Observations of the South Polar Residual Cap suggest a possible erosion of the cap, leading to an increase of the global mass of the atmosphere. We test this assumption by making the first comparison between Viking 1 and InSight surface pressure data, which were recorded 40\uffc2\uffa0years apart. Such a comparison also allows us to determine changes in the dynamics of the seasonal ice caps between these two periods. To do so, we first had to recalibrate the InSight pressure data because of their unexpected sensitivity to the sensor temperature. Then, we had to design a procedure to compare distant pressure measurements. We propose two surface pressure interpolation methods at the local and global scale to do the comparison. The comparison of Viking and InSight seasonal surface pressure variations does not show changes larger than \uffc2\uffb18\uffc2\uffa0Pa in the CO2 cycle. Such conclusions are supported by an analysis of Mars Science Laboratory (MSL) pressure data. Further comparisons with images of the south seasonal cap taken by the Viking 2 orbiter and MARCI camera do not display significant changes in the dynamics of this cap over a 40\uffc2\uffa0year period. Only a possible larger extension of the North Cap after the global storm of MY 34 is observed, but the physical mechanisms behind this anomaly are not well determined. Finally, the first comparison of MSL and InSight pressure data suggests a pressure deficit at Gale crater during southern summer, possibly resulting from a large presence of dust suspended within the crater.
", "keywords": ["Atmospheric sciences", "550", "Astronomy", "Atmosphere (unit)", "FOS: Mechanical engineering", "Library science", "Oceanography", "01 natural sciences", "CO2 ice", "pressure", "Mars Exploration Program", "Engineering", "Surface pressure", "Storm", "Martian Climate", "Space Suit Design and Ergonomics for EVA", "Martian Atmosphere", "Earth and Planetary Astrophysics (astro-ph.EP)", "Climatology", "Global and Planetary Change", "Geography", "Martian Surface", "Physics", "Geology", "Impact crater", "Condensed matter physics", "Anomaly (physics)", "World Wide Web", "Algorithm", "Satellite Observations", "Residual", "Physical Sciences", "Exploration and Study of Mars", "Astrophysics - Instrumentation and Methods for Astrophysics", "Research Article", "FOS: Physical sciences", "Mars", "Aerospace Engineering", "Pressure gradient", "Environmental science", "[SDU] Sciences of the Universe [physics]", "atmospheric mass", "Meteorology", "Orbiter", "0103 physical sciences", "Instrumentation and Methods for Astrophysics (astro-ph.IM)", "Formation and Evolution of the Solar System", "0105 earth and related environmental sciences", "Pressure system", "CO 2 ice", "Astronomy and Astrophysics", "FOS: Earth and related environmental sciences", "Astrobiology", "Computer science", "Physics and Astronomy", "[SDU]Sciences of the Universe [physics]", "13. Climate action", "Global Methane Emissions and Impacts", "Environmental Science", "cap sublimation", "Water on Mars", "Astrophysics - Earth and Planetary Astrophysics"]}, "links": [{"href": "https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2022JE007190"}, {"href": "https://doi.org/10.1029/2022je007190"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Geophysical%20Research%3A%20Planets", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1029/2022je007190", "name": "item", "description": "10.1029/2022je007190", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1029/2022je007190"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-01-25T00:00:00Z"}}, {"id": "10.1051/ocl/2013027", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:58Z", "type": "Journal Article", "created": "2013-10-02", "title": "The Importance Of Land Use Change In The Environmental Balance Of Biofuels", "description": "The potential of first generation biofuels to mitigate climate change is still largely debated in the scientific and policy-making arenas. It is currently assessed through life cycle assessment (LCA), a method for accounting for the greenhouse gas (GHG) emissions of a given product from \u201ccradle-to-grave\u201d, which is widely used to aid decision making on environmental issues. Although LCA is standardized, its application to biofuels leads to inconclusive results often fraught by a high variability and uncertainty. This is due to differences in quantifying the environmental impacts of feedstock production, and the difficulties encountered when considering land use changes (LUC) effects. The occurrence of LUC mechanisms is in part the consequence of policies supporting the use of biofuels in the transport sector, which implicitly increases the competition between various possible uses of land worldwide. Here, we review the methodologies recently put forward to include LUC effects in LCAs, and examples from the US, Europe and France. These cross analysis show that LCA needs to be adapted and combined to other tools such as economic modeling in order to provide a more reliable assessment of the biofuels chains.", "keywords": ["[SDV.SA]Life Sciences [q-bio]/Agricultural sciences", "land use change", "2. Zero hunger", "[SDV.SA] Life Sciences [q-bio]/Agricultural sciences", "Oils", " fats", " and waxes", "330", "02 engineering and technology", "15. Life on land", "sustainability", "01 natural sciences", "7. Clean energy", "lan use change", "biofuels", "12. Responsible consumption", "Sustainability", "life cycle assessment", "13. Climate action", "11. Sustainability", "0202 electrical engineering", " electronic engineering", " information engineering", "sustainability;life cycle assessment;biofuels;lan use change;uncertainty", "TP670-699", "uncertainty", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Ben Aoun, Wassim, Gabrielle, Benoit, Gagnepain, Bruno,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1051/ocl/2013027"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/OCL", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1051/ocl/2013027", "name": "item", "description": "10.1051/ocl/2013027", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1051/ocl/2013027"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2013-09-01T00:00:00Z"}}, {"id": "10.1017/s1742170511000317", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:13Z", "type": "Journal Article", "created": "2011-07-22", "title": "Soil Fertility And Crop Yields In Long-Term Organic And Conventional Cropping Systems In Eastern Nebraska", "description": "AbstractOrganic agriculture aims to build soil quality and provide long-term benefits to people and the environment; however, organic practices may reduce crop yields. This long-term study near Mead, NE was conducted to determine differences in soil fertility and crop yields among conventional and organic cropping systems between 1996 and 2007. The conventional system (CR) consisted of corn (Zea maysL.) or sorghum (Sorghum bicolor(L.) Moench)\uffe2\uff80\uff93soybean (Glycine max(L.) Merr.)\uffe2\uff80\uff93sorghum or corn\uffe2\uff80\uff93soybean, whereas the diversified conventional system (DIR) consisted of corn or sorghum\uffe2\uff80\uff93sorghum or corn\uffe2\uff80\uff93soybean\uffe2\uff80\uff93winter wheat (wheat,Triticum aestivumL.). The animal manure-based organic system (OAM) consisted of soybean\uffe2\uff80\uff93corn or sorghum\uffe2\uff80\uff93soybean\uffe2\uff80\uff93wheat, while the forage-based organic system (OFG) consisted of alfalfa (Medicago sativaL.)\uffe2\uff80\uff93alfalfa\uffe2\uff80\uff93corn or sorghum\uffe2\uff80\uff93wheat. Averaged across sampling years, soil organic matter content (OMC), P, pH, Ca, K, Mg and Zn in the top 15 cm of soil were greatest in the OAM system. However, by 2008 OMC was not different between the two organic systems despite almost two times greater carbon inputs in the OAM system. Corn, sorghum and soybean average annual yields were greatest in either of the two conventional systems (7.65, 6.36 and 2.60 Mg ha\uffe2\uff88\uff921, respectively), whereas wheat yields were greatest in the OAM system (3.07 Mg ha\uffe2\uff88\uff921). Relative to the mean of the conventional systems, corn yields were reduced by 13 and 33% in the OAM and OFG systems, respectively. Similarly, sorghum yields in the OAM and OFG systems were reduced by 16 and 27%, respectively. Soybean yields were 20% greater in the conventional systems compared with the OAM system. However, wheat yields were 10% greater in the OAM system compared with the conventional DIR system and 23% greater than yield in the OFG system. Alfalfa in the OFG system yielded an average of 7.41 Mg ha\uffe2\uff88\uff921annually. Competitive yields of organic wheat and alfalfa along with the soil fertility benefits associated with animal manure and perennial forage suggest that aspects of the two organic systems be combined to maximize the productivity and sustainability of organic cropping systems.
", "keywords": ["2. Zero hunger", "Organic matter content", "Organic farming", "Animal manure", "Soil phosphorus", "Plant Sciences", "Botany", "Plant Biology", "04 agricultural and veterinary sciences", "Horticulture", "15. Life on land", "Perennial forage", "Nutrient budgets", "630", "6. Clean water", "Agronomy and Crop Sciences", "Long-term crop rotations", "0401 agriculture", " forestry", " and fisheries", "Agricultural Science"], "contacts": [{"organization": "Wortman, Samuel E., Galusha, Tomie D., Mason, Stephen C., Francis, Charles A.,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1017/s1742170511000317"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Renewable%20Agriculture%20and%20Food%20Systems", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1017/s1742170511000317", "name": "item", "description": "10.1017/s1742170511000317", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1017/s1742170511000317"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2011-07-22T00:00:00Z"}}, {"id": "10.1017/s1751731108001791", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:13Z", "type": "Journal Article", "created": "2008-04-15", "title": "Effect Of The Tropical Tannin-Rich Shrub Legumes Calliandra Calothyrsus And Flemingia Macrophylla On Methane Emission And Nitrogen And Energy Balance In Growing Lambs", "description": "Open AccessISSN:1751-7311", "keywords": ["Brachiaria; methane; ruminants; tannins; Vigna", "ruminants", "tannins", "methane", "Vigna", "0402 animal and dairy science", "Brachiaria", "04 agricultural and veterinary sciences", "SF1-1100", "Animal culture"], "contacts": [{"organization": "Tiemann, T. T., Lascano, C. E., Wettstein, H.-R, Mayer, A. C., Kreuzer, M., Hess, H. D.,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1017/s1751731108001791"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Animal", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1017/s1751731108001791", "name": "item", "description": "10.1017/s1751731108001791", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1017/s1751731108001791"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2008-01-01T00:00:00Z"}}, {"id": "10.1017/wsc.2017.33", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:13Z", "type": "Journal Article", "created": "2017-09-01", "title": "Weed Abundance And Community Composition Following A Long-Term Organic Vegetable Cropping Systems Experiment", "description": "Weed management is a major constraint in organic cropping systems. In 2004, the Cornell Organic Vegetable Cropping Systems Experiment was established in central New York state using a split-plot randomized complete block design with two crop rotation entry points (split-plot factor). Four organic vegetable cropping systems that varied in cropping intensity and tillage (main plot factor) were compared: (1) intensive, (2) intermediate, (3) bio-extensive, and (4) ridge tillage. The basic crop rotation was cabbage, lettuce, potato, and winter squash, with additional short-season crops in the intensive system and with cover crops and fallow substituted for cabbage and potato in the bio-extensive system. In 2014, two uniformity trials were conducted in which oat and then a mixture of sorghum-sudangrass plus Japanese millet were grown uniformly over the entire experiment. Prior to sowing oat, soil samples were collected from each plot and an emergence bioassay was conducted to assess the soil weed seedbank. Crop biomass, weed density, and weed biomass were sampled in the uniformity crops. Soil weed seedbank density was three to four times greater in the intensive, intermediate, and ridge-tillage systems than in the bio-extensive system. The bio-extensive system also had lower weed density and weed biomass in the oat uniformity trial compared with the other three systems. Oat biomass did not differ between the cropping systems. Weed density and biomass in oat were also affected by the crop rotation entry point. Cropping system legacy effects on weed abundance and community composition were greater in the oat than in the sorghum-sudangrass plus Japanese millet uniformity trial. Our results illustrate the effects of different organic vegetable production practices on weed community structure and highlight the value of tilled fallow periods, cover crops, and prevention of weed seed rain for reducing weed populations.
