{"type": "FeatureCollection", "features": [{"id": "10.1016/j.bioelechem.2020.107621", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-04-03T16:16:13Z", "type": "Journal Article", "created": "2020-07-27", "title": "Tailored glycosylated anode surfaces: Addressing the exoelectrogen bacterial community via functional layers for microbial fuel cell applications", "description": "Grafting of aryldiazonium cations bearing a p-mannoside functionality over microbial fuel cell (MFC) anode materials was performed to investigate the ability of aryl-glycoside layers to regulate colonisation by biocatalytic biofilms. Covalent attachment was achieved via spontaneous reactions and via electrochemically-assisted grafting using potential step experiments. The effect of different functionalisation protocols on MFC performance is discussed in terms of changes in wettability, roughness and electrochemical response of modified electrodes. Water contact angle measurements (WCA) show that aryl-mannoside grafting yields a significant increase in hydrophilic character. Surface roughness determinations via atomic force microscopy (AFM) suggest a more disordered glycan adlayer when electrografting is used to facilitate chemisorption. MFCs were used as living sensors to successfully test the coated electrodes: the response of the MFCs in terms of start-up time was accelerated when compared to that of MFC equipped with non-modified electrodes, this suggests a faster development of a mature biofilm community resulting from aryldiazonium modifications, as confirmed by cyclic voltammetry of MFC anodes. These results therefore indicate that modification with glycans offers a bioinspired route to accelerating biofilm colonisation without any adverse effects on final MFC outputs.", "keywords": ["Microbial fuel cell", "Glycosylation", "Bacteria", "Bioelectric Energy Sources", "Surface Properties", "Microbiota", "02 engineering and technology", "Exoelectrogen biofilms", "540", "01 natural sciences", "7. Clean energy", "[SDV.BIO] Life Sciences [q-bio]/Biotechnology", "0104 chemical sciences", "Electricity", "[CHIM.OTHE] Chemical Sciences/Other", "Biofilms", "Aryl-mannoside layers", "Glycan adlayers", "0210 nano-technology", "Electrodes"]}, "links": [{"href": "https://doi.org/10.1016/j.bioelechem.2020.107621"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Bioelectrochemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.bioelechem.2020.107621", "name": "item", "description": "10.1016/j.bioelechem.2020.107621", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.bioelechem.2020.107621"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-12-01T00:00:00Z"}}, {"id": "10.1016/j.biortech.2020.124095", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:16Z", "type": "Journal Article", "created": "2020-09-07", "title": "Biosynthesized iron sulfide nanoparticles by mixed consortia for enhanced extracellular electron transfer in a microbial fuel cell", "description": "The bioanode of mixed consortia was for the first time used to in-situ synthesize iron sulfide nanoparticles in a microbial fuel cell (MFC) over a long-term period (46\u00a0days). These poorly crystalline nanoparticles with an average size of 29.97\u00a0\u00b1\u00a07.1\u00a0nm, comprising of FeS and FeS2, significantly promoted extracellular electron transfer and thus the electricity generation of the MFC. A maximum power density of 519.00\u00a0mW/m2 was obtained from the MFC, which was 1.92 times as high as that of the control. The cell viability was promoted by a small amount of iron sulfide nanoparticles but inhibited by the thick nanoparticle 'shell' covered on the bacterial cells. Some electroactive and sulfur reducing bacteria (eg. Enterobacteriaceae, Desulfovibrio, and Geobacter) were specifically enriched on the anode. This study provides a novel insight for improving the performance of bioelectrochemical systems through in-situ sustainable nanomaterials biofabrication by mixed consortia.", "keywords": ["Electron Transport", "Electricity", "Bioelectric Energy Sources", "Nanoparticles", "Electrons", "Ferrous Compounds", "Electrodes", "7. Clean energy", "01 natural sciences", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Cui, Yan, Chen, Xueru, Pan, Zhengyong, Wang, Yuqi, Xu, Qiang, Bai, Jiaying, Jia, Honghua, Zhou, Jun, Yong, Xiaoyu, Wu, Xiayuan,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.biortech.2020.124095"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Bioresource%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.biortech.2020.124095", "name": "item", "description": "10.1016/j.biortech.2020.124095", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.biortech.2020.124095"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-12-01T00:00:00Z"}}, {"id": "10.1016/j.bios.2020.112231", "type": "Feature", "geometry": null, "properties": {"license": "Closed Access", "updated": "2026-04-03T16:16:16Z", "type": "Journal Article", "created": "2020-04-23", "title": "Active N dopant states of electrodes regulate extracellular electron transfer of Shewanella oneidensis MR-1 for bioelectricity generation: Experimental and theoretical investigations", "description": "Anodic N doping is an effective way to improve power generation of bioelectrochemical systems (BESs), but the role of various active N dopant states of the anode on BES performance is still unclear. Herein, the effect of anodic active N dopant states on bioelectricity generation of Shewanella oneidensis MR-1 inoculated BESs particularly including microbial extracellular electron transfer (EET) was explored using experiments and theoretical simulations. It was found a positive linear correlation between the peak current density of BESs and pyrrolic N content of the anode, which would mainly ascribe to the enhancement of both direct electron transfer (DET) and mediated electron transfer (MET) of S. oneidensis MR-1. Morever, the molecule dynamic simulation revealed that such EET improvements of S. oneidensis MR-1 could be due to more remarkable reduction in the thermodynamic and kinetic resistances of the DET and MET processes with anodic doping of pyrrolic N compared to pyridinic N and graphitic N. This work provides a valuable guideline to design of high-performance anodes for potential BES applications.", "keywords": ["Electron Transport", "Shewanella", "Electricity", "Bioelectric Energy Sources", "Electrons", "Pyrroles", "02 engineering and technology", "Molecular Dynamics Simulation", "0210 nano-technology", "Electrodes", "01 natural sciences", "0104 chemical sciences"], "contacts": [{"organization": "Wang, Yi-Xuan, Li, Wen-Qiang, He, Chuan-Shu, Zhao, Han-Qing, Han, Jun-Cheng, Liu, Xiao-Cheng, Mu, Yang,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.bios.2020.112231"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Biosensors%20and%20Bioelectronics", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.bios.2020.112231", "name": "item", "description": "10.1016/j.bios.2020.112231", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.bios.2020.112231"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-07-01T00:00:00Z"}}, {"id": "10.1016/j.carbon.2019.11.020", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:17Z", "type": "Journal Article", "created": "2019-11-09", "title": "Bioinspired electro-permeable glycans on carbon: Fouling control for sensing in complex matrices", "description": "Abstract   The effect of glycan adlayers on the electrochemical response of glassy carbon electrodes was studied using standard redox probes and complex aqueous matrices. Aryldiazonium cations of aryl-lactoside precursors were used to modify glassy carbon via spontaneous and electrochemically assisted covalent grafting. Contact angle and fluorescence binding using Peanut Agglutinin (PNA) as a diagnostic lectin indicate that electrografting results in adlayers with greater glycan surface density than those obtained via spontaneous reaction. X-ray photoelectron spectroscopy with a fluorinated analog confirmed that electrografting results in multilayers of cross-linked aryl-lactosides. Adsorption studies with Bovine Serum Albumin (BSA) show that aryl-lactoside adlayers minimize unspecific protein adsorption. However, no significant differences were detected between spontaneous and electrografted layers in their ability to resist protein fouling despite their differences in coverage. Voltammetry studies show that spontaneous grafting has minimal effects on the response of standard redox probes in solution, whereas electrografting results in additional charge transfer impedance arising from increased electrode passivation. Bare and lactoside-modified carbon electrodes were tested for the detection of caffeine before and after prolonged exposure to coffee solutions. Spontaneous grafting was found to result in optimal properties by imparting antifouling performance in these complex matrices while preserving fast interfacial charge transfer.", "keywords": ["Nanoscience & Materials", "GLASSY-CARBON", "GLASSY-CARBON ELECTRODES", "02 engineering and technology", "540", "01 natural sciences", "Bovine Serum Albumin (BSA)", "0104 chemical sciences", "Aqueous matrices", "CARBON", "Glassy carbon", "Coffee solutions", "Glycan adlayers", "0210 nano-technology", "Peanut Agglutinin (PNA)"]}, "links": [{"href": "https://doi.org/10.1016/j.carbon.2019.11.020"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Carbon", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.carbon.2019.11.020", "name": "item", "description": "10.1016/j.carbon.2019.11.020", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.carbon.2019.11.020"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-03-01T00:00:00Z"}}, {"id": "10.1016/j.carbon.2019.03.052", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-04-03T16:16:17Z", "type": "Journal Article", "created": "2019-03-26", "title": "Electrocatalysis of N-doped carbons in the oxygen reduction reaction as a function of pH: N-sites and scaffold effects", "description": "Abstract   Metal-free nitrogenated amorphous carbon electrodes were synthesised via dc plasma magnetron sputtering and post-deposition annealing at different temperatures. The electrocatalytic activity of the electrodes towards the oxygen reduction reaction (ORR) was studied as a function of pH using cyclic voltammetry with a rotating disk electrode. The trends in onset potential were correlated to the carbon nanostructure and chemical composition of the electrodes as determined via Raman spectroscopy and X-ray photoelectron spectroscopy analysis. Results suggest that: 1) the ORR activity in acidic conditions is strongly correlated to the concentration of pyridinic nitrogen sites. 