissolved organic matter (DOM) is a potentially important pathway for the release of permafrost carbon. This study investigates the origin and composition of DOM across sites at different stages of thaw in a discontinuous permafrost area of North Siberia. We determine the optical properties, molecular composition, and stable isotopic (\u03b413C) and radiocarbon (14C) contents of DOM. Early stages of thaw are characterized by high DOC concentrations, high aromaticity, contribution of vegetation-derived DOM, and a high contribution of permafrost carbon. In contrast, in later stages, the microbial contribution to DOM increases, and only modern carbon is detected. This work links DOM composition with its radiocarbon content in permafrost peatlands. It shows that DOM originating from previously frozen permafrost peatlands is highly aromatic and previously processed. It highlights the variability of post-thaw carbon dynamics in boreal and arctic ecosystems.", "keywords": ["570", "550", "Arctic Regions", "Permafrost", "15. Life on land", "GEOF", "01 natural sciences", "Panoply", "Carbon", "Siberia", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Ecosystem", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.9b03735"}, {"href": "https://doi.org/2984123384"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2984123384", "name": "item", "description": "2984123384", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2984123384"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-11-11T00:00:00Z"}}, {"id": "3137244153", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:27:42Z", "type": "Journal Article", "created": "2021-03-13", "title": "X-ray absorption spectroscopy evidence of sulfur-bound cadmium in the Cd-hyperaccumulator Solanum nigrum and the non-accumulator Solanum melongena", "description": "It has been proposed that non-protein thiols and organic acids play a major role in cadmium phytoavailability and distribution in plants. In the Cd-hyperaccumulator Solanum nigrum and non-accumulator Solanum melongena, the role of these organic ligands in the accumulation and detoxification mechanisms of Cd are debated. In this study, we used X-ray absorption spectroscopy to investigate Cd speciation in these plants (roots, stem, leaves) and in the soils used for their culture to unravel the plants responses to Cd exposure. The results show that Cd in the 100\u00a0mg\u00a0kg-1 Cd-doped clayey loam soil is sorbed onto iron oxyhydroxides. In both S.\u00a0nigrum and S.\u00a0melongena, Cd in roots and fresh leaves is mainly bound to thiol ligands, with a small contribution of inorganic S ligands in S.\u00a0nigrum leaves. We interpret the Cd binding to sulfur ligands as detoxification mechanisms, possibly involving the sequestration of Cd complexed with glutathione or phytochelatins in the plant vacuoles. In the stems, results show an increase binding of Cd to -O ligands (>50% for S.\u00a0nigrum). We suggest that Cd is partly complexed by organic acids for transportation in the sap.", "keywords": ["[SDE] Environmental Sciences", "0106 biological sciences", "570", "[CHIM.ANAL] Chemical Sciences/Analytical chemistry", "http://aims.fao.org/aos/agrovoc/c_28566", "cadmium", "http://aims.fao.org/aos/agrovoc/c_2219", "Speciation", "Plant Roots", "01 natural sciences", "[SDV.BV.BOT] Life Sciences [q-bio]/Vegetal Biology/Botanics", "d\u00e9toxification", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDE.ES] Environmental Sciences/Environment and Society", "Soil Pollutants", "http://aims.fao.org/aos/agrovoc/c_32389", "Solanum melongena", "http://aims.fao.org/aos/agrovoc/c_5383", "Solanaceae", "Solanum nigrum", "0105 earth and related environmental sciences", "580", "Toxicity", "thiol", "X-Ray absorption spectroscopy", "[SDV.BV.BOT]Life Sciences [q-bio]/Vegetal Biology/Botanics", "3. Good health", "http://aims.fao.org/aos/agrovoc/c_7731", "bioaccumulation", "Biodegradation", " Environmental", "X-Ray Absorption Spectroscopy", "acide organique", "13. Climate action", "http://aims.fao.org/aos/agrovoc/c_7218", "[SDE]Environmental Sciences", "http://aims.fao.org/aos/agrovoc/c_32250", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "spectroscopie aux rayons x", "H50 - Troubles divers des plantes", "P02 - Pollution", "http://aims.fao.org/aos/agrovoc/c_1178", "Sulfur", "Cadmium"]}, "links": [{"href": "https://doi.org/3137244153"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "3137244153", "name": "item", "description": "3137244153", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/3137244153"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-01-01T00:00:00Z"}}, {"id": "33774364", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:27:56Z", "type": "Journal Article", "created": "2021-03-13", "title": "X-ray absorption spectroscopy evidence of sulfur-bound cadmium in the Cd-hyperaccumulator Solanum nigrum and the non-accumulator Solanum melongena", "description": "It has been proposed that non-protein thiols and organic acids play a major role in cadmium phytoavailability and distribution in plants. In the Cd-hyperaccumulator Solanum nigrum and non-accumulator Solanum melongena, the role of these organic ligands in the accumulation and detoxification mechanisms of Cd are debated. In this study, we used X-ray absorption spectroscopy to investigate Cd speciation in these plants (roots, stem, leaves) and in the soils used for their culture to unravel the plants responses to Cd exposure. The results show that Cd in the 100\u00a0mg\u00a0kg-1 Cd-doped clayey loam soil is sorbed onto iron oxyhydroxides. In both S.