{"type": "FeatureCollection", "features": [{"id": "10.1016/j.chemgeo.2016.11.020", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:21Z", "type": "Journal Article", "created": "2016-11-17", "title": "The gallium isotopic composition of the bulk silicate Earth", "description": "AbstractWe report a new method for precise analysis of gallium (Ga) isotopic composition in geological samples. The purification of Ga is achieved by a three-step ion exchange chromatography to remove matrix and interfering elements. The 71Ga/69Ga ratios are analyzed by multi-collector inductively-coupled-plasma mass-spectrometer (MC-ICP-MS). The external reproducibility of the measurements (0.05\u2030, 2 s.d.) was assessed by replicate analyses of the USGS BCR-2 and BHVO-2 standards. This newly developed technique was then used to investigate the extent of Ga isotopic fractionation during igneous processes by analyzing well-characterized samples from the Kilauea Iki lava lake, USA. These samples were formed in a closed system and have MgO contents ranging from 26.9 to 2.4wt.%. We found that igneous processes do not fractionate Ga isotopes within the analytical uncertainty and that the Ga isotopic composition of mafic-ultramafic lavas can be used to estimate the composition of their mantle source. Twelve ocean island basalts, two mid-ocean-ridge basalts, one continental flood basalt and one komatiite have homogeneous and nearly identical Ga isotopic compositions within analytical uncertainties averaging 0.00\u00b10.06\u2030 (2s.d.). This value represents the best estimate for the Ga isotopic composition of the bulk silicate Earth", "keywords": ["Bulk Silicate Earth", "Komatiite", "Gallium", "Geology", "MORB", "01 natural sciences", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Geochemistry and Petrology", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "14. Life underwater", "OIB", "MC-ICP-MS", "Basalt", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2016.11.020"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2016.11.020", "name": "item", "description": "10.1016/j.chemgeo.2016.11.020", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2016.11.020"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2017.12.006", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:21Z", "type": "Journal Article", "created": "2017-12-13", "title": "Zinc isotope composition of the Earth and its behaviour during planetary accretion", "description": "Abstract   The terrestrial planets are depleted in volatile elements with respect to chondritic meteorites, their possible building blocks. However, the timing, extent and origin of volatile depletion is debated. Zinc is a moderately volatile element (MVE), whose stable isotopic composition can distinguish when and where this depletion took place. Here, we report data for 40 ultramafic rocks comprising pristine upper mantle peridotites from the Balmuccia orogenic lherzolite massif and Archean komatiites that together define the Zn isotope composition of the Earth's primitive mantle. Peridotites and komatiites are shown to have indistinguishable Zn isotopic compositions of \u03b466Zn\u00a0=\u00a0+\u00a00.16\u00a0\u00b1\u00a00.06\u2030 (2SD), (with \u03b466Zn the per mille deviation of 66Zn/64Zn from the JMC-Lyon standard), implying a constant Zn isotope composition for the silicate Earth since 3.5\u00a0Ga. After accounting for Zn sequestration during core formation, the Earth falls on the volatile-depleted end of a carbonaceous chondrite array in \u03b466Zn-Zn/Mg space, implying Earth avoided modification of its MVE budgets during late accretion (e.g. during a giant impact), in contrast to the Moon. The Moon deviates from the chondritic array in a manner consistent with evaporative loss of Zn, where its \u03b466Zn co-varies with Mn/Na, implying post-nebular volatile loss is more pronounced on smaller bodies. Should the giant impact deliver the Earth's volatile complement of Pb and Ag, it cannot account for the budget of lithophile MVEs (e.g. Zn, Rb, Mn), whose abundances reflect those of Earth's nebular building blocks. The Earth initially accreted from material that experienced chemical- and mass-dependent isotopic fractionation akin to carbonaceous chondrites, though volatile depletion was more pronounced on Earth.", "keywords": ["Zinc", "550", "Isotope", "13. Climate action", "Nebula", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "Komatiite", "Mantle", "[SDU.STU.PL] Sciences of the Universe [physics]/Earth Sciences/Planetology", "Peridotite", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://openresearch-repository.anu.edu.au/bitstream/1885/139076/4/1-s2.0-S0009254117306782-main.pdf.jpg"}, {"href": "https://doi.org/10.1016/j.chemgeo.2017.12.006"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2017.12.006", "name": "item", "description": "10.1016/j.chemgeo.2017.12.006", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2017.12.006"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2018.07.007", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:21Z", "type": "Journal Article", "created": "2018-07-18", "title": "High-precision zirconium stable isotope measurements of geological reference materials as measured by double-spike MC-ICPMS", "description": "Abstract   Zirconium plays a major role in geochemistry as it is the major cation of zircons - the oldest preserved minerals on Earth. While Zr isotopic anomalies in meteorites have been widely studied, mass dependant Zr stable isotope fractionation during geological processing has been untouched. Here, we report Zr stable isotopic data for terrestrial igneous rocks and present a novel method for the determination of Zr stable isotope ratios within natural geological materials using ion exchange, double-spike, multiple-collector inductively coupled mass spectrometry (MC-ICPMS). Zirconium is isolated from the rock matrix via a chromatographic separation protocol using a first pass column with AG1-X8 anion exchange resin, and a second pass column containing Eichrom\u00ae DGA resin. A 91Zr\u201396Zr double-spike was created from enriched single 91Zr and 96Zr isotope spikes. Samples were combined with the Zr double-spike at a 43:57 spike:sample [Zr] ratio, prior to dissolution and column chemistry. After column chemistry the purified sample solutions were analysed on a Thermo Scientific Neptune Plus MC-ICPMS and the data was reduced using IsoSpike, with the final Zr isotope data being reported as the per mil deviation of the 94Zr/90Zr from the IPGP-Zr standard (\u03b494/90ZrIPGP-Zr). The \u03b494/90ZrIPGP-Zr of six