2) At high pH, the presence of graphitic nitrogen sites and a graphitized carbon scaffold are the strongest predictors of high ORR onsets, while pyridinic nitrogen site density does not correlate to ORR activity. An inversion region where pyridine-mediated activity competes with graphitic-N mediated activity is identified in the pH region close to the value of pKa of the pyridinium cation. The onset of the ORR is therefore determined by the activity of different sites as a function of pH and evidence for distinct reduction reaction pathways emerges from these results.", "keywords": ["Carbon electrodes", "Nanoscience & Materials", "02 engineering and technology", "540", "Electrocatalysis", "0210 nano-technology", "01 natural sciences", "7. Clean energy", "0104 chemical sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.carbon.2019.03.052"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Carbon", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.carbon.2019.03.052", "name": "item", "description": "10.1016/j.carbon.2019.03.052", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.carbon.2019.03.052"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-07-01T00:00:00Z"}}, {"id": "10.1016/j.envres.2021.112649", "type": "Feature", "geometry": null, "properties": {"license": "Closed Access", "updated": "2026-04-03T16:16:42Z", "type": "Journal Article", "created": "2021-12-31", "title": "N-acyl-homoserine lactones in extracellular polymeric substances from sludge for enhanced chloramphenicol-degrading anode biofilm formation in microbial fuel cells", "description": "Exploring an efficient acclimation strategy to obtain robust bioanodes is of practical significance for antibiotic wastewater treatment by bioelectrochemical systems (BESs). This study investigated the effects of two acclimation conditions on chloramphenicol (CAP)-degrading anode biofilm formation in microbial fuel cells (MFCs). The one was continuously added the extracellular polymeric substances (EPS) extracted from anaerobic sludge and increasing concentrations of CAP after the first start-up phase, while the other was added the EPS-1 (N-acyl-homoserine lactones, namely AHLs were extracted from the EPS) at the same conditions. The results demonstrated that AHLs in the sludge EPS played a crucial role for enhanced CAP-degrading anode biofilm formation in MFCs. The AHL-regulation could not only maintain stable voltage outputs but also significantly accelerate CAP removal in the EPS MFC. The maximum voltage of 653.83\u00a0mV and CAP removal rate of 1.21\u00a0\u00b1\u00a00.05\u00a0mg/L\u00b7h were attained from the EPS MFC at 30\u00a0mg/L of CAP, which were 0.84 and 1.57 times higher than those from the EPS-1 MFC, respectively. These improvements were largely caused by the thick and 3D structured biofilm, strong and homogeneous cell viability throughout the biofilm, and high protein/polysaccharide ratio along with more conductive contents in the biofilm EPS. Additionally, AHLs facilitated the formation of a biofilm with rich biodiversity and balanced bacterial proportions, leading to more beneficial mutualism among different functional bacteria. More bi-functional bacteria (for electricity generation and antibiotic resistance/degradation) were specifically enriched by AHLs as well. These findings provide quorum sensing theoretical knowledge and practical instruction for rapid antibiotic-degrading electrode biofilm acclimation in BESs.", "keywords": ["Chloramphenicol", "Sewage", "Bioelectric Energy Sources", "Extracellular Polymeric Substance Matrix", "Biofilms", "Acyl-Butyrolactones", "Electrodes", "01 natural sciences", "6. Clean water", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Wu, Xiayuan, Zhang, Lina, Lv, Zuopeng, Xin, Fengxue, Dong, Weiliang, Liu, Guannan, Li, Yan, Jia, Honghua,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.envres.2021.112649"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Research", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envres.2021.112649", "name": "item", "description": "10.1016/j.envres.2021.112649", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envres.2021.112649"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-05-01T00:00:00Z"}}, {"id": "10.1016/j.mex.2020.101021", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:17:20Z", "type": "Journal Article", "created": "2020-08-05", "title": "Simultaneous characterization of porous and non-porous electrodes in microbial electrochemical systems,", "description": "Adequate electrochemical characterization of electrode material/biofilms is crucial for a comprehensive understanding and comparative performance of bioelectrochemical systems (BES). However, their responses are greatly affected by the metabolic activity and growth of these living entities and/or the interference of electrode wiring that can act as an electroactive surface for growth or constitute a source of contamination by corrosion. This restricts the meaningful comparison of the performance of distinct electrode materials in BES. This work describes a methodology for simultaneous electrochemical control and measurement of the microbial response on different electrode materials under the same physicochemical and biological conditions. The method is based on the use of a single channel potentiostat and one counter and reference electrodes to simultaneously polarize several electrode materials in a sole bioelectrochemical cell. Furthermore, various strategies to minimize wiring corrosion are proposed. The proposed methodology, then, will enable a more rigorous characterization of microbial electrochemical responses for comparisons purposes.\u2022Experimental Set-up allows to polarize several working electrodes at the same time.\u2022Chronoamperometry can be performed simultaneously with a potentiostat.\u2022The physicochemical and biological conditions in each working electrode will be exactly the same.", "keywords": ["Science", "Q", "Porous and non-porous electrodes", "Electroactive biofilms", "02 engineering and technology", "QD Chemistry", "TP Chemical technology", "01 natural sciences", "0104 chemical sciences", "Bioelectrochemical systems", "Environmental Science", "Qu\u00edmica F\u00edsica", "Electrode materials", "0210 nano-technology"]}, "links": [{"href": "https://doi.org/10.1016/j.mex.2020.101021"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/MethodsX", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.mex.2020.101021", "name": "item", "description": "10.1016/j.mex.2020.101021", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.mex.2020.101021"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-01-01T00:00:00Z"}}, {"id": "10.1016/j.scitotenv.2023.164311", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:17:33Z", "type": "Journal Article", "created": "2023-05-20", "title": "Electroactive microorganisms synthesizing iron sulfide nanoparticles for enhanced hexavalent chromium removal in microbial fuel cells", "description": "Microbial fuel cells (MFCs) have been considered a promising technology for Cr6+ removal, but they are limited by Cr6+-reducing biocathodes with low extracellular electron transfer (EET) and poor microbial activity. In this study, three kinds of nano-FeS hybridized electrode biofilms, obtained through synchronous biosynthesis (Sy-FeS), sequential biosynthesis (Se-FeS) and cathode biosynthesis (Ca-FeS), were applied as biocathodes for Cr6+ removal in MFCs. The Ca-FeS biocathode exhibited the best performance due to the superior properties of biogenic nano-FeS (e.g., more synthetic amount, smaller particle size, better dispersion). The MFC with the Ca-FeS biocathode achieved the highest power density (42.08\u00a0\u00b1\u00a01.42\u00a0mW/m2) and Cr6+ removal efficiency (99.18\u00a0\u00b1\u00a00.1\u00a0%), which were 1.42 and 2.08 times as high as those of the MFC with the normal biocathode, respectively. The synergistic effects of nano-FeS and microorganisms enhanced the bioelectrochemical reduction of Cr6+, first realizing deep reduction of Cr6+ to Cr0 in biocathode MFCs. This significantly alleviated the cathode passivation caused by Cr3+ deposition. In addition, the hybridized nano-FeS as 'armor' layers protected the microbes from toxic attack by Cr6+, improving the biofilm physiological activity and extracellular polymeric substances (EPS) secretion. The hybridized nano-FeS as 'electron bridges' facilitated the microbial community to form a balanced, stable and syntrophic ecological structure. This study proposes a novel strategy through the cathode in-situ biosynthesis of nanomaterials to fabricate hybridized electrode biofilms with enhanced EET and microbial activity for toxic pollutant treatment in bioelectrochemical systems.", "keywords": ["Chromium", "Bioelectric Energy Sources", "Nanoparticles", "7. Clean