", "keywords": ["seedbank", "[SDE] Environmental Sciences", "2. Zero hunger", "[SDV]Life Sciences [q-bio]", "04 agricultural and veterinary sciences", "15. Life on land", "630", "emergence bioassay", "uniformity trial", "[SDV] Life Sciences [q-bio]", "bio-extensive", "[SDE]Environmental Sciences", "tillage", "[SDV.BV]Life Sciences [q-bio]/Vegetal Biology", "0401 agriculture", " forestry", " and fisheries", "[SDV.BV] Life Sciences [q-bio]/Vegetal Biology", "cover crops", "legacy effects"]}, "links": [{"href": "https://doi.org/10.1017/wsc.2017.33"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Weed%20Science", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1017/wsc.2017.33", "name": "item", "description": "10.1017/wsc.2017.33", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1017/wsc.2017.33"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-09-01T00:00:00Z"}}, {"id": "10.1021/acs.analchem.2c04345", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:14Z", "type": "Journal Article", "created": "2022-12-22", "title": "Rapid Single Particle Atmospheric Solids Analysis Probe-Mass Spectrometry for Multimodal Analysis of Microplastics", "description": "Despite mass spectrometry (MS) being proven powerful for the characterization of synthetic polymers, its potential for the analysis of single particle microplastics (MPs) is yet to be fully disclosed. To date, MPs are regarded as ubiquitous contaminants, but the limited availability of techniques that enable full characterizations of MPs results in a lack of systematic data regarding their occurrence. In this study, an atmospheric solid analysis probe (ASAP) coupled to a compact quadrupole MS is proposed for the chemical analysis of single particle microplastics, while maintaining full compatibility with complementary staining and image analysis approaches. A two-stage ASAP probe temperature program was optimized for the removal of additives and surface contaminants followed by the actual polymer characterization. The method showed specific mass spectra for a wide range of single particle MPs, including polyolefins, polyaromatics, polyacrylates, (bio)polyesters, polyamides, polycarbonates, and polyacrylonitriles. The single particle size detection limits for polystyrene MPs were found to be 30 and 5 \u03bcm in full scan and selected ion recording mode, respectively. Moreover, results are presented of a multimodal microplastic analysis approach in which filtered particles are first characterized by staining and fluorescence microscopy, followed by simple probe picking of individual particles for subsequent analysis by ASAP-MS. The method provides a full characterization of MP contamination, including particle number, particle size, particle shape, and chemical identity. The applicability of the developed multimodal method was successfully demonstrated by the analysis of MPs in bioplastic bottled water.", "keywords": ["Microplastics", "Life Science", "Plastics", "01 natural sciences", "Gas Chromatography-Mass Spectrometry", "Water Pollutants", " Chemical", "Mass Spectrometry", "Environmental Monitoring", "0104 chemical sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.analchem.2c04345"}, {"href": "https://doi.org/10.1021/acs.analchem.2c04345"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Analytical%20Chemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.analchem.2c04345", "name": "item", "description": "10.1021/acs.analchem.2c04345", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.analchem.2c04345"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-12-22T00:00:00Z"}}, {"id": "10.1021/acs.jafc.9b00497", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2019-04-23", "title": "Furanolysis with Menthofuran: A New Depolymerization Method for Analyzing Condensed Tannins", "description": "An improved analytical depolymerization method for characterizing condensed tannins was developed with menthofuran (3,6-dimethyl-4,5,6,7-tetrahydro-1-benzofuran) as the nucleophilic trapping reagent. Herein, menthofuran was compared with routinely used nucleophiles, phloroglucinol and 2-mercaptoethanol. At 30 \u00b0C and in the presence of 0.1 M HCl, menthofuran displayed the outstanding ability to enable the fast and full depolymerization of procyanidin B2 using only a 1:1 molar ratio of both reactants. Under the same conditions, phloroglucinol and 2-mercaptoethanol led to a reaction equilibrium with significantly lower conversion yields. Application to commercial tannin extracts showed that a menthofuran-to-extract weight ratio of 1 gave the same yields of procyanidin constitutive units as 10-fold higher molecular equivalent phloroglucinol and 100-fold 2-mercaptoethanol. Finally, guidelines for implementing the menthofuran depolymerization method are proposed to assess the tannin content and composition of extracts as well as of plant materials without prior extraction.", "keywords": ["[CHIM.ANAL] Chemical Sciences/Analytical chemistry", "m\u00e9thode analytique", "Ing\u00e9nierie des aliments", "Menthofuran", "Analytical method", "01 natural sciences", "Catechin", "Chemistry Techniques", " Analytical", "Polymerization", "[CHIM.ANAL]Chemical Sciences/Analytical chemistry", "Food engineering", "Biflavonoids", "Condensed tannins", "Proanthocyanidins", "tanin", "Plant Extracts", "UHPLC-DAD-MS", "540", "6. Clean water", "0104 chemical sciences", "furane", "Furylated flavonoids", "Monoterpenes", "flavono\u00efde", "Furan derivatives", "d\u00e9polym\u00e9risation", "Tannins", "Depolymerization"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.jafc.9b00497"}, {"href": "https://hal.science/hal-02295527/file/Billerach_postprint_2019.pdf"}, {"href": "https://doi.org/10.1021/acs.jafc.9b00497"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Agricultural%20and%20Food%20Chemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.jafc.9b00497", "name": "item", "description": "10.1021/acs.jafc.9b00497", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.jafc.9b00497"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-04-23T00:00:00Z"}}, {"id": "10.1021/acs.energyfuels.2c01746", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-04-03T16:18:14Z", "type": "Journal Article", "created": "2022-09-21", "title": "Understanding the Upgrading of Sewage Sludge-Derived Hydrothermal Liquefaction Biocrude via Advanced Characterization", "description": "Hydrothermal liquefaction (HTL) can thermochemically transform sewage sludge into a biocrude with high energy content, high chemical complexity, and high O and N content. The development of an efficient upgrading process for such complex feedstocks necessitates detailed knowledge of the molecular composition and the specific heteroatom-containing compounds to understand and optimize the hydrotreating reactions. In this study, we present the upgrading of sewage sludge-derived HTL biocrude via a two-stage hydrotreatment process and perform advanced chemical characterization of the feedstock, intermediate, and final upgraded products with gas chromatography-mass spectrometry (GC-MS) and Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS). We show that hydrotreatment significantly improves the quality of the oil, primarily succeeding in cracking the heavy molecules and removing the sulfur- and oxygen-containing components. FTICR-MS analysis shows that the HTL biocrude has a high concentration of fatty acid amides that readily lose their oxygen and nitrogen during hydrotreating and are converted into saturated hydrocarbons, whereas the aromatic OxNy compounds are converted into N1 and N2 classes, which are more resistant to hydrotreating. We also demonstrate that the upgraded HTL oil can be successfully blended with intermediate refinery streams, such as vacuum gas oil (VGO), for further co-processing to in-spec fuels in conventional processes. This provides an alternative route to introduce renewable carbon in existing fossil-based refineries.", "keywords": ["02 engineering and technology", "0204 chemical engineering", "0210 nano-technology", "6. Clean water", "12. Responsible consumption"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.energyfuels.2c01746"}, {"href": "https://doi.org/10.1021/acs.energyfuels.2c01746"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Energy%20%26amp%3B%20Fuels", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.energyfuels.2c01746", "name": "item", "description": "10.1021/acs.energyfuels.2c01746", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.energyfuels.2c01746"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-09-21T00:00:00Z"}}, {"id": "10.1021/acs.est.0c05203", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:14Z", "type": "Journal Article", "created": "2021-02-08", "title": "Mercury Reduction by Nanoparticulate Vivianite", "description": "Open AccessISSN:0013-936X", "keywords": ["abiotic Hg II reduction", "Chemical Sciences not elsewhere classified", "Physiology", "0211 other engineering and technologies", "02 engineering and technology", "Hg 0", "Hg II", "PO", "01 natural sciences", "Phosphates", "Environmental Sciences not elsewhere classified", "Ferrous Compounds", "Hg II reducers", "Molecular Biology", "ferrous iron phosphate mineral vivi.", "Ecosystem", "0105 earth and related environmental sciences", "Pharmacology", "Fe II content", "Ecology", "Nanoparticulate Vivianite Mercury", "Cell Biology", "Mercury", "6. Clean water", "Fe II 3", "13. Climate action", "Oxidation-Reduction", "Biological Sciences not elsewhere classified"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.0c05203"}, {"href": "https://doi.org/10.1021/acs.est.0c05203"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.0c05203", "name": "item", "description": "10.1021/acs.est.0c05203", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.0c05203"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-02-08T00:00:00Z"}}, {"id": "10.1021/acs.est.1c00612", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:14Z", "type": "Journal Article", "created": "2021-04-28", "title": "Hidden Resistome: Enrichment Reveals the Presence of Clinically Relevant Antibiotic Resistance Determinants in Treated Wastewater-Irrigated Soils", "description": "Treated-wastewater (TW) irrigation transfers antibiotic-resistant bacteria (ARB) to soil, but persistence of these bacteria is generally low due to resilience of the soil microbiome. Nonetheless, wastewater-derived bacteria and associated antibiotic resistance genes (ARGs) may persist below detection levels and potentially proliferate under copiotrophic conditions. To test this hypothesis, we exposed soils from microcosm, lysimeter, and field experiments to short-term enrichment in copiotroph-stimulating media. In microcosms, enrichment stimulated growth of multidrug-resistant Escherichia coli up to 2 weeks after falling below detection limits. Lysimeter and orchard soils irrigated in-tandem with either freshwater or TW were subjected to culture-based, qPCR and shotgun metagenomic analyses prior, and subsequent, to enrichment. Although native TW- and freshwater-irrigated soil microbiomes and resistomes were similar to each other, enrichment resulted in higher abundances of cephalosporin- and carbapenem-resistant Enterobacteriaceae and in substantial differences in the composition of microbial communities and ARGs. Enrichment stimulated ARG-harboring Bacillaceae in the freshwater-irrigated soils, whereas in TWW-irrigated soils, ARG-harboring \u03b3-proteobacterial families Enterobacteriaceae and Moraxellaceae were more profuse. We demonstrate that TW-derived ARB and associated ARGs can persist at below detection levels in irrigated soils and believe that similar short-term enrichment strategies can be applied for environmental antimicrobial risk assessment in the future.", "keywords": ["0301 basic medicine", "2. Zero hunger", "0303 health sciences", "Agricultural Irrigation", "Angiotensin-Converting Enzyme Inhibitors", "Drug Resistance", " Microbial", "Wastewater", "6. Clean water", "Anti-Bacterial Agents", "3. Good health", "Angiotensin Receptor Antagonists", "Soil", "03 medical and health sciences", "Genes", " Bacterial", "Humans", "Soil Microbiology"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.1c00612"}, {"href": "https://doi.org/10.1021/acs.est.1c00612"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.1c00612", "name": "item", "description": "10.1021/acs.est.1c00612", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.1c00612"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-04-27T00:00:00Z"}}, {"id": "10.1038/s41396-022-01277-w", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:37Z", "type": "Journal Article", "created": "2022-07-07", "title": "Novel form of collective movement by soil bacteria", "description": "AbstractAlthough migrations are essential for soil microorganisms to exploit scarce and heterogeneously distributed resources, bacterial mobility in soil remains poorly studied due to experimental limitations. In this study, time-lapse images collected using live microscopy techniques captured collective and coordinated groups of B. subtilis cells exhibiting \uffe2\uff80\uff9ccrowd movement\uffe2\uff80\uff9d. Groups of B. subtilis cells moved through