Abstract. Studies of forest nitrogen (N) budgets generally measure inputs to the atmosphere in wet and dry precipitation and outputs via hydrologic export. Although denitrification has been shown to be important in many wetland ecosystems, emission of nitrogen oxides from forest soils is an important, and often overlooked, component of an ecosystem nitrogen budget. During one year (2002-2003), emissions of nitric oxide (NO) and nitrous oxide (N2O) were measured from Sessile oak and Norway spruce forest soils in northeast Hungary. Accumulation in small static chambers followed by gas chromatography-mass spectrometry detection was used for the estimation of N2O emission flux. Because there are rapid chemical reactions of NO and ozone, small dynamic chambers were used for in situ NO flux measurements. Average soil emissions of NO were 1.2 and 2.1 \uffc2\uffb5gNm-2h-1, and for N2O were 15 and 20 \uffc2\uffb5gNm-2h-1, for spruce and oak soils, respectively. The previously determined nitrogen balance between the atmosphere and the forest ecosystem was re-calculated using these soil emission figures. The total (dry + wet) atmospheric N-deposition to the soil was 1.42 and 1.59gNm-2yr-1 for spruce and oak, respectively, while the soil emissions are 0.14 and 0.20 gNm-2yr-1. Thus, about 10-13% of N compounds deposited to the soil, mostly as NH3/NH4+ and HNO3/NO3-, are transformed in the soil and emitted back to the atmosphere, mostly as a greenhouse gas (N2O).
", "keywords": ["[PHYS.ASTR.CO] Physics [physics]/Astrophysics [astro-ph]/Cosmology and Extra-Galactic Astrophysics [astro-ph.CO]", "[SDU.OCEAN] Sciences of the Universe [physics]/Ocean", " Atmosphere", "13. Climate action", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "0401 agriculture", " forestry", " and fisheries", "04 agricultural and veterinary sciences", "15. Life on land", "[SDU.ASTR] Sciences of the Universe [physics]/Astrophysics [astro-ph]", "7. Clean energy", "01 natural sciences", "[SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces", " environment", "6. Clean water", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.atmosenv.2006.07.029"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Atmospheric%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.atmosenv.2006.07.029", "name": "item", "description": "10.1016/j.atmosenv.2006.07.029", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.atmosenv.2006.07.029"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2005-06-24T00:00:00Z"}}, {"id": "10.1016/j.atmosenv.2013.07.006", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:15:44Z", "type": "Journal Article", "created": "2013-07-13", "title": "Nitrous Oxide And Methane Fluxes From A Rice-Wheat Crop Rotation Under Wheat Residue Incorporation And No-Tillage Practices", "description": "Abstract Crop residue incorporation and no-tillage are recommended as management practices and are being increasingly adopted in the agricultural sector. However, few studies have assessed the extent to which these practices integrate annual carbon and nitrogen trace gas fluxes and grain yield. We investigated the effect of wheat straw incorporation and no-tillage on nitrous oxide (N2O) and methane (CH4) fluxes from a rice\u2013wheat system in southeast China, using year-round field measurements. Compared to the treatment with synthetic nitrogen fertilizers alone, the wheat straw incorporation reduced the N2O emissions by 38% (P", "keywords": ["2. Zero hunger", "Earth sciences", "info:eu-repo/classification/ddc/550", "550", "ddc:550", "13. Climate action", "0401 agriculture", " forestry", " and fisheries", "04 agricultural and veterinary sciences", "6. Clean water"]}, "links": [{"href": "https://doi.org/10.1016/j.atmosenv.2013.07.006"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Atmospheric%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.atmosenv.2013.07.006", "name": "item", "description": "10.1016/j.atmosenv.2013.07.006", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.atmosenv.2013.07.006"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2013-11-01T00:00:00Z"}}, {"id": "10.1016/j.biortech.2018.12.064", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:15:47Z", "type": "Journal Article", "created": "2018-12-22", "title": "ADM1 based mathematical model of trace element complexation in anaerobic digestion processes", "description": "In this study, a new model based on anaerobic digestion model no.1 (ADM1) approach has been proposed to simulate trace elements (TEs) complexation, precipitation and their effect on the anaerobic batch methane production. TEs complexation reactions with VFAs and EDTA have been incorporated in an extended ADM1 model which considers TE precipitation/dissolution reactions as well as biodegradation processes. The kinetic model tracks the dynamics of 90 state variables which constitute the components of the proposed anaerobic digestion (AD) model. The incorporation of the complexation reactions required the definition of new inorganic components (EDTA species) and new complexation process rates in the ADM1 framework. The charge balance was modified accordingly to consider the effects of the additional components. The new model is able to predict: a) the effect of TE-EDTA/VFA complexation on methane production, and b) the effect of the initial calcium and magnesium concentrations on process performance.", "keywords": ["ADM1", "Trace elements", "0211 other engineering and technologies", "02 engineering and technology", "Models", " Theoretical", "Fatty Acids", " Volatile", "01 natural sciences", "7. Clean energy", "Trace Elements", "[SDU] Sciences of the Universe [physics]", "Kinetics", "Biodegradation", " Environmental", "Bioreactors", "13. Climate action", "Anaerobic digestion", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "Complexation", "Mathematical modeling", "Anaerobic digestion; Trace elements; Complexation; Mathematical modeling; ADM1;", "Anaerobiosis", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.biortech.2018.12.064"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Bioresource%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.biortech.2018.12.064", "name": "item", "description": "10.1016/j.biortech.2018.12.064", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.biortech.2018.12.064"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-03-01T00:00:00Z"}}, {"id": "10.1016/j.catena.2015.11.008", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:15:49Z", "type": "Journal Article", "created": "2015-11-22", "title": "The Impact Of Manure, Straw And Biochar Amendments On Aggregation And Erosion In A Hillslope Ultisol", "description": "Soil erosion is a serious problem in subtropical China where hillslope red soils (Ultisols in US soil taxonomy) are intensively cultivated. Manure and amendments have been reported to improve crop growth and soil structural stability in long-term experiments so the objective of this study was to determine the effect of different organic amendments on soil aggregate stability, agronomic performance, runoff, and erosion. Four treatments consisted of inorganic NPK fertilizer (NPK), NPK fertilizer plus rice straw mulch (NPK + Str), NPK fertilizer plus rice straw-derived biochar (NPK + BC), and NPK fertilizer plus swine manure (NPK + OM) located on land with a 9\u201314% slope planted with peanut (Arachis hypogaea L.). During the peanut season, soil erosion ranged from around 2600 ton km\u2212 2 with just inorganic NPK fertilizer down to 627 ton km\u2212 2 with fertilizer plus swine manure, while addition of swine manure also increased the above-ground biomass and SOC (P 0.05) except the SOC, because biochar was susceptible to erosion (2115 ton km\u2212 2). The least erosion was observed in the straw mulch treatment (225 ton km\u2212 2), while it improved the above-ground biomass (P < 0.05) but not the C stock. The results indicated that the application of organic manure was a more appropriate practice for hillslope Ultisols management than using biochar.", "keywords": ["2. Zero hunger", "soil erosion", "[SDE.MCG]Environmental Sciences/Global Changes", "[SDU.STU]Sciences of the Universe [physics]/Earth Sciences", "04 agricultural and veterinary sciences", "15. Life on land", "630", "6. Clean water", "3. Good health", "[SDE.MCG] Environmental Sciences/Global Changes", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "0401 agriculture", " forestry", " and fisheries", "biochar", "soil structure", "organic amendment", "aggregate stability"], "contacts": [{"organization": "Peng, Xinhua, Zhu, Q. H., Xie, Zubin, Darboux, Fr\u00e9d\u00e9ric, Holden, Nick M.,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.catena.2015.11.008"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/CATENA", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.catena.2015.11.008", "name": "item", "description": "10.1016/j.catena.2015.11.008", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.catena.2015.11.008"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-03-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2016.11.020", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:15:50Z", "type": "Journal Article", "created": "2016-11-17", "title": "The gallium isotopic composition of the bulk silicate Earth", "description": "AbstractWe report a new method for precise analysis of gallium (Ga) isotopic composition in geological samples. The purification of Ga is achieved by a three-step ion exchange chromatography to remove matrix and interfering elements. The 71Ga/69Ga ratios are analyzed by multi-collector inductively-coupled-plasma mass-spectrometer (MC-ICP-MS). The external reproducibility of the measurements (0.05\u2030, 2 s.d.) was assessed by replicate analyses of the USGS BCR-2 and BHVO-2 standards. This newly developed technique was then used to investigate the extent of Ga isotopic fractionation during igneous processes by analyzing well-characterized samples from the Kilauea Iki lava lake, USA. These samples were formed in a closed system and have MgO contents ranging from 26.9 to 2.4wt.%. We found that igneous processes do not fractionate Ga isotopes within the analytical uncertainty and that the Ga isotopic composition of mafic-ultramafic lavas can be used to estimate the composition of their mantle source. Twelve ocean island basalts, two mid-ocean-ridge basalts, one continental flood basalt and one komatiite have homogeneous and nearly identical Ga isotopic compositions within analytical uncertainties averaging 0.00\u00b10.06\u2030 (2s.d.). This value represents the best estimate for the Ga isotopic composition of the bulk silicate Earth", "keywords": ["Bulk Silicate Earth", "Komatiite", "Gallium", "Geology", "MORB", "01 natural sciences", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Geochemistry and Petrology", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "14. Life underwater", "OIB", "MC-ICP-MS", "Basalt", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2016.11.020"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2016.11.020", "name": "item", "description": "10.1016/j.chemgeo.2016.11.020", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2016.11.020"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2017.12.006", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:15:50Z", "type": "Journal Article", "created": "2017-12-13", "title": "Zinc isotope composition of the Earth and its behaviour during planetary accretion", "description": "Abstract The terrestrial planets are depleted in volatile elements with respect to chondritic meteorites, their possible building blocks. However, the timing, extent and origin of volatile depletion is debated. Zinc is a moderately volatile element (MVE), whose stable isotopic composition can distinguish when and where this depletion took place. Here, we report data for 40 ultramafic rocks comprising pristine upper mantle peridotites from the Balmuccia orogenic lherzolite massif and Archean komatiites that together define the Zn isotope composition of the Earth's primitive mantle. Peridotites and komatiites are shown to have indistinguishable Zn isotopic compositions of \u03b466Zn\u00a0=\u00a0+\u00a00.16\u00a0\u00b1\u00a00.06\u2030 (2SD), (with \u03b466Zn the per mille deviation of 66Zn/64Zn from the JMC-Lyon standard), implying a constant Zn isotope composition for the silicate Earth since 3.5\u00a0Ga. After accounting for Zn sequestration during core formation, the Earth falls on the volatile-depleted end of a carbonaceous chondrite array in \u03b466Zn-Zn/Mg space, implying Earth avoided modification of its MVE budgets during late accretion (e.g. during a giant impact), in contrast to the Moon. The Moon deviates from the chondritic array in a manner consistent with evaporative loss of Zn, where its \u03b466Zn co-varies with Mn/Na, implying post-nebular volatile loss is more pronounced on smaller bodies. Should the giant impact deliver the Earth's volatile complement of Pb and Ag, it cannot account for the budget of lithophile MVEs (e.g. Zn, Rb, Mn), whose abundances reflect those of Earth's nebular building blocks. The Earth initially accreted from material that experienced chemical- and mass-dependent isotopic fractionation akin to carbonaceous chondrites, though volatile depletion was more pronounced on Earth.", "keywords": ["Zinc", "550", "Isotope", "13. Climate action", "Nebula", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Komatiite", "Mantle", "[SDU.STU.PL] Sciences of the Universe [physics]/Earth Sciences/Planetology", "Peridotite", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://openresearch-repository.anu.edu.au/bitstream/1885/139076/4/1-s2.0-S0009254117306782-main.pdf.jpg"}, {"href": "https://doi.org/10.1016/j.chemgeo.2017.12.006"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2017.12.006", "name": "item", "description": "10.1016/j.chemgeo.2017.12.006", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2017.12.006"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2018.03.030", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:15:50Z", "type": "Journal Article", "created": "2018-03-20", "title": "The stable strontium isotopic composition of ocean island basalts, mid-ocean ridge basalts, and komatiites", "description": "Ocean island basalts Mid-ocean ridge basalts Komatiites Kilauea Iki Bulk silicate earth A B S T R A C T The radiogenic 87 Rb-87 Sr system has been widely applied to the study of geological and planetary processes. In contrast, the stable Sr isotopic composition of the bulk silicate Earth (BSE) and the effects of igneous differentiation on stable Sr isotopes are not well-established. Here we report the stable Sr isotope (88 Sr/ 86 Sr, reported as \u03b4 88/86 Sr, in parts per mil relative to NIST SRM 987) compositions for ocean islands basalts (OIB), mid-ocean ridge basalts (MORB) and komatiites from a variety of locations. Stable Sr isotopes display limited fractionation in a OIB sample suite from the Kilauea Iki lava lake suggesting that igneous processes have limited effect on stable Sr isotope fractionation (\u00b1 0.12\u2030 over 20% MgO variation; 2sd). In addition, OIB (\u03b4 88/ 86 Sr = 0.16-0.46\u2030; average 0.28 \u00b1 0.17\u2030), MORB (\u03b4 88/86 Sr = 0.27-0.34\u2030; average 0.31 \u00b1 0.05\u2030) and komatiites (\u03b4 88/86 Sr = 0.20-0.97\u2030; average 0.41 \u00b1 0.16\u2030) from global localities exhibit broadly similar Sr stable isotopic compositions. Heavy stable Sr isotope compositions (\u03b4 88/86 Sr > 0.5\u2030) in some Barberton Greenstone belt komatiites may reflect Archean seawater alteration or metamorphic processes and preferential removal of the lighter isotopes of Sr. To first order, the similarity among OIBs from three different ocean basins suggests homogeneity of stable Sr isotopes in the mantle. Earth's mantle stable Sr isotopic composition is established from the data on OIB, MORB and komatiites to be \u03b4 88/86 Sr = 0.30 \u00b1 0.02\u2030 (2sd). The BSE \u03b4 88/86 Sr value is identical, within uncertainties, to the composition of carbonaceous chondrites (\u03b4 88/ 86 Sr = 0.29 \u00b1 0.06\u2030; 2sd) measured in this study.", "keywords": ["Ocean island basalts", "Bulk silicate earth", "Sr isotopes", "Mid-ocean ridge basalts", "Kilauea Iki", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "14. Life underwater", "Komatiites", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2018.03.030"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2018.03.030", "name": "item", "description": "10.1016/j.chemgeo.2018.03.030", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2018.03.030"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-04-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2021.120283", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:15:50Z", "type": "Journal