igneous standard reference materials: two basalts (BHVO-2 and JB-2), one andesite (AGV-2), two granites (GA and GS-N) and a serpentinite (UB-N) as well as one individual zircon grain (Plesovice zircon), are presented using this method. Sample measurements are presented with an analytical uncertainty of \u00b1~0.05\u2030 (2sd) for \u03b494/90ZrIPGP-Zr and these rocks exhibit isotopic variations of ~0.15\u2030 for \u03b494/90ZrIPGP-Zr. These results demonstrate that natural variations of Zr isotopes occur within terrestrial igneous rocks, and are resolvable with this method. Finally the variation of \u03b494/90ZrIPGP-Zr values observed within the magmatic rock reference materials is correlated (R2\u202f=\u202f0.78; n\u202f=\u202f5) with SiO2, suggesting that Zr isotopes could serve as a sensitive tracer of magmatic processes.", "keywords": ["[SDU] Sciences of the Universe [physics]", "Non-traditional stable isotope", "13. Climate action", "MC-ICPMS", "Double-spike", "Differentiation", "Zirconium", "Reference materials", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2018.07.007"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2018.07.007", "name": "item", "description": "10.1016/j.chemgeo.2018.07.007", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2018.07.007"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-08-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2015.08.002", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:21Z", "type": "Journal Article", "created": "2015-08-07", "title": "Barium stable isotope composition of the Earth, meteorites, and calcium\u2013aluminum-rich inclusions", "description": "Abstract   High-precision stable Ba isotope ratios are reported in a variety of terrestrial samples, undifferentiated primitive meteorites, and calcium\u2013aluminum-rich inclusions (CAIs) from the Allende chondrite. All whole-rock terrestrial and meteorite samples are isotopically indistinguishable at a 50 parts per million (ppm) level per atomic mass unit (amu). Three CAIs are isotopically light, with \u03b4138/137Ba (permil deviation of the 138Ba/137Ba ratio from a terrestrial standard) values down to \u2212\u00a00.6\u2030 compared to whole-rock meteorites, whereas the matrix is enriched in heavy isotopes (\u03b4138/137Ba: +\u00a00.2\u2030). Similar light isotope enrichments in CAIs have been previously observed for Eu, Sr, and Ca, while for most other elements CAIs are enriched in the heavier isotopes (e.g. Mg, Fe). Kinetic isotopic fractionation is a possible explanation for the enrichment in the lightest isotopes, either by condensation from a vapor phase enriched in light isotopes by kinetic effects or by kinetic fractionation during non-equilibrium condensation of an undercooled gas as suggested for Ca isotopes. However, the common property of Ba, Eu, and Sr is that they all have a low first ionization potential. We suggest that electromagnetic sorting of ionized species in the early Solar System is a possible alternative mechanism to explain the depletion in heavy isotopes observed in refractory inclusions for those elements.", "keywords": ["CAIs", "[SDU] Sciences of the Universe [physics]", "Isotope geochemistry", "Barium", "13. Climate action", "4. Education", "0103 physical sciences", "01 natural sciences", "7. Clean energy", "Meteorites", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2015.08.002"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2015.08.002", "name": "item", "description": "10.1016/j.chemgeo.2015.08.002", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2015.08.002"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2015-10-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2017.03.013", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:21Z", "type": "Journal Article", "created": "2017-03-20", "title": "Tin stable isotope analysis of geological materials by double-spike MC-ICPMS", "description": "Abstract   Tin is a volatile as well as chalcophile and siderophile element, and this geochemical behaviour gives rise to a broad range of potential applications for Sn as a stable isotope tracer in geological processes. We present the first high-precision method to analyse the stable isotopic composition of Sn in geological materials using ion-exchange chromatography and double-spike multi-collector inductively-coupled-plasma mass-spectrometry (MC-ICPMS). We apply these methods to analyse the Sn stable isotopic composition of four geological reference materials, including a number of replicate digestions of BHVO-2 and BCR-2 to assess the reproducibility of the technique. Tin was purified prior to analysis using TRU resin to remove matrix and interfering elements. Isotopic ratios were measured using a Thermo-Fischer Neptune Plus MC-ICPMS combined with a 117Sn\u2013122Sn double-spike to correct for any mass dependent fractionation resulting from instrumental mass bias or incomplete yields from chemical purification. Results are expressed in delta notation as \u03b4 122/118Sn, representing the per mil (\u2030) difference in the 122/118Sn ratio of the sample relative to our in-house standard Sn_IPGP. Based on replicate analyses of the USGS reference materials BHVO-2 and BCR-2, we estimate the external reproducibility to be ca. \u00b1 0.065\u2030 (2 sd) on the \u03b4 122/118Sn ratio, or ca. \u00b1 0.016\u2030 per amu. Analyses of these plus two additional USGS reference materials, AGV-2 and GSP-2, show a large range (>0.2\u2030 on \u03b4 122/118Sn) of Sn stable isotopic compositions that are correlated with igneous differentiation indicators (e.g. SiO2 content), indicating that Sn isotopes are fractionated during igneous processes. These results indicate significant potential for Sn stable isotopes as a tracer of magmatic differentiation and the redox state of the mantle. In addition, Sn stable isotopes may prove useful in tracing diverse geological processes such as volatilisation/condensation and metal\u2013silicate/metal\u2013sulphide differentiation.", "keywords": ["Geochemistry and Petrology", "13. Climate action", "Geology", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2017.03.013"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2017.03.013", "name": "item", "description": "10.1016/j.chemgeo.2017.03.013", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2017.03.013"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-05-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2018.03.030", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:21Z", "type": "Journal Article", "created": "2018-03-20", "title": "The stable strontium