energy", "Electrodes"], "contacts": [{"organization": "Fan, Mengjie, Zhuang, Xinglei, Gao, Zhen, Lv, Zuopeng, Dong, Weiliang, Xin, Fengxue, Chen, Yingwen, Jia, Honghua, Wu, Xiayuan,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.scitotenv.2023.164311"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20of%20The%20Total%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.scitotenv.2023.164311", "name": "item", "description": "10.1016/j.scitotenv.2023.164311", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.scitotenv.2023.164311"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-09-01T00:00:00Z"}}, {"id": "10.1021/acs.est.9b00345", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:16Z", "type": "Journal Article", "created": "2019-05-30", "title": "Cathode-Introduced Atomic H* for Fe(II)-Complex Regeneration to Effective Electro-Fenton Process at a Natural pH", "description": "Promotion of iron solubility using ligands is the preliminary step in the homogeneous electro-Fenton (EF) process at a mild pH, but the chelate efficiencies of most organic ligands are unsatisfactory, resulting in insufficient Fe(II) availability. In this study, atomic H* was, for the first time, introduced to the EF process to accelerate the regeneration of the Fe(II)-complex at a mild pH using a Ni-deposited carbon felt (Ni-CF) cathode. The introduction of atomic H* significantly elevated total organic carbon (TOC) abatement of ciprofloxacin (CIP) from 42% (CF) to 81% (Ni-CF) at a natural pH. In the presence of humic acids (HAs), atomic H* introduced via Ni-CF enhanced the CIP degradation rate to 10 times that of the CF at a mild pH. The electron spin resonance (ESR), density functional theory (DFT) calculations, electrochemical characterization, and in situ electrochemical Raman study clearly demonstrated that the atomic H* generated from the Ni-CF cathode was highly efficient at reducing Fe(III)-complexes at a natural pH. Additionally, the Ni-CF could generate atomic H* without significant nickel leaching. Thus, the atomic H* could continuously facilitate iron cycling and, consequently, enhance pollutant mineralization via the homogeneous EF process at a mild pH in an environmentally friendly manner.", "keywords": ["0211 other engineering and technologies", "Ferrous Compounds", "Hydrogen Peroxide", "02 engineering and technology", "Hydrogen-Ion Concentration", "Electrodes", "Ferric Compounds", "Oxidation-Reduction", "01 natural sciences", "Water Pollutants", " Chemical", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Xiao-Cheng Liu, Wen-Qiang Li, Yi-Ran Wang, Guan-Nan Zhou, Yi-Xuan Wang, Chuan-Shu He, Gong-Ming Wang, Yang Mu,", "roles": ["creator"]}]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.9b00345"}, {"href": "https://doi.org/10.1021/acs.est.9b00345"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.9b00345", "name": "item", "description": "10.1021/acs.est.9b00345", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.9b00345"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-05-22T00:00:00Z"}}, {"id": "10.1111/1758-2229.13187", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-04-03T16:19:49Z", "type": "Journal Article", "created": "2023-07-22", "title": "Coupling the electrocatalytic dechlorination of 2,4\u2010D with electroactive microbial anodes", "description": "Abstract<p>This work proves the feasibility of dechlorinating 2,4\uffe2\uff80\uff90D, a customary commercial herbicide, using cathodic electrocatalysis driven by the anodic microbial electrooxidation of sodium acetate. A set of microbial electrochemical systems (MES) were run under two different operating modes, namely microbial fuel cell (MFC) mode, with an external resistance of 120\uffe2\uff80\uff89\uffce\uffa9, or microbial electrolysis cell (MEC) mode, by supplying external voltage (0.6\uffe2\uff80\uff89V) for promoting the (bio)electrochemical reactions taking place. When operating the MES as an MFC, 32% dechlorination was obtained after 72\uffe2\uff80\uff89h of treatment, which was further enhanced by working under MEC mode and achieving a 79% dechlorination. In addition, the biodegradability (expressed as the ratio BOD/COD) of the synthetic polluted wastewater was tested prior and after the MES treatment, which was improved from negative values (corresponding to toxic effluents) up to 0.135 in the MFC and 0.453 in the MEC. Our MES approach proves to be a favourable option from the point of view of energy consumption. Running the system under MFC mode allowed to co\uffe2\uff80\uff90generate energy along the dechlorination process (\uffe2\uff88\uff920.0120\uffe2\uff80\uff89kWh\uffe2\uff80\uff89mol\uffe2\uff88\uff921), even though low removal rates were attained. The energy input under MEC operation was 1.03\uffe2\uff80\uff89kWh\uffe2\uff80\uff89mol\uffe2\uff88\uff921\uffe2\uff80\uff94a competitive value compared to previous works reported in the literature for (non\uffe2\uff80\uff90biological) electrochemical reactors for 2,4\uffe2\uff80\uff90D electrodechlorination.</p", "keywords": ["Bioelectric Energy Sources", "Bioanode", "Electroactive microbial anodes", "Cathodic elec-trodechlorination of 2", "4-D", "Dechlorination", "Feasibility", "Microbial fuel", "Wastewater", "2", "4-Dichlorophenoxyacetic Acid", "7. Clean energy", "Electrodes", "6. Clean water", "Research Articles"], "contacts": [{"organization": "Luis F. Leon\u2010Fernandez, Xochitl Dominguez\u2010Benetton, Jos\u00e9 Villase\u00f1or Camacho, Francisco Jes\u00fas Fernandez\u2010Morales,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1111/1758-2229.13187"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Microbiology%20Reports", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1111/1758-2229.13187", "name": "item", "description": "10.1111/1758-2229.13187", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1111/1758-2229.13187"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-07-21T00:00:00Z"}}, {"id": "10.3390/bios14050215", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:22:28Z", "type": "Journal Article", "created": "2024-04-26", "title": "Comparative Study of Field-Effect Transistors Based on Graphene Oxide and CVD Graphene in Highly Sensitive NT-proBNP Aptasensors", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>Graphene-based materials are actively being investigated as sensing elements for the detection of different analytes. Both graphene grown by chemical vapor deposition (CVD) and graphene oxide (GO) produced by the modified Hummers\u2019 method are actively used in the development of biosensors. The production costs of CVD graphene- and GO-based sensors are similar; however, the question remains regarding the most efficient graphene-based material for the construction of point-of-care diagnostic devices. To this end, in this work, we compare CVD graphene aptasensors with the aptasensors based on reduced GO (rGO) for their capabilities in the detection of NT-proBNP, which serves as the gold standard biomarker for heart failure. Both types of aptasensors were developed using commercial gold interdigitated electrodes (IDEs) with either CVD graphene or GO formed on top as a channel of liquid-gated field-effect transistor (FET), yielding GFET and rGO-FET sensors, respectively. The functional properties of the two types of aptasensors were compared. Both demonstrate good dynamic range from 10 fg/mL to 100 pg/mL. The limit of detection for NT-proBNP in artificial saliva was 100 fg/mL and 1 pg/mL for rGO-FET- and GFET-based aptasensors, respectively. While CVD GFET demonstrates less variations in parameters, higher sensitivity was demonstrated by the rGO-FET due to its higher roughness and larger bandgap. The demonstrated low cost and scalability of technology for both types of graphene-based aptasensors may be applicable for the development of different graphene-based biosensors for rapid, stable, on-site, and highly sensitive detection of diverse biochemical markers.</p></article>", "keywords": ["Transistors", " Electronic", "graphene", "field-effect transistor", "heart failure", "aptamer", "Biosensing Techniques", "02 engineering and technology", "Aptamers", " Nucleotide", "01 natural sciences", "point-of-care diagnostic", "Article", "Peptide Fragments", "0104 chemical sciences", "Limit of Detection", "Natriuretic Peptide", " Brain", "graphene oxide", "Humans", "Graphite", "Gold", "0210 nano-technology", "Electrodes", "TP248.13-248.65", "Biomarkers", "Biotechnology"]}, "links": [{"href": "https://www.mdpi.com/2079-6374/14/5/215/pdf"}, {"href": "https://doi.org/10.3390/bios14050215"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Biosensors", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.3390/bios14050215", "name": "item", "description": "10.3390/bios14050215", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.3390/bios14050215"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-04-26T00:00:00Z"}}, {"id": "10.3390/molecules25122723", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:22:37Z", "type": "Journal Article", "created": "2020-06-16", "title": "Ammonium Recovery and Biogas Upgrading in a Tubular Micro-Pilot Microbial Electrolysis Cell (MEC)", "description": "<p>Here, a 12-liter tubular microbial electrolysis cell (MEC) was developed as a post treatment unit for simultaneous biogas upgrading and ammonium recovery from the liquid effluent of an anaerobic digestion process. The MEC configuration adopted a cation exchange membrane to separate the inner anodic chamber and the external cathodic chamber, which were filled with graphite granules. The cathodic chamber performed the CO2 removal through the bioelectromethanogenesis reaction and alkalinity generation while the anodic oxidation of a synthetic fermentate partially sustained the energy demand of the process. Three different nitrogen load rates (73, 365, and 2229 mg N/Ld) were applied to the inner anodic chamber to test the performances of the whole process in terms of COD (Chemical Oxygen Demand) removal, CO2 removal, and nitrogen recovery. By maintaining the organic load rate at 2.55 g COD/Ld and the anodic chamber polarization at +0.2 V vs. SHE (Standard Hydrogen Electrode), the increase of the nitrogen load rate promoted the ammonium migration and recovery, i.e., the percentage of current counterbalanced by the ammonium migration increased from 1% to 100% by increasing the nitrogen load rate by 30-fold. The CO2 removal slightly increased during the three periods, and permitted the removal of 65% of the influent CO2, which corresponded to an average removal of 2.2 g CO2/Ld. During the operation with the higher nitrogen load rate, the MEC energy consumption, which was simultaneously used for the different operations, was lower than the selected benchmark technologies, i.e., 0.47 kW/N\uffc2\uffb7m3 for CO2 removal and 0.88 kW\uffc2\uffb7h/kg COD for COD oxidation were consumed by the MEC while the ammonium nitrogen recovery consumed 2.3 kW\uffc2\uffb7h/kg N.