transparent soil (nafion polymer with particle size resembling sand) toward plant roots and re-arranged dynamically around root tips in the form of elongating and retracting \uffe2\uff80\uff9cflocks\uffe2\uff80\uff9d resembling collective behaviour usually associated with higher organisms (e.g., bird flocks or fish schools). Genetic analysis reveals B. subtilis flocks are likely driven by the diffusion of extracellular signalling molecules (e.g., chemotaxis, quorum sensing) and may be impacted by the physical obstacles and hydrodynamics encountered in the soil like environment. Our findings advance understanding of bacterial migration through soil matrices and expand known behaviours for coordinated bacterial movement. of alginate via 5-dehydro-4-deoxy-D-glucuronate (DDG) and 3-deoxy-D-glycerol-2,5-hexdiulosonate (DGH) as the intermediates to 2-keto-3-deoxy-gluconate (KDG) was constructed based on the metagenomic and metaproteomic analysis. In summary, this work documented the core enzymes and metabolic pathway for alginate degradation, which provides a good paradigm when analyzing the degrading mechanism of unacquainted substrates. The outcome will further contribute to the application of Bacteroides-dominated ADC on WAS methanogenesis in the future.", "keywords": ["DDG and DGH", "alginate-degrading consortia", "Bacteria", "Sewage", "Alginates", "two chemostats in series", "0211 other engineering and technologies", "02 engineering and technology", "01 natural sciences", "6. Clean water", "Glucuronic Acid", "extracellular alginate lyase (EC 4.2.2.3)", "Bacteroides", "new Entner\u2212Doudoroff pathway", "Metabolic Networks and Pathways", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1021/acs.est.1c05289"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.1c05289", "name": "item", "description": "10.1021/acs.est.1c05289", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.1c05289"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-12-03T00:00:00Z"}}, {"id": "10.1021/acs.est.2c03149", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:14Z", "type": "Journal Article", "created": "2022-09-14", "title": "Chemotactic Bacteria Facilitate the Dispersion of Nonmotile Bacteria through Micrometer-Sized Pores in Engineered Porous Media", "description": "Recent research has demonstrated that chemotactic bacteria can disperse inside microsized pores while traveling toward favorable conditions. Microbe-microbe cotransport might enable nonmotile bacteria to be carried with motile partners to enhance their dispersion and reduce their deposition in porous systems. The aim of this study was to demonstrate the enhancement in the dispersion of nonmotile bacteria (Mycobacterium gilvum VM552, a polycyclic aromatic hydrocarbon-degrader, and Sphingobium sp. D4, a hexachlorocyclohexane-degrader, through micrometer-sized pores near the exclusion-cell-size limit, in the presence of motile Pseudomonas putida G7 cells. For this purpose, we used bioreactors equipped with two chambers that were separated with membrane filters with 3, 5, and 12 \u03bcm pore sizes and capillary polydimethylsiloxane (PDMS) microarrays (20 \u03bcm \u00d7 35 \u03bcm \u00d7 2.2 mm). The cotransport of nonmotile bacteria occurred exclusively in the presence of a chemoattractant concentration gradient, and therefore, a directed flow of motile cells. This cotransport was more intense in the presence of larger pores (12 \u03bcm) and strong chemoeffectors (\u03b3-aminobutyric acid). The mechanism that governed cotransport at the cell scale involved mechanical pushing and hydrodynamic interactions. Chemotaxis-mediated cotransport of bacterial degraders and its implications in pore accessibility opens new avenues for the enhancement of bacterial dispersion in porous media and the biodegradation of heterogeneously contaminated scenarios.", "keywords": ["Chemotactic Factors", "Pseudomonas putida", "Chemotaxis", "Bioaccessibility", "01 natural sciences", "Microbe-microbe cotransport", "Dimethylpolysiloxanes", "Polycyclic Aromatic Hydrocarbons", "Micrometer-sized pores", "Porosity", "Hexachlorocyclohexane", "gamma-Aminobutyric Acid", "Hitchhiking", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.2c03149"}, {"href": "https://doi.org/10.1021/acs.est.2c03149"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.2c03149", "name": "item", "description": "10.1021/acs.est.2c03149", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.2c03149"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-09-14T00:00:00Z"}}, {"id": "10.1021/acs.est.2c03925", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:15Z", "type": "Journal Article", "created": "2022-08-23", "title": "Coexisting Goethite Promotes Fe(II)-Catalyzed Transformation of Ferrihydrite to Goethite", "description": "Open AccessISSN:0013-936X", "keywords": ["Minerals", "template-directed nucleation", "Fe(II)\u2212Fe(III) electron transfer", "recrystallization", "Water", "electron hopping", "Ferric Compounds", "01 natural sciences", "Catalysis", "Soil", "Isotopes", "13. Climate action", "Ferrous Compounds", "labile Fe(III)", "Oxidation-Reduction", "Iron Compounds", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.2c03925"}, {"href": "https://doi.org/10.1021/acs.est.2c03925"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.2c03925", "name": "item", "description": "10.1021/acs.est.2c03925", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.2c03925"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-08-23T00:00:00Z"}}, {"id": "10.1021/acscatal.0c03594", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2020-11-02", "title": "A Whole-Cell Inorganic-Biohybrid System Integrated by Reduced Graphene Oxide for Boosting Solar Hydrogen Production", "description": "The photoelectron transfer between semiconductors and cells is the rate-determining step that controls the solar H2 production of whole-cell inorganic-biohybrid systems (IBSs). Herein, we construct...", "keywords": ["02 engineering and technology", "0210 nano-technology", "01 natural sciences", "0104 chemical sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acscatal.0c03594"}, {"href": "https://doi.org/10.1021/acscatal.0c03594"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/ACS%20Catalysis", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acscatal.0c03594", "name": "item", "description": "10.1021/acscatal.0c03594", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acscatal.0c03594"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-11-02T00:00:00Z"}}, {"id": "10.1021/acs.est.1c04605", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:14Z", "type": "Journal Article", "created": "2021-12-02", "title": "Exploring Spatially Explicit Changes in Carbon Budgets of Global River Basins during the 20th Century", "description": "Rivers play an important role in the global carbon (C) cycle. However, it remains unknown how long-term river C fluxes change because of climate, land-use, and other environmental changes. Here, we investigated the spatiotemporal variations in global freshwater C cycling in the 20th century using the mechanistic IMAGE-Dynamic Global Nutrient Model extended with the Dynamic In-Stream Chemistry Carbon module (DISC-CARBON) that couples river basin hydrology, environmental conditions, and C delivery with C flows from headwaters to mouths. The results show heterogeneous spatial distribution of dissolved inorganic carbon (DIC) concentrations in global inland waters with the lowest concentrations in the tropics and highest concentrations in the Arctic and semiarid and arid regions. Dissolved organic carbon (DOC) concentrations are less than 10 mg C/L in most global inland waters and are generally high in high-latitude basins. Increasing global C inputs, burial, and CO2 emissions reported in the literature are confirmed by DISC-CARBON. Global river C export to oceans has been stable around 0.9 Pg yr-1. The long-term changes and spatial patterns of concentrations and fluxes of different C forms in the global river network unfold the combined influence of the lithology, climate, and hydrology of river basins, terrestrial and biological C sources, in-stream C transformations, and human interferences such as damming.", "keywords": ["global budget", "Arctic Regions", "Fresh Water", "General Chemistry", "15. Life on land", "carbon biogeochemistry", "Dissolved Organic Matter", "01 natural sciences", "river fluxes", "6. Clean water", "process-based hydrology-biogeochemistry model", "Rivers", "13. Climate action", "SDG 13 - Climate Action", "Environmental Chemistry", "Humans", "SDG 14 - Life Below Water", "14. Life underwater", "Hydrology", "spatiotemporal variations", "SDG 15 - Life on Land", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.1c04605"}, {"href": "https://doi.org/10.1021/acs.est.1c04605"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.1c04605", "name": "item", "description": "10.1021/acs.est.1c04605", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.1c04605"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-12-02T00:00:00Z"}}, {"id": "10.1021/acs.est.1c08789", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:14Z", "type": "Journal Article", "created": "2022-04-18", "title": "Stabilization of Ferrihydrite and Lepidocrocite by Silicate during Fe(II)-Catalyzed Mineral Transformation: Impact on Particle Morphology and Silicate Distribution", "description": "Open AccessISSN:0013-936X", "keywords": ["Minerals", "magnetite", "Silicates", "elemental mapping", "Water", "Ferric Compounds", "01 natural sciences", "Catalysis", "Ferrosoferric Oxide", "atom exchange", "Soil", "iron", "redox", "goethite", "Oxidation-Reduction", "crystal morphology", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.1c08789"}, {"href": "https://doi.org/10.1021/acs.est.1c08789"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.1c08789", "name": "item", "description": "10.1021/acs.est.1c08789", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.1c08789"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-04-18T00:00:00Z"}}, {"id": "10.1021/acs.est.2c03397", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:14Z", "type": "Journal Article", "created": "2021-03-04", "title": "Spatial Control of Microbial Pesticide Degradation in Soil: A Model-Based Scenario Analysis", "description": "
<p>Despite all legislative efforts, pesticides persist in soils at low concentrations and are leached to groundwater. This environmental issue has previously been associated with control factors relevant in natural soils but elusive in lab experiments and standard modeling approaches. One such factor is the small-scale spatial distribution of pesticide-degrading microorganisms in soil. Microbes are distributed heterogeneously in natural soils. They are aggregated in biogeochemical &#8220;hotspots&#8221; at the centimeter scale. The aim of our study is to investigate the relevance of such aggregation for pesticide degradation. For this, we upscaled the effect of the heterogeneity-induced accessibility limitations to degradation to the soil-column scale and analyzed kinetic constraints and amplifying factors under contrasting unsaturated flow regimes.</p><p>We performed a 2D spatially explicit, site-specific model-based scenario analysis for bioreactive transport of the model pesticide 4-chloro-2-methylphenoxyacetic acid (MCPA) in an arable soil (Luvisol). Stochastic centimeter-scale spatial distributions of microbial degraders were simulated with a spatial statistical model (log Gaussian Cox process), parametrized to meet experimentally observed spatial distribution metrics. Three heterogeneity levels were considered, representing homogenized soil conditions, and the lower and upper limit of expected microbial spatial aggregation in natural soils. Additionally, two contrasting precipitation scenarios (continuous light rain vs. heavy rain events directly following MCPA application) were assessed. A reactive transport model was set up to simulate a 0.3 m x 0.9 m soil column based on hydraulic and bioreactive measurements from a soil monitoring station (Germany, SM#3/ DFG CRC 1253 CAMPOS).</p><p>Our simulations revealed that heavy precipitation events were the main driver of pesticide leaching. Leached amounts from the topsoil increased by two to five orders of magnitude compared to the light rain scenario and at max. ca. 20 ng was leached from 90 cm after one year. With the increasing spatial aggregation of microbial degraders, upscaled pesticide degradation rates decreased, and considerable differences emerged between homogeneous and highly aggregated scenarios. In the latter, leaching from the plow layer into the subsoil was more pronounced and MCPA was detectable (LOD = 4 &#181;g/kg) 5-6 times longer. In heterogeneous scenarios, degradation in microbial hotspots was mainly diffusion-limited during &#8220;hot moments&#8221; (times of high substrate availability), with a fraction of MCPA simultaneously &#8220;locked in&#8221; in coldspots with low microbial abundance. During intense precipitation events MCPA was remobilised from these coldspots by advective-dispersive transport, thereby increasing pesticide accessibility.</p><p>Our results indicate that predicted environmental concentrations and detectability of pesticides might be underestimated if spatial heterogeneity of microbial degraders is neglected, and they highlight the importance of heavy rain events as drivers of leaching and substrate accessibility.</p>
