Metasurfaces have emerged as a breakthrough platform for manipulating light at the nanoscale and enabling on\uffe2\uff80\uff90demand optical functionalities for next\uffe2\uff80\uff90generation biosensing, imaging, and light\uffe2\uff80\uff90generating photonic devices. However, translating this technology to practical applications requires low\uffe2\uff80\uff90cost and high\uffe2\uff80\uff90throughput fabrication methods. Due to the limited choice of materials with suitable optical properties, it is particularly challenging to produce metasurfaces for the technologically relevant mid\uffe2\uff80\uff90infrared spectral range. These constraints are overcome by realizing functional metasurfaces on almost completely transparent free\uffe2\uff80\uff90standing metal\uffe2\uff80\uff90oxide membranes. A versatile nanofabrication process is developed and implemented for highly efficient dielectric and plasmonic mid\uffe2\uff80\uff90infrared metasurfaces with wafer\uffe2\uff80\uff90scale and complementary metal\uffe2\uff80\uff93oxide\uffe2\uff80\uff93semiconductor (CMOS)\uffe2\uff80\uff90compatible manufacturing techniques. The advantages of this method are revealed by demonstrating highly uniform and functional metasurfaces, including high\uffe2\uff80\uff90Q structures enabling fine spectral selectivity, large\uffe2\uff80\uff90area metalenses\uffc2\uffa0with\uffc2\uffa0diffraction\uffe2\uff80\uff90limited focusing capabilities, and birefringent metasurfaces providing polarization control at record\uffe2\uff80\uff90high conversion efficiencies.\uffc2\uffa0 Aluminum plasmonic devices and their integration into microfluidics for real\uffe2\uff80\uff90time and label\uffe2\uff80\uff90free mid\uffe2\uff80\uff90infrared biosensing of proteins and lipid vesicles are further demonstrated. The versatility of this approach and its compatibility with mass\uffe2\uff80\uff90production processes bring infrared metasurfaces markedly closer to commercial applications, such as thermal imaging, spectroscopy, and biosensing.Metasurfaces have emerged as a breakthrough platform for manipulating light at the nanoscale and enabling on\uffe2\uff80\uff90demand optical functionalities for next\uffe2\uff80\uff90generation biosensing, imaging, and light\uffe2\uff80\uff90generating photonic devices. However, translating this technology to practical applications requires low\uffe2\uff80\uff90cost and high\uffe2\uff80\uff90throughput fabrication methods. Due to the limited choice of materials with suitable optical properties, it is particularly challenging to produce metasurfaces for the technologically relevant mid\uffe2\uff80\uff90infrared spectral range. These constraints are overcome by realizing functional metasurfaces on almost completely transparent free\uffe2\uff80\uff90standing metal\uffe2\uff80\uff90oxide membranes. A versatile nanofabrication process is developed and implemented for highly efficient dielectric and plasmonic mid\uffe2\uff80\uff90infrared metasurfaces with wafer\uffe2\uff80\uff90scale and complementary metal\uffe2\uff80\uff93oxide\uffe2\uff80\uff93semiconductor (CMOS)\uffe2\uff80\uff90compatible manufacturing techniques. The advantages of this method are revealed by demonstrating highly uniform and functional metasurfaces, including high\uffe2\uff80\uff90Q structures enabling fine spectral selectivity, large\uffe2\uff80\uff90area metalenses\uffc2\uffa0with\uffc2\uffa0diffraction\uffe2\uff80\uff90limited focusing capabilities, and birefringent metasurfaces providing polarization control at record\uffe2\uff80\uff90high conversion efficiencies.\uffc2\uffa0 Aluminum plasmonic devices and their integration into microfluidics for real\uffe2\uff80\uff90time and label\uffe2\uff80\uff90free mid\uffe2\uff80\uff90infrared biosensing of proteins and lipid vesicles are further demonstrated. The versatility of this approach and its compatibility with mass\uffe2\uff80\uff90production processes bring infrared metasurfaces markedly closer to commercial applications, such as thermal imaging, spectroscopy, and biosensing.5) and coarser texture were associated with higher Cd concentration and Cd uptake by T. caerulescens.", "keywords": ["04 agricultural and veterinary sciences", "Hydrogen-Ion Concentration", "15. Life on land", "01 natural sciences", "Carbon", "6. Clean