Article", "created": "2021-04-27", "title": "Imprint of chemical weathering and hydrothermalism on the Ge/Si ratio and Si isotope composition of rivers in a volcanic tropical island, Basse-Terre, Guadeloupe (French West Indies)", "description": "Abstract A significant portion of the disproportionally high chemical weathering flux in volcanic island arcs may originate from hydrothermal fluid-rock interaction, thereby compromising the accurate estimate of atmospheric CO2 consumption rates. The objective of this study is to evaluate how the riverine Ge/Si ratio and Si isotopes, two well-established tracers of weathering, respond to hydrothermal inputs. The work took place in Basse-Terre, Guadeloupe, a tropical volcanic island with a dense river network, high chemical weathering fluxes and various hydrothermal surface manifestations. We characterized the Ge/Si ratio and \u03b430Si of 15 thermal springs, nine non-impacted (NI) rivers and 13 hydrothermally-impacted (HI) rivers. The soil solution from a highly weathered soil profile (Ferralsol) and a clayey-rock corresponding to the material exposed in an extinct hydrothermal system were also measured. A new purification method was successfully developed in order to allow the reliable measurement of Si isotopes in SO42\u2212- and Cl\u2212-rich thermal spring and HI river waters by mass spectrometry. Basse-Terre's thermal springs have variable Ge/Si ratios (0.05\u201321.03\u00a0\u03bcmol.mol\u22121) and \u03b430Si (0.71\u20131.50\u2030), but with no apparent relationship to the water compositional type. The Ge/Si ratio (0.15\u20132.57\u00a0\u03bcmol.mol\u22121) and Si isotope composition (0.26\u20131.21\u2030) values of the NI rivers reveal differences in the watersheds' weathering degree. Dissolution of Ge- and 28Si-rich secondary minerals explains the high Ge/Si and isotopically light composition of the northern NI rivers draining strongly weathered terranes. The Ge/Si ratio and \u03b430Si values measured for the NI and HI rivers overlap, implying that they cannot be used to diagnose hydrothermal contributions to river basins unambiguously. However, when combined with the Cl\u2212 and SO42\u2212 concentrations, the analysis of Ge and Si in the HI rivers suggests that water seeping through an extinct hydrothermal system produces SO4-rich drainages with distinctively lower Ge/Si ratios than those inferred for watersheds receiving thermal spring discharges associated with an active hydrothermal system. Overall, our results provide new constraints for applying and interpreting Ge/Si and Si isotope measurements to study weathering in volcanic environments.", "keywords": ["[SDE] Environmental Sciences", "Volcanic hydrothermal system", "Chemical weathering", "River geochemistry", "Si isotope", "Ge/Si ratio", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Guadeloupe", "01 natural sciences", "6. Clean water", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2021.120283"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2021.120283", "name": "item", "description": "10.1016/j.chemgeo.2021.120283", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2021.120283"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-09-01T00:00:00Z"}}, {"id": "10.1016/j.rse.2016.02.046", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:33Z", "type": "Journal Article", "created": "2016-03-05", "title": "Comparison of remote sensing and simulated soil moisture datasets in Mediterranean landscapes", "description": "AbstractThis paper presents the comparison of three global soil moisture products (ASCAT, AMSR and SMOS) versus a land surface model over a region representative of several Mediterranean landscapes located in the Northeast of the Iberian Peninsula. Our approach has been for agricultural and water management applications at the regional and local scale. Despite being a rather small area, we were able to observe different signal behaviours corresponding to major land cover classes in Mediterranean areas i.e.: dryland and irrigated crops, forests and natural vegetation (grass-shrubs). The area also allowed assessing the impact of topography. The first result of the study is that the results are very dependent on the normalizations used to make the data comparable, thus their impact must be carefully analysed. In this study, we applied two different normalisation methods (called ZV35 and ZV) and different moving average windows (1, 10 and 30days) in order to enhance seasonal effects. Using no smoothing window, ASCAT is the soil moisture product that correlates best with the LSM over all cover classes, whatever the method. Using smoothing window, AMSR-E tends to outperform other soil moisture products with the ZV method. The ZV35 method is not able to identify a small heavily irrigated area. The reason for these different results is that ZV35, tends to eliminate the monthly scale soil moisture memory and therefore becomes more sensitive to precipitation and less sensitive to the monthly evolution of superficial soil moisture. The comparison shows in general good agreement for all soil moisture products with the LSM on the temporal series simulated over flat, non irrigated areas which are not close to the sea. SMOS has difficulties in areas close to the sea and in areas with steep relief and the current version of the L2 Operational Algorithm (V5.51) depicts few values in forested areas. ASCAT, in its turn, shows some limitations over agricultural and natural vegetation where it shows an increase of soil moisture from June to October probably due to increase of penetration depth in dry soil moisture conditions. AMSR-E LPRM shows a clear vegetation cycle over all the land cover classes. From all the remote sensing products, SMOS is the only one able to see irrigation and the only that does not show clear vegetation or roughness effects. In this study, we were able to assess the impact of higher resolution soil moisture products to map irrigated areas.", "keywords": ["2. Zero hunger", "0207 environmental engineering", "Soil Science", "Agriculture", "Geology", "AMSR-E", "02 engineering and technology", "15. Life on land", "16. Peace & justice", "01 natural sciences", "6. Clean water", "Water management", "ASCAT", "13. Climate action", "Regional scale", "LSM", "Soil moisture", "Computers in Earth Sciences", "Irrigation", "SMOS", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.rse.2016.02.046"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Remote%20Sensing%20of%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.rse.2016.02.046", "name": "item", "description": "10.1016/j.rse.2016.02.046", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.rse.2016.02.046"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-07-01T00:00:00Z"}}, {"id": "10.1016/j.envpol.2008.11.050", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:01Z", "type": "Journal Article", "created": "2009-01-19", "title": "Ion Activity And Distribution Of Heavy Metals In Acid Mine Drainage Polluted Subtropical Soils", "description": "The oxidative dissolution of mine wastes gives rise to acidic, metal-enriched mine drainage (AMD) and has typically posed an additional risk to the environment. The poly-metallic mine Dabaoshan in South China is an excellent test site to understand the processes affecting the surrounding polluted agricultural fields. Our objectives were firstly to investigate metal ion activity in soil solution, distribution in solid constituents, and spatial distribution in samples, secondly to determine dominant environment factors controlling metal activity in the long-term AMD-polluted subtropical soils. Soil Column Donnan Membrane Technology (SC-DMT) combined with sequential extraction shows that unusually large proportion of the metal ions are present as free ion in the soil solutions. The narrow range of low pH values prevents any pH effects during the binding onto oxides or organic matter. The differences in speciation of the soil solutions may explain the different soil degradation observed between paddy and non-paddy soils.", "keywords": ["China", "Time Factors", "550", "Speciation", "0211 other engineering and technologies", "Industrial Waste", "02 engineering and technology", "Chemical Fractionation", "01 natural sciences", "Mining", "Soil", "Acid mine drainage", "X-Ray Diffraction", "Metals", " Heavy", "Soil Pollutants", "Humic Substances", "0105 earth and related environmental sciences", "Ions", "Hydrogen-Ion Concentration", "15. Life on land", "6. Clean water", "Tropical soils", "13. Climate action", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "Sorption", "Free ion", "Environmental Monitoring"]}, "links": [{"href": "https://doi.org/10.1016/j.envpol.2008.11.050"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envpol.2008.11.050", "name": "item", "description": "10.1016/j.envpol.2008.11.050", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envpol.2008.11.050"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-04-01T00:00:00Z"}}, {"id": "10.1016/j.envpol.2021.116897", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:02Z", "type": "Journal Article", "created": "2021-03-13", "title": "X-ray absorption spectroscopy evidence of sulfur-bound cadmium in the Cd-hyperaccumulator Solanum nigrum and the non-accumulator Solanum melongena", "description": "It has been proposed that non-protein thiols and organic acids play a major role in cadmium phytoavailability and distribution in plants. In the Cd-hyperaccumulator Solanum nigrum and non-accumulator Solanum melongena, the role of these organic ligands in the accumulation and detoxification mechanisms of Cd are debated. In this study, we used X-ray absorption spectroscopy to investigate Cd speciation in these plants (roots, stem, leaves) and in the soils used for their culture to unravel the plants responses to Cd exposure. The results show that Cd in the 100\u00a0mg\u00a0kg-1 Cd-doped clayey loam soil is sorbed onto iron oxyhydroxides. In both S.\u00a0nigrum and S.\u00a0melongena, Cd in roots and fresh leaves is mainly bound to thiol ligands, with a small contribution of inorganic S ligands in S.\u00a0nigrum leaves. We interpret the Cd binding to sulfur ligands as detoxification mechanisms, possibly involving the sequestration of Cd complexed with glutathione or phytochelatins in the plant vacuoles. In the stems, results show an increase binding of Cd to -O ligands (>50% for S.\u00a0nigrum). We suggest that Cd is partly complexed by organic acids for transportation in the sap.", "keywords": ["[SDE] Environmental Sciences", "0106 biological sciences", "570", "[CHIM.ANAL] Chemical Sciences/Analytical chemistry", "Speciation", "Plant Roots", "01 natural sciences", "[SDV.BV.BOT] Life Sciences [q-bio]/Vegetal Biology/Botanics", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDE.ES] Environmental Sciences/Environment and Society", "Soil Pollutants", "Solanum melongena", "Solanaceae", "Solanum nigrum", "0105 earth and related environmental sciences", "580", "Toxicity", "X-Ray absorption spectroscopy", "[SDV.BV.BOT]Life Sciences [q-bio]/Vegetal Biology/Botanics", "3. Good health", "Biodegradation", " Environmental", "X-Ray Absorption Spectroscopy", "13. Climate action", "[SDE]Environmental Sciences", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "Sulfur", "Cadmium"]}, "links": [{"href": "https://doi.org/10.1016/j.envpol.2021.116897"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envpol.2021.116897", "name": "item", "description": "10.1016/j.envpol.2021.116897", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envpol.2021.116897"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-01-01T00:00:00Z"}}, {"id": "10.1016/j.epsl.2016.12.008", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:03Z", "type": "Journal Article", "created": "2016-12-22", "title": "Chromium isotope evidence in ejecta deposits for the nature of Paleoproterozoic impactors", "description": "Non-mass dependent chromium isotopic signatures have been successfully used to determine the presence and identification of extra-terrestrial materials in terrestrial impact rocks. Paleoproterozoic spherule layers from Greenland (Graenseso) and Russia (Zaonega), as well as some distal ejecta deposits (Lake Superior region) from the Sudbury impact (1,849 +/- 0.3 Ma) event, have been analyzed for their Cr isotope compositions. Our results suggest that 1) these distal ejecta deposits are all of impact origin, 2) the Graenseso and Zaonega spherule layers contain a distinct carbonaceous chondrite component, and are possibly related to the same impact event, which could be Vredefort (2,023 +/- 4 Ma) or another not yet identified large impact event from that of similar age, and 3) the Sudbury ejecta record a complex meteoritic signature, which is different from the Graenseso and Zaonega spherule layers, and could indicate the impact of a heterogeneous chondritic body.", "keywords": ["TERRESTRIAL", "KARELIA", "impact ejecta", "FOS: Physical sciences", "01 natural sciences", "METEORITIC COMPONENTS", "SOLAR-SYSTEM", "[SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "SOUTH GREENLAND", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "GEOCHEMICAL EVIDENCE", "Vredefort", "Sudbury", "0105 earth and related environmental sciences", "Earth and Planetary Astrophysics (astro-ph.EP)", "crater", "KETILIDIAN OROGEN", "meteorite", "EARLY EARTH", "105105 Geochemistry", "EVENT", "13. Climate action", "chromium isotopes", "[SDU.STU.PL] Sciences of the Universe [physics]/Earth Sciences/Planetology", "105105 Geochemie", "SPHERULES", "Astrophysics - Earth and Planetary Astrophysics"]}, "links": [{"href": "https://doi.org/10.1016/j.epsl.2016.12.008"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Earth%20and%20Planetary%20Science%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.epsl.2016.12.008", "name": "item", "description": "10.1016/j.epsl.2016.12.008", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.epsl.2016.12.008"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-02-01T00:00:00Z"}}, {"id": "10.1016/j.epsl.2017.04.002", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:03Z", "type": "Journal Article", "created": "2017-04-14", "title": "The origin of volatile element depletion in early solar system material: Clues from Zn isotopes in chondrules", "description": "Abstract Volatile lithophile elements are depleted in the different planetary materials to various degrees, but the origin of these depletions is still debated. Stable isotopes of moderately volatile elements such as Zn can be used to understand the origin of volatile element depletions. Samples with significant volatile element depletions, including the Moon and terrestrial tektites, display heavy Zn isotope compositions (i.e. enrichment of 66Zn vs. 64Zn), consistent with kinetic Zn isotope fractionation during evaporation. However, Luck et al. (2005) found a negative correlation between \u03b4 66 Zn and 1/[Zn] between CI, CM, CO, and CV chondrites, opposite to what would be expected if evaporation caused the Zn abundance variations among chondrite groups. We have analyzed the Zn isotope composition of multiple samples of the major carbonaceous chondrite classes: CI (1), CM (4), CV (2), CO (4), CB (2), CH (2), CK (4), and CK/CR (1). The bulk chondrites define a negative correlation in a plot of \u03b4 66 Zn vs 1/[Zn], confirming earlier results that Zn abundance variations among carbonaceous chondrites cannot be explained by evaporation. Exceptions are CB and CH chondrites, which display Zn systematics consistent with a collisional formation mechanism that created enrichment in heavy Zn isotopes relative to the trend defined by CI\u2013CK. We further report Zn isotope analyses of chondrite components, including chondrules from Allende (CV3) and Mokoia (CV3), as well as an aliquot of Allende matrix. All chondrules are enriched in light Zn isotopes (\u223c500 ppm on 66Zn/64Zn) relative to the bulk, contrary to what would be expected if Zn were depleted during evaporation, on the other hand the matrix has a complementary heavy isotope composition. We report sequential leaching experiments in un-equilibrated ordinary chondrites, which show sulfides are isotopically heavy compared to silicates and the bulk meteorite by ca. +0.65 per mil on 66Zn/64Zn. We suggest isotopically heavy sulfides were removed from either chondrules or their precursors, thereby producing the light Zn isotope enrichments in chondrules.", "keywords": ["chondrules", "550", "protoplanetary disk", "551", "carbonaceous chondrites", "01 natural sciences", "volatiles", "[SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDU.STU.PL] Sciences of the Universe [physics]/Earth Sciences/Planetology", "zinc