isotopic composition of ocean island basalts, mid-ocean ridge basalts, and komatiites", "description": "Ocean island basalts Mid-ocean ridge basalts Komatiites Kilauea Iki Bulk silicate earth A B S T R A C T The radiogenic 87 Rb-87 Sr system has been widely applied to the study of geological and planetary processes. In contrast, the stable Sr isotopic composition of the bulk silicate Earth (BSE) and the effects of igneous differentiation on stable Sr isotopes are not well-established. Here we report the stable Sr isotope (88 Sr/ 86 Sr, reported as \u03b4 88/86 Sr, in parts per mil relative to NIST SRM 987) compositions for ocean islands basalts (OIB), mid-ocean ridge basalts (MORB) and komatiites from a variety of locations. Stable Sr isotopes display limited fractionation in a OIB sample suite from the Kilauea Iki lava lake suggesting that igneous processes have limited effect on stable Sr isotope fractionation (\u00b1 0.12\u2030 over 20% MgO variation; 2sd). In addition, OIB (\u03b4 88/ 86 Sr = 0.16-0.46\u2030; average 0.28 \u00b1 0.17\u2030), MORB (\u03b4 88/86 Sr = 0.27-0.34\u2030; average 0.31 \u00b1 0.05\u2030) and komatiites (\u03b4 88/86 Sr = 0.20-0.97\u2030; average 0.41 \u00b1 0.16\u2030) from global localities exhibit broadly similar Sr stable isotopic compositions. Heavy stable Sr isotope compositions (\u03b4 88/86 Sr > 0.5\u2030) in some Barberton Greenstone belt komatiites may reflect Archean seawater alteration or metamorphic processes and preferential removal of the lighter isotopes of Sr. To first order, the similarity among OIBs from three different ocean basins suggests homogeneity of stable Sr isotopes in the mantle. Earth's mantle stable Sr isotopic composition is established from the data on OIB, MORB and komatiites to be \u03b4 88/86 Sr = 0.30 \u00b1 0.02\u2030 (2sd). The BSE \u03b4 88/86 Sr value is identical, within uncertainties, to the composition of carbonaceous chondrites (\u03b4 88/ 86 Sr = 0.29 \u00b1 0.06\u2030; 2sd) measured in this study.", "keywords": ["Ocean island basalts", "Bulk silicate earth", "Sr isotopes", "Mid-ocean ridge basalts", "Kilauea Iki", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "14. Life underwater", "Komatiites", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2018.03.030"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2018.03.030", "name": "item", "description": "10.1016/j.chemgeo.2018.03.030", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2018.03.030"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-04-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2019.119279", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:21Z", "type": "Journal Article", "created": "2019-08-15", "title": "Volatile loss under a diffusion-limited regime in tektites: Evidence from tin stable isotopes", "description": "Abstract   Tektites are glasses derived from near-surface continental crustal rocks that were molten and ejected from the Earth's surface during hypervelocity meteorite impacts. They are among the driest terrestrial samples, although the exact mechanism of water loss and the behaviour of other volatile species during these processes are debated. Based on the difference in magnitude of the Cu and Zn isotopic fractionations in tektites, and the difference of diffusivity between these elements, it was suggested that volatile loss was diffusion-limited. Tin is potentially well suited to testing this model, as it has a lower diffusivity in silicate melts than both Cu and Zn, but a similar volatility to Zn. Here, we analysed the Sn stable isotopic composition in a suite of seven tektites, representing three of the four known tektite strewn fields, and for which Zn and Cu isotopes were previously reported. Tin is enriched in the heavier isotopes (\u22652.5\u2030 on the 122Sn/118Sn ratio) in tektites, correlated with the degree of Sn elemental depletion in their respective samples as well as with Cu and Zn isotope ratios, implying a common control. While the isotope fractionation of Sn, Cu and Zn is a result of volatility, the magnitude of isotope fractionation is strongly moderated by their relative rates of diffusion in the molten tektite droplets. An Australasian Muong Nong-type tektite analysed has the least Sn depletion and Sn isotope fractionation, consistent with these samples being more proximal to the source and experiencing a shorter time at high temperatures.", "keywords": ["Volatiles", "ORIGIN", "FRACTIONATION", "01 natural sciences", "Tektites", "[SDU] Sciences of the Universe [physics]", "EVAPORATION", "ZINC", "105105 Geochemistry", "SILICATE MELTS", "Tin", "DISSOLUTION", "13. Climate action", "Impacts", "105105 Geochemie", "GEOCHEMISTRY", "CU", "GEOLOGICAL-MATERIALS", "Stable isotopes", "IMPACT GLASSES", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2019.119279"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2019.119279", "name": "item", "description": "10.1016/j.chemgeo.2019.119279", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2019.119279"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-12-01T00:00:00Z"}}, {"id": "10.1016/j.chemgeo.2021.120327", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2021-05-18", "title": "Eruptive style controls the formation of silicon hexafluoride salts on volcanic ash: The case of the 2010 eruption of Eyjafjallaj\u00f6kull volcano, Iceland", "description": "Abstract   The presence of fluoride (F\u2212)-bearing compounds in volcanic ash fallout is recognised to pose significant environmental and health hazards. Nevertheless, understanding of the formation and composition of these compounds remains limited, or even inconsistent. This hampers full comprehension of the risks and impacts elicited by fluorine-rich ash emissions after an explosive eruption. The 2010 activity of Eyjafjallajokull volcano in Iceland was characterised by contrasted eruptive styles - phreatomagmatic and magmatic - which produced ash deposits with distinct soluble F\u2212 contents. Based on X-ray photoelectron spectroscopy and leachate analyses of Eyjafjallajokull ash materials, we infer the existence of silicon hexafluoride salts, particularly Na2SiF6, dominantly if not exclusively on the magmatic ash, and suggest a reaction mechanism for their formation. The presence of Na2SiF6 explains the much greater F\u2212 concentration and higher acidity measured in leachates of the magmatic ash compared to those of the phreatomagmatic ash. River waters affected by ash deposition during the magmatic activity showed a temporary increase in F\u2212 and decrease in dissolved silicon isotope values (\u03b430Si). We contend that the formation of silicon hexafluoride salts on ash leads to a surface enrichment of the ash's silicate glass and mineral components in 28Si, with the release of this light Si from the magmatic ash during the early stage of weathering causing a depression in the riverine \u03b430Si. This supports existing evidence of silicate dissolution processes being influenced by the presence of fluorine. Our study also points to the likely important role of Na2SiF6 in modulating the environmental and health effects of ash emissions from fluorine-rich magmatic eruptions.", "keywords": ["Silicon hexafluoride salts", "13. Climate action", "Eyjafjallaj\u00f6kull volcano", "Silicon isotopes", "Ash", "Fluoride", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemgeo.2021.120327"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemical%20Geology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemgeo.2021.120327", "name": "item", "description": "10.1016/j.chemgeo.2021.120327", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemgeo.2021.120327"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-09-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2003.10.005", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2003-11-17", "title": "Heavy Metal Accumulation By Nicotiana Glauca Graham In A Solid Waste Disposal Site", "description": "Nicotiana glauca Graham, is the only perennial shrub growing in a solid waste contaminated site in the Negev desert of Israel. The concentration of heavy metals (Cu, Fe, Mn, Zn, Ni, Cd and Pb) in the upper soil layer was significantly higher (p<0.01) than in non-contaminated desert soil. In root and shoot of N. glauca, growing in the site, the concentration of Cu, Zn and Fe was significantly higher (p<0.05) than in plants of a non-contaminated site. In a controlled experiment, the concentrations of Zn and Cu in root of plants grown, in a mixture of contaminated and non-contaminated soil (1:1) was 9.5 and 4.7 higher than that of plants grown in non-contaminated soil, respectively. While Zn was accumulated in shoot of plants grown in contaminated soil (531 mgkg(-1)) in significantly higher concentration than in plants grown in non-contaminated soil (56 mgkg(-1)), no significant differences were found in Cu accumulation. Growth of N. glauca was inhibited on contaminated soil, but no other obvious stress symptoms were apparent. Therefore, long term experiments under controlled conditions are planned to study the mechanism of heavy metal tolerance and accumulation in N. glauca.", "keywords": ["Nicotiana", "0106 biological sciences", "Soil", "Metals", " Heavy", "Biomass", "Israel", "Plant Roots", "01 natural sciences", "6. Clean water", "Refuse Disposal", "0105 earth and related environmental sciences", "12. Responsible consumption"], "contacts": [{"organization": "Oz Barazani, P. Sathiyamoorthy, Uttam Manandhar, Raya Vulkan, Avi Golan-Goldhirsh,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2003.10.005"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2003.10.005", "name": "item", "description": "10.1016/j.chemosphere.2003.10.005", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2003.10.005"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2004-02-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2004.04.043", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2004-07-30", "title": "Effects Of Environmental Factors On N2o Emission From And Ch4 Uptake By The Typical Grasslands In The Inner Mongolia", "description": "The fluxes of N2O emission from and CH4 uptake by the typical semi-arid grasslands in the Inner Mongolia, China were measured in 1998-1999. Three steppes, i.e. the ungrazed Leymus chinensis (LC), the moderately grazed Leymus chinensis (LC) and the ungrazed Stipa grandis (SG), were investigated, at a measurement frequency of once per week in the growing seasons and once per month in the non-growing seasons of the LC steppes. In addition, four diurnal-cycles of the growing seasons of the LC steppes, each in an individual stage of grass growth, were measured. The investigated steppes play a role of source for the atmospheric N2O and sink for the atmospheric CH4, with a N2O emission flux of 0.06-0.21 kg N ha(-1) yr(-1) and a CH4 uptake flux of 1.8-2.3 kg C ha(-1) yr(-1). Soil moisture primarily and positively regulates the spatial and seasonal variability of N2O emission. The usual difference in soil moisture among various semi-arid steppes does not lead to significantly different CH4 uptake intensities. Soil moisture, however, negatively regulates the seasonal variability in CH4 uptake. Soil temperature of the most top layer might be the primary driving factor for CH4 uptake when soil moisture is relatively low. The annual net emission of N2O and CH4 from the ungrazed LC steppe, the moderately grazed LC steppe and the ungrazed SG steppe is at a CO2 equivalent rate of 7.7, 0.8 and -7.5 kg CO2-C ha(-1) yr(-1), respectively, which is at an ignorable level. This implies that the role of the semi-arid grasslands in the atmospheric greenhouse effect in terms of net emission of greenhouse gases (CO2, CH4 and N2O) may exclusively depend upon the net exchange of net ecosystem CO2 exchange.", "keywords": ["2. Zero hunger", "China", "Time Factors", "Atmosphere", "Nitrous Oxide", "Temperature", "04 agricultural and veterinary sciences", "Carbon Dioxide", "15. Life on land", "Poaceae", "01 natural sciences", "Soil", "13. Climate action", "0401 agriculture", " forestry", " and fisheries", "Methane", "Ecosystem", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2004.04.043"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2004.04.043", "name": "item", "description": "10.1016/j.chemosphere.2004.04.043", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2004.04.043"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2005-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2004.11.097", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2005-01-27", "title": "Microbial Biomass And Enzyme Activities In Submerged Rice Soil Amended With Municipal Solid Waste Compost And Decomposed Cow Manure", "description": "We studied the suitability of municipal solid waste compost (MSWC) application to submerged rice paddies in the perspective of metal pollution hazards associated with such materials. Experiments were conducted during the wet seasons of 1997, 1998 and 1999 on rice grown under submerged condition, at the Agriculture Experimental Farm, Calcutta University at Baruipur, West Bengal, India. The treatments consisted of control, no input; MSWC, at 60 