water", "Thlaspi", "Soil", "Zinc", "Clay", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Aluminum Silicates", "Biomass", "Plant Shoots", "Cadmium", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.envpol.2005.03.013"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envpol.2005.03.013", "name": "item", "description": "10.1016/j.envpol.2005.03.013", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envpol.2005.03.013"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2006-01-01T00:00:00Z"}}, {"id": "10.1016/j.envpol.2005.10.017", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-23T16:15:58Z", "type": "Journal Article", "created": "2005-11-30", "title": "Field Evaluation Of In Situ Remediation Of A Heavy Metal Contaminated Soil Using Lime And Red-Mud", "description": "We evaluated the effectiveness of lime and red mud (by-product of aluminium manufacturing) to reduce metal availability to Festuca rubra and to allow re-vegetation on a highly contaminated brown-field site. Application of both lime and red mud (at 3 or 5%) increased soil pH and decreased metal availability. Festuca rubra failed to establish in the control plots, but grew to a near complete vegetative cover on the amended plots. The most effective treatment in decreasing grass metal concentrations in the first year was 5% red mud, but by year two all amendments were equally effective. In an additional pot experiment, P application in combination with red mud or lime decreased the Pb concentration, but not total uptake of Pb in Festuca rubra compared to red mud alone. The results show that both red mud and lime can be used to remediate a heavily contaminated acid soil to allow re-vegetation.", "keywords": ["Festuca", "Geologic Sediments", "Time Factors", "Lime", "Phosphate", "Phosphorus", "Hydrogen-Ion Concentration", "15. Life on land", "01 natural sciences", "6. Clean water", "Calcium Carbonate", "Heavy metals", "Metals", " Heavy", "Clay", "Soil Pollutants", "Aluminum Silicates", "In situ remediation", "Environmental Restoration and Remediation", "Red mud", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.envpol.2005.10.017"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envpol.2005.10.017", "name": "item", "description": "10.1016/j.envpol.2005.10.017", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envpol.2005.10.017"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2006-08-01T00:00:00Z"}}, {"id": "10.1016/j.envpol.2006.03.003", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-23T16:15:58Z", "type": "Journal Article", "created": "2006-05-09", "title": "Effect Of Submergence-Emergence Sequence And Organic Matter Or Aluminosilicate Amendment On Metal Uptake By Woody Wetland Plant Species From Contaminated Sediments", "description": "Site-specific hydrological conditions affect the availability of trace metals for vegetation. In a greenhouse experiment, the effect of submersion on the metal uptake by the wetland plant species Salix cinerea and Populus nigra grown on a contaminated dredged sediment-derived soil and on an uncontaminated soil was evaluated. An upland hydrological regime for the polluted sediment caused elevated Cd concentrations in leaves and cuttings for both species. Emergence and soil oxidation after initial submersion of a polluted sediment resulted in comparable foliar Cd and Zn concentrations for S. cinerea as for the constant upland treatment. The foliar Cd and Zn concentrations were clearly higher than for submerged soils after initial upland conditions. These results point at the importance of submergence-emergence sequence for plant metal availability. The addition of foliar-based organic matter or aluminosilicates to the polluted sediment-derived soil in upland conditions did not decrease Cd and Zn uptake by S. cinerea.", "keywords": ["Geologic Sediments", "Biological Availability", "Water", "Salix", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "6. Clean water", "Plant Leaves", "Zinc", "Populus", "13. Climate action", "Metals", " Heavy", "Immersion", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Aluminum Silicates", "Seasons", "Oxidation-Reduction", "Ecosystem", "Plant