isotopes", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.epsl.2017.04.002"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Earth%20and%20Planetary%20Science%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.epsl.2017.04.002", "name": "item", "description": "10.1016/j.epsl.2017.04.002", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.epsl.2017.04.002"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-06-01T00:00:00Z"}}, {"id": "10.1016/j.epsl.2017.05.033", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:04Z", "type": "Journal Article", "created": "2017-06-16", "title": "Rubidium isotopic composition of the Earth, meteorites, and the Moon: Evidence for the origin of volatile loss during planetary accretion", "description": "Abstract Understanding the origin of volatile element variations in the inner Solar System has long been a goal of cosmochemistry, but many early studies searching for the fingerprint of volatile loss using stable isotope systems failed to find any resolvable variations. An improved method for the chemical purification of Rb for high-precision isotope ratio measurements by multi-collector inductively-coupled-plasma mass-spectrometry. This method has been used to measure the Rb isotopic composition for a suite of planetary materials, including carbonaceous, ordinary, and enstatite chondrites, as well as achondrites (eucrite, angrite), terrestrial igneous rocks (basalt, andesite, granite), and Apollo lunar samples (mare basalts, alkali suite). Volatile depleted bodies (e.g. HED parent body, thermally metamorphosed meteorites) are enriched in the heavy isotope of Rb by up to several per mil compared to chondrites, suggesting volatile loss by evaporation at the surface of planetesimals. In addition, the Moon is isotopically distinct from the Moon in Rb. The variations in Rb isotope compositions in the volatile-poor samples are attributed to volatile loss from planetesimals during accretion. This suggests that either the Rb (and other volatile elements) were lost during or following the giant impact or by evaporation earlier during the accretion history of Theia.", "keywords": ["volatile depletion", "[SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "the Moon", "[SDU.STU.PL] Sciences of the Universe [physics]/Earth Sciences/Planetology", "01 natural sciences", "chondrites", "rubidium isotopes", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.epsl.2017.05.033"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Earth%20and%20Planetary%20Science%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.epsl.2017.05.033", "name": "item", "description": "10.1016/j.epsl.2017.05.033", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.epsl.2017.05.033"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-09-01T00:00:00Z"}}, {"id": "10.1016/j.epsl.2017.12.042", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:04Z", "type": "Journal Article", "created": "2018-01-16", "title": "Chondritic Mn/Na ratio and limited post-nebular volatile loss of the Earth", "description": "Abstract The depletion pattern of volatile elements on Earth and other differentiated terrestrial bodies provides a unique insight as to the nature and origin of planetary building blocks. The processes responsible for the depletion of volatile elements range from the early incomplete condensation in the solar nebula to the late de-volatilization induced by heating and impacting during planetary accretion after the dispersion of the H2-rich nebular gas. Furthermore, as many volatile elements are also siderophile (metal-loving), it is often difficult to deconvolve the effect of volatility from core formation. With the notable exception of the Earth, all the differentiated terrestrial bodies for which we have samples have non-chondritic Mn/Na ratios, taken as a signature of post-nebular volatilization. The bulk silicate Earth (BSE) is unique in that its Mn/Na ratio is chondritic, which points to a nebular origin for the depletion; unless the Mn/Na in the BSE is not that of the bulk Earth (BE), and has been affected by core formation through the partitioning of Mn in Earth's core. Here we quantify the metal\u2013silicate partitioning behavior of Mn at deep magma ocean pressure and temperature conditions directly applicable to core formation. The experiments show that Mn becomes more siderophile with increasing pressure and temperature. Modeling the partitioning of Mn during core formation by combining our results with previous data at lower P\u2013T conditions, we show that the core likely contains a significant fraction (20 to 35%) of Earth's Mn budget. However, we show that the derived Mn/Na value of the bulk Earth still lies on the volatile-depleted end of a trend defined by chondritic meteorites in a Mn/Na vs Mn/Mg plot, which tend to higher Mn/Na with increasing volatile depletion. This suggests that the material that formed the Earth recorded similar chemical fractionation processes for moderately volatile elements as chondrites in the solar nebula, and experienced limited post nebular volatilization.", "keywords": ["550", "13. Climate action", "0103 physical sciences", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://researchonline.jcu.edu.au/62754/1/62754.pdf"}, {"href": "https://doi.org/10.1016/j.epsl.2017.12.042"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Earth%20and%20Planetary%20Science%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.epsl.2017.12.042", "name": "item", "description": "10.1016/j.epsl.2017.12.042", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.epsl.2017.12.042"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-03-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2015.07.003", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:14Z", "type": "Journal Article", "created": "2015-07-10", "title": "Isotope fractionation of Si in protonation/deprotonation reaction of silicic acid: A new pH proxy", "description": "Isotopic fractionation of Si in protonation/deprotonation reactions of monomeric silicic acids was theoretically and experimentally studied. The reduced partition function ratio for Si (as 1000 ln \u03b2) complexes was theoretically estimated by ab initio methods. Three permil of isotope fractionation was estimated to be possible for the 28Si-30Si isotope pair. This prediction was experimentally demonstrated by multi-collector inductively coupled plasma mass spectrometer measurements of Si-bearing aqueous solutions, for which equilibrated Si(OH)4 and SiO(OH)3\u2212 were separated using an anionic exchange column. The results create a new possibility for the application of Si isotopes as proxies for paleo-pH in the 9 < pH < 12 range.", "keywords": ["13. Climate action", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "01 natural sciences", "7. Clean energy", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2015.07.003"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2015.07.003", "name": "item", "description": "10.1016/j.gca.2015.07.003", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2015.07.003"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2015-11-01T00:00:00Z"}}, {"id": "10.1016/j.rse.2019.111627", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:33Z", "type": "Journal Article", "created": "2020-01-10", "title": "Irrigation retrieval from Landsat optical/thermal data integrated into a crop water balance model: A case study over winter wheat fields in a semi-arid region", "description": "Abstract Monitoring irrigation is essential for an efficient management of water resources in arid and semi-arid regions. We propose to estimate the timing and the amount of irrigation throughout the agricultural season using optical and thermal Landsat-7/8 data. The approach is implemented in four steps: i) partitioning the Landsat land surface temperature (LST) to derive the crop water stress coefficient (Ks), ii) estimating the daily root zone soil moisture (RZSM) from the integration of Landsat-derived Ks into a crop water balance model, iii) retrieving irrigation at the Landsat pixel scale and iv) aggregating pixel-scale irrigation estimates at the crop field scale. The new irrigation retrieval method is tested over three agricultural areas during four seasons and is evaluated over five winter wheat fields under different irrigation techniques (drip, flood and no-irrigation). The model is very accurate for the seasonal accumulated amounts (R ~ 0.95 and RMSE ~ 44\u00a0mm). However, lower agreements with observed irrigations are obtained at the daily scale. To assess the performance of the irrigation retrieval method over a range of time periods, the daily predicted and observed irrigations are cumulated from 1 to 90\u00a0days. Generally, acceptable errors (R\u00a0=\u00a00.52 and RMSE\u00a0=\u00a027\u00a0mm) are obtained for irrigations cumulated over 15\u00a0days and the performance gradually improves by increasing the accumulation period, depicting a strong link to the frequency of Landsat overpasses (16\u00a0days or 8\u00a0days by combining Landsat-7 and -8). Despite the uncertainties in retrieved irrigations at daily to weekly scales, the daily RZSM and evapotranspiration simulated from the retrieved daily irrigations are estimated accurately and are very close to those estimated from actual irrigations. This research demonstrates the utility of high spatial resolution optical and thermal data for estimating irrigation and consequently for better closing the water budget over agricultural areas. We also show that significant improvements can be expected at daily to weekly time scales by reducing the revisit time of high-spatial resolution thermal data, as included in the TRISHNA future mission requirements.", "keywords": ["[SDE] Environmental Sciences", "2. Zero hunger", "550", "Evapotranspiration", "0208 environmental biotechnology", "Root-zone soil moisture", "0207 environmental engineering", "FAO-56 model", "02 engineering and technology", "15. Life on land", "630", "[SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces", " environment", "6. Clean water", "[SDE]Environmental Sciences", "[SDU.STU.HY] Sciences of the Universe [physics]/Earth Sciences/Hydrology", "[SDU.STU.HY]Sciences of the Universe [physics]/Earth Sciences/Hydrology", "[SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces", "environment", "Irrigation", "Landsat", "Land surface temperature"], "contacts": [{"organization": "Olivera-Guerra, Luis Enrique, Merlin, Olivier, Er-Raki, Salah,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.rse.2019.111627"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Remote%20Sensing%20of%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.rse.2019.111627", "name": "item", "description": "10.1016/j.rse.2019.111627", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.rse.2019.111627"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-03-01T00:00:00Z"}}, {"id": "10.1016/j.foreco.2016.03.003", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:13Z", "type": "Journal Article", "created": "2016-03-09", "title": "Contribution Of Acacia Senegal To Biomass And Soil Carbon In Plantations Of Varying Age In Sudan", "description": "Abstract The carbon (C) stocks of drylands, particularly in Africa, have become considerably depleted through land degradation leading to loss of soil fertility and water retention. Increasing tree cover is considered a practical means of increasing soil organic carbon (SOC) contents. However, few field studies have been carried out in the eastern part of the Sahel zone to test this hypothesis. In this study the C stocks in biomass and soil were determined in Acacia senegal plantations of varying age (7\u201324\u00a0years) and adjacent open grasslands in two locations in Sudan. The contribution of C3 plants to SOC was estimated using a simple \u03b413C partitioning model. Total biomass C stocks increased with plantation age, reaching 1020\u00a0g\u00a0m\u22122. While most of this increase was due to the trees, the C stock of the ground vegetation also increased with plantation age and was greater in the oldest plantations than in the open grassland. This finding supports the hypothesis that trees facilitate ground vegetation in semi-arid environments. Plantation SOC stocks (0\u201350\u00a0cm) ranged from 846 to 1250\u00a0g\u00a0m\u22122, increased with age and were greater than open grassland values (867\u2013950\u00a0g\u00a0m\u22122). The contribution of C3 plants (trees and herbs) to plantation under canopies SOC stocks (0\u201310\u00a0cm) was 47.2% and 53.4% at the two sites. SOC sequestration rates up to 19\u00a0g\u00a0C\u00a0m\u22122\u00a0yr\u22121 were achieved in the oldest plantations at one of the sites. Our findings indicate that planting trees in drylands could considerably increase SOC stocks and efforts to plant Acacia trees in the Sahel should therefore be encouraged.", "keywords": ["0106 biological sciences", "2. Zero hunger", "Earth sciences", "info:eu-repo/classification/ddc/550", "550", "ddc:550", "590", "15. Life on land", "01 natural sciences", "630", "6. Clean water", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.foreco.2016.03.003"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Forest%20Ecology%20and%20Management", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.foreco.2016.03.003", "name": "item", "description": "10.1016/j.foreco.2016.03.003", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.foreco.2016.03.003"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-05-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2015.10.009", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:14Z", "type": "Journal Article", "created": "2015-10-23", "title": "High-precision sulfur isotope composition of enstatite meteorites and implications of the formation and evolution of their parent bodies", "description": "Abstract In order to better understand the formation and evolution of their parent bodies, the three isotope ratios of sulfur were analyzed in 33 enstatite meteorites (24 enstatite chondrites and 9 aubrites). The results show that on average all enstatite chondrite groups are enriched in the lightest isotopes compared to other chondrite groups, with means of \u03b4 34 S of \u22120.28\u00a0\u00b1\u00a00.22\u2030 for EH3/4, \u22120.16\u00a0\u00b1\u00a00.16\u2030 for EH5, \u22120.32\u00a0\u00b1\u00a00.15\u2030 for EL3, \u22120.67\u00a0\u00b1\u00a00.16\u2030 for EL6 and \u22120.64\u00a0\u00b1\u00a00.00\u2030 for EL7 (all 1 \u03c3 ). Aubrites show a larger isotope variability in their composition, with a \u03b4 34 S varying from \u22121.350\u2030 to +0.154\u2030. Contrary to previously published results, our data show a distinct composition for EL6 compared to other enstatite chondrites. This could be related to an impact-induced loss of isotopically heavy oldhamite (\u03b4 34 S\u00a0=\u00a0by 3.62\u00a0\u00b1\u00a03.02\u2030 (1 \u03c3 )) on the EL parent body. Although the bulk sulfur in both enstatite meteorites and aubrites does not show any significant \u0394 33 S and \u0394 36 S, the oldhamite fraction shows clear evidence of mass independent fractionation on the 36 S/ 32 S ratio (in 3 out of 9 analyzes, \u0394 36 S up to +2.2\u2030), a signal that is not correlated to any 33 S/ 32 S anomaly (in 1 out of 9 analyzes, \u0394 33 S down to \u22120.085\u2030). Though a nebular or photochemical origin cannot be ruled out, the most plausible mechanism to produce such isolated non-mass dependent 36 S/ 32 S anomalies would be a contribution of FeCl 2 containing excesses of 36 S due to the decay of 36 Cl to the leached oldhamite fraction. Even though the sulfur isotopic composition measured in enstatite meteorites is distinct from the Bulk Silicate Earth (BSE), the isotopically lightest samples of EL6, EL7 and aubrites are approaching the isotopic composition of the BSE and enstatite meteorites remain the meteorites with the sulfur isotopic composition the closest to the terrestrial one.", "keywords": ["550", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "549", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "10. No inequality", "01 natural sciences", "3. Good health", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2015.10.009"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2015.10.009", "name": "item", "description": "10.1016/j.gca.2015.10.009", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2015.10.009"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-01-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2018.04.032", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:14Z", "type": "Journal Article", "created": "2018-05-07", "title": "Constraining compositional proxies for Earth\u2019s accretion and core formation through high pressure and high temperature Zn and S metal-silicate partitioning", "description": "Abstract Zinc is a moderately volatile and slightly siderophile element, and therefore provides information into the timing and conditions of