kgNha(-1); well decomposed cow manure (DCM), at 60 kgNha(-1); MSWC (30 kgNha(-1)) +Urea (30 kgNha(-1)); DCM (30 kgNha(-1)) +U (30 kgNha(-1)) and Fertilizer, (at 60:30:30 NPK kgha(-1) through urea, single superphosphate and muriate of potash respectively). Soil microbial biomass-C (MBC), MBC as percentage of organic-C (ratio index value, RIV), urease and acid phosphatase activities were higher in DCM than MSWC-treated soils, due to higher amount of biogenic organic materials like water soluble organic carbon, carbohydrate and mineralizable nitrogen in the former. The studied parameters were higher when urea was integrated with DCM or MSWC, compared to their single applications. Soil MBC, urease and acid phosphatase activities periodically declined up to 60 day after transplanting (DAT) and then increased after crop harvest. The heavy metals in MSWC did not detrimentally influence MBC, urease and acid phosphatase activities of soil. In the event of long term MSWC application, changes in soil quality parameters should be monitored regularly, since heavy metals once entering into soil persist over a long period.", "keywords": ["2. Zero hunger", "Oryza", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "6. Clean water", "Enzymes", "Refuse Disposal", "12. Responsible consumption", "Manure", "Soil", "13. Climate action", "11. Sustainability", "Animals", "0401 agriculture", " forestry", " and fisheries", "Cattle", "Biomass", "Fertilizers", "Soil Microbiology", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Ashis Kumar Chakraborty, Kalyan Chakrabarti, Pradip Bhattacharyya,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2004.11.097"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2004.11.097", "name": "item", "description": "10.1016/j.chemosphere.2004.11.097", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2004.11.097"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2005-07-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2006.03.038", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2006-05-09", "title": "Decomposition Of Heavy Metal Contaminated Nettles (Urtica Dioica L.) In Soils Subjected To Heavy Metal Pollution By River Sediments", "description": "Two incubation experiments were conducted to evaluate differences in the microbial use of non-contaminated and heavy metal contaminated nettle (Urtica dioica L.) shoot residues in three soils subjected to heavy metal pollution (Zn, Pb, Cu, and Cd) by river sediments. The microbial use of shoot residues was monitored by changes in microbial biomass C, biomass N, biomass P, ergosterol, N mineralisation, CO(2) production and O(2) consumption rates. Microbial biomass C, N, and P were estimated by fumigation extraction. In the non-amended soils, the mean microbial biomass C to soil organic C ratio decreased from 2.3% in the low metal soil to 1.1% in the high metal soils. In the 42-d incubation experiment, the addition of 2% nettle residues resulted in markedly increased contents of microbial biomass P (+240%), biomass C (+270%), biomass N (+310%), and ergosterol (+360%). The relative increase in the four microbial properties was similar for the three soils and did not show any clear heavy metal effect. The contents of microbial biomass C, N and P and ergosterol contents declined approximately by 30% during the incubation as in the non-amended soils. The ratios microbial biomass C to N, microbial biomass C to P, and ergosterol to microbial biomass C remained constant at 5.2, 26, and 0.5%, respectively. In the 6-d incubation experiment, the respiratory quotient CO(2)/O(2) increased from 0.74 in the low metal soil to 1.58 in the high metal soil in the non-amended soils. In the treatments amended with 4% nettle residues, the respiratory quotient was constant at 1.13, without any effects of the three soils or the two nettle treatments. Contaminated nettle residues led generally to significantly lower N mineralisation, CO(2) production and O(2) consumption rates than non-contaminated nettle residues. However, the absolute differences were small.", "keywords": ["2. Zero hunger", "Geologic Sediments", "Minerals", "Time Factors", "Nitrogen", "Urtica dioica", "04 agricultural and veterinary sciences", "Carbon Dioxide", "01 natural sciences", "6. Clean water", "12. Responsible consumption", "Oxygen", "Rivers", "13. Climate action", "Ergosterol", "Metals", " Heavy", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Biomass", "Soil Microbiology", "Environmental Monitoring", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Rainer Georg Joergensen, Khalid Saifullah Khan,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2006.03.038"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2006.03.038", "name": "item", "description": "10.1016/j.chemosphere.2006.03.038", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2006.03.038"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2006-11-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2007.06.085", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2007-08-21", "title": "Warming And Drought Change Trace Element Bioaccumulation Patterns In A Mediterranean Shrubland", "description": "A field experiment consisting of drought and warming manipulation was conducted in a Mediterranean shrubland dominated by the shrubs Erica multiflora and Globularia alypum. The aim was to investigate the effects of the climatic changes predicted by IPCC models for the coming decades on trace element concentration and accumulation in aboveground biomass, plant litter, and soil. Warming increased concentrations and aboveground accumulation of some trace elements related to plant root uptake, such as Al, As, Cr, Cu, and partially Pb. This effect was more general in E. multiflora than in G. alypum. The stronger effects were increases in Al leaf concentrations (42%) and aboveground accumulation (500gha(-1)) in E. multiflora, in As stem biomass accumulation (0.2gha(-1)) in E. multiflora, and in Cr leaf concentrations (51%) in G. alypum and stem aboveground accumulation in E. multiflora (1.1gha(-1)). These species-specific increases were related to greater retranslocation, photosynthetic capacity and growth in E. multiflora than in G. alypum. Warming decreased the concentrations of some trace elements in leaf litter, implying the existence of an increased leaf retranslocation. Drought increased As (40%) and Cd (55%) in E. multiflora stems, whereas it decreased Cu (50%) in leaves, Ni (28%) in stems and Pb (32%) in leaf litter of G. alypum. The increasing concentrations of some trace elements in E. multiflora and not in