Shoots", "Cadmium", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.envpol.2006.03.003"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envpol.2006.03.003", "name": "item", "description": "10.1016/j.envpol.2006.03.003", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envpol.2006.03.003"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2007-01-01T00:00:00Z"}}, {"id": "10.1016/j.envpol.2016.11.048", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-23T16:15:59Z", "type": "Journal Article", "created": "2016-11-19", "title": "Influence of bacterial extracellular polymeric substances on the sorption of Zn on \u03b3-alumina: A combination of FTIR and EXAFS studies", "description": "Extracellular polymeric substances (EPS) isolated from bacteria, are abound of functional groups which can react with metals and consequently influence the immobilization of metals. In this study, we combined with Zn K-edge Extended X-ray Absorption Fine Structure (EXAFS), Fourier Transform Infrared (FTIR) spectroscopy, and High-Resolution Transmission Electron Microscopy (HRTEM) techniques to study the effects of EPS isolated from Bacillus subtilis and Pseudomonas putida on Zn sorption on \u03b3-alumina. The results revealed that Zn sorption on aluminum oxide was pH-dependent and significantly influenced by bacterial EPS. At pH 7.5, Zn sorbed on \u03b3-alumina was in the form of Zn-Al layered doubled hydroxide (LDH) precipitates, whereas at pH 5.5, Zn sorbed on \u03b3-alumina was as a Zn-Al bidentate mononuclear surface complex. The amount of sorbed Zn at pH 7.5 was 1.3-3.7 times higher than that at pH 5.5. However, in the presence of 2\u00a0g\u00a0L-1 EPS, regardless of pH conditions and EPS source, Zn\u00a0+\u00a0EPS + \u03b3-alumina ternary complex was formed on the surface of \u03b3-alumina, which resulted in decreased Zn sorption (reduced by 8.4-67.8%) at pH 7.5 and enhanced Zn sorption (increased by 10.0-124.7%) at pH 5.5. The FTIR and EXAFS spectra demonstrated that both the carboxyl and phosphoryl moieties of EPS were crucial in this process. These findings highlight EPS effects on Zn interacts with \u03b3-alumina.", "keywords": ["Polymers", "Pseudomonas putida", "0211 other engineering and technologies", "02 engineering and technology", "Hydrogen-Ion Concentration", "01 natural sciences", "Zinc", "X-Ray Absorption Spectroscopy", "Spectroscopy", " Fourier Transform Infrared", "Aluminum Oxide", "Hydroxides", "Adsorption", "Bacillus subtilis", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.envpol.2016.11.048"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envpol.2016.11.048", "name": "item", "description": "10.1016/j.envpol.2016.11.048", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envpol.2016.11.048"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-01-01T00:00:00Z"}}, {"id": "10.1016/j.geoderma.2016.08.026", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-23T16:16:18Z", "type": "Journal Article", "created": "2016-09-24", "title": "Black Carbon And Black Nitrogen Storage Under Long-Term Paddy And Non-Paddy Management In Major Reference Soil Groups", "description": "Crop-residue burning and frequent paddy-soil flooding can lead to a substantial accumulation of black carbon (BC), thus contributing to long-term C sequestration. There is evidence that the turnover of BC in soils also depends on the soil mineral assembly. We studied the effects of paddy and non-paddy soil management and different major reference soil groups on BC storage. We hypothesized that overall BC storage in soil relates to paddy management and the abundance of reactive mineral phases such as Fe and Al oxides, and clay-sized minerals. Parallel to BC, black nitrogen (BN) should accumulate in soil. Paddy and non-paddy soils were sampled in three different climate zones (tropical, subtropical, and temperate). The soil profiles comprised six replicates of Andosols, Alisols and Vertisols from Java (Indonesia), and Alisols and Cambisols from China, as well as one Fluvisol and Gleysol from Northern Italy. Samples were taken by horizon down to >\u00a01\u00a0m depth and analyzed for soil organic carbon (SOC) and BC. The latter was analyzed by oxidation to benzene polycarboxylic acids. Abundance of BN (as aromatic N) was estimated by X-ray photoelectron spectroscopic analyses of selected topsoil horizons. In topsoils BC vs. SOC accumulation was affected by management for Andosol, Alisols in China, and