", "keywords": ["2. Zero hunger", "Soil", "Herbicides", "13. Climate action", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "04 agricultural and veterinary sciences", "2-Methyl-4-chlorophenoxyacetic Acid", "Pesticides", "15. Life on land", "Soil Microbiology", "6. Clean water"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.2c03397"}, {"href": "https://doi.org/10.1021/acs.est.2c03397"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.2c03397", "name": "item", "description": "10.1021/acs.est.2c03397", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.2c03397"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-03-04T00:00:00Z"}}, {"id": "10.1021/acs.est.3c01336", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:15Z", "type": "Journal Article", "created": "2023-06-09", "title": "Coprecipitation with Ferrihydrite Inhibits Mineralization of Glucuronic Acid in an Anoxic Soil", "description": "Open AccessISSN:0013-936X", "keywords": ["Soil", "Minerals", "Iron", "organic carbon", "anoxic soils", "organic carbon; anoxic soils; mineralization; iron minerals", "mineralization", "Ferric Compounds", "Oxidation-Reduction", "iron minerals", "Carbon"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.3c01336"}, {"href": "https://doi.org/10.1021/acs.est.3c01336"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.3c01336", "name": "item", "description": "10.1021/acs.est.3c01336", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.3c01336"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-06-09T00:00:00Z"}}, {"id": "10.1021/acsearthspacechem.3c00174", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:17Z", "type": "Journal Article", "created": "2024-01-25", "title": "Structural Effects of Aluminum and Iron Occupancy in Minerals of the Jarosite-Alunite Solid Solution", "description": "Open AccessISSN:2472-3452", "keywords": ["Mo\u0308ssbauer spectroscopy", "Raman spectroscopy", "atom substitution", "energy dispersive X-ray spectroscopy", "Raman spectroscopy; energy dispersive X-ray spectroscopy; X-ray diffraction; atom substitution; Mo\u0308ssbauer spectroscopy", "X-ray diffraction"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acsearthspacechem.3c00174"}, {"href": "https://doi.org/10.1021/acsearthspacechem.3c00174"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/ACS%20Earth%20and%20Space%20Chemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acsearthspacechem.3c00174", "name": "item", "description": "10.1021/acsearthspacechem.3c00174", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acsearthspacechem.3c00174"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-01-25T00:00:00Z"}}, {"id": "10.1021/acs.est.3c00434", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:15Z", "type": "Journal Article", "created": "2023-06-26", "title": "A New Approach for Investigating Iron Mineral Transformations in Soils and Sediments Using 57Fe-Labeled Minerals and 57Fe M\u00f6ssbauer Spectroscopy", "description": "Open AccessIron minerals in soils and sediments play important roles in many biogeochemical processes and therefore influence the cycling of major and trace elements and the fate of pollutants in the environment. However, the kinetics and pathways of Fe mineral recrystallization and transformation processes under environmentally relevant conditions are still elusive. Here, we present a novel approach enabling us to follow the transformations of Fe minerals added to soils or sediments in close spatial association with complex solid matrices including other minerals, organic matter, and microorganisms. Minerals enriched with the stable isotope 57Fe are mixed with soil or sediment, and changes in Fe speciation are subsequently studied by 57Fe M\u00f6ssbauer spectroscopy, which exclusively detects 57Fe. In this study, 57Fe-labeled ferrihydrite was synthesized, mixed with four soils differing in chemical and physical properties, and incubated for 12+ weeks under anoxic conditions. Our results reveal that the formation of crystalline Fe(III)(oxyhydr)oxides such as lepidocrocite and goethite was strongly suppressed, and instead formation of a green rust-like phase was observed in all soils. These results contrast those from Fe(II)-catalyzed ferrihydrite transformation experiments, where formation of lepidocrocite, goethite, and/or magnetite often occurs. The presented approach allows control over the composition and crystallinity of the initial Fe mineral, and it can be easily adapted to other experimental setups or Fe minerals. It thus offers great potential for future investigations of Fe mineral transformations in situ under environmentally relevant conditions, in both the laboratory and the field.", "keywords": ["Minerals", "550", "Iron", "iron reduction", "01 natural sciences", "Ferric Compounds", "ferrihydrite", "microcosm", "Soil", "Spectroscopy", " Mossbauer", "green rust", "13. Climate action", "Oxidation-Reduction", "Fe(II)-catalyzed transformation", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1021/acs.est.3c00434"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.3c00434", "name": "item", "description": "10.1021/acs.est.3c00434", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.3c00434"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-06-26T00:00:00Z"}}, {"id": "10.1021/acs.est.4c01519", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:15Z", "type": "Journal Article", "created": "2024-06-04", "title": "Iron Oxyhydroxide Transformation in a Flooded Rice Paddy Field and the Effect of Adsorbed Phosphate", "description": "Open AccessISSN:0013-936X", "keywords": ["2. Zero hunger", "Minerals", "Iron", "iron reduction", "Oryza", "15. Life on land", "Ferric Compounds", "ferrihydrite", "6. Clean water", "Phosphates", "Mossbauer", "Soil", "Spectroscopy", " Mossbauer", "Fe(II)-catalyzed", "lepidocrocite", "13. Climate action", "microsite", "Adsorption", "isotope", "Oxidation-Reduction"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.4c01519"}, {"href": "https://doi.org/10.1021/acs.est.4c01519"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.4c01519", "name": "item", "description": "10.1021/acs.est.4c01519", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.4c01519"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-06-04T00:00:00Z"}}, {"id": "10.1021/acs.est.4c09261", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:15Z", "type": "Journal Article", "created": "2024-11-04", "title": "Geochemical Decoupling of Iron and Zinc during Transformation of Zn-Bearing Ferrihydrite in Reducing Sediments", "description": "Open AccessISSN:0013-936X", "keywords": ["Geologic Sediments", "zinc carbonate", "Iron", "Mossbauer spectroscopy", "X-ray absorption spectroscopy", "mineral transformation; Mossbauer spectroscopy; X-ray absorption spectroscopy; environmental speciation; green rust; zinc sulfide; zinc carbonate", "Ferric Compounds", "Zinc", "Spectroscopy", " Mossbauer", "green rust", "X-Ray Absorption Spectroscopy", "zinc sulfide", "Oxidation-Reduction", "mineral transformation", "environmental speciation"], "contacts": [{"organization": "Lefebvre, Pierre, Grigg, Andrew R. C., Kretzschmar, Ruben,", "roles": ["creator"]}]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.4c09261"}, {"href": "https://doi.org/10.1021/acs.est.4c09261"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.4c09261", "name": "item", "description": "10.1021/acs.est.4c09261", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.4c09261"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-11-04T00:00:00Z"}}, {"id": "10.1021/acs.est.3c08734", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:15Z", "type": "Journal Article", "created": "2024-04-10", "title": "Plastic Fruit Stickers in Industrial Composting\u2500Surface and Structural Alterations Revealed by Electron Microscopy and Computed Tomography", "description": "Often large quantities of plastics are found in compost, with price look-up stickers being a major but little-explored component in the contamination path. Stickers glued to fruit or vegetable peels usually remain attached to the organic material despite sorting processes in the composting plant. Here, we investigated the effects of industrial composting on the structural alterations of these stickers. Commercial polypropylene (PP) stickers on banana peels were added to a typical organic material mixture for processing in an industrial composting plant and successfully resampled after a prerotting (11 days) and main rotting step (25 days). Afterward, both composted and original stickers were analyzed for surface and structural changes via scanning electron microscopy, Fourier-transform infrared spectroscopy, and micro- and nano-X-ray computed tomography (CT) combined with deep learning approaches. The composting resulted in substantial surface changes and degradation in the form of microbial colonization, deformation, and occurrence of cracks in all stickers. Their pore volumes increased from 16.7% in the original sticker to 26.3% at the end of the compost process. In a similar way, the carbonyl index of the stickers increased. Micro-CT images additionally revealed structural changes in the form of large adhesions that penetrated the surface of the sticker. These changes were accompanied by delamination after 25 days of composting, thus overall hinting at the degradation of the stickers and the subsequent formation of smaller microplastic pieces.", "keywords": ["Technology", "ddc:600", "ddc:550", "Composting", "600", "02 engineering and technology", "540", "Polypropylenes", "01 natural sciences", "620", "Soil", "Fruit", "Microscopy", " Electron", " Scanning", "info:eu-repo/classification/ddc/600", "Tomography", " X-Ray Computed", "0210 nano-technology", "Plastics", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.3c08734"}, {"href": "https://doi.org/10.1021/acs.est.3c08734"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.3c08734", "name": "item", "description": "10.1021/acs.est.3c08734", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.3c08734"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-04-10T00:00:00Z"}}, {"id": "10.1021/acs.est.4c10664", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:15Z", "type": "Journal Article", "created": "2025-04-18", "title": "An Analytical Workflow to Quantify Biodegradable Polyesters in Soils and Its Application to Incubation Experiments", "description": "Open AccessSoil biodegradable polyesters are designed to undergo to microbial utilization in aerobic soils, forming carbon dioxide and microbial biomass. These polyesters are thus viable substitutes for conventional, persistent polymers (e.g., polyethylene) in specific applications for which the transfer of some of the polymers into the soil is inevitable. While polymer biodegradability is often assessed in laboratory incubations using respirometric analysis of formed CO2, approaches to accurately quantify biodegradable polyesters in soils and to track their mass loss in field incubations over time remain missing. This study first introduces an analytical workflow combining Soxhlet extraction with proton nuclear magnetic resonance spectroscopy for the accurate, high-throughput, and chemically selective quantification of eight commercially important biodegradable polyesters (i.e., poly(butylene adipate-co-terephthalate), polylactic acid, poly(3-hydroxybutyrate-co-3-hydroxyhexanoate), poly(3-hydroxybutyrate-co-3-hydroxyvalerate), polycaprolactone, polybutylene adipate, polybutylene azelate, and polybutylene succinate), and the nonbiodegradable polymer polystyrene, in six soils spanning a range of types and physicochemical properties. This work introduces an effective sample deployment-retrieval approach that, combined with the analytical method, allows the biodegradation of poly(butylene adipate-co-terephthalate) and polylactic acid from a biodegradable mulch film in three agricultural soils to be monitored. In combination, the two parts of this work lay the foundation to accurately quantify and monitor biodegradable polymers in soils.", "keywords": ["Soxhlet extraction", "Soxhlet extraction; biodegradable polymer; biodegradation; soil; H-1-NMR; mulch film", "biodegradable polymer", "biodegradation", "H-1-NMR", "mulch film", "soil"], "contacts": [{"organization": "Mattia Cerri, Flora Wille, Silvan Arn, Thomas D. Bucheli, Franco Widmer, Rhayn Werz, Kristopher McNeill, Alessandro Manfrin, Michael Sander,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1021/acs.est.4c10664"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.4c10664", "name": "item", "description": "10.1021/acs.est.4c10664", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.4c10664"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2025-04-18T00:00:00Z"}}, {"id": "10.1021/acs.est.8b02895", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2018-06-27", "title": "Multiscale Coupling Strategy for Nano Ecotoxicology Prediction", "keywords": ["0301 basic medicine", "03 medical and health sciences", "02 engineering