G. alypum were related to a greater growth reduction in E. multiflora than in G. alypum. Warming increased As soil solubility (67%) and decreased total soil As (21%). Those changes were related to a greater Fe mobilization in warming plot and to a greater plant capture. Drought increased Hg (350%) concentrations in soils but had no significant effects on trace element accumulation in aboveground biomass. The different response to warming and drought in the two dominant species implies uneven changes in the quality of the plant tissues that may have implications for herbivores. This may be specially important for the performance of the studied Mediterranean ecosystems under the warmer and drier conditions predicted by the next decades by the GCM and ecophysiological models.", "keywords": ["2. Zero hunger", "Trace elements", "Biomass concentrations", "Mediterranean Region", "15. Life on land", "Models", " Biological", "01 natural sciences", "Soil content", "6. Clean water", "Trace Elements", "Disasters", "Mediterranean shrubland", "Heavy metals", "13. Climate action", "Metals", " Heavy", "Climate change", "Soil Pollutants", "Biomass", "Seasons", "Weather", "Ecosystem", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2007.06.085"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2007.06.085", "name": "item", "description": "10.1016/j.chemosphere.2007.06.085", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2007.06.085"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2008-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2008.07.056", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2008-10-01", "title": "Integration Of Toxicological And Chemical Tools To Assess The Bioavailability Of Metals And Energetic Compounds In Contaminated Soils", "description": "Bioavailability is critical for understanding effects that might result from exposure of biota to contaminated soils. Soils from military range and training areas (RTAs) are contaminated principally by energetic materials (EM) and metals. Their chemical characteristics are relatively well known and toxicity assessment of soils from RTAs are in some cases available. However, bioavailability on these sites needs to be comprehensively characterized. A holistic approach to bioavailability, incorporating both chemical and earthworm toxicological indicators, was applied to soils from an anti-tank firing range at a Canadian Forces Base. Results showed that HMX and the metals Zn, Pb, Bi and Cd, though not consistently the prevailing toxicants, were the most accessible to earthworms. Some metals (notably Cu, Zn, Cr and Bi) were also accumulated in earthworm tissue but those were not necessarily expected given their bioaccessibility (i.e., the chemical availability of contaminants in the environment for the organisms) at the beginning of the exposure. The tested soils impaired earthworm reproduction and reduced adult growth. Measurement of selected sublethal parameters indicated that lysosomal integrity (determined as the neutral red retention time--NRRT) was decreased, while elevated superoxide dismutase (SOD) activity suggested that earthworms experienced oxidative stress. The correspondence between the NRRT and metal contamination pattern suggested that metals may be the main cause of lysosomal disruption in EM-contaminated soils. The approach to bioavailability appraisal adopted in this case appears to be a promising practice for site-specific assessment of contaminated land.", "keywords": ["zinc/metabolism/pharmacokinetics/toxicity", "assessment", "metals", "Biological Availability", "lead/metabolism/pharmacokinetics/toxicity", "01 natural sciences", "biological availability", "soil pollutants/metabolism/pharmacokinetics/toxicity", "Animals", "Soil Pollutants", "bismuth/metabolism/pharmacokinetics/toxicity", "Oligochaeta", "oligochaeta/rug effects/growth & development/metabolism", "soils", "0105 earth and related environmental sciences", "metals/metabolism/pharmacokinetics/ toxicity", "explosives", "04 agricultural and veterinary sciences", "bioaccessibility", "6. Clean water", "Zinc", "Lead", "Metals", "13. Climate action", "0401 agriculture", " forestry", " and fisheries", "cadmium/metabolism/pharmacokinetics/toxicity", "bioavailability", "Bismuth", "Cadmium"], "contacts": [{"organization": "\u00c9meline Valton, Bertin Trottier, Aurelie Auroy, Aurelie Auroy, Yann Berthelot, Pierre Yves Robidoux, Pierre Yves Robidoux,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2008.07.056"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2008.07.056", "name": "item", "description": "10.1016/j.chemosphere.2008.07.056", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2008.07.056"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2008-12-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2004.12.032", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2005-02-08", "title": "A Microcosm Approach To Assessing The Effects Of Earthworm Inoculation And Oat Cover Cropping On Co2 Fluxes And Biological Properties In An Amended Semiarid Soil", "description": "We designed a microcosm experiment to assess the influence of inoculation with Eisenia foetida earthworms and the establishment of an Avena sativa cover crop on biological (enzyme activities and labile carbon fractions) soil quality indicators in a soil treated with a composted organic residue, and to determine the contribution of these treatments to carbon dioxide emissions from the soil to the atmosphere of the microcosm. The microcosms were incubated for 53 days under 28 degrees C/18 degrees C day/night temperatures. The addition of earthworms and the planting of A. sativa increased dehydrogenase activity of compost amended soil by about 44% after 23 days of incubation. The metabolic potential, calculated as the ratio dehydrogenase activity/water soluble C, was higher in the compost amended soil planted with A. sativa. The highest total amount of CO2-C evolved occurred in the soil treated with composted residue and earthworms (about 40% of the total amount of CO2 evolved came from earthworm activity). The planting of A. sativa increased the decomposition rate constant of organic matter in the amended soil but decreased the potentially mineralizable C pool. In conclusion, the establishment of an A. sativa cover crop and the addition of E. foetida to a degraded agricultural soil treated with composted residue were effective treatments for improving the biological and biochemical quality and the metabolic potential of the soil.", "keywords": ["2. Zero hunger", "Water soluble carbon", "Time