Vertisols. However, both flooding and crop-residue management seemed to control this. BC contents relative to SOC also differed between the reference soil groups, independent of management (p\u00a0<\u00a00.0001), yet were surprisingly constant within replicates. We conclude that BC co-accumulated with SOC in all soils. However, the overall storage of BC (1\u00a0m depth) was affected by a combination of soil group and management. Vertisols contained the largest BC stocks (17\u201319\u00a0t\u00a0ha\u2212\u00a01 in non-paddy and paddy fields), followed by Andosols and Alisols (6\u201310\u00a0t\u00a0BC\u00a0ha\u2212\u00a01 under paddy management; 3\u20138\u00a0t\u00a0ha\u2212\u00a01 under non-paddy management). The Gleysol and Fluvisol had the smallest BC stocks, independent of soil use (3\u20134\u00a0t\u00a0ha\u2212\u00a01). Aromatic N proportions increased to >\u00a050% of total N after combustion of rice straw. However, aromatic N was barely, or not detectable in soil, and there was no correlation to BC. We conclude that burned crop residues were not a major source for aromatic N in soil. BC and aromatic N showed no distinct relations to soil properties, such as the abundance of clay-sized minerals, and Al and Fe oxides. Differences in BC stocks between the soils were most pronounced in the subsoils, likely caused by physical processes, such as swelling and shrinking of clays and/or translocation by leaching. Climate and regional soil-adjusted management also affected BC accumulation, but this first snapshot indicates that global BC maps may be linked to global soil maps.", "keywords": ["2. Zero hunger", "13. Climate action", "0401 agriculture", " forestry", " and fisheries", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "Aluminum oxides; Black carbon; Black nitrogen; C sequestration; Clay-size fraction; Iron oxides; Soil Science", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://iris.unito.it/bitstream/2318/1607391/2/Geoderma_284_214_postprint_4aperto.pdf"}, {"href": "https://doi.org/10.1016/j.geoderma.2016.08.026"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geoderma", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.geoderma.2016.08.026", "name": "item", "description": "10.1016/j.geoderma.2016.08.026", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.geoderma.2016.08.026"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-12-01T00:00:00Z"}}, {"id": "10.1038/nature12670", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-23T16:17:31Z", "type": "Journal Article", "created": "2013-10-29", "title": "Decoupling Of Soil Nutrient Cycles As A Function Of Aridity In Global Drylands", "description": "The biogeochemical cycles of carbon (C), nitrogen (N) and phosphorus (P) are interlinked by primary production, respiration and decomposition in terrestrial ecosystems. It has been suggested that the C, N and P cycles could become uncoupled under rapid climate change because of the different degrees of control exerted on the supply of these elements by biological and geochemical processes. Climatic controls on biogeochemical cycles are particularly relevant in arid, semi-arid and dry sub-humid ecosystems (drylands) because their biological activity is mainly driven by water availability. The increase in aridity predicted for the twenty-first century in many drylands worldwide may therefore threaten the balance between these cycles, differentially affecting the availability of essential nutrients. Here we evaluate how aridity affects the balance between C, N and P in soils collected from 224 dryland sites from all continents except Antarctica. We find a negative effect of aridity on the concentration of soil organic C and total N, but a positive effect on the concentration of inorganic P. Aridity is negatively related to plant cover, which may favour the dominance of physical processes such as rock weathering, a major source of P to ecosystems, over biological processes that provide more C and N, such as litter decomposition. Our findings suggest that any predicted increase in aridity with climate change will probably reduce the concentrations of N and C in global drylands, but increase that of P. These changes would uncouple the C, N and P cycles in drylands and could negatively affect the provision of key services