volatile element delivery to Earth as well as the redistribution of these elements during planetary differentiation. Specifically, due to its similar volatility with S, it has been assumed that the Earth and its source material maintain the same relative abundances of these elements, and therefore the same S/Zn ratio. In this study, we have conducted Zn metal-silicate partitioning experiments at pressures up to 81\u202fGPa and temperatures up to 4100\u202fK in diamond anvil cells, for two distinct silicate compositions (one pyrolitic, one basaltic) and varying S contents in order to characterize Zn metal-silicate partitioning as a function of these variables. These results have been input into Earth formation models where various parametric controls have been evaluated\u2013namely source material, impactor size and volatile delivery\u2013to determine plausible sets of conditions that can generate present-day bulk silicate Earth (BSE) Zn and S abundances. Modelling results indicate that to arrive at present-day BSE contents for Zn and S, and with core S contents of \u223c2\u202fwt% or less, the Earth likely accreted heterogeneously \u2013 initially from a volatile-depleted source material compositionally akin to the metal and silicate chondrules of CH chondrites, with later delivery of more volatile-rich material.", "keywords": ["0301 basic medicine", "03 medical and health sciences", "550", "13. Climate action", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2018.04.032"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2018.04.032", "name": "item", "description": "10.1016/j.gca.2018.04.032", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2018.04.032"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-08-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2016.03.006", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:14Z", "type": "Journal Article", "created": "2016-03-11", "title": "Cosmogenic effects on Cu isotopes in IVB iron meteorites", "description": "We measured Cu isotope compositions of 12 out of the 14 known IVB iron meteorites. Our results show that IVB iron meteorites display a very large range of \u03b465Cu values (\u22125.84\u2030\u00a0<\u00a0\u03b465Cu\u00a0<\u00a0\u22120.24\u2030; defined as per mil deviation of the 65Cu/63Cu ratio from the NIST-976 standard). These Cu isotopic data display clear correlations with W, Pt, and Os isotope ratios, which are very sensitive to secondary neutron capture due to galactic cosmic ray (GCR) irradiation. This demonstrates that \u03b465Cu in IVB irons is majorly modified by neutron capture by the reaction 62Ni(n,\u03b3)63Ni followed by beta decay to 63Cu. Using correlations with Pt and Os neutron dosimeters, we calculated a pre-exposure \u03b465Cu of \u22120.3\u00a0\u00b1\u00a00.8\u2030 (95% conf.) of IVB irons that agrees well with the Cu isotopic compositions of other iron meteorite groups and falls within the range of chondrites. This shows that the volatile depletion of the IVB parent body is not due to evaporation that should have enriched IVB irons in the heavy Cu isotopes.", "keywords": ["HF-W CHRONOMETRY", "COPPER", "01 natural sciences", "PROTRACTED CORE FORMATION", "COOLING RATES", "CHONDRITES", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Geochemistry and Petrology", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "RAY-PRODUCED NUCLIDES", "PARENT BODIES", "NEUTRON-CAPTURE", "HETEROGENEITY", "RAPID ACCRETION", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2016.03.006"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2016.03.006", "name": "item", "description": "10.1016/j.gca.2016.03.006", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2016.03.006"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-06-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2016.06.008", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:14Z", "type": "Journal Article", "created": "2016-06-20", "title": "Silicon isotopes reveal recycled altered oceanic crust in the mantle sources of Ocean Island Basalts", "description": "Open Access23 pages, 5 figures, 2 tables", "keywords": ["Ocean Island Basalts", "Earth and Planetary Astrophysics (astro-ph.EP)", "GE", "550", "NDAS", "500", "Silicon isotopes", "FOS: Physical sciences", "7. Clean energy", "01 natural sciences", "12. Responsible consumption", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Recycling", "14. Life underwater", "BDC", "Mantle heterogeneity", "GE Environmental Sciences", "Astrophysics - Earth and Planetary Astrophysics", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2016.06.008"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2016.06.008", "name": "item", "description": "10.1016/j.gca.2016.06.008", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2016.06.008"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-09-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2016.09.013", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:14Z", "type": "Journal Article", "created": "2016-09-22", "title": "Elemental partitioning and isotopic fractionation of Zn between metal and silicate and geochemical estimation of the S content of the Earth\u2019s core", "description": "Open AccessZinc metal-silicate fractionation provides experimental access to the conditions of core formation and Zn has been used to estimate the S contents of the Earth's core and of the bulk Earth, assuming that they share similar volatility and that Zn was not partitioned into the Earth's core. We have conducted a suite of partitioning experiments to characterize Zn metal-silicate elemental and isotopic fractionation as a function of time, temperature, and composition. Experiments were conducted at temperatures from 1473-2273K, with run durations from 5-240 minutes for four starting materials. Chemical and isotopic equilibrium is achieved within 10 minutes. Zinc metal-silicate isotopic fractionation displays no resolvable dependence on temperature, composition, or oxygen fugacity. Thus, the Zn isotopic composition of silicate phases can be used as a proxy for bulk telluric bodies. Results from this study and literature data were used to parameterize Zn metal-silicate partitioning as a function of temperature, pressure, and redox state. Using this parameterization and viable formation conditions, we have estimated a range of Zn contents in the cores of iron meteorite parent bodies (i.e. iron meteorites) of ~0.1-150 ppm, in good agreement with natural observations. We have calculated the first geochemical estimates for the Zn contents of the Earth's core and of the bulk Earth, at 242 +/-107 ppm and 114 +/-34 ppm (respectively), that consider the slightly siderophile behavior of Zn and are therefore significantly higher than previous estimates. Assuming similar volatility for S and Zn, a chondritic S/Zn ratio, and considering our new estimates, we have calculated a geochemical upper bound for the S content of the Earth's core of 6.3 +/-1.9 wt%. This indicates that S may be a major contributor to the density deficit of the Earth's core or that the S/Zn ratio for the Earth is non-chondritic.", "keywords": ["Earth and Planetary Astrophysics (astro-ph.EP)", "550", "[SDU.ASTR.EP] Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]", "FOS: Physical sciences", "01 natural sciences", "Iron meteorites", "13. Climate action", "Core formation", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Zinc metal-silicate partitioning", "Isotopic fractionation", "Sulfur", "Astrophysics - Earth and Planetary Astrophysics", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2016.09.013"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2016.09.013", "name": "item", "description": "10.1016/j.gca.2016.09.013", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2016.09.013"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-01-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2017.09.027", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:14Z", "type": "Journal Article", "created": "2017-09-20", "title": "A history of violence: Insights into post-accretionary heating in carbonaceous chondrites from volatile element abundances, Zn isotopes and water contents", "description": "Open AccessCarbonaceous chondrites (CCs) may have been the carriers of water, volatile and moderately volatile elements to Earth. Investigating the abundances of these elements, their relative volatility, and isotopes of state-change tracer elements such as Zn, and linking these observations to water contents, provide vital information on the processes that govern the abundances and isotopic signatures of these species in CCs and other planetary bodies. Here we report Zn isotopic data for 28 CCs (20 CM, 6 CR, 1 C2-ung, and 1 CV3), as well as trace element data for Zn, In, Sn, Tl, Pb, and Bi in 16 samples (8 CM, 6 CR, 1 C2-ung, and 1 CV3), that display a range of elemental abundances from case-normative to intensely depleted. We use these data, water content data from literature and Zn isotopes to investigate volatile depletions and to discern between closed and open system heating. Trace element data have been used to construct relative volatility scales among the elements for the CM and CR chondrites. From least volatile to most, the scale in CM chondrites is Pb-Sn-Bi-In-Zn-Tl, and for CR chondrites it is Tl-Zn-Sn-Pb-Bi-In. These observations suggest that heated CM and CR chondrites underwent volatile loss under different conditions to one another and to that of the solar nebula, e.g. differing oxygen fugacities. Furthermore, the most water and volatile depleted samples are highly enriched in the heavy isotopes of Zn. Taken together, these lines of evidence strongly indicate that heated CM and CR chondrites incurred open system heating, stripping them of water and volatiles concomitantly, during post-accretionary shock impact(s).", "keywords": ["Earth and Planetary Astrophysics (astro-ph.EP)", "550", "[SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]", "500", "[SDU.ASTR.EP] Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]", "FOS: Physical sciences", "01 natural sciences", "Moderately volatile elements", "Volatity", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Heated meteorites", "Shock impacts", "Carbonaceous chondrites", "Astrophysics - Earth and Planetary Astrophysics", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2017.09.027"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2017.09.027", "name": "item", "description": "10.1016/j.gca.2017.09.027", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2017.09.027"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-01-01T00:00:00Z"}}, {"id": "10.1016/j.gca.2019.06.035", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:14Z", "type": "Journal Article", "created": "2019-07-02", "title": "Experimentally determined Si isotope fractionation between zircon and quartz", "description": "Abstract The silicon isotope composition of detrital quartz and zircon have the potential to inform us about secular changes to the silica cycle and weathering reactions on Earth. However, inferring source melt Si isotope composition from out-of-context minerals is hampered by the fact that, to-date, there is limited Si isotope equilibrium fractionation data for minerals. Here, we report experimental data to constrain Si isotope equilibrium fractionation between zircon and quartz, using two fundamentally different strategies, but with the same experimental design. First, zircon and quartz were hydrothermally synthesized from Zr(OH)4 and SiO2 at 1.5\u202fGPa and temperatures of 725, 800, and 900\u202f\u00b0C. The second experimental strategy utilized the three-isotope method; the starting materials consisted of natural zircon and isotopically-labelled SiO2. Three sets of hydrothermal time-series experiments were conducted at the same pressure and temperatures as the direct synthesis experiments. For all experiments, quartz and zircon were separated and 30Si/28Si and 29Si/28Si ratios were measured by solution multi-collector inductively coupled plasma mass spectrometry. The three-isotope method, which provides the best indicator of equilibrium fractionations, yields the following relationship: \u0394 30 S i ( q t z - z r c ) = ( 0.53 \u00b1 0.14 ) \u00d7 10 6 / T 2 where \u039430Si(qtz-zrc) is the relative difference in 30Si/28Si between quartz and zircon in permil, T is temperature in K, and the error is 2\u202fs.e. This relationship can be used to calculate the fractionation between zircon and other phases, and to estimate the Si isotope composition of the melt from which a zircon crystallized. The results may be used to assess equilibrium-disequilibrium isotope fractionations between quartz and zircon and co-existing phases in igneous rocks. These data can also be applied to out-of-context zircon (and quartz) to estimate the isotope composition of the host rock. Zircons crystallizing from a melt derived from purely igneous sources \u2013 i.e., without the involvement of \u201cweathered\u201d material \u2013 are expected to display a \u03b430SiNBS-28 (permil deviation of the 30Si/28Si from the NBS-28 standard) range from \u22120.7 to \u22120.35\u2030. Deviations from this range indicate assimilation of non-igneous (i.e., sedimentary) material in the melt source.", "keywords": ["Zircon", "GE", "550", "NDAS", "Quartz", "Si isotopes", "7. Clean energy", "01 natural sciences", "Three-istope", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "Igneous", "Three-isotope", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Fractionation", "GE Environmental Sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.gca.2019.06.035"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gca.2019.06.035", "name": "item", "description": "10.1016/j.gca.2019.06.035", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gca.2019.06.035"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-09-01T00:00:00Z"}}, {"id": "10.1016/j.geoderma.2015.04.019", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:18Z", "type": "Journal Article", "created": "2015-04-27", "title": "Application of smoothed particle hydrodynamics (SPH) and pore morphologic model to predict saturated water conductivity from X-ray CT imaging in a silty loam Cambisol", "description": "20 This study aims to estimate saturated hydraulic conductivity in a silty loam soil and compare modelled data with 21 experimental ones. The flow characteristics of twelve undisturbed soil cores (5 cm in diameter \u00d7 6 cm high) were 22 measured in the laboratory after performing X-ray computed microtomography (microCT) analysis. MicroCT 3D 23 imaging was integrated with an existing pore morphologic model and a numerical simulation based on mesh-24 free smoothed particle hydrodynamics (SPH) to calculate the water flow through the macropore network 25 (pores N 40 \u03bcm). Results showed that the proposed SPH method was able to predict hydraulic conductivity of 26 large-sized samples as falling in the range of the experimental ones. By contrast the morphologic model generally 27 underestimated the water flow and was slightly affected by the pore shape. Increasing microCT imaging resolu-28 tion and expanding the variability with other soil types will improve the understanding of the role of micropore 29 size and morphology on water conductivity. 