Factors", "Avena", "Atmosphere", "Temperature", "Soil respiration", "04 agricultural and veterinary sciences", "Carbon Dioxide", "15. Life on land", "01 natural sciences", "Soil", "Eisenia foetida", "Dehydrogenase activity", "Animals", "0401 agriculture", " forestry", " and fisheries", "Oligochaeta", "Organic Chemicals", "Oxidoreductases", "Mineralization potential", "Ecosystem", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2004.12.032"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2004.12.032", "name": "item", "description": "10.1016/j.chemosphere.2004.12.032", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2004.12.032"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2005-06-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2006.12.071", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2007-02-21", "title": "The Copper Tolerance Strategies And The Role Of Antioxidative Enzymes In Three Plant Species Grown On Copper Mine", "description": "This study was undertaken to identify the strategies and the status of antioxidant enzyme activities involved in three plant species tolerance against Cu-toxicity in copper mine. The following methods were used for evaluations in three wild type species; Datura stramonium, Malva sylvestris and Chenopodium ambrosioides. The level of chlorophyll and the activities of superoxide dismutase (SOD), glutathione peroxidase (GPX) and catalase (CAT) by spectrometry, malondialdehyde (MDA) and dityrosine by HPLC and the levels of Cu in tissues and soils by atomic absorption spectrometry (AAS). Analysis showed that total and available copper were at toxic levels for plants growing on contaminated soil (zone 1). However, there were not any visual and conspicuous symptoms of Cu toxicity in plant species. Among three species, excess copper was transferred only into the D. stramonium and C. ambrosioides tissues. The C. ambrosioides accumulated Cu in roots and then in leaves, in which the leaves chloroplasts stored Cu around two times of vacuoles. In D. stramonium most of Cu was accumulated in leaves in which the storage rate in vacuoles and chloroplasts were 42% and 8%, respectively. In zone 1, the chlorophyll levels increased significantly in leaves of C. ambrosioides with respect to the same plant growing on uncontaminated soil (zone 2). There was insignificant decrease in chlorophyll content of D. stramonium leaves, collected from zone 1 with respect to zone 2. The D. stramonium and C. ambrosioides in zone 1, both revealed significant increase in their tissues antioxidant enzyme activities in comparison with the same samples of zone 2. There was significant elevation in oxidative damage biomarkers; MDA and dityrosine, when the aerial parts of D. stramonium in zone 1 were compared with the same parts of zone 2. We concluded that there were different tolerance strategies in studied plant species that protected them against copper toxicity. In M. sylvestris, exclusion of Cu from the roots or its stabilization in the soil restricted Cu toxicity effects. On the other hand D. stramonium and C. ambrosioides, elevated their antioxidative enzyme activities in response to cu-toxicity. In addition, the species D. stramonium accumulated excess of Cu in leaves vacuoles.", "keywords": ["Chlorophyll", "0106 biological sciences", "0301 basic medicine", "Chloroplasts", "Malva", "Plants", "15. Life on land", "Lipid Metabolism", "Plant Roots", "01 natural sciences", "Antioxidants", "Mining", "6. Clean water", "Chenopodium", "Oxidative Stress", "Soil", "03 medical and health sciences", "Malondialdehyde", "Vacuoles", "Datura", "Tyrosine", "Biomass", "Copper", "Plant Proteins"], "contacts": [{"organization": "Massod Mashhadi Akbar Boojar, Faranak Goodarzi,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2006.12.071"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2006.12.071", "name": "item", "description": "10.1016/j.chemosphere.2006.12.071", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2006.12.071"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2007-05-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2007.09.006", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2007-10-26", "title": "Tillage Management To Mitigate Herbicide Loss In Runoff Under Simulated Rainfall Conditions", "description": "Conservation tillage mitigates soil loss in cropland because plant residues help protect the soil, but effects on pesticide movement in surface runoff are not as straightforward. Effects of soil disturbance on surface runoff loss of chlorimuron and alachlor were evaluated utilizing runoff trays. Soil in the trays was either disturbed (tilled) and kept bare or was not tilled, and existing decomposed plant residue was left on the surface. Rainfall (25mm, 20min) was simulated 1d after alachlor (2.8kg ha(-1)) or chlorimuron (54g ha(-1)) application, and runoff was collected. Runoff fractions were analyzed for herbicide and sediment. Total alachlor loss from bare plots was greater than that in no-tillage plots (4.5% vs. 2.3%, respectively). More than one-third of total alachlor lost from bare plots occurred in the first l of runoff, while no-tillage plots had less runoff volume with a more even distribution of alachlor concentration in the runoff during the rainfall simulation and subsequent runoff period. In contrast, more chlorimuron was lost from no-tillage plots than bare plots (12% vs. 1.5%) even though total runoff volume was lower in the no-tillage plots (10.6mm vs. 13.6mm). This was attributed to dense coverage with partially decomposed plant residue in no-tillage plots (1652kg ha(-1)) that intercepted chlorimuron. It was likely that chlorimuron, a polar compound, was more easily washed off surface plant residues and transported in runoff.", "keywords": ["2. Zero hunger", "Herbicides", "Rain", "04 agricultural and veterinary sciences", "Models", " Theoretical", "15. Life on land", "01 natural sciences", "6. Clean water", "Soil", "Acetamides", "Water Movements", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2007.09.006"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2007.09.006", "name": "item", "description": "10.1016/j.chemosphere.2007.09.006", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2007.09.006"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2008-02-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2009.01.042", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2009-02-16", "title": "Effects Of Earthworms On Metal Uptake Of Heavy Metals From Polluted Mine Soils By Different Crop Plants", "description": "A pot experiment was conducted