and technology", "0210 nano-technology"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.8b02895"}, {"href": "https://doi.org/10.1021/acs.est.8b02895"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.8b02895", "name": "item", "description": "10.1021/acs.est.8b02895", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.8b02895"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-06-27T00:00:00Z"}}, {"id": "10.1021/acs.est.7b02944", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:15Z", "type": "Journal Article", "created": "2017-10-11", "title": "Novel Multi-isotope Tracer Approach To Test ZnO Nanoparticle and Soluble Zn Bioavailability in Joint Soil Exposures", "description": "Here we use two enriched stable isotopes, 68Znen and 64Znen (>99%), to prepare 68ZnO nanoparticles (NPs) and soluble 64ZnCl2. The standard LUFA 2.2 test soil was dosed with 68ZnO NPs and soluble 64ZnCl2 to 5 mg kg-1 each, plus between 0 and 95 mg kg-1 of soluble ZnCl2 with a natural isotope composition. After 0, 1, 3, 6, and 12 months of soil incubation, earthworms (Eisenia andrei) were introduced for 72 h exposures. Analyses of soils, pore waters, and earthworm tissues using multiple collector inductively coupled plasma mass spectrometry allowed the simultaneous measurement of the diagnostic 68Zn/66Zn, 64Zn/66Zn, and 68Zn/64Zn ratios, from which the three different isotopic forms of Zn were quantified. Eisenia andrei was able to regulate Zn body concentrations with no difference observed between the different total dosing concentrations. The accumulation of labeled Zn by the earthworms showed a direct relationship with the proportion of labeled to total Zn in the pore water, which increased with longer soil incubation times and decreasing soil pH. The 68Znen/64Znen ratios determined for earthworms (1.09 \u00b1 0.04), soils (1.09 \u00b1 0.02), and pore waters (1.08 \u00b1 0.02) indicate indistinguishable environmental distribution and uptake of the Zn forms, most likely due to rapid dissolution of the ZnO NPs.", "keywords": ["104002 Analytische Chemie", "550", "TRANSFORMATIONS", "FATE", "0211 other engineering and technologies", "Biological Availability", "02 engineering and technology", "01 natural sciences", "Soil", "104002 Analytical chemistry", "104023 Umweltchemie", "ENGINEERED NANOMATERIALS", "MD Multidisciplinary", "Animals", "Soil Pollutants", "105906 Environmental geosciences", "210004 Nanomaterials", "Oligochaeta", "EARTHWORM EISENIA-ANDREI", "0105 earth and related environmental sciences", "ENVIRONMENT", "104023 Environmental chemistry", "KNOWLEDGE GAPS", "[SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces", " environment", "6. Clean water", "Zinc", "Nanoparticles", "Zinc Isotopes", "Zinc Oxide", "210004 Nanomaterialien", "Environmental Sciences", "105906 Umweltgeowissenschaften"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.7b02944"}, {"href": "https://doi.org/10.1021/acs.est.7b02944"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.7b02944", "name": "item", "description": "10.1021/acs.est.7b02944", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.7b02944"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-10-26T00:00:00Z"}}, {"id": "10.1021/acsestwater.4c00348", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:17Z", "type": "Journal Article", "created": "2024-11-20", "title": "In Situ Calibration of a Tube Passive Sampler in Wastewater Effluent with Adjustable Volumetric Flow for the Assessment of Micropollutants with Fluctuating Concentrations", "description": "We present a versatile flow-through tube passive sampling device (TPS), with a controllable feedwater volumetric flow, that can be calibrated in situ against the feedwater load of organic micropollutants (OMPs). This semipassive approach has the advantage of a determinable water load feeding the sampling device. The design of the TPS allows for new sampling scenarios in closed piping while providing stable and controlled sampling conditions. The calibration referencing an OMP's feedwater load can describe the uptake behavior from wastewater treatment plant effluent with potentially highly fluctuating OMP concentrations. The TPS and its load-dependent calibration under realistic environmental conditions proves possible for a variety of organic trace substances in a challenging matrix. Nine of the 20 monitored representative OMPs could be calibrated load-dependently, leading to a good agreement between the calculated concentration from the TPS and the average concentration of corresponding direct measurements. Due to the simple measuring principle and the membrane-less discs, many influencing factors such as diffusion, turbulence, and lag time phenomena can be neglected. The TPS could support the existing online measurement analytics in a (process-) water treatment plant by delivering integrated water concentrations for discharge monitoring.", "keywords": ["fluctuating concentration", "organic micropollutants", "flow-through", "organic contaminants", "load dependent calibration", "wastewater", "passive sampling"], "contacts": [{"organization": "Hensel, Tobias Sebastian, Hein, J\u00f6rg-Helge, Reemtsma, Thorsten, Sperlich, Alexander, Gnirss, Regina, Zietzschmann, Frederik,", "roles": ["creator"]}]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acsestwater.4c00348"}, {"href": "https://doi.org/10.1021/acsestwater.4c00348"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/ACS%20ES%26amp%3BT%20Water", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acsestwater.4c00348", "name": "item", "description": "10.1021/acsestwater.4c00348", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acsestwater.4c00348"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-11-19T00:00:00Z"}}, {"id": "10.1021/acs.est.9b00345", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2019-05-30", "title": "Cathode-Introduced Atomic H* for Fe(II)-Complex Regeneration to Effective Electro-Fenton Process at a Natural pH", "description": "Promotion of iron solubility using ligands is the preliminary step in the homogeneous electro-Fenton (EF) process at a mild pH, but the chelate efficiencies of most organic ligands are unsatisfactory, resulting in insufficient Fe(II) availability. In this study, atomic H* was, for the first time, introduced to the EF process to accelerate the regeneration of the Fe(II)-complex at a mild pH using a Ni-deposited carbon felt (Ni-CF) cathode. The introduction of atomic H* significantly elevated total organic carbon (TOC) abatement of ciprofloxacin (CIP) from 42% (CF) to 81% (Ni-CF) at a natural pH. In the presence of humic acids (HAs), atomic H* introduced via Ni-CF enhanced the CIP degradation rate to 10 times that of the CF at a mild pH. The electron spin resonance (ESR), density functional theory (DFT) calculations, electrochemical characterization, and in situ electrochemical Raman study clearly demonstrated that the atomic H* generated from the Ni-CF cathode was highly efficient at reducing Fe(III)-complexes at a natural pH. Additionally, the Ni-CF could generate atomic H* without significant nickel leaching. Thus, the atomic H* could continuously facilitate iron cycling and, consequently, enhance pollutant mineralization via the homogeneous EF process at a mild pH in an environmentally friendly manner.", "keywords": ["0211 other engineering and technologies", "Ferrous Compounds", "Hydrogen Peroxide", "02 engineering and technology", "Hydrogen-Ion Concentration", "Electrodes", "Ferric Compounds", "Oxidation-Reduction", "01 natural sciences", "Water Pollutants", " Chemical", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Xiao-Cheng Liu, Wen-Qiang Li, Yi-Ran Wang, Guan-Nan Zhou, Yi-Xuan Wang, Chuan-Shu He, Gong-Ming Wang, Yang Mu,", "roles": ["creator"]}]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.9b00345"}, {"href": "https://doi.org/10.1021/acs.est.9b00345"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.9b00345", "name": "item", "description": "10.1021/acs.est.9b00345", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.9b00345"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-05-22T00:00:00Z"}}, {"id": "10.1021/acs.est.9b07324", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2020-05-15", "title": "A novel pathway for chloramphenicol catabolism in the activated sludge bacterial isolate Sphingobium CAP-1", "description": "The chlorinated nitroaromatic antibiotic chloramphenicol (CAP) is a refractory contaminant that is widely present in various environments. However, few CAP-mineralizing bacteria have been documented, and a complete CAP catabolism pathway has yet to be identified. In this study, the bacterial strain Sphingobium sp. CAP-1 was isolated from an activated sludge sample and was shown to be capable of aerobically subsisting on CAP as the sole carbon, nitrogen, and energy source while simultaneously and efficiently degrading CAP. p-Nitrobenzoic acid (PNBA), p-nitrobenzaldehyde (PNBD), protocatechuate (PCA), and the novel side chain C3-hydroxy-oxygenated product of CAP (O-CAP) were identified during CAP degradation. Strain CAP-1 was able to convert O-CAP to intermediate product PNBA. The putative functional genes associated with PNBA catabolism into the tricarboxylic acid cycle via PCA and floc formation were also identified by genome sequencing and comparative proteome analysis. A complete pathway for CAP catabolism was proposed. The discovery of a novel CAP oxidation/detoxification process and a complete pathway for CAP catabolism enriches the fundamental understanding of the bacterial catabolism of antibiotics, providing new insights into the microbial-mediated fate, transformation, and resistance risk of CAP in the environment. The molecular basis of CAP catabolism and floc formation in strain CAP-1 also offers theoretical guidance for the enhanced bioremediation of CAP-containing environments.", "keywords": ["Sphingomonadaceae", "0301 basic medicine", "03 medical and health sciences", "Biodegradation", " Environmental", "Chloramphenicol", "Sewage", "11. Sustainability", "01 natural sciences", "6. Clean water", "Anti-Bacterial Agents", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Xiaodan Ma, Hui Yun, Hui Yun, Shuang-Jiang Liu, Ke Shi, Yuanqiang Guo, Peisheng Yan, Mengyuan Qi, Bin Liang, Bin Liang, Zhiling Li, Aijie Wang, Aijie Wang,", "roles": ["creator"]}]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.9b07324"}, {"href": "https://doi.org/10.1021/acs.est.9b07324"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.9b07324", "name": "item", "description": "10.1021/acs.est.9b07324", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.9b07324"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-05-15T00:00:00Z"}}, {"id": "10.1038/nature02403", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:35Z", "type": "Journal Article", "created": "2004-04-21", "title": "The Worldwide Leaf Economics Spectrum", "description": "Bringing together leaf trait data spanning 2,548 species and 175 sites we describe, for the first time at global scale, a universal spectrum of leaf economics consisting of key chemical, structural and physiological properties. The spectrum runs from quick to slow return on investments of nutrients and dry mass in leaves, and operates largely independently of growth form, plant functional type or biome. Categories along the spectrum would, in general, describe leaf economic variation at the global scale better than plant functional types, because functional types overlap substantially in their leaf traits. Overall, modulation of leaf traits and trait relationships by climate is surprisingly modest, although some striking and significant patterns can be seen. Reliable quantification of the leaf economics spectrum and its interaction with climate will prove valuable for modelling nutrient fluxes and vegetation boundaries under changing land-use and climate.", "keywords": ["leaf traits", "0106 biological sciences", "INVESTMENT", "Climate", "Rain", "CLIMATE CHANGE", "SEED PRODUCTION", "01 natural sciences", "spectrum", "BIOMASS", "dry mass", "Biologie/Milieukunde (BIOL)", "MODELS", " BIOLOGICAL", "CLIMATE EFFECT", "Nutritional Physiological Phenomena", "Biomass", "Photosynthesis", "LAND USE", "PRIORITY JOURNAL", "functional-groups", "biodiversity", "ALLOMETRY", "2. Zero hunger", "INVESTMENTS", "Geography", "BIOME", "HUMAN", "04 agricultural and veterinary sciences", "INFORMATION SCIENCE", "Life sciences", "tree", "NUTRITION PHYSIOLOGY", "leaf economics", "LEAF ECONOMICS SPECTRUM", "leaves", "ECONOMIC AND SOCIAL EFFECTS", "GEOGRAPHY", "Models", " Biological", "photosynthesis-nitrogen relations", "LEAF", "PLANT LEAF", "nutrients", "high-rainfall", "DATA REDUCTION", "NONHUMAN", "PLANT LEAVES", "NUTRIENT AVAILABILITY", "ARTICLE", "PHYSIOLOGY", "Ecosystem", "580", "life-span", "ECONOMICS", "PHOTOSYNTHESIS", "RAIN", "nutrient", "land use", "area", "use efficiency", "15. Life on land", "PLANT GROWTH", "CLIMATE", "Plant Leaves", "SPECTRUM ANALYSIS", "DRY MASS", "ECOSYSTEM", "0401 agriculture", " forestry", " and