30", "keywords": ["2. Zero hunger", "550", "[ SDV.SA.SDS ] Life Sciences [q-bio]/Agricultural sciences/Soil study", "0207 environmental engineering", "600", "04 agricultural and veterinary sciences", "02 engineering and technology", "Pore size distribution", "[ SDE.IE ] Environmental Sciences/Environmental Engineering", "Saturated hydraulic conductivity", "Soil structure", "0401 agriculture", " forestry", " and fisheries", "[ SDU.STU.HY ] Sciences of the Universe [physics]/Earth Sciences/Hydrology", "X-ray computed microtomography"]}, "links": [{"href": "https://doi.org/10.1016/j.geoderma.2015.04.019"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geoderma", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.geoderma.2015.04.019", "name": "item", "description": "10.1016/j.geoderma.2015.04.019", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.geoderma.2015.04.019"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2015-10-01T00:00:00Z"}}, {"id": "10.1016/j.geoderma.2025.117290", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:20Z", "type": "Journal Article", "created": "2025-04-11", "title": "Soil structural indicators as predictors of biological activity under various soil management practices", "description": "Soil structure is a key feature in controlling the turnover of organic matter in soils. The spatial arrangement of solids and pores in agricultural topsoil can be actively influenced by management practices, such as tillage and cropping systems, which in turn can affect the resident microbial communities and their activities. However, carbon mineralisation and microbial activity are usually measured in sieved samples, which provides information on gross potentials under optimal conditions. Under these conditions, the spatial heterogeneities that are specific to different management practices are reduced or totally removed. In this study, we combined X-ray computer tomography (X-ray CT) and isothermal calorimetry to investigate the effect of soil structure on heat dissipation, as an indicator of biological activity. Samples were collected from the topsoil of a long-term field experiment (12\u00a0years) that included four different land uses: conventional vs. reduced tillage, each with either maize or winter wheat as the main crop in the rotation. We compared the response of undisturbed soil cores (3\u00a0cm in height, 2.7\u00a0cm in diameter) to the addition of water and glucose in specific pore sizes, ranging in radii of 15 to 75\u00a0\u00b5m or 3 to 75\u00a0\u00b5m. The pore structure and indicators of particulate organic material were quantified using X-ray CT with a voxel resolution of 15\u00a0\u00b5m. This allowed us to distinguish between the effects of crop rotation and tillage regime on biological activity, soil structure and the feedback between the two. Heat dissipation correlated significantly with X-ray CT derived porosity, pore surface density and soil matrix grey value, all of which were affected by both tillage regime and crop rotation. Heat dissipation in maize plots after glucose addition to the pore size range with radii of 3 to 75\u00a0\u00b5m was greater than in the winter wheat systems, but not when added to the pore size range with radii of 15 to 75\u00a0\u00b5m. The study showed that structural indicators can explain up to 81\u00a0% and 95\u00a0% of the variance in total heat dissipation after glucose and water addition, respectively, but only 60\u00a0% of the heat dynamics, here defined as the time taken for 50\u00a0% of total heat to be dissipated. The results emphasise the importance of soil structure in regulating microbial decomposition of soil organic matter and warrants further investigations.", "keywords": ["X-ray CT", "Crop rotation", "Biological activity", "Science", "Soil structure", "Q", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "Soil Science", "Tillage regime", "Micro-habitat", "Calorimetry"]}, "links": [{"href": "https://pub.epsilon.slu.se/37077/1/leuther-f-et-al-20250508.pdf"}, {"href": "https://doi.org/10.1016/j.geoderma.2025.117290"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geoderma", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.geoderma.2025.117290", "name": "item", "description": "10.1016/j.geoderma.2025.117290", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.geoderma.2025.117290"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2025-05-01T00:00:00Z"}}, {"id": "10.1016/j.geodrs.2024.e00801", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:20Z", "type": "Journal Article", "created": "2024-04-20", "title": "National-scale digital soil mapping performances are related to covariates and sampling density: Lessons from France", "description": "Accurate soil property and class predictions through spatial modelling necessitate a thoughtful selection of explanatory variables and sample size, as their choice greatly impacts model performance. Within the framework of Global Soil Nutrient and Nutrient Budgets maps (GSNmap), the FAO Global Soil Partnership (GSP) launched a country-driven digital soil mapping (DSM) approach. The GSP asked the countries if they could implement the DSM prediction of ten soil properties, using their national point data and a set of widely available covariates (GSP_Cov). In this study, we examined the effect of including additional national-based covariates and soil observations on the performance of the prediction models using mainland France as a pilot. The learning soil dataset was based on a systematic 16-to-16\u202fkm grid. For a subset of soil properties, we also assessed using repeated k-fold cross-validation the effect of adding to this dataset many other irregularly spread measurements. The GSP_Cov included common widely available covariates that represented information about terrain, climate, and organisms. The second set of covariates consisted of the GSP_Cov, extended to extra covariates available at a national level, such as previously existing soil maps, geological maps, remote sensing products and others. Random Forest approach in combination with the Boruta selection method was employed for mapping ten soil properties: soil organic carbon (SOC), pH (water), total nitrogen (N), available phosphorus (P), available potassium (K), cation exchange capacity (CEC), bulk density (BD), and texture (clay, silt, and sand). The results revealed noteworthy enhancements in prediction performance for more than half of the properties, although, for some of them, the improvements were negligible. The most significant improvements were obtained for pH, CEC and texture, where geological variables and a previous pH map significantly contributed to the increase in accuracy. Adding numerous points (around 25,000) to the learning dataset improved the performance of soil particle-size fractions predictions. By broadening the spectrum of covariates and better covering the feature and geographical spaces considered in soil prediction models, this research underscores the importance of implementing a more diverse range of covariates at a national scale and of densifying soil information to enlarge the feature and geographical spaces of multidimensional soil/covariates combinations. This information should be taken into account in national and continental digital soil mapping endeavours.", "keywords": ["2. Zero hunger", "Soil", "Digital soil mapping", "13. Climate action", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "[SDU.STU]Sciences of the Universe [physics]/Earth Sciences", "Spatial sampling", "[SDV.SA.SDS]Life Sciences [q-bio]/Agricultural sciences/Soil study", "15. Life on land", "[SDV.SA.SDS] Life Sciences [q-bio]/Agricultural sciences/Soil study", "Covariates", "Modelling", "Random forest"], "contacts": [{"organization": "Suleymanov, Azamat, Richer-De-Forges, Anne C, Saby, Nicolas P. A., Arrouays, Dominique, Martin, Manuel P, Bispo, Antonio,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.geodrs.2024.e00801"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geoderma%20Regional", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.geodrs.2024.e00801", "name": "item", "description": "10.1016/j.geodrs.2024.e00801", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.geodrs.2024.e00801"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-06-01T00:00:00Z"}}, {"id": "10.1016/j.gexplo.2025.107868", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:21Z", "type": "Journal Article", "created": "2025-07-21", "title": "Improving spatial interpolation for anomaly analysis in presence of sparse, clustered or imprecise data sets", "description": "In this study, we present a new method of interpolation and anomaly detection especially designed for sparse, clustered or imprecise environmental data (SIC). Such data cannot be processed by current state of the art spatial methods and models, including the most widely used, such as kriging. Indeed, the statistics obtained on SIC data (on the order of 5\u201330) do not allow us to define a covariance or to calibrate the numerous hyper-parameters of sophisticated Bayesian or deep image prior models. We therefore adapted an information dissemination algorithm to handle SIC data. This probabilistic model has been enriched (anisotropy, de-clustering, auto-variography, multi-support, treatment of covariates, and censored data) in a way that fully meets the needs for environmental SIC data and can be used in conjunction with hybrid propagation of epistemic and aleatoric uncertainties and anomaly detection, whatever their mathematical form. The new interpolator for anomaly detection was applied on a very small set of 13 sparse data points characteristic of small-scale environmental studies, on digital-challenge datasets and on two real datasets, i.e., a large-scale geochemical dataset and a SIC urban soil dataset. Results highlight the added value of the proposed algorithm, that is able to pinpoint anomalies in SIC data, while avoiding in particular the smoothing effects of certain previous methods", "keywords": ["Sparse clustered", "Uncertainty", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "Spatial interpolation", "Anomaly detection", "European geochemistry"], "contacts": [{"organization": "Belb\u00e8ze, St\u00e9phane, Rohmer, J\u00e9r\u00e9my, Guyonnet, Dominique, N\u00e9grel, Philippe, Tarvainen, Timo,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.gexplo.2025.107868"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Geochemical%20Exploration", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.gexplo.2025.107868", "name": "item", "description": "10.1016/j.gexplo.2025.107868", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.gexplo.2025.107868"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2025-12-01T00:00:00Z"}}, {"id": "10.1016/j.heliyon.2019.e02288", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:21Z", "type": "Journal Article", "created": "2019-08-14", "title": "Defluoridation of water through the transformation of octacalcium phosphate into fluorapatite", "description": "The consumption of water with fluoride concentration higher than 1.5 mg/L (WHO recommended limit) is recognized to cause serious diseases, and fluoride removal from natural contaminated waters is a health priority for more than 260 million people worldwide. The octacalcium phosphate (OCP), a mineralogical precursor of bio-apatite, is here tested as a fluoride remover. A new two-step method for the synthesis of OCP is proposed: 1) synthesis of brushite from calcium carbonate and phosphoric acid; 2) subsequent hydrolysis of brushite. Fluoride removal experiments are performed in batch-mode using different initial concentrations of fluoride (from 40 to 140 mg/L) and reaction times. Most of fluoride is removed within the first 2 h of all experiments, and the drinkable limit of 1.5 mg/L is reached within a minimum of 3 h for an initial fluoride concentration of 40 mg/L. The experimental fluoride removal capacity of OCP is 25.7 mg/g, and 4 g of OCP can effectively treat 1 L of water with fluoride concentration up to 50 times higher than the drinking limit of 1.5 mg/L. XRD and chemical characterization of the solid phases, before and after the removal experiments, indicate that OCP transforms into fluorapatite (FAP) uptaking fluoride from solution.", "keywords": ["H1-99", "Science (General)", "02 engineering and technology", "01 natural sciences", "Dissolved fluoride removal;Earth sciences; Environmental geochemistry; Environmental pollution; Environmental science; Materials science; Materials synthesis; OCP synthesis; OCP-FAP transformation; Water defluoridation method; Water pollution; Water quality", "Materials science", "Environmental science", "Environmental pollution", "Article", "6. Clean water", "Social sciences (General)", "Q1-390", "Water pollution", "Environmental geochemistry", "Materials synthesis", "0210 nano-technology", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://iris.unica.it/bitstream/11584/276011/1/Heliyon%202019.pdf"}, {"href": "https://doi.org/10.1016/j.heliyon.2019.e02288"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Heliyon", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.heliyon.2019.e02288", "name": "item", "description": "10.1016/j.heliyon.2019.e02288", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.heliyon.2019.e02288"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-08-01T00:00:00Z"}}, {"id": "10.1016/j.jconhyd.2018.03.004", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:25Z", "type": "Journal Article", "created": "2018-03-18", "title": "Comparison of theory and experiment for NAPL dissolution in porous media", "description": "Contamination of groundwater resources by an immiscible organic phase commonly called NAPL (Non Aqueous Phase Liquid) represents a major scientific challenge considering the residence time of such a pollutant. This contamination leads to the formation of NAPL blobs trapped in the soil and impact of this residual saturation cannot be ignored for correct predictions of the contaminant fate. In this paper, we present results of micromodel experiments on the dissolution of pure hydrocarbon phase (toluene). They were conducted for two values of the P\u00e9clet number. These experiments provide data for comparison and validation of a two-phase non-equilibrium theoretical model developed by Quintard and Whitaker (1994) using the volume averaging method. The model was directly upscaled from the averaged pore-scale mass balance equations. The effective properties of the macroscopic model were calculated over periodic unit cells designed from images of the experimental flow cell. Comparison of experimental and numerical results shows that the transport model predicts correctly - with no fitting parameters - the main mechanisms of NAPL mass transfer. The study highlights the crucial need of having a fair recovery of pore-scale characteristic lengths to predict the mass transfer coefficient with accuracy.", "keywords": ["Volume averaging method", "[SPI.FLUID]Engineering Sciences [physics]/Reactive fluid environment", "0208 environmental biotechnology", "Porous media", "0207 environmental engineering", "02 engineering and technology", "Models", " Theoretical", "Porous media flow", "Hydrocarbons", "6. Clean water", "[SPI.MECA.MEFL]Engineering Sciences [physics]/Mechanics [physics.med-ph]/Fluids mechanics [physics.class-ph]", "Soil", "Solubility", "Upscaling transport", "13. Climate action", "Volume Averaging", "Upscaling", "NAPL dissolution", "[SDU.STU.HY]Sciences of the Universe [physics]/Earth Sciences/Hydrology", "Hydrology", "Groundwater", "Porosity", "Water Pollutants", " Chemical", "Toluene"]}, "links": [{"href": "https://doi.org/10.1016/j.jconhyd.2018.03.004"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Contaminant%20Hydrology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.jconhyd.2018.03.004", "name": "item", "description": "10.1016/j.jconhyd.2018.03.004", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.jconhyd.2018.03.004"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-04-01T00:00:00Z"}}, {"id": "10.1016/j.jenvman.2019.02.120", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:26Z", "type": "Journal Article", "created": "2019-03-06", "title": "Distribution trend of trace elements in digestate exposed to air: Laboratory-scale investigations using DGT-based fractionation", "description": "The use of digestate as amendment for agricultural soils has already been proposed as an alternative to mineral fertilizers or undigested organic matter. However, little information is available concerning the effect of digestate atmospheric exposure on trace elements speciation and, consequently, on their mobility and bio-accessibility when digestate is stored in open tanks or handled before land spreading. In this study, we investigated at laboratory-scale the effect of digestate aeration on the distribution of Al, As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Se and W using the diffusive gradients in thin films technique (DGT)-based fractionation. For this purpose, experiments were performed to assess the variation in distribution between the labile, soluble and particulate fractions over time in digested sewage sludge during passive and forced aeration. Results showed that aeration promoted a dissolution of Al, As, Co, Cr, Cu, Fe, Mn, Mo and Pb, suggesting a possible increase in their mobility that may likely occur during storage in open tanks or handling before land spreading. Labile elements' fraction increased only during forced aeration (except for Fe and Mn), suggesting that their short-term bio-accessibility can increase only after significant aeration as the one assumed to occur when land spreading takes place.", "keywords": ["550", "[SPI.GPROC] Engineering Sciences [physics]/Chemical and Process Engineering", "Speciation", "[SDU.STU]Sciences of the Universe [physics]/Earth Sciences", "Diffusive gradients in thin films (DGT)", "Chemical Fractionation", "01 natural sciences", "630", "Soil", "Digested sewage sludge", "[SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering", "Fractionation", "Diffusive gradients in thin films (DGT); Digested sewage sludge; Fractionation; Metalloids; Metals; Speciation; Chemical Fractionation; Environmental Monitoring; Sewage; Soil; Trace Elements", "Metalloids", "0105 earth and related environmental sciences", "2. Zero hunger", "Sewage", "04 agricultural and veterinary sciences", "15. Life on land", "6. Clean water", "Trace Elements", "Metals", "13. Climate action", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "0401 agriculture", " forestry", " and fisheries", "Environmental Monitoring"]}, "links": [{"href": "https://doi.org/10.1016/j.jenvman.2019.02.120"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Environmental%20Management", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.jenvman.2019.02.120", "name": "item", "description": "10.1016/j.jenvman.2019.02.120", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.jenvman.2019.02.120"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-05-01T00:00:00Z"}}, {"id": "10.1016/j.jhazmat.2024.136496", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:28Z", "type": "Journal Article", "created": "2024-11-17", "title": "Mobilization of poly- and perfluoroalkyl substances (PFAS) from heterogeneous soils: Desorption by ethanol/xanthan gum mixture", "description": "Remediating soils contaminated by per- and polyfluoroalkyl substances (PFAS) is a challenging task due to the unique properties of these compounds, such as variable solubility and resistance to degradation. In-situ soil flushing with solvents has been considered as a remediation technique for PFAS-contaminated soils. The use of non-Newtonian fluids, displaying variable viscosity depending on the applied shear rate, can offer certain advantages in improving the efficiency of the process, particularly in heterogeneous porous media. In this work, the efficacy of ethanol/xanthan mixture (XE) in the recovery of a mixture of perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA), perfluorohexane sulfonate (PFHxS), and perfluorobutane sulfonate (PFBS) from soil has been tested at lab-scale. XE's non-Newtonian behavior was examined through rheological measurements, confirming that ethanol did not affect xanthan gum's (XG) shear-thinning behavior. The recovery of PFAS in batch-desorption exceeded 95\u00a0% in ethanol, and 99\u00a0% in XE, except for PFBS which reached 94\u00a0%. 