</p>", "keywords": ["Bioelectric Energy Sources", "Nitrogen", "Organic chemistry", "Pilot Projects", "Waste Disposal", " Fluid", "01 natural sciences", "7. Clean energy", "Article", "Electrolysis", "biogas upgrading", " nitrogen recovery", " microbial electrolysis cell", " bioelectromethanogenesis", " digestate", "biogas upgrading", "QD241-441", "Bioreactors", "Ammonium Compounds", "Anaerobiosis", "Cation Exchange Resins", "Electrodes", "0105 earth and related environmental sciences", "Biological Oxygen Demand Analysis", "Electrochemical Techniques", "microbial electrolysis cell", "6. Clean water", "Biodegradation", " Environmental", "13. Climate action", "digestate", "Biofuels", "nitrogen recovery", "bioelectromethanogenesis"]}, "links": [{"href": "http://www.mdpi.com/1420-3049/25/12/2723/pdf"}, {"href": "https://iris.uniroma1.it/bitstream/11573/1415412/1/Cristiani_Ammonium_2020.pdf"}, {"href": "https://www.mdpi.com/1420-3049/25/12/2723/pdf"}, {"href": "https://doi.org/10.3390/molecules25122723"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Molecules", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.3390/molecules25122723", "name": "item", "description": "10.3390/molecules25122723", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.3390/molecules25122723"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-06-12T00:00:00Z"}}, {"id": "10.3390/molecules26164755", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:22:37Z", "type": "Journal Article", "created": "2021-08-06", "title": "Controlling the Carbon-Bio Interface via Glycan Functional Adlayers for Applications in Microbial Fuel Cell Bioanodes", "description": "<p>Surface modification of electrodes with glycans was investigated as a strategy for modulating the development of electrocatalytic biofilms for microbial fuel cell applications. Covalent attachment of phenyl-mannoside and phenyl-lactoside adlayers on graphite rod electrodes was achieved via electrochemically assisted grafting of aryldiazonium cations from solution. To test the effects of the specific bio-functionalities, modified and unmodified graphite rods were used as anodes in two-chamber microbial fuel cell devices. Devices were set up with wastewater as inoculum and acetate as nutrient and their performance, in terms of output potential (open circuit and 1 k\uffe2\uff84\uffa6 load) and peak power output, was monitored over two months. The presence of glycans was found to lead to significant differences in startup times and peak power outputs. Lactosides were found to inhibit the development of biofilms when compared to bare graphite. Mannosides were found, instead, to promote exoelectrogenic biofilm adhesion and anode colonization, a finding that is supported by quartz crystal microbalance experiments in inoculum media. These differences were observed despite both adlayers possessing thickness in the nm range and similar hydrophilic character. This suggests that specific glycan-mediated bioaffinity interactions can be leveraged to direct the development of biotic electrocatalysts in bioelectrochemical systems and microbial fuel cell devices.</p>", "keywords": ["microbial fuel cells", "Bioelectric Energy Sources", "Surface Properties", "carbon", "Organic chemistry", "02 engineering and technology", "7. Clean energy", "Article", "Carbon", "6. Clean water", "aryldiazonium", "bioanodes", "QD241-441", "Polysaccharides", "Biofilms", "[CHIM] Chemical Sciences", "functionalization", "electrocatalysis", "Graphite", "0210 nano-technology", "Electrodes", "bioelectrochemical systems"]}, "links": [{"href": "http://www.mdpi.com/1420-3049/26/16/4755/pdf"}, {"href": "https://www.mdpi.com/1420-3049/26/16/4755/pdf"}, {"href": "https://doi.org/10.3390/molecules26164755"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Molecules", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.3390/molecules26164755", "name": "item", "description": "10.3390/molecules26164755", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.3390/molecules26164755"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-08-06T00:00:00Z"}}, {"id": "10.3390/plants10112322", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:22:38Z", "type": "Journal Article", "created": "2021-10-29", "title": "Radial Oxygen Loss from Plant Roots\u2014Methods", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>In flooded soils, an efficient internal aeration system is essential for root growth and plant survival. Roots of many wetland species form barriers to restrict radial O2 loss (ROL) to the rhizosphere. The formation of such barriers greatly enhances longitudinal O2 diffusion from basal parts towards the root tip, and the barrier also impedes the entry of phytotoxic compounds produced in flooded soils into the root. Nevertheless, ROL from roots is an important source of O2 for rhizosphere oxygenation and the oxidation of toxic compounds. In this paper, we review the methodological aspects for the most widely used techniques for the qualitative visualization and quantitative determination of ROL from roots. Detailed methodological approaches, practical set-ups and examples of ROL from roots with or without barriers to ROL are included. This paper provides practical knowledge relevant to several disciplines, including plant\u2013soil interactions, biogeochemistry and eco-physiological aspects of roots and soil biota.</p></article>", "keywords": ["0301 basic medicine", "0303 health sciences", "Botany", "microelectrodes", "root-sleeving electrodes", "planar optodes", "Review", "15. Life on land", "microsensors", "6. Clean water", "methylene blue staining", "03 medical and health sciences", "QK1-989", "Methylene blue staining; Microelectrodes; Microsensors; Planar optodes; Root-sleeving electrodes"]}, "links": [{"href": "https://air.uniud.it/bitstream/11390/1215619/1/plants-10-02322.pdf"}, {"href": "https://doi.org/10.3390/plants10112322"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Plants", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.3390/plants10112322", "name": "item", "description": "10.3390/plants10112322", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.3390/plants10112322"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-10-28T00:00:00Z"}}, {"id": "10578/33035", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-04-03T16:27:02Z", "type": "Journal Article", "created": "2023-07-22", "title": "Coupling the electrocatalytic dechlorination of 2,4\u2010                     D                     with electroactive microbial anodes", "description": "Abstract                   <p>                     This work proves the feasibility of dechlorinating 2,4\uffe2\uff80\uff90D, a customary commercial herbicide, using cathodic electrocatalysis driven by the anodic microbial electrooxidation of sodium acetate. A set of microbial electrochemical systems (MES) were run under two different operating modes, namely microbial fuel cell (MFC) mode, with an external resistance of 120\uffe2\uff80\uff89\uffce\uffa9, or microbial electrolysis cell (MEC) mode, by supplying external voltage (0.6\uffe2\uff80\uff89V) for promoting the (bio)electrochemical reactions taking place. When operating the MES as an MFC, 32% dechlorination was obtained after 72\uffe2\uff80\uff89h of treatment, which was further enhanced by working under MEC mode and achieving a 79% dechlorination. In addition, the biodegradability (expressed as the ratio                     BOD/COD                     ) of the synthetic polluted wastewater was tested prior and after the MES treatment, which was improved from negative values (corresponding to toxic effluents) up to 0.135 in the MFC and 0.453 in the MEC. Our MES approach proves to be a favourable option from the point of view of energy consumption. Running the system under MFC mode allowed to co\uffe2\uff80\uff90generate energy along the dechlorination process (\uffe2\uff88\uff920.0120\uffe2\uff80\uff89kWh\uffe2\uff80\uff89mol                     \uffe2\uff88\uff921                     ), even though low removal rates were attained. The energy input under MEC operation was 1.03\uffe2\uff80\uff89kWh\uffe2\uff80\uff89mol                     \uffe2\uff88\uff921                     \uffe2\uff80\uff94a competitive value compared to previous works reported in the literature for (non\uffe2\uff80\uff90biological) electrochemical reactors for 2,4\uffe2\uff80\uff90D electrodechlorination.                   </p", "keywords": ["Bioelectric Energy Sources", "Bioanode", "Electroactive microbial anodes", "Cathodic elec-trodechlorination of 2", "4-D", "Dechlorination", "Feasibility", "Microbial fuel", "Wastewater", "2", "4-Dichlorophenoxyacetic Acid", "7. Clean energy", "Electrodes", "6. Clean water", "Research Articles"]}, "links": [{"href": "https://doi.org/10578/33035"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Microbiology%20Reports", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10578/33035", "name": "item", "description": "10578/33035", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10578/33035"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-07-21T00:00:00Z"}}, {"id": "11390/1215619", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:27:11Z", "type": "Journal Article", "created": "2021-10-28", "title": "Radial Oxygen Loss from Plant Roots\u2014Methods", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>In flooded soils, an efficient internal aeration system is essential for root growth and plant survival. Roots of many wetland species form barriers to restrict radial O2 loss (ROL) to the rhizosphere. The formation of such barriers greatly enhances longitudinal O2 diffusion from basal parts towards the root tip, and the barrier also impedes the entry of phytotoxic compounds produced in flooded soils into the root. Nevertheless, ROL from roots is an important source of O2 for rhizosphere oxygenation and the oxidation of toxic compounds. In this paper, we review the methodological aspects for the most widely used techniques for the qualitative visualization and quantitative determination of ROL from roots. Detailed methodological approaches, practical set-ups and examples of ROL from roots with or without barriers to ROL are included. This paper provides practical knowledge relevant to several disciplines, including plant\u2013soil interactions, biogeochemistry and eco-physiological aspects of roots and soil biota.</p></article>", "keywords": ["0301 basic medicine", "0303 health sciences", "Botany", "microelectrodes", "root-sleeving electrodes", "planar optodes", "Review", "15. Life on land", "microsensors", "6. Clean water", "methylene blue staining", "03 medical and health sciences", "QK1-989", "Methylene blue staining; Microelectrodes; Microsensors; Planar optodes; Root-sleeving electrodes"]}, "links": [{"href": "https://air.uniud.it/bitstream/11390/1215619/1/plants-10-02322.pdf"}, {"href": "https://doi.org/11390/1215619"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Plants", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "11390/1215619", "name": "item", "description": "11390/1215619", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/11390/1215619"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-10-28T00:00:00Z"}}, {"id": "2262/86113", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:28:00Z", "type": "Journal Article", "created": "2019-03-26", "title": "Electrocatalysis of N-doped carbons in the oxygen reduction reaction as a function of pH: N-sites and scaffold effects", "description": "Abstract   Metal-free nitrogenated amorphous carbon electrodes were synthesised via dc plasma magnetron sputtering and post-deposition annealing at different temperatures. The electrocatalytic activity of the electrodes towards the oxygen reduction reaction (ORR) was studied as a function of pH using cyclic voltammetry with a rotating disk electrode. The trends in onset potential were correlated to the carbon nanostructure and chemical composition of the electrodes as determined via Raman spectroscopy and X-ray photoelectron spectroscopy analysis. Results suggest that: 1) the ORR activity in acidic conditions is strongly correlated to the concentration of pyridinic nitrogen sites. 2) At high pH, the presence of graphitic nitrogen sites and a graphitized carbon scaffold are the strongest predictors of high ORR onsets, while pyridinic nitrogen site density does not correlate to ORR activity. An inversion region where pyridine-mediated activity competes with graphitic-N mediated activity is identified in the pH region close to the value of pKa of the pyridinium cation. The onset of the ORR is therefore determined by the activity of different sites as a function of pH and evidence for distinct reduction reaction pathways emerges from these results.", "keywords": ["Carbon electrodes", "Nanoscience & Materials", "02 engineering and technology", "540", "Electrocatalysis", "0210 nano-technology", "7. Clean energy", "01 natural sciences", "0104 chemical sciences"]}, "links": [{"href": "https://doi.org/2262/86113"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Carbon", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2262/86113", "name": "item", "description": "2262/86113", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2262/86113"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-07-01T00:00:00Z"}}, {"id": "2262/92874", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:28:00Z", "type": "Journal Article", "created": "2019-11-09", "title": "Bioinspired electro-permeable glycans on carbon: Fouling control for sensing in complex matrices", "description": "Abstract   The effect of glycan adlayers on the electrochemical response of glassy carbon electrodes was studied using standard redox probes and complex aqueous matrices. Aryldiazonium cations of aryl-lactoside precursors were used to modify glassy carbon via spontaneous and electrochemically assisted covalent grafting. Contact angle and fluorescence binding using Peanut Agglutinin (PNA) as a diagnostic lectin indicate that electrografting results in adlayers with greater glycan surface density than those obtained via spontaneous reaction. X-ray photoelectron spectroscopy with a fluorinated analog confirmed that electrografting results in multilayers of cross-linked aryl-lactosides. Adsorption studies with Bovine Serum Albumin (BSA) show that aryl-lactoside adlayers minimize unspecific protein adsorption. However, no significant differences were detected between spontaneous and electrografted layers in their ability to resist protein fouling despite their differences in coverage. Voltammetry studies show that spontaneous grafting has minimal effects on the response of standard redox probes in solution, whereas electrografting results in additional charge transfer impedance arising from increased electrode passivation. Bare and lactoside-modified carbon electrodes were tested for the detection of caffeine before and after prolonged exposure to coffee solutions. Spontaneous grafting was found to result in optimal properties by imparting antifouling performance in these complex matrices while preserving fast interfacial charge transfer.", "keywords": ["Nanoscience & Materials", "GLASSY-CARBON", "GLASSY-CARBON ELECTRODES", "02 engineering and technology", "540", "01 natural sciences", "Bovine Serum Albumin (BSA)", "0104 chemical sciences", "Aqueous matrices", "CARBON", "Glassy carbon", "Coffee solutions", "Glycan adlayers", "0210 nano-technology", "Peanut Agglutinin (PNA)"]}, "links": [{"href": "https://doi.org/2262/92874"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Carbon", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2262/92874", "name": "item", "description": "2262/92874", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2262/92874"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-03-01T00:00:00Z"}}, {"id": "2262/93879", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:28:00Z", "type": "Journal Article", "created": "2020-07-27", "title": "Tailored glycosylated anode surfaces: Addressing the exoelectrogen bacterial community via functional layers for microbial fuel cell applications", "description": "Grafting of aryldiazonium cations bearing a p-mannoside functionality over microbial fuel cell (MFC) anode materials was performed to investigate the ability of aryl-glycoside layers to regulate colonisation by biocatalytic biofilms. Covalent attachment was achieved via spontaneous reactions and via electrochemically-assisted grafting using potential step experiments. The effect of different functionalisation protocols on MFC performance is discussed in terms of changes in wettability, roughness and electrochemical response of modified electrodes. Water contact angle measurements (WCA) show that aryl-mannoside grafting yields a significant increase in hydrophilic character. Surface roughness determinations via atomic force microscopy (AFM) suggest a more disordered glycan adlayer when electrografting is used to facilitate chemisorption. MFCs were used as living sensors to successfully test the coated electrodes: the response of the MFCs in terms of start-up time was accelerated when compared to that of MFC equipped with non-modified electrodes, this suggests a faster development of a mature biofilm community resulting from aryldiazonium modifications, as confirmed by cyclic voltammetry of MFC anodes. These results therefore indicate that modification with glycans offers a bioinspired route to accelerating biofilm colonisation without any adverse effects on final MFC outputs.", "keywords": ["Microbial fuel cell", "Glycosylation", "Bacteria", "Bioelectric Energy Sources", "Surface Properties", "Microbiota", "02 engineering and technology", "Exoelectrogen biofilms", "540", "7. Clean energy", "01 natural sciences", "[SDV.BIO] Life Sciences [q-bio]/Biotechnology", "0104 chemical sciences", "Electricity", "[CHIM.OTHE] Chemical Sciences/Other", "Biofilms", "Aryl-mannoside layers", "Glycan adlayers", "0210 nano-technology", "Electrodes"]}, "links": [{"href": "https://doi.org/2262/93879"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Bioelectrochemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2262/93879", "name": "item", "description": "2262/93879", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2262/93879"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-12-01T00:00:00Z"}}, {"id": "2311.04674", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:28:01Z", "type": "Journal Article", "created": "2024-04-09", "title": "Direct electrochemical reduction of graphene oxide thin film for aptamer-based selective and highly sensitive detection of matrix metalloproteinase 2", "description": "Simple and low-cost biosensing solutions are suitable for point-of-care applications aiming to overcome the gap between scientific concepts and technological production. To compete with sensitivity and selectivity of golden standards, such as liquid chromatography, the functionalization of biosensors is continuously optimized to enhance the signal and improve their performance, often leading