fisheries", "BIODIVERSITY", "VEGETATION"]}, "links": [{"href": "https://doi.org/10.1038/nature02403"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Nature", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1038/nature02403", "name": "item", "description": "10.1038/nature02403", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1038/nature02403"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2004-04-01T00:00:00Z"}}, {"id": "10.1021/acs.est.9b07092", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2020-02-20", "title": "Direct Visualization of Arsenic Binding on Green Rust Sulfate", "description": "'Green rust' (GR), a redox-active Fe(II)-Fe(III) layered double hydroxide, is a potential environmentally relevant mineral substrate for arsenic (As) sequestration in reduced, subsurface environments. GR phases have high As uptake capacities at circum-neutral pH conditions, but the exact interaction mechanism between the GR phases and As species is still poorly understood. Here, we documented the bonding and interaction mechanisms between GR sulfate and As species [As(III) and As(V)] under anoxic and circum-neutral pH conditions through scanning transmission electron microscopy (STEM) coupled with energy-dispersive X-ray (EDX) spectroscopy and combined it with synchrotron-based X-ray total scattering, pair distribution function (PDF) analysis, and As K-edge X-ray absorption spectroscopy (XAS). Our highly spatially resolved STEM-EDX data revealed that the preferred adsorption sites of both As(III) and As(V) are at GR crystal edges. Combining this data with differential PDF and XAS allowed us to conclude that As adsorption occurs primarily as bidentate binuclear (2C) inner-sphere surface complexes. In the As(III)-reacted GR sulfate, no secondary Fe-As phases were observed. However, authigenic parasymplesite (ferrous arsenate nanophase), exhibiting a threadlike morphology, formed in the As(V)-reacted GR sulfate and acts as an additional immobilization pathway for As(V) (\u223c87% of immobilized As). We demonstrate that only by combining high-resolution STEM imaging and EDX mapping with the bulk (differential) PDF and extended X-ray absorption fine structure (EXAFS) data can one truly determine the de facto As binding nature on GR surfaces. More importantly, these new insights into As-GR interaction mechanisms highlight the impact of GR phases on As sequestration in anoxic subsurface environments.", "keywords": ["X-Ray Absorption Spectroscopy", "Sulfates", "Adsorption", "540", "Ferric Compounds", "01 natural sciences", "6. Clean water", "Arsenic", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://eprints.whiterose.ac.uk/157636/1/acs.est.9b07092.pdf"}, {"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.9b07092"}, {"href": "https://doi.org/10.1021/acs.est.9b07092"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.9b07092", "name": "item", "description": "10.1021/acs.est.9b07092", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.9b07092"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-02-20T00:00:00Z"}}, {"id": "10.1021/acs.jafc.3c04532", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2023-10-05", "title": "Ultra-high Performance Liquid Chromatography\u2013Ion Mobility\u2013High-Resolution Mass Spectrometry to Evaluate the Metabolomic Response of Durum Wheat to Sustainable Treatments", "description": "Sustainable agriculture aims at achieving a healthy food production while reducing the use of fertilizers and greenhouse gas emissions using biostimulants and soil amendments. Untargeted metabolomics by ultra-high performance liquid chromatography-ion mobility-high-resolution mass spectrometry, operating in a high-definition MSE mode, was applied to investigate the metabolome of durum wheat in response to sustainable treatments, i.e., the addition of biochar, commercial plant growth promoting microbes, and their combination. Partial least squares-discriminant analysis provided a good discrimination among treatments with sensitivity, specificity, and a non-error rate close to 1. A total of 88 and 45 discriminant compounds having biological, nutritional, and technological implications were tentatively identified in samples grown in 2020 and 2021. The addition of biochar-biostimulants produced the highest up-regulation of lipids and flavonoids, with the glycolipid desaturation being the most impacted pathway, whereas carbohydrates were mostly down-regulated. The findings achieved suggest the safe use of the combined biochar-biostimulant treatment for sustainable wheat cultivation.", "keywords": ["2. Zero hunger", "Settore CHEM-01/A - Chimica analitica", "630", "Mass Spectrometry", "12. Responsible consumption", "ultra-high performance liquid chromatography\u2212high-resolution mass spectrometry ion mobility untargeted metabolomics multivariate data analysis durum wheat biostimulants soil amendments", "13. Climate action", "Settore AGRI-06/A - Genetica agraria", "615", "Metabolomics", "ultra-high performance liquid chromatography\u2013high-resolution mass spectrometry ion mobility untargeted metabolomics multivariate data analysis durum wheat biostimulants soil amendments", "Settore BIOS-10/A - Biologia cellulare e applicata", "Chromatography", " High Pressure Liquid", "Triticum"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.jafc.3c04532"}, {"href": "https://doi.org/10.1021/acs.jafc.3c04532"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Agricultural%20and%20Food%20Chemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.jafc.3c04532", "name": "item", "description": "10.1021/acs.jafc.3c04532", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.jafc.3c04532"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-10-05T00:00:00Z"}}, {"id": "10.1021/acs.jafc.5c02128", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2025-03-27", "title": "Enhancing Zinc Bioavailability in Rice Using the Novel Synthetic Siderophore Ligand Proline-2\u2032-Deoxymugineic Acid (PDMA): Critical Insights from Metal Binding Studies and Geochemical Speciation Modeling", "description": "Bioavailable ligands that bind metals mediate their uptake in plants, leading to the study of artificial ligands as potential fertilizers. Proline-2'-deoxymugineic acid (PDMA) has shown a high affinity for FeIII, enhancing iron uptake in rice and suggesting that it could be used for improving zinc uptake. This work studied chemical solution parameters, i.e., redox potential, ion strength, pH, and ligand/metal concentrations controlling ZnII-PDMA complex formation in rice-producing soils using geochemical speciation modeling. We show that PDMA is generally selective for ZnII in reducing, saline, and alkaline soil solutions. Comparison with a recent micronutrient uptake study in rice suggests that free PDMA should be added in reducing conditions to avoid competition with CuII and FeIII or as the ZnII-PDMA complex at pH below 9. The Zn/M ratios (M = CuII, FeIII) needed to form stable ZnII-PDMA complexes were also identified. This study shows the promise of PDMA as a fertilizer to overcome zinc deficiencies in alkaline and flooded soils.", "keywords": ["Zinc", "Soil", "Proline", "Iron", "Siderophores", "Biological Availability", "Oryza", "Hydrogen-Ion Concentration", "Ligands", "Fertilizers", "Azetidinecarboxylic Acid"]}, "links": [{"href": "https://doi.org/10.1021/acs.jafc.5c02128"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Agricultural%20and%20Food%20Chemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.jafc.5c02128", "name": "item", "description": "10.1021/acs.jafc.5c02128", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.jafc.5c02128"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2025-03-27T00:00:00Z"}}, {"id": "10.1021/acs.jpcb.6b05104", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2016-07-26", "title": "Effect of Surface and Salt Properties on the Ion Distribution around Spherical Nanoparticles: Monte Carlo Simulations", "description": "Nanoparticle surface charge properties represent key parameters to predict their fate, reactivity, and complexation in natural, biological, and industrial dispersions. In this context, we present here an original approach to better understand the surface charge electrostatic properties of spherical nanoparticles (NPs). The ion distribution around one nanoparticle is investigated using Monte Carlo simulations and by adjusting a wide range of parameters including NP properties (surface charge density and site distribution), salt concentration (ionic strength and cation concentration), and salt valency (mono-, di-, and trivalent salt). A canonical Metropolis Monte Carlo method is used to reach equilibrium states and a primitive Coulomb model is applied to describe the electrostatic interactions between explicit discrete sites, counterions, and salt particles. Our results show that the presence of explicit surface charges on the NP and in solution has a strong influence on the local ion distribution and on the effective surface charge of the nanoparticles. The increase of surface charge density reduces the NP effective charge by the formation of a condensation layer around the nanoparticle. However, a limit of condensation is achieved due to steric effects and electrostatic repulsions. The presence of di- and trivalent cations is also found to strongly modify the effective charge and improve condensation state as long as electrostatic repulsion between the cations close to the surface are not so strong. At high trivalent cation concentration, the NP effective charge is greatly reduced and the local environment around the nanoparticle becomes more structured with the formation of a multi layer structure composed by anions and cations.", "keywords": ["ddc:333.7-333.9", "info:eu-repo/classification/ddc/333.7-333.9", "info:eu-repo/classification/ddc/550", "ddc:550", "02 engineering and technology", "0210 nano-technology", "01 natural sciences", "0104 chemical sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.jpcb.6b05104"}, {"href": "https://doi.org/10.1021/acs.jpcb.6b05104"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/The%20Journal%20of%20Physical%20Chemistry%20B", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.jpcb.6b05104", "name": "item", "description": "10.1021/acs.jpcb.6b05104", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.jpcb.6b05104"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-08-09T00:00:00Z"}}, {"id": "10.1021/acs.nanolett.0c00091", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2020-03-10", "title": "Polarization-Controlled Plasmonic Structured Illumination", "description": "Structured light in the subwavelength scale is important for a broad range of applications ranging from lithography to imaging. Of particular importance is the ability to dynamically shift the pattern of the fields, which has led to the development of structured illumination microscopy. Further extension of structured illumination to plasmonic systems has enabled imaging beyond diffraction limit. However, structured illumination usually requires complicated optical setups entailing moving mechanical parts. Here a polarization tunable structured plasmonic field (SPF) is proposed and experimentally demonstrated. The SPF is formed by surface plasmon interference (SPI) generated by a fishbone-shaped metasurface on a thin gold film. Importantly, the SPF can be continuously shifted by merely varying the linear polarization state of an incident beam. The precise control of the fringes of structured illumination and elimination of mechanical control will have great potential in subdiffractional imaging for practical applications.", "keywords": ["02 engineering and technology", "0210 nano-technology"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.nanolett.0c00091"}, {"href": "https://doi.org/10.1021/acs.nanolett.0c00091"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Nano%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.nanolett.0c00091", "name": "item", "description": "10.1021/acs.nanolett.0c00091", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.nanolett.0c00091"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-03-10T00:00:00Z"}}, {"id": "20.500.11850/678052", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-04-03T16:27:44Z", "type": "Report", "title": "Iron Oxyhydroxide Transformation in a Flooded Rice Paddy Field and the Effect of Adsorbed Phosphate", "description": "Open AccessISSN:0013-936X", "keywords": ["ferrihydrite; lepidocrocite; Mossbauer; iron reduction; microsite; Fe(II)-catalyzed; isotope"], "contacts": [{"organization": "Schulz, Katrin; id_orcid0000-0001-9608-0882, Wisawapipat, Worachart, Barmettler, Kurt, Grigg, Andrew R.C., Kubeneck, Luisa Jo\u00eblle; id_orcid0000-0003-1894-6809, Notini de Andrade, Luiza; id_orcid0000-0003-2972-6588, ThomasArrigo, Laurel K., Kretzschmar, Ruben; id_orcid0000-0003-2587-2430,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/20.500.11850/678052"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.11850/678052", "name": "item", "description": "20.500.11850/678052", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.11850/678052"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-06-18T00:00:00Z"}}, {"id": "10.1021/acs.jafc.9b06429", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2020-02-24", "title": "High-Throughput Screening for Engineered Nanoparticles That Enhance Photosynthesis Using