1D-column experiments revealed overshoots in PFAS breakthrough curves during ethanol and XE injection, due to over-solubilization. XE, (XG 0.05\u00a0% w/w) could recover 99\u00a0% PFOA, 98\u00a0% PFBS, 97\u00a0% PFHxS, and 92\u00a0% PFOS. Numerical modeling successfully reproduces breakthrough curves for PFOA, PFHxS, and PFBS with the convection-dispersion-sorption equation and Langmuir sorption isotherm.", "keywords": ["Heterogeneity of porous media", "PFAS", "628", "H2020", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "[SDU.STU]Sciences of the Universe [physics]/Earth Sciences", "Desorption", "551", "Alcohol", "PROMISCES", "Poly- and perfluoroalkyl substances (PFAS)", "Non-Newtonian fluids (NNF)"], "contacts": [{"organization": "Batikh, Ali, Colombano, St\u00e9fan, Cochennec, Maxime, Davarzani, Dorian, Perrault, Arnault, Lions, Julie, Grandcl\u00e9ment, Julien, Guyonnet, Dominique, Togola, Anne, Zornig, Cl\u00e9ment, Devau, Nicolas, Lion, Fabien, Alamooti, Amir, Bristeau, S\u00e9bastien, Djemil, Mohamed, van Hullebusch, E.D.,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.jhazmat.2024.136496"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Hazardous%20Materials", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.jhazmat.2024.136496", "name": "item", "description": "10.1016/j.jhazmat.2024.136496", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.jhazmat.2024.136496"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2025-01-01T00:00:00Z"}}, {"id": "10.1016/j.ocecoaman.2018.04.019", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:30Z", "type": "Journal Article", "created": "2018-05-09", "title": "Loss And Recovery Of Carbon And Nitrogen After Mangrove Clearing", "description": "Abstract Offsetting carbon (C) emissions and reducing nitrogen (N) pollution have been goals of mangrove restoration programs around the world. There is a common, yet dubious expectation that mangrove restoration will result in immediate and perpetual delivery of ecosystem services. There are expected time lags between mangrove clearing and C and N losses, and between restoration and C and N gains. Obtaining accurate rates of losses and gains requires frequent and long-term sampling, which is expensive and time consuming. To address this knowledge gap, we used a chronosequence of mangrove forests in mangroves in Matang Mangrove Forest Reserve (MMFR) in Malaysia, a region with one of the most C dense forests in the world. In this site, we assessed the ecosystem C and N stocks, including soil, downed wood, downed litter, and trees. The objective was to measure C and N changes through time. After mangrove clearing, C and N losses in soil and downed wood were rapid, with stocks halved after just one year. In the first 10 years after replantation, the forest recovered quickly, with rates of C accumulation of 9.5\u202fMg\u202fC\u202fha\u22121 yr\u22121. After ten years, the rate of accumulation decreased to 2.8\u202fMg\u202fC\u202fha\u22121 yr\u22121. However, 40 years after replantation, mangroves were still about 26% lower in C and 15% lower in N compared to our reference forest. The trajectory of recovery of C and N stocks in these forests was different among mangrove components: forest litter recovered rapidly, but downed wood and soil recovered much slower. Programs aimed at reducing C emissions and N pollution should consider that there are temporal lags and ecosystem trade-offs when assessing the effectiveness of mangrove protection and restoration as climate change mitigation strategies.", "keywords": ["Environmental sciences", "580", "0106 biological sciences", "Earth sciences", "570", "13. Climate action", "QH Natural history", "Human society", "Q Science (General)", "Marine and estuarine ecology (incl. marine ichthyology)", "15. Life on land", "01 natural sciences", "333"], "contacts": [{"organization": "Adame, MF, Zakaria, RM, Fry, B, Chong, VC, Then, YHA, Brown, CJ, Lee, SY,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.ocecoaman.2018.04.019"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Ocean%20%26amp%3B%20Coastal%20Management", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.ocecoaman.2018.04.019", "name": "item", "description": "10.1016/j.ocecoaman.2018.04.019", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.ocecoaman.2018.04.019"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-07-01T00:00:00Z"}}, {"id": "10.1016/j.quascirev.2018.09.037", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:32Z", "type": "Journal Article", "created": "2018-10-06", "title": "Short-term soil formation events in last glacial east European loess, evidence from multi-method luminescence dating", "description": "Here we provide a robust luminescence chronology for Stayky (Ukraine), a reference profile in European Late Pleistocene loess stratigraphy, based on optically stimulated luminescence (OSL) dating on quartz (4-11 \u03bcm, 63-90 \u03bcm) and post infrared-infrared stimulated luminescence (pIR-IRSL)) on polymineral fine grains. For the Bug loess unit, the equivalent of Marine Isotope Stage (MIS 2), results are in agreement between methods, demonstrating that the suite of embryonic soils previously interpreted as reflecting climate variability similar to Greenland interstadials (GI) actually date to \u223c29/27-15 ka, with most emplaced around or after 20 ka. This temporal span is further confirmed by age-depth modelling of available data. Apart from GI-2, no interstadial-type climate events are recorded in Greenland ice core data for that time interval. As short-term pedogenetic phases are also documented in records from central-western Europe, there is a need for more research into the European mid-latitude terrestrial environments response to MIS 2 hydroclimate variability. The dating of Vytachiv paleosol, previously debatably linked to various GI events within MIS 3 resulted in ages of \u223c40 \u00b1 4 ka and \u223c53 \u00b1 4 ka at the lower transition, and \u223c26 \u00b1 2 ka to \u223c30 \u00b1 2 ka in the overlying loess. These ages indicate that the truncated Vytachiv paleosol is either not continuous, or that it encompasses a broader age range within MIS 3 than previously considered. In both cases, data would not allow for an unambiguous linking of this paleosol with specific GI events as previously attempted. The pIR-IRSL290 dating of the loams immediately underneath Pryluky unit in the range of \u223c120 ka to \u223c168 ka and of the Pryluky mollisol from \u223c90 ka to 126 ka confirm the broad correspondence of this unit with MIS 5, although poor dose recovery results open the possibility for further testing on the degree these ages provide overestimated results. Quartz data severely underestimate the pIR-IRSL290 ages for these samples. The application of pIR-IRSL290 dating for the underlying Dnieper till previously linked to the Saalian glaciation resulted in natural signals at the level of laboratory saturation, yielding minimum ages of c. 700 ka. For the same sample, the natural SAR-OSL signals for 4-11 \u03bcm quartz were found significantly below laboratory saturation level, resulting in finite ages of \u223c250-270 ka interpreted here as underestimates, while coarse quartz (63-90 \u03bcm) signals reached about 85% of the laboratory saturation level. These data suggest extreme caution must be taken when dating such old samples using quartz OSL. Results from our high-resolution luminescence dating raises important implications for the chronological representativeness of Stayky as a key loess site in Eastern Europe beyond MIS 2.", "keywords": ["Embryonic soils", "550", "Millennial-scale loess records", "Luminescence dating", "Loess", "Eastern Europe", "551", "Climate dynamics", "Pleistocene", "[SDU.STU.CL] Sciences of the Universe [physics]/Earth Sciences/Climatology", "[SDU.STU.CL]Sciences of the Universe [physics]/Earth Sciences/Climatology", "13. Climate action", "[SDU.STU.ST]Sciences of the Universe [physics]/Earth Sciences/Stratigraphy", "[SDU.STU.ST] Sciences of the Universe [physics]/Earth Sciences/Stratigraphy", "MIS 2 embryonic soils"]}, "links": [{"href": "https://doi.org/10.1016/j.quascirev.2018.09.037"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Quaternary%20Science%20Reviews", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.quascirev.2018.09.037", "name": "item", "description": "10.1016/j.quascirev.2018.09.037", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.quascirev.2018.09.037"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-11-01T00:00:00Z"}}, {"id": "10.1016/j.renene.2019.03.134", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:32Z", "type": "Journal Article", "created": "2018-09-04", "title": "Scoping the potential usefulness of seasonal climate forecasts for solar power management", "description": "Solar photovoltaic energy is widespread worldwide and particularly in Europe, which became in 2016 the first region in the world to pass the 100\u202fGW of installed capacity. As with all the renewable energy sources, for an effective management of solar power, it is essential to have reliable and accurate information about weather/climate conditions that affect the production of electricity. Operations in the solar energy industry are normally based on daily (or intra-daily) forecasts. Nevertheless, information about the incoming months can be relevant to support and inform operational and maintenance activities. This paper discusses a methodology to assess whether a seasonal climate forecast can provide a useful prediction for a specific sector, in this paper the European solar power industry. After evaluating the quality of the forecasts in providing probabilistic information for solar radiation, we describe how to assess their potential usefulness for a generic user by proposing an approach that takes into account not only their accuracy but also other potentially relevant factors. This approach is called index of opportunity and is then illustrated by presenting an example for the European solar power sector. The index of opportunity provides indications about where and when seasonal climate forecasts can benefit the decision-making in the photovoltaic sector. Even more importantly, it suggests an approach on how to evaluate their usefulness for the user's decision-making. This approach has the advantage of not limiting the definition of the usefulness only to the quality of the forecasts but rather considering, in an explicit way, all the factors that must be combined with the forecast's quality to define what is useful or not for the user.", "keywords": ["bepress|Physical Sciences and Mathematics", "330", "EarthArXiv|Physical Sciences and Mathematics|Environmental Sciences|Sustainability", "EarthArXiv|Physical Sciences and Mathematics|Environmental Sciences", "bepress|Physical Sciences and Mathematics|Earth Sciences", "02 engineering and technology", "EarthArXiv|Physical Sciences and Mathematics|Earth Sciences", "7. Clean energy", "01 natural sciences", "EarthArXiv|Physical Sciences and Mathematics", "Sustainability", "13. Climate action", "Physical Sciences and Mathematics", "Earth Sciences", "0202 electrical engineering", " electronic engineering", " information engineering", "bepress|Physical Sciences and Mathematics|Environmental Sciences", "bepress|Physical Sciences and Mathematics|Environmental Sciences|Sustainability", "Environmental Sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://eprints.whiterose.ac.uk/149508/1/usefulness-climate-fcsts-solar-power.revised_3rd.pdf"}, {"href": "https://ueaeprints.uea.ac.uk/id/eprint/70701/1/Accepted_Manuscript.pdf"}, {"href": "https://doi.org/10.1016/j.renene.2019.03.134"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Renewable%20Energy", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.renene.2019.03.134", "name": "item", "description": "10.1016/j.renene.2019.03.134", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.renene.2019.03.134"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-09-04T00:00:00Z"}}, {"id": "10.1016/j.rse.2025.114918", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:33Z", "type": "Journal Article", "created": "2025-07-23", "title": "Spectral indices in remote sensing of soil: definition, popularity, and issues. A critical overview", "description": "Serving as a powerful proxy in remote sensing studies, spectral indices can generate meaningful environmental interpretation from either raw or atmospherically corrected spectral data, and characterise and quantify some important properties of various objects on Earth\u2019s surface. However, while numerous spectral indices have been developed over time, since the very launch of civilian satellites until now, some critical issues in their usage, such as comparability, remain scarcely studied, which may lead to incorrect, inconsistent, and unreliable results. In this study, we collected 471 spectral indices of various environment components (vegetation, water, and soil) that might be leveraged for soil studies, and traced their popularity in scientific publications over the past decades. The bibliometric analysis revealed a growing interest and utilisation of spectral indices as Earthobserving satellite technology advanced. Based on both literature and, for sake of complementation and illustration, some targeted regional-scale case studies, we discuss the issues of naming confusion, comparability, applicability, accuracy trade-offs, and reproducibility of using spectral indices. Overall, this overview provides an extensive list of spectral indices, both soil indices and soil-related indices, that can be useful for characterising these environment components by remote sensing. It draws attention to some misuses and confusions that must be avoided to prevent scientific pitfalls. The comparisons between different spectral indices, sensors, and correction methods, highlight the confusing effects that the misuse and non-standardised practices of the spectral indices useful for soil, may have on soil property mapping and monitoring. Insights to the judicious and appropriate usage of spectral indices in the remote sensing of soil are provided.", "keywords": ["monitoring", "remote sensing", "vegetation", "soil properties", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "spectral indices", "water bodies", "bibliometrics", "[SDV.SA.SDS] Life Sciences [q-bio]/Agricultural sciences/Soil study"]}, "links": [{"href": "https://doi.org/10.1016/j.rse.2025.114918"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Remote%20Sensing%20of%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.rse.2025.114918", "name": "item", "description": "10.1016/j.rse.2025.114918", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.rse.2025.114918"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2025-11-01T00:00:00Z"}}, {"id": "10.1029/2019jd030387", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:17:12Z", "type": "Journal Article", "created": "2019-06-19", "title": "Global 3-D Simulations of the Triple Oxygen Isotope Signature \u0394 17 O in Atmospheric CO 2", "description": "AbstractThe triple oxygen isotope signature \uffce\uff9417O in atmospheric CO2, also known as its \uffe2\uff80\uff9c17O excess,\uffe2\uff80\uff9d has been proposed as a tracer for gross primary production (the gross uptake of CO2 by vegetation through photosynthesis). We present the first global 3\uffe2\uff80\uff90D model simulations for \uffce\uff9417O in atmospheric CO2 together with a detailed model description and sensitivity analyses. In our 3\uffe2\uff80\uff90D model framework we include the stratospheric source of \uffce\uff9417O in CO2 and the surface sinks from vegetation, soils, ocean, biomass burning, and fossil fuel combustion. The effect of oxidation of atmospheric CO on \uffce\uff9417O in CO2 is also included in our model. We estimate that the global mean \uffce\uff9417O (defined as with \uffce\uffbbRL = 0.5229) of CO2 in the lowest 500\uffc2\uffa0m of the atmosphere is 39.6\uffc2\uffa0per meg, which is \uffe2\uff88\uffbc20\uffc2\uffa0per meg lower than estimates from existing box models. We compare our model results with a measured stratospheric \uffce\uff9417O in CO2 profile from Sodankyl\uffc3\uffa4 (Finland), which shows good agreement. In addition, we compare our model results with tropospheric measurements of \uffce\uff9417O in CO2 from G\uffc3\uffb6ttingen (Germany) and Taipei (Taiwan), which shows some agreement but we also find substantial discrepancies that are subsequently discussed. Finally, we show model results for Zotino (Russia), Mauna Loa (United States), Manaus (Brazil), and South Pole, which we propose as possible locations for future measurements of \uffce\uff9417O in tropospheric CO2 that can help to further increase our understanding of the global budget of \uffce\uff9417O in atmospheric CO2.