to complex chemical assay development. In this research, the efforts are made on optimizing the methodology for electrochemical reduction of graphene oxide to produce thin film-modified gold electrodes. Under the employed specific conditions, 20 cycles of cyclic voltammetry (CV) are shown to be optimal for superior electrical activation of graphene oxide into electrochemically reduced graphene oxide (ERGO). This platform is further used to develop a matrix metalloproteinase 2 (MMP-2) biosensor, where specific anti-MMP2 aptamers are utilized as a biorecognition element. MMP-2 is a protein which is typically overexpressed in tumor tissues, with important roles in tumor invasion, metastasis as well as in tumor angiogenesis. Based on impedimetric measurements, we were able to detect as low as 3.32 pg/mL of MMP-2 in PBS with a dynamic range of 10 pg/mL - 10 ng/mL. Besides high specificity, ERGO-based aptasensor showed a potential of reuse due to demonstrated successful signal restoration after experimental detection of MMP-2.", "keywords": ["Physics - Instrumentation and Detectors", "FOS: Physical sciences", "Biomolecules (q-bio.BM)", "Physics - Applied Physics", "Electrochemical Techniques", "Biosensing Techniques", "02 engineering and technology", "Applied Physics (physics.app-ph)", "Instrumentation and Detectors (physics.ins-det)", "Aptamers", " Nucleotide", "01 natural sciences", "0104 chemical sciences", "03 medical and health sciences", "0302 clinical medicine", "Quantitative Biology - Biomolecules", "Limit of Detection", "FOS: Biological sciences", "Matrix Metalloproteinase 2", "Humans", "Graphite", "Gold", "0210 nano-technology", "Oxidation-Reduction", "Electrodes"]}, "links": [{"href": "https://doi.org/2311.04674"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Talanta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2311.04674", "name": "item", "description": "2311.04674", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2311.04674"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-07-01T00:00:00Z"}}, {"id": "3083211908", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:28:31Z", "type": "Journal Article", "created": "2020-09-07", "title": "Biosynthesized iron sulfide nanoparticles by mixed consortia for enhanced extracellular electron transfer in a microbial fuel cell", "description": "The bioanode of mixed consortia was for the first time used to in-situ synthesize iron sulfide nanoparticles in a microbial fuel cell (MFC) over a long-term period (46\u00a0days). These poorly crystalline nanoparticles with an average size of 29.97\u00a0\u00b1\u00a07.1\u00a0nm, comprising of FeS and FeS2, significantly promoted extracellular electron transfer and thus the electricity generation of the MFC. A maximum power density of 519.00\u00a0mW/m2 was obtained from the MFC, which was 1.92 times as high as that of the control. The cell viability was promoted by a small amount of iron sulfide nanoparticles but inhibited by the thick nanoparticle 'shell' covered on the bacterial cells. Some electroactive and sulfur reducing bacteria (eg. Enterobacteriaceae, Desulfovibrio, and Geobacter) were specifically enriched on the anode. This study provides a novel insight for improving the performance of bioelectrochemical systems through in-situ sustainable nanomaterials biofabrication by mixed consortia.", "keywords": ["Electron Transport", "Electricity", "Bioelectric Energy Sources", "Nanoparticles", "Electrons", "Ferrous Compounds", "Electrodes", "01 natural sciences", "7. Clean energy", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Cui, Yan, Chen, Xueru, Pan, Zhengyong, Wang, Yuqi, Xu, Qiang, Bai, Jiaying, Jia, Honghua, Zhou, Jun, Yong, Xiaoyu, Wu, Xiayuan,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/3083211908"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Bioresource%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "3083211908", "name": "item", "description": "3083211908", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/3083211908"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-12-01T00:00:00Z"}}, {"id": "3188229186", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:28:43Z", "type": "Journal Article", "created": "2021-08-06", "title": "Controlling the Carbon-Bio Interface via Glycan Functional Adlayers for Applications in Microbial Fuel Cell Bioanodes", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>Surface modification of electrodes with glycans was investigated as a strategy for modulating the development of electrocatalytic biofilms for microbial fuel cell applications. Covalent attachment of phenyl-mannoside and phenyl-lactoside adlayers on graphite rod electrodes was achieved via electrochemically assisted grafting of aryldiazonium cations from solution. To test the effects of the specific bio-functionalities, modified and unmodified graphite rods were used as anodes in two-chamber microbial fuel cell devices. Devices were set up with wastewater as inoculum and acetate as nutrient and their performance, in terms of output potential (open circuit and 1 k\u2126 load) and peak power output, was monitored over two months. The presence of glycans was found to lead to significant differences in startup times and peak power outputs. Lactosides were found to inhibit the development of biofilms when compared to bare graphite. Mannosides were found, instead, to promote exoelectrogenic biofilm adhesion and anode colonization, a finding that is supported by quartz crystal microbalance experiments in inoculum media. These differences were observed despite both adlayers possessing thickness in the nm range and similar hydrophilic character. This suggests that specific glycan-mediated bioaffinity interactions can be leveraged to direct the development of biotic electrocatalysts in bioelectrochemical systems and microbial fuel cell devices.</p></article>", "keywords": ["microbial fuel cells", "Bioelectric Energy Sources", "Surface Properties", "carbon", "Organic chemistry", "02 engineering and technology", "7. Clean energy", "Article", "Carbon", "6. Clean water", "aryldiazonium", "bioanodes", "QD241-441", "Polysaccharides", "Biofilms", "[CHIM] Chemical Sciences", "functionalization", "electrocatalysis", "Graphite", "0210 nano-technology", "Electrodes", "bioelectrochemical systems"]}, "links": [{"href": "http://www.mdpi.com/1420-3049/26/16/4755/pdf"}, {"href": "https://www.mdpi.com/1420-3049/26/16/4755/pdf"}, {"href": "https://doi.org/3188229186"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Molecules", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "3188229186", "name": "item", "description": "3188229186", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/3188229186"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-08-06T00:00:00Z"}}, {"id": "32927315", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:28:50Z", "type": "Journal Article", "created": "2020-09-07", "title": "Biosynthesized iron sulfide nanoparticles by mixed consortia for enhanced extracellular electron transfer in a microbial fuel cell", "description": "The bioanode of mixed consortia was for the first time used to in-situ synthesize iron sulfide nanoparticles in a microbial fuel cell (MFC) over a long-term period (46\u00a0days). These poorly crystalline nanoparticles with an average size of 29.97\u00a0\u00b1\u00a07.1\u00a0nm, comprising of FeS and FeS2, significantly promoted extracellular electron transfer and thus the electricity generation of the MFC. A maximum power density of 519.00\u00a0mW/m2 was obtained from the MFC, which was 1.92 times as high as that of the control. The cell viability was promoted by a small amount of iron sulfide nanoparticles but inhibited by the thick nanoparticle 'shell' covered on the bacterial cells. Some electroactive and sulfur reducing bacteria (eg. Enterobacteriaceae, Desulfovibrio, and Geobacter) were specifically enriched on the anode. This study provides a novel insight for improving the performance of bioelectrochemical systems through in-situ sustainable nanomaterials biofabrication by mixed consortia.", "keywords": ["Electron Transport", "Electricity", "Bioelectric Energy Sources", "Nanoparticles", "Electrons", "Ferrous Compounds", "Electrodes", "7. Clean energy", "01 natural sciences", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Cui, Yan, Chen, Xueru, Pan, Zhengyong, Wang, Yuqi, Xu, Qiang, Bai, Jiaying, Jia, Honghua, Zhou, Jun, Yong, Xiaoyu, Wu, Xiayuan,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/32927315"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Bioresource%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "32927315", "name": "item", "description": "32927315", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/32927315"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-12-01T00:00:00Z"}}, {"id": "34979128", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:28:54Z", "type": "Journal Article", "created": "2021-12-31", "title": "N-acyl-homoserine lactones in extracellular polymeric substances from sludge for enhanced chloramphenicol-degrading anode biofilm formation in microbial fuel cells", "description": "Exploring an efficient acclimation strategy to obtain robust bioanodes is of practical significance for antibiotic wastewater treatment by bioelectrochemical systems (BESs). This study investigated the effects of two acclimation conditions on chloramphenicol (CAP)-degrading anode biofilm formation in microbial fuel cells (MFCs). The one was continuously added the extracellular polymeric substances (EPS) extracted from anaerobic sludge and increasing concentrations of CAP after the first start-up phase, while the other was added the EPS-1 (N-acyl-homoserine lactones, namely AHLs were extracted from the EPS) at the same conditions. The results demonstrated that AHLs in the sludge EPS played a crucial role for enhanced CAP-degrading anode biofilm formation in MFCs. The