\u00a0nigrum and S.\u00a0melongena, Cd in roots and fresh leaves is mainly bound to thiol ligands, with a small contribution of inorganic S ligands in S.\u00a0nigrum leaves. We interpret the Cd binding to sulfur ligands as detoxification mechanisms, possibly involving the sequestration of Cd complexed with glutathione or phytochelatins in the plant vacuoles. In the stems, results show an increase binding of Cd to -O ligands (>50% for S.\u00a0nigrum). We suggest that Cd is partly complexed by organic acids for transportation in the sap.", "keywords": ["[SDE] Environmental Sciences", "0106 biological sciences", "570", "[CHIM.ANAL] Chemical Sciences/Analytical chemistry", "http://aims.fao.org/aos/agrovoc/c_28566", "cadmium", "http://aims.fao.org/aos/agrovoc/c_2219", "Speciation", "Plant Roots", "01 natural sciences", "[SDV.BV.BOT] Life Sciences [q-bio]/Vegetal Biology/Botanics", "d\u00e9toxification", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDE.ES] Environmental Sciences/Environment and Society", "Soil Pollutants", "http://aims.fao.org/aos/agrovoc/c_32389", "Solanum melongena", "http://aims.fao.org/aos/agrovoc/c_5383", "Solanaceae", "Solanum nigrum", "0105 earth and related environmental sciences", "580", "Toxicity", "thiol", "X-Ray absorption spectroscopy", "[SDV.BV.BOT]Life Sciences [q-bio]/Vegetal Biology/Botanics", "3. Good health", "http://aims.fao.org/aos/agrovoc/c_7731", "bioaccumulation", "Biodegradation", " Environmental", "X-Ray Absorption Spectroscopy", "acide organique", "13. Climate action", "http://aims.fao.org/aos/agrovoc/c_7218", "[SDE]Environmental Sciences", "http://aims.fao.org/aos/agrovoc/c_32250", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "spectroscopie aux rayons x", "H50 - Troubles divers des plantes", "P02 - Pollution", "http://aims.fao.org/aos/agrovoc/c_1178", "Sulfur", "Cadmium"]}, "links": [{"href": "https://doi.org/33774364"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "33774364", "name": "item", "description": "33774364", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/33774364"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-01-01T00:00:00Z"}}, {"id": "31710219", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:27:45Z", "type": "Journal Article", "created": "2019-11-11", "title": "Contribution of Peatland Permafrost to Dissolved Organic Matter along a Thaw Gradient in North Siberia", "description": "Permafrost peatlands are important carbon stocks currently experiencing rapid evolution after permafrost thaw. Following thaw, dissolved organic matter (DOM) is a potentially important pathway for the release of permafrost carbon. This study investigates the origin and composition of DOM across sites at different stages of thaw in a discontinuous permafrost area of North Siberia. We determine the optical properties, molecular composition, and stable isotopic (\u03b413C) and radiocarbon (14C) contents of DOM. Early stages of thaw are characterized by high DOC concentrations, high aromaticity, contribution of vegetation-derived DOM, and a high contribution of permafrost carbon. In contrast, in later stages, the microbial contribution to DOM increases, and only modern carbon is detected. This work links DOM composition with its radiocarbon content in permafrost peatlands. It shows that DOM originating from previously frozen permafrost peatlands is highly aromatic and previously processed. It highlights the variability of post-thaw carbon dynamics in boreal and arctic ecosystems.", "keywords": ["570", "550", "Arctic Regions", "Permafrost", "15. Life on land", "GEOF", "01 natural sciences", "Panoply", "Carbon", "Siberia", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Ecosystem", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.9b03735"}, {"href": "https://doi.org/31710219"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "31710219", "name": "item", "description": "31710219", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/31710219"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-11-11T00:00:00Z"}}], "links": [{"rel": "self", "type": "application/geo+json", "title": "This document as GeoJSON", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=%5BSDU.STU.GC%5D+Sciences+of+the+Universe+%5Bphysics%5D%2FEarth+Sciences%2FGeochemistry&f=json", "hreflang": "en-US"}, {"rel": "alternate", "type": "text/html", "title": "This document as HTML", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=%5BSDU.STU.GC%5D+Sciences+of+the+Universe+%5Bphysics%5D%2FEarth+Sciences%2FGeochemistry&f=html", "hreflang": "en-US"}, {"rel": "collection", "type": "application/json", "title": "Collection URL", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main", "hreflang": "en-US"}, {"type": "application/geo+json", "rel": "first", "title": "items (first)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=%5BSDU.STU.GC%5D+Sciences+of+the+Universe+%5Bphysics%5D%2FEarth+Sciences%2FGeochemistry&", "hreflang": "en-US"}, {"rel": "last", "type": "application/geo+json", "title": "items (last)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=%5BSDU.STU.GC%5D+Sciences+of+the+Universe+%5Bphysics%5D%2FEarth+Sciences%2FGeochemistry&offset=45", "hreflang": "en-US"}], "numberMatched": 45, "numberReturned": 45, "distributedFeatures": [], "timeStamp": "2026-04-16T12:29:53.314111Z"}