", "keywords": ["CARBONIC-ANHYDRASE ACTIVITY", "550", "STRATOSPHERIC CO2", "STOMATAL CONDUCTANCE", "TRACER", "stable isotopes", "MASS", "carbon dioxide (CO)", "01 natural sciences", "7. Clean energy", "DIOXIDE EXCHANGE", "O excess (\u0394O)", "3-DIMENSIONAL SYNTHESIS", "carbon dioxide (CO2)", "carbon cycle", "O-17 excess (Delta O-17)", "SDG 13 - Climate Action", "SDG 14 - Life Below Water", "Research Articles", "0105 earth and related environmental sciences", "O-18 CONTENT", "info:eu-repo/classification/ddc/550", "mass-independent fractionation (MIF)", "ddc:550", "gross primary production (GPP)", "15. Life on land", "Earth sciences", "13. Climate action", "MODEL TM5", "17O excess (\u039417O)", "FIRE EMISSIONS"]}, "links": [{"href": "https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2019JD030387"}, {"href": "https://doi.org/10.1029/2019jd030387"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Geophysical%20Research%3A%20Atmospheres", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1029/2019jd030387", "name": "item", "description": "10.1029/2019jd030387", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1029/2019jd030387"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-08-04T00:00:00Z"}}, {"id": "10.1016/j.scib.2018.01.018", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:33Z", "type": "Journal Article", "created": "2018-01-31", "title": "Barium isotope cosmochemistry and geochemistry", "description": "While the isotopic variations of barium were reported for the first time fourty years ago, the number of studies on barium isotopes significantly increased only after 2010. Barium isotope anomalies in meteorites have been successfully used to provide constraints about the origin of presolar SiC grains. In carbonaceous chondrites Ba isotope anomalies are indicative of the heterogeneity of the early solar system, possibly resulting from of a later injection of material after the cooling of solar system. Barium isotope fractionation in the same carbonaceous chondrites suggests that a strong magnetic field was present in the innermost part of the early solar system. Barium mass-dependent isotope fractionation has also been detected throughout Earth surface materials. While igneous rocks show limited Ba isotopic variations, relatively large isotopic variations are observed amongst and within soils, rivers, and biological materials. Indeed, plants seem to fractionate Ba isotopes during Ba uptake from soil solutions. Therefore, Ba isotope signatures have the potential to provide clues on the biological cycling of Ba at the Earth surface. In seawater, Ba isotopic variations have been mapped out, and are mainly related to barite precipitation, which is in turn related to organic matter remineralization in the water column. This makes Ba isotopes a potentially powerful tool to reconstruct past ocean productivity, although constraints are still lacking regarding the inputs of dissolved Ba to the oceans by rivers or hydrothermalism.", "keywords": ["13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDU.OTHER] Sciences of the Universe [physics]/Other", "01 natural sciences", "[SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces", " environment", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Fr\u00e9d\u00e9ric Moynier, Fr\u00e9d\u00e9ric Moynier, Julien Bouchez, Quentin Charbonnier,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.scib.2018.01.018"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20Bulletin", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.scib.2018.01.018", "name": "item", "description": "10.1016/j.scib.2018.01.018", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.scib.2018.01.018"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-03-01T00:00:00Z"}}, {"id": "10.3929/ethz-b-000663192", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:19:53Z", "type": "Journal Article", "title": "Vivianite formation and transformation processes in intertidal sediments and the influence of isomorphic substitution", "description": "unspecifiedPhosphor (P) ist ein wesentlicher N\u00e4hrstoff f\u00fcr die Prim\u00e4rproduktion in aqautischen \u00d6kosystemen, aber \u00fcberm\u00e4\u00dfiger P Eintrag kann zur Eutrophierung dieser \u00d6kosysteme f\u00fchren. Wie P in Sedimenten gebunden ist, wirkt sich auf dessen Bioverf\u00fcgbarkeit aus. Unter reduzierenden, sulfid-freien Bedingungen kann das eisenhaltige Phosphatmineral Vivianit eine wesentliche Rolle bei der P-Bindung in K\u00fcstensedimenten spielen und somit die Wasserqualit\u00e4t positiv beeinflussen. Trotz der Bedeutung von Vivianit f\u00fcr die Regulierung der P-Verf\u00fcgbarkeit in K\u00fcstensedimenten sind die in-situ Bildung, Zusammensetzung und Stabilit\u00e4t von Vivianit nur unzureichend untersucht. In dieser Doktorarbeit wurden Feldexperimente mit einer Laborstudie kombiniert, um die Bildungs- und Umwandlungsprozesse von Vivianit in gezeitenbeeinflussten Sedimenten und den Einfluss der isomorphen Substitution auf diese Prozesse aufzudecken. Diese Erkenntnisse bieten wertvolle Einblicke in die Prozesse des P-Kreislaufs in K\u00fcstensedimenten und sind bedeutend f\u00fcr die Entwicklung industrieller Anwendungen, die darauf abzielen, den anthropogenen P-Kreislauf zu schlie\u00dfen. Im ersten Teil der Arbeit wurde eine Methode entwickelt, bei der isotopisch 57Fe-markiertes Ferrihydrit mit dem Sediment vermischt wurde, um die Vivianitbildung in-situ in gezeitenbeeinflussten Sedimenten zu verfolgen. Mit dieser Methode konnte gezeigt werden, dass sich Vivianit innerhalb von sieben Wochen in gezeitenbeeinflussten Sedimenten mit g\u00fcnstigen geochemischen Bedingungen bilden kann. Die Adsorption von Phosphat an Ferrihydrit war ein wesentlicher Vorl\u00e4ufer f\u00fcr die Bildung von Vivianit. Die reduktive Aufl\u00f6sung des Ferrihydrits bildete wahrscheinlich lokale Bedingen, welche n\u00f6tig waren, um die Vivianitbildung auszul\u00f6sen. W\u00e4hrend das gebildete Vivianit nur ein kleiner Teil des Eisen (Fe)-Pools war (bis zu 15%), machte es bis zu 72% des P-Pools aus basierend auf st\u00f6chiometrischen Berechnungen. Diese Ergebnisse zeigen, dass Vivianit eine entscheidende Rolle bei der Regulierung der P-Retention in K\u00fcstensedimenten spielen kann. In der Umwelt enth\u00e4lt Vivianit h\u00e4ufig andere zweiwertige Kationen, wie Mangan (Mn) und Magnesium (Mg), die in der Kristallstruktur Fe ersetzen. Im zweiten Experiment wurde untersucht, ob Mn oder Mg bei unterschiedlichen Salzgehalten bevorzugt eingebaut wird und wie die isomorphe Substitution die Kristallstruktur und Morphologie ver\u00e4ndert. Die Synthese von neunzehn Vivianiten mit unterschiedlichen Mn- und/oder Mg-Konzentrationen bei verschiedenen Salzgehalten ergab, dass bei niedriger Ionenst\u00e4rke sowohl Mn als auch Mg Fe in der Kristallstruktur gleichwertig ersetzen k\u00f6nnen, wobei Mn bei h\u00f6herer Ionenst\u00e4rke bevorzugt wurde. Vivianit weist zwei unterschiedliche Fe-Atompositionen auf. Die Substitution von Fe durch Mn und/oder Mg fand vorzugsweise an der Atomposition statt, welche Elektronentransfer ausf\u00fchren kann, wodurch Vivianit gegen Oxidation stabilisiert wird. Somit kann sich die isomorphe Substitution wahrscheinlich direkt auf das Oxidationsverhalten von Vivianit auswirken. Au\u00dferdem f\u00fchrte die isomorphe Substitution zu kleineren, raueren Kristallen mit geringerer Kristallinit\u00e4t. Diese beobachteten Ver\u00e4nderungen k\u00f6nnten sich auf die Reaktivit\u00e4t von Vivianit in der Umwelt auswirken, weshalb die isomorphe Substitution bei der Untersuchung der Reaktivit\u00e4t von Vivianit ber\u00fccksichtigt werden sollte. Umweltver\u00e4nderungen, einschlie\u00dflich des Anstiegs des Meeresspiegels, k\u00f6nnten die Bildung von Sulfid in derzeit nicht sulfidischen Sedimenten, die Vivianit enthalten, verst\u00e4rken und zu thermodynamisch instabilen Bedingungen f\u00fcr Vivianit f\u00fchren. Das letzte Experiment untersuchte die in-situ Stabilit\u00e4t von unsubstituiertem und Mn-Mg-substituiertem Vivianit, gemischt mit Meeressand und mit oder ohne die Zugabe von Kalziumkarbonat. Die Mischungen wurden 56 Tage lang in zwei Gezeitenzonen inkubiert, von denen ein Standort eine niedrige und der andere eine hohe Sulfidkonzentration aufwies. Die Inkubation von unsubstituiertem und Mn-Mg-substituiertem Vivianit bei unterschiedlichen Sulfidkonzentrationen ergab eine teilweise Aufl\u00f6sung von Vivianit, die durch die isomorphe Substitution deutlich verst\u00e4rkt wurde. Der gr\u00f6\u00dfte Teil der verbleibenden Mineralphase wurde weiterhin als Vivianit charakterisiert, was darauf hindeutet, dass ein Teil des Vivianits \u00fcber die Versuchsdauer erhalten blieb. Bei niedrigen Sulfidkonzentrationen war Gr\u00fcner Rost das Hauptumwandlungsprodukt, das wahrscheinlich einen Teil des freigesetzten Phosphats adsorbierte. Bei hohem Sulfidgehalt dominierte die Bildung von Fe-Sulfidmineralen, welche aufgrund der geringen Sorptionskapazit\u00e4t f\u00fcr Phosphat zu einem erh\u00f6hten P-Verlust f\u00fchrte. Ein erh\u00f6htes Sorptionspotenzial f\u00fcr Phosphat durch die Zugabe von Kalziumkarbonat k\u00f6nnte den Phosphatverlust geringf\u00fcgig verringern. Diese Ergebnisse zeigen, dass vivianithaltige Sedimente als Quelle f\u00fcr bioverf\u00fcgbares Phosphat dienen k\u00f6nnen, wenn sich die geochemischen Bedingungen \u00e4ndern. Diese Arbeit liefert neue experimentelle Ans\u00e4tze zur Untersuchung und Quantifizierung von Umwandlungs- und Bildungsprozessen von Vivianit. Die Ergebnisse zeigen eine schnelle in-situ Bildungskinetik, w\u00e4hrend die Aufl\u00f6sung von Vivianit unter den untersuchten Bedingungen langsam verl\u00e4uft. Die schnelle in-situ Bildungskinetik deutet darauf hin, dass die Vivianitbildung die P-Retention in Umgebungen mit sowohl schwankenden als auch stabilen geochemischen Bedingungen regulieren kann. Die Ver\u00e4nderungen der Kristallstruktur und -morphologie durch isomorphe Substitution erh\u00f6hten das Ausma\u00df der Aufl\u00f6sung und Umwandlung des Vivianits. Aufgrund der langsamen in-situ Aufl\u00f6sung k\u00f6nnte Vivianit bei kurzfristigen Umweltst\u00f6rungen eine stabile P-Retentionsphase darstellen. Langfristig destabilisierende Bedingungen k\u00f6nnten jedoch zu einer vollst\u00e4ndigen Aufl\u00f6sung f\u00fchren und die P-Retentionskapazit\u00e4t des Sediments schw\u00e4chen. Die Ergebnisse unterstreichen die Bedeutung von Vivianit als P-Retentionsphase in salzarmen K\u00fcstensedimenten, k\u00f6nnten aber auch f\u00fcr das Verst\u00e4ndnis von Bildungs- und Umwandlungsprozessen von Vivianit in anderen Umweltsystemen, wie limnischen Sedimenten und B\u00f6den in Feuchtgebieten, von Bedeutung sein. Dar\u00fcber hinaus haben diese Ergebnisse Auswirkungen auf andere Forschungsbereiche, wie die Gew\u00e4ssersanierung und die industrielle P-R\u00fcckgewinnung.", "keywords": ["iron biogeochemistry", "info:eu-repo/classification/ddc/550", "Phosphorus cycling", "Coastal biogeochemistry", "X-ray absorption spectroscopy", "Laboratory experiments", "VIVIANITE (MINERALOGY)", "Field experiments", "6. Clean water", "M\u00f6ssbauer Spectroscopy", "Earth sciences", "X-Ray Diffraction", "13. Climate action", "IRON PHOSPHATES (INORGANIC CHEMISTRY)", "14. Life underwater", "iron minerals", "mineral transformation", "Redox geochemistry"], "contacts": [{"organization": "Kubeneck, Luisa Jo\u00eblle", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.3929/ethz-b-000663192"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Thesis/Dissertation", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.3929/ethz-b-000663192", "name": "item", "description": "10.3929/ethz-b-000663192", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.3929/ethz-b-000663192"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-01-01T00:00:00Z"}}, {"id": "10.1016/j.scitotenv.2024.171347", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:38Z", "type": "Journal Article", "created": "2024-03-02", "title": "Selection of soil health indicators for modelling soil functions to promote smart urban planning", "description": "The contribution of soil health to global health receives a growing interest, especially in urban environment. Therefore, there is a true need to develop methods to evaluate ecological functions provided by urban soils in order to promote smart urban planning. This work aims first at identifying relevant soil indicators based either on in situ description, in situ measurement or lab analysis. Then, 9 soil functions and sub-functions were selected to meet the main expectations regarding soil health in urban contexts. A crucial step of the present research was then to select adequate indicators for each soil function and then to create adapted reference frameworks; they were in the form of 4 classes with scores ranging from 0 to 3. All the reference frameworks were developed to evaluate soil indicators in order to score soil functions, either by using existing scientific or technical standards or references or based on the expertise of the co-authors. Our model was later tested on an original database of 109 different urban soils located in 7 cities of Western Europe and under various land uses. The scores calculated for 8 soil functions of 109 soils followed a Gaussian distribution. The scoring successfully expressed the strong contrasts between the various soils; the lowest scores were calculated for sealed soils and soils located in urban brownfields, whereas the highest were found for soils located in city parks or urban agriculture. Despite requiring a soil expertise, the proposed approach is easy to implement and could help reveal the true potential of urban soils in order to promote smart urban planning and enhance their contribution to global health.", "keywords": ["[SDE] Environmental Sciences", "Urban soils", "550", "11. Sustainability", "Soil indicators", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "[SDU.STU]Sciences of the Universe [physics]/Earth Sciences", "Ecosystem services", "[SDV.SA.SDS]Life Sciences [q-bio]/Agricultural sciences/Soil study", "15. Life on land", "Soil functions", "[SDV.SA.SDS] Life Sciences [q-bio]/Agricultural sciences/Soil study"]}, "links": [{"href": "https://doi.org/10.1016/j.scitotenv.2024.171347"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20of%20The%20Total%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.scitotenv.2024.171347", "name": "item", "description": "10.1016/j.scitotenv.2024.171347", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.scitotenv.2024.171347"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-05-01T00:00:00Z"}}, {"id": "10.1016/j.scitotenv.2024.172589", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:38Z", "type": "Journal