AHL-regulation could not only maintain stable voltage outputs but also significantly accelerate CAP removal in the EPS MFC. The maximum voltage of 653.83\u00a0mV and CAP removal rate of 1.21\u00a0\u00b1\u00a00.05\u00a0mg/L\u00b7h were attained from the EPS MFC at 30\u00a0mg/L of CAP, which were 0.84 and 1.57 times higher than those from the EPS-1 MFC, respectively. These improvements were largely caused by the thick and 3D structured biofilm, strong and homogeneous cell viability throughout the biofilm, and high protein/polysaccharide ratio along with more conductive contents in the biofilm EPS. Additionally, AHLs facilitated the formation of a biofilm with rich biodiversity and balanced bacterial proportions, leading to more beneficial mutualism among different functional bacteria. More bi-functional bacteria (for electricity generation and antibiotic resistance/degradation) were specifically enriched by AHLs as well. These findings provide quorum sensing theoretical knowledge and practical instruction for rapid antibiotic-degrading electrode biofilm acclimation in BESs.", "keywords": ["Chloramphenicol", "Sewage", "Bioelectric Energy Sources", "Extracellular Polymeric Substance Matrix", "Biofilms", "Acyl-Butyrolactones", "Electrodes", "01 natural sciences", "6. Clean water", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Wu, Xiayuan, Zhang, Lina, Lv, Zuopeng, Xin, Fengxue, Dong, Weiliang, Liu, Guannan, Li, Yan, Jia, Honghua,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/34979128"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Research", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "34979128", "name": "item", "description": "34979128", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/34979128"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-05-01T00:00:00Z"}}, {"id": "37211100", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:28:58Z", "type": "Journal Article", "created": "2023-05-20", "title": "Electroactive microorganisms synthesizing iron sulfide nanoparticles for enhanced hexavalent chromium removal in microbial fuel cells", "description": "Microbial fuel cells (MFCs) have been considered a promising technology for Cr6+ removal, but they are limited by Cr6+-reducing biocathodes with low extracellular electron transfer (EET) and poor microbial activity. In this study, three kinds of nano-FeS hybridized electrode biofilms, obtained through synchronous biosynthesis (Sy-FeS), sequential biosynthesis (Se-FeS) and cathode biosynthesis (Ca-FeS), were applied as biocathodes for Cr6+ removal in MFCs. The Ca-FeS biocathode exhibited the best performance due to the superior properties of biogenic nano-FeS (e.g., more synthetic amount, smaller particle size, better dispersion). The MFC with the Ca-FeS biocathode achieved the highest power density (42.08\u00a0\u00b1\u00a01.42\u00a0mW/m2) and Cr6+ removal efficiency (99.18\u00a0\u00b1\u00a00.1\u00a0%), which were 1.42 and 2.08 times as high as those of the MFC with the normal biocathode, respectively. The synergistic effects of nano-FeS and microorganisms enhanced the bioelectrochemical reduction of Cr6+, first realizing deep reduction of Cr6+ to Cr0 in biocathode MFCs. This significantly alleviated the cathode passivation caused by Cr3+ deposition. In addition, the hybridized nano-FeS as 'armor' layers protected the microbes from toxic attack by Cr6+, improving the biofilm physiological activity and extracellular polymeric substances (EPS) secretion. The hybridized nano-FeS as 'electron bridges' facilitated the microbial community to form a balanced, stable and syntrophic ecological structure. This study proposes a novel strategy through the cathode in-situ biosynthesis of nanomaterials to fabricate hybridized electrode biofilms with enhanced EET and microbial activity for toxic pollutant treatment in bioelectrochemical systems.", "keywords": ["Chromium", "Bioelectric Energy Sources", "Nanoparticles", "7. Clean energy", "Electrodes"], "contacts": [{"organization": "Fan, Mengjie, Zhuang, Xinglei, Gao, Zhen, Lv, Zuopeng, Dong, Weiliang, Xin, Fengxue, Chen, Yingwen, Jia, Honghua, Wu, Xiayuan,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/37211100"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20of%20The%20Total%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "37211100", "name": "item", "description": "37211100", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/37211100"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-09-01T00:00:00Z"}}, {"id": "PMC11117807", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:31:00Z", "type": "Journal Article", "created": "2024-04-26", "title": "Comparative Study of Field-Effect Transistors Based on Graphene Oxide and CVD Graphene in Highly Sensitive NT-proBNP Aptasensors", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>Graphene-based materials are actively being investigated as sensing elements for the detection of different analytes. Both graphene grown by chemical vapor deposition (CVD) and graphene oxide (GO) produced by the modified Hummers\u2019 method are actively used in the development of biosensors. The production costs of CVD graphene- and GO-based sensors are similar; however, the question remains regarding the most efficient graphene-based material for the construction of point-of-care diagnostic devices. To this end, in this work, we compare CVD graphene aptasensors with the aptasensors based on reduced GO (rGO) for their capabilities in the detection of NT-proBNP, which serves as the gold standard biomarker for heart failure. Both types of aptasensors were developed using commercial gold interdigitated electrodes (IDEs) with either CVD graphene or GO formed on top as a channel of liquid-gated field-effect transistor (FET), yielding GFET and rGO-FET sensors, respectively. The functional properties of the two types of aptasensors were compared. Both demonstrate good dynamic range from 10 fg/mL to 100 pg/mL. The limit of detection for NT-proBNP in artificial saliva was 100 fg/mL and 1 pg/mL for rGO-FET- and GFET-based aptasensors, respectively. While CVD GFET demonstrates less variations in parameters, higher sensitivity was demonstrated by the rGO-FET due to its higher roughness and larger bandgap. The demonstrated low cost and scalability of technology for both types of graphene-based aptasensors may be applicable for the development of different graphene-based biosensors for rapid, stable, on-site, and highly sensitive detection of diverse biochemical markers.</p></article>", "keywords": ["Transistors", " Electronic", "graphene", "field-effect transistor", "heart failure", "aptamer", "Biosensing Techniques", "02 engineering and technology", "Aptamers", " Nucleotide", "01 natural sciences", "point-of-care diagnostic", "Article", "Peptide Fragments", "0104 chemical sciences", "Limit of Detection", "Natriuretic Peptide", " Brain", "graphene oxide", "Humans", "Graphite", "Gold", "0210 nano-technology", "Electrodes", "TP248.13-248.65", "Biomarkers", "Biotechnology"]}, "links": [{"href": "https://www.mdpi.com/2079-6374/14/5/215/pdf"}, {"href": "https://doi.org/PMC11117807"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Biosensors", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "PMC11117807", "name": "item", "description": "PMC11117807", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/PMC11117807"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-04-26T00:00:00Z"}}, {"id": "PMC8400688", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:31:07Z", "type": "Journal Article", "created": "2021-08-06", "title": "Controlling the Carbon-Bio Interface via Glycan Functional Adlayers for Applications in Microbial Fuel Cell Bioanodes", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>Surface modification of electrodes with glycans was investigated as a strategy for modulating the development of electrocatalytic biofilms for microbial fuel cell applications. Covalent attachment of phenyl-mannoside and phenyl-lactoside adlayers on graphite rod electrodes was achieved via electrochemically assisted grafting of aryldiazonium cations from solution. To test the effects of the specific bio-functionalities, modified and unmodified graphite rods were used as anodes in two-chamber microbial fuel cell devices. Devices were set up with wastewater as inoculum and acetate as nutrient and their performance, in terms of output potential (open circuit and 1 k\u2126 load) and peak power output, was monitored over two months. The presence of glycans was found to lead to significant differences in startup times and peak power outputs. Lactosides were found to inhibit the development of biofilms when compared to bare graphite. Mannosides were found, instead, to promote exoelectrogenic biofilm adhesion and anode colonization, a finding that is supported by quartz crystal microbalance experiments in inoculum media. These differences were observed despite both adlayers possessing thickness in the nm range and similar hydrophilic character. This suggests that specific glycan-mediated bioaffinity interactions can be leveraged to direct the development of biotic electrocatalysts in bioelectrochemical systems and microbial fuel cell devices.