provided by these ecosystems.", "keywords": ["0301 basic medicine", "Nitrogen", "Biolog\u00eda", "Climate Change", "Carbon Cycle", "Soil", "03 medical and health sciences", "Ecological Impacts of Climate Change", "XXXXXX - Unknown", "Ecological impacts of climate change and ecological adaptation", "Biomass", "Desiccation", "Ecosystem", "Soil Chemistry (excl Carbon Sequestration Science)", "2. Zero hunger", "drylands", "Geography", "soil fertility", "Phosphorus", "04 agricultural and veterinary sciences", "biogeochemical cycle", "Models", " Theoretical", "Nitrogen Cycle", "Plants", "15. Life on land", "Carbon", "Phosphoric Monoester Hydrolases", "Soil chemistry and soil carbon sequestration (excl. carbon sequestration science)", "climate change", "Medio Ambiente", "13. Climate action", "Ecosystem Function", "Clay", "0401 agriculture", " forestry", " and fisheries", "Aluminum Silicates", "Desert Climate"]}, "links": [{"href": "https://doi.org/10.1038/nature12670"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Nature", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1038/nature12670", "name": "item", "description": "10.1038/nature12670", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1038/nature12670"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2013-10-01T00:00:00Z"}}, {"id": "10.1021/es302545b", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-23T16:17:17Z", "type": "Journal Article", "created": "2012-09-27", "title": "Biochar Carbon Stability In A Clayey Soil As A Function Of Feedstock And Pyrolysis Temperature", "description": "The stability of biochar carbon (C) is the major determinant of its value for long-term C sequestration in soil. A long-term (5 year) laboratory experiment was conducted under controlled conditions using 11 biochars made from five C3 biomass feedstocks (Eucalyptus saligna wood and leaves, papermill sludge, poultry litter, cow manure) at 400 and/or 550 \u00b0C. The biochars were incubated in a vertisol containing organic C from a predominantly C4-vegetation source, and total CO(2)-C and associated \u03b4(13)C were periodically measured. Between 0.5% and 8.9% of the biochar C was mineralized over 5 years. The C in manure-based biochars mineralized faster than that in plant-based biochars, and C in 400 \u00b0C biochars mineralized faster than that in corresponding 550 \u00b0C biochars. The estimated mean residence time (MRT) of C in biochars varied between 90 and 1600 years. These are conservative estimates because they represent MRT of relatively labile and intermediate-stability biochar C components. Furthermore, biochar C MRT is likely to be higher under field conditions of lower moisture, lower temperatures or nutrient availability constraints. Strong relationships of biochar C stability with the initial proportion of nonaromatic C and degree of aromatic C condensation in biochar support the use of these properties to predict biochar C stability in soil.", "keywords": ["Paper", "Eucalyptus", "550", "Temperature", "Industrial Waste", "04 agricultural and veterinary sciences", "15. Life on land", "Wood", "Carbon", "Poultry", "Manure", "Plant Leaves", "Soil", "Animals", "Clay", "0401 agriculture", " forestry", " and fisheries", "Aluminum Silicates", "Cattle"]}, "links": [{"href": "https://doi.org/10.1021/es302545b"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/es302545b", "name": "item", "description": "10.1021/es302545b", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/es302545b"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2012-10-10T00:00:00Z"}}, {"id": "10.1023/b:plso.0000020970.40167.40", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-23T16:17:24Z", "type": "Journal Article", "created": "2004-03-24", "title": "Phosphorus Mobilization In Agroforestry: Organic Anions, Phosphatase Activity And Phosphorus Fractions In The Rhizosphere", "description": "In agroforestry systems on Ferralsols in the tropics, maize crop yields are low owing to a lack of P. However, some agroforestry tree species adapted to P-fixing soils may be able to utilize less available P sources and concurrently increase P availability to adjacent crops. Adaptations for enhanced P acquisition from P-fixing soils include exudation of low molecular weight (LMW) organic anions (OA) and phosphatase enzymes. We identified major organic anions, and measured acid phosphatase activity and P fractions in the rhizosphere soil of maize (Zea mays\u00a0L.), as well as in the perennial species Grevillea robusta A. Cunn., Cassia spectabilis DC. (syn. Senna spectabilis (DC.) H.S. Irwin and R.C. Barneby), Tithonia diversifolia (Hemsl.) A. Gray, Eucalyptus grandis W. Hill ex Maiden and Cedrella serrata Royle. Maize and trees were grown simultaneously at field sites and in large pots. Rhizosphere soil of C.