Article", "created": "2024-04-22", "title": "Determination of organic fluorinated compounds content in complex samples through combustion ion chromatography methods: a way to define a \u201cTotal Per- and Polyfluoroalkyl Substances (PFAS)\u201d parameter?", "description": "Emerging contaminants are a growing concern for scientists and public authorities. The group of per-polyfluoroalkyl substances (PFAS), known as 'forever chemicals', in complex environmental liquid and solid matrices was analysed in this study. The development of global analytical methods based on combustion ion chromatography (CIC) is expected to provide accurate picture of the overall PFAS contamination level via the determination of extractable organic fluorine (EOF) and adsorbable organic fluorine (AOF). The obtained results may be put into perspective with other methods such as targeted analyses (LC-MS/MS). The impact of pH, the presence of dissolved organic carbon and suspended particles on AOF measurements were explored. The effectiveness of the washing step to remove adsorbed inorganic fluorine (IF) has been proven for samples containing up to 8 mgF.L-1. CIC-based methods showed good repeatability and reproducibility for the complex matrices studied. Environmental applications of these methods have been tested. AOF and EOF analyses could explain between 1\u00a0% and 23\u00a0% and 0.1\u00a0% to 2\u00a0% of total organic fluorine (TOF), respectively. The sum of PFAS compounds expressed as fluorine could explain from 0.2\u00a0% to 11\u00a0% and from 0.003\u00a0% to 5\u00a0% for AOF and EOF, respectively. These results also suggest that some fluorinated compounds are not adsorbed or extractable and/or lost by volatilisation during the application of AOF and EOF analytical procedure. These findings highlight that AOF and EOF are not entirely efficient as proxy to assess 'total PFAS' for assessing environmental contamination by PFAS. However, these methods could still be applied to gain a better understanding of the sources and fate of PFAS in the environment.", "keywords": ["Combustion ion chromatography", "13. Climate action", "Organic fluorine", "chemical analysis", "PFAS", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "H2020", "Environment", "PROMISCES", "Analysis"]}, "links": [{"href": "https://doi.org/10.1016/j.scitotenv.2024.172589"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20of%20The%20Total%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.scitotenv.2024.172589", "name": "item", "description": "10.1016/j.scitotenv.2024.172589", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.scitotenv.2024.172589"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-07-01T00:00:00Z"}}, {"id": "10.1016/j.soilbio.2004.08.025", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:39Z", "type": "Journal Article", "created": "2004-12-15", "title": "Long-Term Effects Of Metal-Containing Farmyard Manure And Sewage Sludge On Soil Organic Matter In A Fluvisol", "description": "Abstract Our aim was to establish the long-term effects of repeated applications after 20\u00a0y of organic amendments (farmyard manure at 10\u00a0t\u00a0ha \u22121 \u00a0y \u22121 , and urban sewage sludge at two different rates, 10\u00a0t\u00a0ha \u22121 \u00a0y \u22121 and 100\u00a0t\u00a0ha \u22121 every 2\u00a0y) on the quality of a sandy and poorly buffered soil (Fluvisol, pH 6). Chemical characteristics and biodegradability of the labile organic matter, which is mainly derived from microbial biomass and biodegradation products of organic residues, were chosen as indicators for soil quality. The organic C content had reached a maximal value (30.6\u00a0g\u00a0C\u00a0kg \u22121 in the 100\u00a0t sludge-treated soil), i.e. about 2.5 times that in the control. Six years after the last application, the organic C content and the microbial biomass content remained higher in sludge-treated soils than in the control. In contrast, the proportion of labile organic matter was significantly lower in sludge-treated soils than in manure-treated and control soils. The labile organic matter of sludge extracts appeared less humified than that of manure-treated and control soils.", "keywords": ["2. Zero hunger", "Sandy soils", "04 agricultural and veterinary sciences", "[SDV.SA.SDS]Life Sciences [q-bio]/Agricultural sciences/Soil study", "15. Life on land", "630", "Soil quality", "6. Clean water", "12. Responsible consumption", "[SDV.EE] Life Sciences [q-bio]/Ecology", " environment", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDV.EE]Life Sciences [q-bio]/Ecology", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "11. Sustainability", "Farmyard manure", "Zn", "0401 agriculture", " forestry", " and fisheries", "Labile organic matter", "[SDV.SA.SDS] Life Sciences [q-bio]/Agricultural sciences/Soil study", "Sewage sludge", "environment", "Cu", "Pb"]}, "links": [{"href": "https://doi.org/10.1016/j.soilbio.2004.08.025"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Soil%20Biology%20and%20Biochemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.soilbio.2004.08.025", "name": "item", "description": "10.1016/j.soilbio.2004.08.025", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.soilbio.2004.08.025"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2005-04-01T00:00:00Z"}}, {"id": "10.1016/j.soilbio.2009.07.025", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:42Z", "type": "Journal Article", "created": "2009-08-06", "title": "Tillage And Crop Residue Management Significantly Affects N-Trace Gas Emissions During The Non-Rice Season Of A Subtropical Rice-Wheat Rotation", "description": "Abstract Field operations of tillage and residue incorporation could have potentially important influences on N-trace gas fluxes, though poorly quantified. Here we studied the effects of straw incorporation in the preceding rice season and no-tillage prior to wheat sowing on nitric oxide (NO) and nitrous oxide (N2O) emissions during the non-rice period of a typical rice-wheat rotation in the Yangtze River Delta. Compared to conventional management practice (no straw incorporation along with rotary harrowing tillage to 10\u00a0cm before wheat sowing), straw incorporation alone decreased cumulative N2O emissions over the entire non-rice period by 32% (1.53 vs. 2.24\u00a0kg\u00a0N\u00a0ha-1, P", "keywords": ["2. Zero hunger", "Earth sciences", "info:eu-repo/classification/ddc/550", "550", "ddc:550", "13. Climate action", "0401 agriculture", " forestry", " and fisheries", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.soilbio.2009.07.025"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Soil%20Biology%20and%20Biochemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.soilbio.2009.07.025", "name": "item", "description": "10.1016/j.soilbio.2009.07.025", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.soilbio.2009.07.025"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-10-01T00:00:00Z"}}, {"id": "10.1016/j.soilbio.2010.04.005", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:16:42Z", "type": "Journal Article", "created": "2010-04-21", "title": "Model Of Apparent And Real Priming Effects: Linking Microbial Activity With Soil Organic Matter Decomposition", "description": "The most frequently used models simulating soil organic matter (SOM) dynamics are based on first-order kinetics. These models fail to describe and predict such interactions as priming effects (PEs), which are short-term changes in SOM decomposition induced by easily available C or N sources. We hypothesized that if decomposition rate depends not only on size of the SOM pool, but also on microbial biomass and its activity, then PE can be simulated. A simple model that included these interactions and that consisted of three C pools \u2013 SOM, microbial biomass, and easily available C \u2013 was developed. The model was parameterized and evaluated using results of 12C\u2013CO2 and 14C\u2013CO2 efflux after adding 14C-labeled glucose to a loamy Haplic Luvisol. Experimentally measured PE, i.e., changes in SOM decomposition induced by glucose, was compared with simulated PE. The best agreement between measured and simulated CO2 efflux was achieved by considering both the total amount of microbial biomass and its activity. Because it separately described microbial turnover and SOM decomposition, the model successfully simulated apparent and real PE. The proposed PE model was compared with three alternative approaches with similar complexity but lacking interactions between the pools and neglecting the activity of microbial biomass. The comparison showed that proposed new model best described typical PE dynamics in which the first peak of apparent PE lasted for 1 day and the subsequent real PE gradually increased during 60 days. This sequential decomposition scheme of the new model, with immediate microbial consumption only of soluble substrate, was superior to the parallel decomposition scheme with simultaneous microbial consumption of two substrates with different decomposability. Incorporating microbial activity function in the model improved the fit of simulation results with experimental data, by providing the flexibility necessary to properly describe PE dynamics. We conclude that microbial biomass should be considered in models of C and N dynamics in soil not only as a pool but also as an active driver of C and N turnover.", "keywords": ["Earth sciences", "info:eu-repo/classification/ddc/550", "550", "ddc:550", "0401 agriculture", " forestry", " and fisheries", "04 agricultural and veterinary sciences", "15. Life on land"]}, "links": [{"href": "https://doi.org/10.1016/j.soilbio.2010.04.005"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Soil%20Biology%20and%20Biochemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.soilbio.2010.04.005", "name": "item", "description": "10.1016/j.soilbio.2010.04.005", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.soilbio.2010.04.005"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2010-08-01T00:00:00Z"}}, {"id": "10.1029/2023jd040657", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:17:13Z", "type": "Journal Article", "created": "2024-06-11", "title": "Impact of Dust Source Patchiness on the Existence of a Constant Dust Flux Layer During Aeolian Erosion Events", "description": "AbstractDust emission fluxes during wind soil erosion are usually estimated using a dust concentration vertical gradient, by assuming a constant dust flux layer between the surface and the dust measurement levels. Here, we investigate the existence of this layer during erosion events recorded in Iceland and Jordan. Size\uffe2\uff80\uff90resolved dust fluxes were estimated at three levels between 2 and 4\uffc2\uffa0m using the eddy\uffe2\uff80\uff90covariance method. Dust fluxes were found mainly constant only between the two upper levels in Iceland, the lower dust flux being often stronger and richer in coarse particles, while dust fluxes in Jordan were nearly constant across all levels. The wind dynamics could not explain the absence of a constant dust flux layer in Iceland. We show that the presence of stationary dust source patches in Iceland, related to surface humidity, created a non\uffe2\uff80\uff90uniform dust layer near the surface, named dust roughness sublayer (DRSL), where individual plumes behind each patch interact but do not fully mix. The lowest dust measurement level was probably located within this sublayer while the upper ones were located above, such that there the emitted dust became spatially well\uffe2\uff80\uff90mixed. This explains near the surface in Iceland, the more intermittent dust concentration, its low correlation with the dust concentrations above, and the richer dust flux in coarse particles due to their lower deposition contribution. Our findings highlight the importance of estimating dust fluxes above a dust blending height whose characteristics depend on the dust source patchiness caused by surface humidity or the presence of sparse non\uffe2\uff80\uff90erosive elements.The \uffe2\uff80\uff9cRusty Rock\uffe2\uff80\uff9d 66095 is one of the most volatile-rich rocks from the Moon. The abundance and isotopic composition of volatile elements in the Rusty Rock demonstrates that its lunar interior source became highly depleted in volatile elements and compounds, including Zn, Cl, and Pb. Depletion of these and other volatile elements occurred during thermomagmatic evolution of the Moon and a magma ocean phase. The volatile-rich nature of some rocks on the lunar surface likely originates from extreme degassing and volatile loss from the Moon\uffe2\uff80\uff99s interior. Light zinc isotopic compositions in the Rusty Rock and in the lunar volcanic glass beads (74220, 15426) imply that these samples are partly derived from reservoirs that experienced vapor condensation from a volatile-poor Moon.
", "keywords": ["13. Climate action", "condensates", "magma ocean", "volatile-poor", "[SDU.STU.PL] Sciences of the Universe [physics]/Earth Sciences/Planetology", "Moon", "01 natural sciences", "Rusty Rock", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pnas.org/doi/pdf/10.1073/pnas.1708236114"}, {"href": "https://doi.org/10.1073/pnas.1708236114"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Proceedings%20of%20the%20National%20Academy%20of%20Sciences", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1073/pnas.1708236114", "name": "item", "description": "10.1073/pnas.1708236114", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1073/pnas.1708236114"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-08-21T00:00:00Z"}}, {"id": "10.1073/pnas.1807263115", "type": "Feature", "geometry": null, "properties": {"updated": "2026-10-06T16:17:33Z", "type": "Journal Article", "created": "2018-08-06", "title": "Volatile element evolution of chondrules through time", "description": "SignificanceWe present time-anchored elemental abundance data for some of the Solar System\uffe2\uff80\uff99s first solids by tracking Pb\uffe2\uff88\uff92Pb dated chondrule compositions. Volatile element contents generally rise, while redox conditions (based on chondrule Mn/Na ratios) decline beginning \uffe2\uff88\uffbc1 My after Solar System formation (\uffe2\uff88\uffbc4,567 Ma). These results reflect a continued rise in volatile element contents and their fugacities during chondrule recycling, and early water influx to the inner Solar System followed by its express removal. These observations support the early formation of Mars under oxidizing condition and Earth\uffe2\uff80\uff99s protracted growth under more reducing conditions in an environment increasing in volatile contents with time, while also calling into question the coupling of water and volatile elements during Solar System evolution.
", "keywords": ["550", "pebble accretion", "[SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]", "[SDU.ASTR.EP] Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP]", "planetary formation", "01 natural sciences", "meteorites", "12. Responsible consumption", "Solar System evolution", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "cosmochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Physical Sciences", "10. No inequality", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://pnas.org/doi/pdf/10.1073/pnas.1807263115"}, {"href": "https://researchonline.jcu.edu.au/62756/1/62756.pdf"}, {"href": "https://doi.org/10.1073/pnas.1807263115"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Proceedings%20of%20the%20National%20Academy%20of%20Sciences", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1073/pnas.1807263115", "name": "item", "description": "10.1073/pnas.1807263115", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1073/pnas.1807263115"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-08-06T00:00:00Z"}}], "links": [{"rel": "self", "type": "application/geo+json", "title": "This document as GeoJSON", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Earth+sciences&offset=50&f=json", "hreflang": "en-US"}, {"rel": "alternate", "type": "text/html", "title": "This document as HTML", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Earth+sciences&offset=50&f=html", "hreflang": "en-US"}, {"rel": "collection", "type": "application/json", "title": "Collection URL", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main", "hreflang": "en-US"}, {"type": "application/geo+json", "rel": "prev", "title": "items (prev)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Earth+sciences&offset=0", "hreflang": "en-US"}, {"rel": "next", "type": "application/geo+json", "title": "items (next)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Earth+sciences&offset=100", "hreflang": "en-US"}], "numberMatched": 359, "numberReturned": 50, "distributedFeatures": [], "timeStamp": "2026-10-24T14:57:48.036828Z"}