Mesophyll Protoplasts", "description": "Certain engineered nanoparticles (NPs) have unique properties that have exhibited significant potential for promoting photosynthesis and enhancing crop productivity. Understanding the fundamental interactions between NPs and plants is crucial for the sustainable development of nanoenabled agriculture. Leaf mesophyll protoplasts, which maintain similar physiological response and cellular activity as intact plants, were selected as a model system to study the impact of NPs on photosynthesis. The mesophyll protoplasts isolated from spinach were cultivated with different NMs (Fe, Mn3O4, SiO2, Ag, and MoS2) dosing at 50 mg/L for 2 h under illumination. The potential maximum quantum yield and adenosine triphosphate (ATP) production of mesophyll protoplasts were significantly increased by Mn3O4 and Fe NPs (23% and 43%, respectively), and were decreased by Ag and MoS2 NPs. The mechanism for the photosynthetic enhancement by Mn3O4 and Fe is to increase the photocurrent and electron transfer rate, as revealed by photoelectrochemical measurement. GC-MS based single cell type metabolomics reveal that NPs (Fe and MoS2) altered the metabolic profiles of mesophyll cells during 2 h of illumination period. Separately, the effect of NPs exposure on photosynthesis and biomass were also conducted at the whole plant level. A strong correlation was observed with protoplast data; plant biomass was significantly increased by Mn3O4 exposure (57%) but was decreased (24%) by treatment of Ag NPs. The use of mesophyll protoplasts can be a fast and reliable tool for screening NPs to enhance photosynthesis for potential nanofertilizer use. Importantly, inclusion of a metabolic analysis can provide mechanistic toxicity data to ensure the development 'safer-by-design' nanoenabled platforms.", "keywords": ["0301 basic medicine", "2. Zero hunger", "0303 health sciences", "03 medical and health sciences", "Protoplasts", "Nanoparticles", "Photosynthesis", "Silicon Dioxide", "High-Throughput Screening Assays"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.jafc.9b06429"}, {"href": "https://doi.org/10.1021/acs.jafc.9b06429"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Agricultural%20and%20Food%20Chemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.jafc.9b06429", "name": "item", "description": "10.1021/acs.jafc.9b06429", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.jafc.9b06429"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-02-24T00:00:00Z"}}, {"id": "10.1021/acs.jpcc.2c04828", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2022-08-19", "title": "Madelung Formalism for Electron Spill-Out in Nonlocal Nanoplasmonics", "description": "Current multiscale plasmonic systems pose a modeling challenge. Classical macroscopic theories fail to capture quantum effects in such systems, whereas quantum electrodynamics is impractical given the total size of the experimentally relevant systems, as the number of interactions is too large to be addressed one by one. To tackle the challenge, in this paper we propose to use the Madelung form of the hydrodynamic Drude model, in which the quantum effect electron spill-out is incorporated by describing the metal-dielectric interface using a super-Gaussian function. The results for a two-dimensional nanoplasmonic wedge are correlated to those from nonlocal full-wave numerical calculations based on a linearized hydrodynamic Drude model commonly employed in the literature, showing good qualitative agreement. Additionally, a conformal transformation perspective is provided to explain qualitatively the findings. The methodology described here may be applied to understand, both numerically and theoretically, the modular inclusions of additional quantum effects, such as electron spill-out and nonlocality, that cannot be incorporated seamlessly by using other approaches.", "keywords": ["0103 physical sciences", "02 engineering and technology", "0210 nano-technology", "01 natural sciences"], "contacts": [{"organization": "Alves, R\u00faben A., Pacheco-Pe\u00f1a, V\u00edctor, Navarro-C\u00eda, Miguel,", "roles": ["creator"]}]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.2c04828"}, {"href": "https://eprints.ncl.ac.uk/fulltext.aspx?url=300384/889C4E35-FE1D-401D-88C7-A7925000D2D6.pdf&pub_id=300384"}, {"href": "https://doi.org/10.1021/acs.jpcc.2c04828"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/The%20Journal%20of%20Physical%20Chemistry%20C", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.jpcc.2c04828", "name": "item", "description": "10.1021/acs.jpcc.2c04828", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.jpcc.2c04828"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-08-19T00:00:00Z"}}, {"id": "10.1021/acs.nanolett.0c03613", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2020-11-19", "title": "Hybrid Metal-Dielectric Metasurfaces for Refractive Index Sensing", "description": "Hybrid metal-dielectric nanostructures have recently gained prominence because they combine strong field enhancement of plasmonic metals and the several low-loss radiation channels of dielectric resonators, which are qualities pertaining to the best of both worlds. In this work, an array of such hybrid nanoantennas is successfully fabricated over a large area and utilized for bulk refractive index sensing with a sensitivity of 208 nm/RIU. Each nanoantenna combines a Si cylinder with an Al disk, separated by a SiO2 spacer. Its optical response is analyzed in detail using the multipoles supported by its subparts and their mutual coupling. The nanoantenna is further modified experimentally with an undercut in the SiO2 region to increase the interaction of the electric field with the background medium, which augments the sensitivity to 245 nm/RIU. A detailed multipole analysis of the hybrid nanoantenna supports our experimental findings.", "keywords": ["bulk refractive index sensing", "undercut", "LSPR", "02 engineering and technology", "0210 nano-technology", "hybridization", "Hybrid nanoantenna"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.nanolett.0c03613"}, {"href": "https://doi.org/10.1021/acs.nanolett.0c03613"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Nano%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.nanolett.0c03613", "name": "item", "description": "10.1021/acs.nanolett.0c03613", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.nanolett.0c03613"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-11-18T00:00:00Z"}}, {"id": "10.1021/acsaem.2c02012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2022-09-21", "title": "Tuning the Thermoelectric Performance of CaMnO3-Based Ceramics by Controlled Exsolution and Microstructuring", "description": "The thermoelectric properties of CaMnO3-\u03b4/CaMn2O4 composites were tuned via microstructuring and compositional adjustment. Single-phase rock-salt-structured CaO-MnO materials with Ca:Mn ratios larger than unity were produced in reducing atmosphere and subsequently densified by spark plasma sintering in vacuum. Annealing in air at 1340 \u00b0C between 1 and 24 h activated redox-driven exsolution and resulted in a variation in microstructure and CaMnO3-\u03b4 materials with 10 and 15 vol % CaMn2O4, respectively. The nature of the CaMnO3-\u03b4/CaMn2O4 grain boundary was analyzed by transmission electron microscopy on short- and long-term annealed samples, and a sharp interface with no secondary phase formation was indicated in both cases. This was further complemented by density functional theory (DFT) calculations, which confirmed that the CaMnO3-\u03b4 indeed is a line compound. DFT calculations predict segregation of oxygen vacancies from the bulk of CaMnO3-\u03b4 to the interface between CaMnO3-\u03b4 and CaMn2O4, resulting in an enhanced electronic conductivity of the CaMnO3-\u03b4 phase. Samples with 15 vol % CaMn2O4 annealed for 24 h reached the highest electrical conductivity of 73 S\u00b7cm-1 at 900 \u00b0C. The lowest thermal conductivity was obtained for composites with 10 vol % CaMn2O4 annealed for 8 h, reaching 0.56 W\u00b7m-1K-1 at 700 \u00b0C. However, the highest thermoelectric figure-of-merit, zT, was obtained for samples with 15 vol % CaMn2O4 reaching 0.11 at temperatures between 800 and 900 \u00b0C, due to the enhanced power factor above 700 \u00b0C. This work represents an approach to boost the thermoelectric performance of CaMnO3-\u03b4 based composites.", "keywords": ["oxide thermoelectrics", "Dewey Decimal Classification::500 | Naturwissenschaften::540 | Chemie", "composite CaMnO 3-\u03b4", "electrical conductivity", "thermal conductivity", "02 engineering and technology", "0210 nano-technology", "01 natural sciences", "heterostructuring", "0104 chemical sciences"]}, "links": [{"href": "https://doi.org/10.1021/acsaem.2c02012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/ACS%20Applied%20Energy%20Materials", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acsaem.2c02012", "name": "item", "description": "10.1021/acsaem.2c02012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acsaem.2c02012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-09-21T00:00:00Z"}}, {"id": "20.500.11850/711438", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:27:45Z", "type": "Journal Article", "created": "2023-11-28", "title": "Microplastic Analysis in Soils: A Comparative Assessment", "description": "Microplastic (MiP) contamination poses environmental risks, but harmonizing data from different quantification methods and sample matrices remains challenging. We compared analytical protocols for MiP quantification in soil, consisting of Digital, Fluorescence, Fourier-transform infrared (FTIR), and Raman Microscopy as well as quantitative Pyrolysis-Gas Chromatography-Mass Spectroscopy (Py-GC-MS) and 1-proton nuclear magnetic resonance (1H NMR) spectroscopy as detection techniques. Each technique was coupled with a specific extraction procedure and evaluated for three soils with different textures and organic carbon contents, amended with eight types of large MiPs (0.5\u20131 mm) \u2013 high- and low-density polyethylene (HDPE and LDPE), polypropylene (PP), polystyrene (PS), polyamide (PA), polyethylene terephthalate (PET), polyvinyl chloride (PVC), and a biodegradable mulch film product composed of polybutylene adipate-co-terephthalate/ polylactic acid (PBAT/ PLA). In addition, we included two types of small MiPs (20\u2013250 \u00b5m) composed of either LDPE or PBAT/ PLA in the tests. The results showed that protocols for Digital, Fluorescence, and ATR-FTIR microscopy recovered 74\u201398 % of the large MiPs, with fluorescence yielding the highest recoveries. Raman spectroscopy was most sensitive to soil organic matter residues, requiring more sophisticated sample pretreatment. Fluorescence staining with subsequent Fluorescence microscopy detection effectively recovered most small-sized LDPE-MiP but missed 56\u201393 % of small PBAT/ PLA particles. For the latter, reliable quantification was achieved only using Soxhlet extraction combined with 1H NMR spectroscopic quantification. Pyrolysis-GC-MS showed intermediate results, displaying low sensitivity to plastic type and lower recoveries as soil clay content increased. We conclude that different methods have different sensitivities for different MiP materials in different soils, i.e. comparisons of MiP loads and threshold settings for MiP loads across methodologies require careful consideration. Yet, our data indicate that adding stained large MiP as an internal standard could enhance extraction control, while Soxhlet-extraction with subsequent 1H NMR analysis is most powerful for controlling future thresholds of small MiP from biodegradable materials.", "keywords": ["ddc:550", "Soil pollution", "Spectroscopy; Soil pollution; Conventional synthetic and biodegradable; polymers", "Conventional synthetic and biodegradable", "Environmental pollution", "543", "Environmental sciences", "TD172-193.5", "628", "Life Science", "GE1-350", "Conventional synthetic and biodegradable polymers", "Spectroscopy", "polymers"]}, "links": [{"href": "https://doi.org/20.500.11850/711438"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Ecotoxicology%20and%20Environmental%20Safety", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.11850/711438", "name": "item", "description": "20.500.11850/711438", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.11850/711438"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-01-01T00:00:00Z"}}, {"id": "10.1021/acsaelm.4c02334", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2025-04-23", "title": "High-Sensitivity Solution-Processed Organic Phototransistor Based on a Bulk Heterojunction with a Persistent Radical as the Electron Acceptor", "description": "In bilayer organic phototransistors (OPTs), charge transport and light-sensing functionalities are separately performed and optimized in two different layers. For optimizing the sensitivity of solution-processed bilayer OPTs, the approach of using a donor-acceptor bulk heterojunction (BHJ) as the light-sensing layer is well established in the literature, but the choice of the electron-accepting materials is often limited to fullerene-soluble derivatives or to standard nonfullerene