</p></article>", "keywords": ["microbial fuel cells", "Bioelectric Energy Sources", "Surface Properties", "carbon", "Organic chemistry", "02 engineering and technology", "7. Clean energy", "Article", "Carbon", "6. Clean water", "aryldiazonium", "bioanodes", "QD241-441", "Polysaccharides", "Biofilms", "[CHIM] Chemical Sciences", "functionalization", "electrocatalysis", "Graphite", "0210 nano-technology", "Electrodes", "bioelectrochemical systems"]}, "links": [{"href": "http://www.mdpi.com/1420-3049/26/16/4755/pdf"}, {"href": "https://www.mdpi.com/1420-3049/26/16/4755/pdf"}, {"href": "https://doi.org/PMC8400688"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Molecules", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "PMC8400688", "name": "item", "description": "PMC8400688", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/PMC8400688"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-08-06T00:00:00Z"}}, {"id": "chen,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:32:52Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/chen,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "chen,2012", "name": "item", "description": "chen,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/chen,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "chen,y.,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:32:52Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/chen,y.,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "chen,y.,2012", "name": "item", "description": "chen,y.,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/chen,y.,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "chen,x.,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:32:52Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/chen,x.,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "chen,x.,2012", "name": "item", "description": "chen,x.,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/chen,x.,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "e,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:33:07Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/e,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "e,2012", "name": "item", "description": "e,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/e,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "evans,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:33:24Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/evans,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "evans,2012", "name": "item", "description": "evans,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/evans,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "fan,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:33:33Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/fan,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "fan,2012", "name": "item", "description": "fan,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/fan,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "feng,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:33:37Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/feng,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "feng,2012", "name": "item", "description": "feng,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/feng,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "guan,g.,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:33:44Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/guan,g.,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "guan,g.,2012", "name": "item", "description": "guan,g.,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/guan,g.,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "hao,x.,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:33:45Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/hao,x.,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "hao,x.,2012", "name": "item", "description": "hao,x.,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/hao,x.,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "li,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:36:25Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/li,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "li,2012", "name": "item", "description": "li,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/li,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "liang,b.,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:36:25Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/liang,b.,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "liang,b.,2012", "name": "item", "description": "liang,b.,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/liang,b.,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "luo,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:36:26Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/luo,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "luo,2012", "name": "item", "description": "luo,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/luo,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "ma,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:36:27Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/ma,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "ma,2012", "name": "item", "description": "ma,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/ma,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "millersa,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:36:27Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/millersa,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "millersa,2012", "name": "item", "description": "millersa,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/millersa,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "morenovallejo,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:36:28Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/morenovallejo,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "morenovallejo,2012", "name": "item", "description": "morenovallejo,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/morenovallejo,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "peng,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:36:48Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/peng,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "peng,2012", "name": "item", "description": "peng,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/peng,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "qiao,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:36:52Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/qiao,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "qiao,2012", "name": "item", "description": "qiao,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/qiao,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "qu,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:36:52Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/qu,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "qu,2012", "name": "item", "description": "qu,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/qu,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "ren,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:37:03Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/ren,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "ren,2012", "name": "item", "description": "ren,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/ren,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "sekar,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:37:03Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/sekar,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "sekar,2012", "name": "item", "description": "sekar,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/sekar,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "sika,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:37:03Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/sika,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "sika,2012", "name": "item", "description": "sika,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/sika,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "tu,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:37:08Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/tu,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "tu,2012", "name": "item", "description": "tu,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/tu,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}, {"id": "wang,2012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:37:11Z", "type": "Journal Article", "created": "2016-12-24", "description": "Using a combined special glass electrode it is possible to monitor pH ratios and pH variation in the subcutaneous tissue of the infant scalp continuously. Tests on a normal sample of newborn babies immediately after birth showed a significant correlation between tissue pH and capillary blood pH, with the trend of pH variation being broadly similar in both measurement media.", "keywords": ["03 medical and health sciences", "Scalp", "0302 clinical medicine", "Infant", " Newborn", "Humans", "Glass", "Hydrogen-Ion Concentration", "Fetal Blood", "Electrodes", "Monitoring", " Physiologic"], "contacts": [{"organization": "Urs Latscha, Otto Stamm, Aldo Campana, Paul Janecek,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/wang,2012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/American%20Journal%20of%20Obstetrics%20and%20Gynecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "wang,2012", "name": "item", "description": "wang,2012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/wang,2012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1976-01-01T00:00:00Z"}}], "links": [{"rel": "self", "type": "application/geo+json", "title": "This document as GeoJSON", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Electrodes&f=json", "hreflang": "en-US"}, {"rel": "alternate", "type": "text/html", "title": "This document as HTML", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Electrodes&f=html", "hreflang": "en-US"}, {"rel": "collection", "type": "application/json", "title": "Collection URL", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main", "hreflang": "en-US"}, {"type": "application/geo+json", "rel": "first", "title": "items (first)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Electrodes&", "hreflang": "en-US"}, {"rel": "next", "type": "application/geo+json", "title": "items (next)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Electrodes&offset=50", "hreflang": "en-US"}], "numberMatched": 58, "numberReturned": 50, "distributedFeatures": [], "timeStamp": "2026-04-04T09:00:12.496056Z"}