\u00a0spectabilis contained at least 29\u00a0\u03bcmol oxalate\u00a0g\u22121 soil, derived from a high exudation rate in the range of at least 5\u201310\u00a0\u03bcmol oxalate\u00a0m\u22121 root day\u22121. Incubation of Ferralsols with much lower concentrations of citrate increased labile P fractions, but there was no clear relation between OA concentration and an increase in labile P fractions in rhizosphere soils, where P mobilization and P uptake occur at the same time. Acid phosphatase activity in rhizosphere soil of all species was two to five times greater in rhizosphere soil compared with bulk soil, and correlated in rhizosphere soil of G.\u00a0robusta with a shift from organic P to inorganic P in soil P fractions. We conclude that organic anion exudation and acid phosphatase activity of tree roots may increase mobilization of P in the rhizosphere, the extent of which depends on the species, the organic anion and pH. However, it is unlikely that the extent of P mobilization will benefit adjacent crop plants unless crop roots exert insufficient P-mobilization effects themselves, and grow in the rhizosphere of tree roots.", "keywords": ["0106 biological sciences", "2. Zero hunger", "plant-roots", "hexaphosphate", "availability", "04 agricultural and veterinary sciences", "15. Life on land", "lupinus-albus l", "01 natural sciences", "soil-root interface", "aluminum", "0401 agriculture", " forestry", " and fisheries", "excretion", "acids", "competitive adsorption", "solubilization"]}, "links": [{"href": "https://doi.org/10.1023/b:plso.0000020970.40167.40"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Plant%20and%20Soil", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1023/b:plso.0000020970.40167.40", "name": "item", "description": "10.1023/b:plso.0000020970.40167.40", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1023/b:plso.0000020970.40167.40"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2004-02-01T00:00:00Z"}}, {"id": "10.1071/ar00043", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-23T16:17:49Z", "type": "Journal Article", "created": "2002-09-16", "title": "Effects Of Lime And Gypsum On Growth Of Sweet Potato In Two Strongly Acid Soils", "description": "
There were strong relationships between exchangeable aluminium (Al) and relative top yield, and between soil pH and relative top yield in the Garret and Bisinella soils. Sweet potato plants produced maximum top yields at soil exchangeable Al <3.0 cmol ((+)/kg, with a 10% yield reduction coinciding with a value of approximately 5.0 cmol (+)/kg. The value was lower for the Bisinella soil than the Garret soil. In the case of pH, maximum yield in both soils was evident at a soil pH of 5.0 with 90% of maximum yield being achieved at about pH 4.7. These results suggest that soil pH would be a good index for Al toxicity. The close relationships between sweet potato growth and both exchangeable Al and soil pH need to be explored further to determine whether it will hold across a wide range of acid soil groups.
", "keywords": ["2. Zero hunger", "Manganese", "Multidisciplinary", "Ph", "Cultivars", "Agriculture", "04 agricultural and veterinary sciences", "C1", "Land and Farm Management", "Subsoil Horizons", "0401 agriculture", " forestry", " and fisheries", "Calcium", "Root Elongation", "Aluminum", "0701 Agriculture"], "contacts": [{"organization": "Ilaava, Vele P., Blamey, Pax, Asher, Colin J.,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1071/ar00043"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Australian%20Journal%20of%20Agricultural%20Research", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1071/ar00043", "name": "item", "description": "10.1071/ar00043", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1071/ar00043"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2000-01-01T00:00:00Z"}}, {"id": "10.1590/s0103-90162006000500013", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-23T16:19:34Z", "type": "Journal