acceptors. Herein, we report the unprecedented use of an organic persistent radical as an electron acceptor in the BHJ light-sensing layer of solution-processed bilayer OPTs. The radical acceptor is coupled at different donor:acceptor ratios to a low-band-gap polymer that absorbs in the near-infrared (NIR) region. At a donor:acceptor ratio of 1:3, the organic radical forms isolated domains within the BHJ. Such a morphology, coupled with the strong electron-accepting characteristics of the radical, leads to efficient trapping of electrons and efficient hole transport within the BHJ, as measured in charge-selective devices operated in the space-charge limited current (SCLC) range. This, together with the chemical and photostability of the persistent radical, allows us to obtain an OPT with photosensitivity (P) of 1 \u00d7 105 in response to NIR irradiation at 2 mW/cm2 and excellent photostability over time.", "keywords": ["electron trapping; electron-only device; photogain; photosensitivity; radical acceptor; solution-processed organic phototransistor;"]}, "links": [{"href": "https://boa.unimib.it/bitstream/10281/553298/1/Baroni-et-al-2025-ACS%20Applied%20Electronic%20Materials-VoR.pdf"}, {"href": "https://doi.org/10.1021/acsaelm.4c02334"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/ACS%20Applied%20Electronic%20Materials", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acsaelm.4c02334", "name": "item", "description": "10.1021/acsaelm.4c02334", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acsaelm.4c02334"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2025-04-23T00:00:00Z"}}, {"id": "10.1021/acsanm.3c01382", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2023-06-05", "title": "Directed Assembly of Au Nanostar@Ag Satellite Nanostructures for SERS-Based Sensing of Hg2+ Ions", "description": "Embedding Raman reporters within nanosized gaps of metallic nanoparticles is an attractive route for surface-enhanced Raman spectroscopy (SERS) applications, although often this involves complex synthesis procedures that limit their practical use. Herein, we present the tip-selective direct growth of silver satellites surrounding gold nanostars (AuNSt@AgSAT), mediated by a dithiol Raman reporter 1,4-benzenedithiol (BDT). We propose that BDT is embedded within nanogaps which form between the AuNSt tips and the satellites, and plays a key role in mediating the satellite growth. Not only proposing a rationale for the mechanistic growth of the AuNSt@AgSAT, we also demonstrate an example for its use for the detection of Hg2+ ions in water. The presence of Hg2+ resulted in amalgamation of the AuNSt@AgSAT, which altered both its structural morphology and Raman enhancement properties. This provides a basis for the detection where the Raman intensity of BDT is inversely proportional to the Hg2+ concentrations. As a result, Hg2+ could be detected at concentrations as low as 0.1 ppb. This paper not only provides important mechanistic insight into the tip-selective direct growth of the anisotropic nanostructure but also proposes its excellent Raman enhancement capability for bioimaging as well as biological and chemical sensing applications.", "keywords": ["directed assembly", "name=SDG 6 - Clean Water and Sanitation", "SERS", "/dk/atira/pure/sustainabledevelopmentgoals/clean_water_and_sanitation; name=SDG 6 - Clean Water and Sanitation", "540", "name=SDG 3 - Good Health and Well-being", "/dk/atira/pure/sustainabledevelopmentgoals/clean_water_and_sanitation", "620", "name=SDG 13 - Climate Action", "/dk/atira/pure/sustainabledevelopmentgoals/climate_action", "/dk/atira/pure/sustainabledevelopmentgoals/good_health_and_well_being", "gold nanostars", "/dk/atira/pure/sustainabledevelopmentgoals/climate_action; name=SDG 13 - Climate Action", "mercury detection", "/dk/atira/pure/sustainabledevelopmentgoals/good_health_and_well_being; name=SDG 3 - Good Health and Well-being", "nanogap"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acsanm.3c01382"}, {"href": "https://doi.org/10.1021/acsanm.3c01382"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/ACS%20Applied%20Nano%20Materials", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acsanm.3c01382", "name": "item", "description": "10.1021/acsanm.3c01382", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acsanm.3c01382"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-06-05T00:00:00Z"}}, {"id": "10.1021/es061765v", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:17Z", "type": "Journal Article", "created": "2007-03-29", "title": "Interactions Between Elevated Co2 And Warming Could Amplify Doc Exports From Peatland Catchments", "description": "Peatlands export more dissolved organic carbon (DOC) than any other biome, contributing 20% of all terrestrial DOC exported to the oceans. Both warming and elevated atmospheric CO2 (eCO2) can increase DOC exports, but their interaction is poorly understood. Peat monoliths were, therefore, exposed to eCO2, warming and eCO2 + warming (combined). The combined treatment produced a synergistic (i.e., significant interaction) rise in DOC concentrations available for export (119% higher than the control, interaction P < 0.05) and enriched this pool with phenolic compounds (284%). We attribute this to increased plant inputs, coupled with impaired microbial degradation induced by competition with the vegetation for nutrients and inhibitory phenolics. Root biomass showed a synergistic increase (407% relative to the control, P < 0.1 only), while exudate inputs increased additively. Phenol oxidase was suppressed synergistically (58%, interaction P < 0.1 only) and beta-glucosidase (27%) additively, while microbial nutritional stress increased (51%) additively. Such results suggest intensified carbon exports from peatlands, with potentially widespread ramifications for aquatic processes in the receiving waters.", "keywords": ["Nitrogen", "litter decomposition", "Bryophyta", "01 natural sciences", "sphagnum", "soil", "Magnoliopsida", "Soil", "Phenols", "0105 earth and related environmental sciences", "Monophenol Monooxygenase", "beta-Glucosidase", "Temperature", "temperature", "04 agricultural and veterinary sciences", "Carbon Dioxide", "15. Life on land", "dissolved organic carbon", "matter", "Carbon", "Phosphoric Monoester Hydrolases", "6. Clean water", "enzyme", "bog", "13. Climate action", "community", "0401 agriculture", " forestry", " and fisheries"]}, "links": [{"href": "https://doi.org/10.1021/es061765v"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/es061765v", "name": "item", "description": "10.1021/es061765v", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/es061765v"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2007-03-29T00:00:00Z"}}, {"id": "10.1021/acsmeasuresciau.3c00027", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:17Z", "type": "Journal Article", "created": "2023-09-08", "title": "Evaluation of Pure PFAS Decrease in Controlled Settings", "description": "Since 1940, poly- or perfluorinated alkyl substances (PFAS) have been largely used in many applications, including paints, fire foaming, household items, product packaging, and fabrics. Because of their extremely high persistency, they have been defined as 'forever chemicals'. Although the EU is taking action to reduce their use, their widespread occurrence in environmental matrices and their harmful effects on human health require the use of highly performing analytical methods for efficient monitoring. Furthermore, novel PFAS are constantly revealed by both EU and National environmental agencies. The objective of this work is to investigate the cause of the signal decrease during the analysis of a standard PFAS mixture in water-based matrices, by proposing an efficient technical procedure for laboratory specialists. The analyses were carried out on a mixture of 30 PFAS, including both regulated and unknown substances (which are expected to be introduced in the guidelines), characterized by different chemical features, using LC-vials of two different materials, namely, glass and polypropylene, and dissolved in two solvents, namely, water and water-methanol. The temperature of analysis and the concentration of PFAS were also considered through LC-MS analyses at different times, in the 0-15 h range. Depending on the chemical structure and length of the PFAS, sampling and treatment procedures may be adopted to tackle the decrease and the release from the containers, reducing the risk of underestimating PFAS also in real water matrices.", "keywords": ["pfas; mass spectrometry; adsorption; drinking water; containers", "QD71-142", "Analytical chemistry"]}, "links": [{"href": "https://iris.uniroma1.it/bitstream/11573/1696744/1/Mancini_Evaluation_2023.pdf"}, {"href": "https://pubs.acs.org/doi/pdf/10.1021/acsmeasuresciau.3c00027"}, {"href": "https://doi.org/10.1021/acsmeasuresciau.3c00027"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/ACS%20Measurement%20Science%20Au", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acsmeasuresciau.3c00027", "name": "item", "description": "10.1021/acsmeasuresciau.3c00027", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acsmeasuresciau.3c00027"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-09-07T00:00:00Z"}}, {"id": "10.1021/acsomega.4c01599", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-04-03T16:18:17Z", "type": "Journal Article", "created": "2024-05-09", "title": "Single-Walled Carbon Nanotube-Modified Gold Leaf Immunosensor for Escherichia coli Detection", "description": "The requirement to prevent foodborne illnesses underscores the need for reliable detection tools, stimulating biosensor technology with practical solutions for in-field applications. This study introduces a low-cost immunosensor based on a single-walled carbon nanotube (SWCNT)-modified gold leaf electrode (GLE) for the sensitive detection of Escherichia coli. The immunosensor is realized with a layer-by-layer (LbL) assembly technique, creating an electrostatic bond between positively charged polyethylenimine (PEI) and negatively charged carboxyl-functionalized SWCNTs on the GLE. The structural and functional characterization of the PEI-SWCNT film was performed with Raman spectroscopy, high-resolution scanning electron microscopy (HRSEM), and electrical measurements. The PEI-SWCNT film was used as a substrate for antibody immobilization, and the electrochemical sensing potential was validated using electrochemical impedance spectroscopy (EIS). The results showed a wide dynamic range of E. coli detection, 101-108 cfu/mL, with a limit of detection (LOD) of 1.6 cfu/mL in buffer and 15 cfu/mL in the aqueous solution used for cleansing fresh lettuce leaves, affirming its efficiency as a practical and affordable tool in enhancing food safety.", "keywords": ["Chemistry", "QD1-999"]}, "links": [{"href": "https://doi.org/10.1021/acsomega.4c01599"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/ACS%20Omega", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acsomega.4c01599", "name": "item", "description": "10.1021/acsomega.4c01599", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acsomega.4c01599"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-05-09T00:00:00Z"}}, {"id": "10.1021/acsphotonics.0c01030", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:17Z", "type": "Journal Article", "created": "2020-09-14", "title": "Dielectric Metasurfaces Enabling Advanced Optical Biosensors", "description": "Dielectric metasurfaces have emerged as a powerful platform for novel optical biosensors. Due to their low optical loss and strong light\u2013matter interaction, they demonstrate several exotic optical ...", "keywords": ["02 engineering and technology", "0210 nano-technology", "01 natural sciences", "0104 chemical sciences"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acsphotonics.0c01030"}, {"href": "https://doi.org/10.1021/acsphotonics.0c01030"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/ACS%20Photonics", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acsphotonics.0c01030", "name": "item", "description": "10.1021/acsphotonics.0c01030", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acsphotonics.0c01030"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-09-14T00:00:00Z"}}], "links": [{"rel": "self", "type": "application/geo+json", "title": "This document as GeoJSON", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=-&offset=1500&f=json", "hreflang": "en-US"}, {"rel": "alternate", "type": "text/html", "title": "This document as HTML", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=-&offset=1500&f=html", "hreflang": "en-US"}, {"rel": "collection", "type": "application/json", "title": "Collection URL", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main", "hreflang": "en-US"}, {"type": "application/geo+json", "rel": "prev", "title": "items (prev)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=-&offset=1450", "hreflang": "en-US"}, {"rel": "next", "type": "application/geo+json", "title": "items (next)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=-&offset=1550", "hreflang": "en-US"}], "numberMatched": 11236, "numberReturned": 50, "distributedFeatures": [], "timeStamp": "2026-04-04T11:51:06.756657Z"}