Article", "created": "2006-10-19", "title": "Surface Application Of Lime Ameliorates Subsoil Acidity And Improves Root Growth And Yield Of Wheat In An Acid Soil Under No-Till System", "description": "Crop root growth and grain yield can be affected by chemical modifications in the soil profile due to surface lime application. A field trial was carried out on a loamy dystrophic Typic Hapludox at Ponta Grossa, State of Paran\uffc3\uffa1, Brazil, to evaluate root growth and grain yield of wheat (Triticum aestivum L. cv. CD 104, moderately susceptible to Al), about 10 years after surface liming (0, 2, 4, and 6 Mg ha-1) and three years after surface re-liming (0 and 3 Mg ha-1), in a long-term no-till cultivation system. Soil acidity limited wheat root growth and yield severely, probably as a result of extended water deficits during the vegetative stage. Surface liming caused increases up to 66% in the root growth (0-60 cm) and up to 140% in the grain yield. Root density and grain yield were correlated positively with soil pH and exchangeable Ca2+, and negatively with exchangeable Al3+ and Al3+ saturation, in the surface and subsurface layers.
", "keywords": ["calcium", "aluminum", "c\u00e1lcio", "dolomitic lime", "0401 agriculture", " forestry", " and fisheries", "04 agricultural and veterinary sciences", "alum\u00ednio", "Triticum aestivum L.", "calc\u00e1rio dolom\u00edtico"], "contacts": [{"organization": "Caires, Eduardo F\u00e1vero, Corr\u00eaa, Jos\u00e9 Cristov\u00e3o Leal, Churka, Susana, Barth, Gabriel, Garbuio, Fernando Jos\u00e9,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1590/s0103-90162006000500013"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Scientia%20Agricola", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1590/s0103-90162006000500013", "name": "item", "description": "10.1590/s0103-90162006000500013", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1590/s0103-90162006000500013"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2006-10-01T00:00:00Z"}}, {"id": "10.5194/bg-2-159-2005", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-23T16:21:24Z", "type": "Journal Article", "created": "2010-04-29", "description": "Abstract. Extreme sensitivity of soil organic carbon (SOC) to climate and land use change warrants further research in different terrestrial ecosystems. The aim of this study was to investigate the link between aggregate and SOC dynamics in a chronosequence of three different land uses of a south Chilean Andisol: a second growth Nothofagus obliqua forest (SGFOR), a grassland (GRASS) and a Pinus radiata plantation (PINUS). Total carbon content of the 0-10cm soil layer was higher for GRASS (6.7 kg C m-2) than for PINUS (4.3 kg C m-2, while TC content of SGFOR (5.8 kg C m-2) was not significantly different from either one. High extractable oxalate and pyrophosphate Al concentrations (varying from 20.3-24.4 g kg-1, and 3.9-11.1 g kg-1, respectively) were found in all sites. In this study, SOC and aggregate dynamics were studied using size and density fractionation experiments of the SOC, \uffce\uffb413C and total carbon analysis of the different SOC fractions, and C mineralization experiments. The results showed that electrostatic sorption between and among amorphous Al components and clay minerals is mainly responsible for the formation of metal-humus-clay complexes and the stabilization of soil aggregates. The process of ligand exchange between SOC and Al would be of minor importance resulting in the absence of aggregate hierarchy in this soil type. Whole soil C mineralization rate constants were highest for SGFOR and PINUS, followed by GRASS (respectively 0.495, 0.266 and 0.196 g CO2-Cm-2d-1 for the top soil layer). In contrast, incubation experiments of isolated macro organic matter fractions gave opposite results, showing that the recalcitrance of the SOC decreased in another order: PINUS>SGFOR>GRASS. We deduced that electrostatic sorption processes and physical protection of SOC in soil aggregates were the main processes determining SOC stabilization. As a result, high aggregate carbon concentrations, varying from 148 till 48 g kg-1, were encountered for all land use sites. Al availability and electrostatic charges are dependent on pH, resulting in an important influence of soil pH on aggregate stability. Recalcitrance of the SOC did not appear to largely affect SOC stabilization. Statistical correlations between extractable amorphous Al contents, aggregate stability and C mineralization rate constants were encountered, supporting this hypothesis. Land use changes affected SOC dynamics and aggregate stability by modifying soil pH (and thus electrostatic charges and available Al content), root SOC input and management practices (such as ploughing and accompanying drying of the soil).
", "keywords": ["DECOMPOSITION", "NEW-ZEALAND", "DENSITY FRACTIONS", "[SDU.ASTR] Sciences of the Universe [physics]/Astrophysics [astro-ph]", "HUMIC-ACID", "Life", "QH501-531", "QH540-549.5", "2. Zero hunger", "QE1-996.5", "CULTIVATED SOILS", "Ecology", "[SDU.OCEAN] Sciences of the Universe [physics]/Ocean", " Atmosphere", "Geology", "LAND-USE CHANGE", "04 agricultural and veterinary sciences", "ALUMINUM", "15. Life on land", "[SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces", " environment", "MACROORGANIC MATTER", "C SEQUESTRATION", "[PHYS.ASTR.CO] Physics [physics]/Astrophysics [astro-ph]/Cosmology and Extra-Galactic Astrophysics [astro-ph.CO]", "Earth and Environmental Sciences", "FOREST SOILS", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "0401 agriculture", " forestry", " and fisheries"], "contacts": [{"organization": "Huygens, D., Boeckx, P., van Cleemput, O., Oyarz\u00fan, C., Godoy, R.,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.5194/bg-2-159-2005"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Biogeosciences", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.5194/bg-2-159-2005", "name": "item", "description": "10.5194/bg-2-159-2005", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.5194/bg-2-159-2005"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2005-06-24T00:00:00Z"}}, {"id": "3198887158", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-23T16:25:49Z", "type": "Journal Article", "created": "2021-09-08", "title": "Wafer\u2010Scale Functional Metasurfaces for Mid\u2010Infrared Photonics and Biosensing", "description": "AbstractMetasurfaces have emerged as a breakthrough platform for manipulating light at the nanoscale and enabling on\uffe2\uff80\uff90demand optical functionalities for next\uffe2\uff80\uff90generation biosensing, imaging, and light\uffe2\uff80\uff90generating photonic devices. However, translating this technology to practical applications requires low\uffe2\uff80\uff90cost and high\uffe2\uff80\uff90throughput fabrication methods. Due to the limited choice of materials with suitable optical properties, it is particularly challenging to produce metasurfaces for the technologically relevant mid\uffe2\uff80\uff90infrared spectral range. These constraints are overcome by realizing functional metasurfaces on almost completely transparent free\uffe2\uff80\uff90standing metal\uffe2\uff80\uff90oxide membranes. A versatile nanofabrication process is developed and implemented for highly efficient dielectric and plasmonic mid\uffe2\uff80\uff90infrared metasurfaces with wafer\uffe2\uff80\uff90scale and complementary metal\uffe2\uff80\uff93oxide\uffe2\uff80\uff93semiconductor (CMOS)\uffe2\uff80\uff90compatible manufacturing techniques. The advantages of this method are revealed by demonstrating highly uniform and functional metasurfaces, including high\uffe2\uff80\uff90Q structures enabling fine spectral selectivity, large\uffe2\uff80\uff90area metalenses\uffc2\uffa0with\uffc2\uffa0diffraction\uffe2\uff80\uff90limited focusing capabilities, and birefringent metasurfaces providing polarization control at record\uffe2\uff80\uff90high conversion efficiencies.\uffc2\uffa0 Aluminum plasmonic devices and their integration into microfluidics for real\uffe2\uff80\uff90time and label\uffe2\uff80\uff90free mid\uffe2\uff80\uff90infrared biosensing of proteins and lipid vesicles are further demonstrated. The versatility of this approach and its compatibility with mass\uffe2\uff80\uff90production processes bring infrared metasurfaces markedly closer to commercial applications, such as thermal imaging, spectroscopy, and biosensing.