in order to assess the effect of the earthworm Eisenia fetida on the uptake of Pb, Zn, Cd and Cu from soils polluted by mining activities using maize (Zea mays) and barley (Hordeum vulgare). Results from single and sequential extractions showed that the soil chemical partitioning of heavy metals was significantly changed by E. fetida, leading to a higher concentration of metals in the non-residual fractions of the soil. Earthworm activities significantly increased shoot biomass (65% for maize and 73% for barley) and root metal concentration for all the metals under study in both maize and barley. The total accumulation rate values for Cd, Cu, Pb and Zn were significantly higher in the presence of E. fetida for both crop plants. Those latter effects led to an increase in Zn extraction yields of up to 3.7-fold and 2.3-fold for barley and maize, respectively.", "keywords": ["2. Zero hunger", "Hordeum", "04 agricultural and veterinary sciences", "Chemical Fractionation", "Plant Roots", "Zea mays", "01 natural sciences", "Mining", "Biodegradation", " Environmental", "13. Climate action", "Metals", " Heavy", "Animals", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Biomass", "Oligochaeta", "Plant Shoots", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2009.01.042"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2009.01.042", "name": "item", "description": "10.1016/j.chemosphere.2009.01.042", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2009.01.042"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-05-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2009.06.053", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2009-08-03", "title": "Impacts Of Woodchip Biochar Additions On Greenhouse Gas Production And Sorption/Degradation Of Two Herbicides In A Minnesota Soil", "description": "A potential abatement to increasing levels of carbon dioxide (CO(2)) in the atmosphere is the use of pyrolysis to convert vegetative biomass into a more stable form of carbon (biochar) that could then be applied to the soil. However, the impacts of pyrolysis biochar on the soil system need to be assessed before initiating large scale biochar applications to agricultural fields. We compared CO(2) respiration, nitrous oxide (N(2)O) production, methane (CH(4)) oxidation and herbicide retention and transformation through laboratory incubations at field capacity in a Minnesota soil (Waukegan silt loam) with and without added biochar. CO(2) originating from the biochar needs to be subtracted from the soil-biochar combination in order to elucidate the impact of biochar on soil respiration. After this correction, biochar amendments reduced CO(2) production for all amendment levels tested (2, 5, 10, 20, 40 and 60% w/w; corresponding to 24-720 tha(-1) field application rates). In addition, biochar additions suppressed N(2)O production at all levels. However, these reductions were only significant at biochar amendment levels >20% w/w. Biochar additions also significantly suppressed ambient CH(4) oxidation at all levels compared to unamended soil. The addition of biochar (5% w/w) to soil increased the sorption of atrazine and acetochlor compared to non-amended soils, resulting in decreased dissipation rates of these herbicides. The recalcitrance of the biochar suggests that it could be a viable carbon sequestration strategy, and might provide substantial net greenhouse gas benefits if the reductions in N(2)O production are lasting.", "keywords": ["Greenhouse Effect", "2. Zero hunger", "Toluidines", "Herbicides", "Minnesota", "Nitrous Oxide", "04 agricultural and veterinary sciences", "Carbon Dioxide", "15. Life on land", "01 natural sciences", "6. Clean water", "12. Responsible consumption", "Soil", "13. Climate action", "Charcoal", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Atrazine", "Adsorption", "Gases", "Methane", "Oxidation-Reduction", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2009.06.053"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2009.06.053", "name": "item", "description": "10.1016/j.chemosphere.2009.06.053", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2009.06.053"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-10-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2009.04.001", "type": "Feature", "geometry": null, "properties": {"license": "Closed Access", "updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2009-05-06", "title": "Reduced Plant Uptake Of Pesticides With Biochar Additions To Soil", "description": "We investigated the effectiveness of two types of biochars in reducing the bioavailability of two soil-applied insecticides (chlorpyrifos and carbofuran) to Spring onion (Allium cepa). The biochars prepared from the pyrolysis of Eucalyptus spp. wood chips at 450 and 850 degrees C (BC850) were thoroughly mixed into the soil to achieve 0%, 0.1%, 0.5% and 1% by soil weight. A spring onion crop was grown for 5 wk in the biochar-amended soils spiked with 50 mgkg(-1) of each pesticide. The loss of both pesticides due to degradation and or sequestration in soils decreased significantly with increasing amounts of biochars in soil. Over 35 d, 86-88% of the pesticides were lost from the control soil, whereas it was only 51% of carbofuran and 44% of chlorpyrifos from the soil amended with 1.0% BC850. Despite greater persistence of the pesticide residues in biochar-amended soils, the plant uptake of pesticides decreased markedly with increasing biochar content of the soil. With 1% of BC850 soil amendment, the total plant residues for chlorpyrifos and carbofuran decreased to 10% and 25% of that in the control treatment, respectively. The BC850 was particularly effective in reducing phytoavailability of both pesticides from soil, due to its high affinity for and ability to sequester pesticide residues.", "keywords": ["2. Zero hunger", "Insecticides", "Pesticide Residues", "Biological Availability", "Water", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "6. Clean water", "Carbofuran", "Soil", "Solubility", "Charcoal", "Onions", "0401 agriculture", " forestry", " and fisheries", "Chlorpyrifos", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2009.04.001"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2009.04.001", "name": "item", "description": "10.1016/j.chemosphere.2009.04.001", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2009.04.001"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-07-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2009.09.070", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2009-10-23", "title": "Cumulative And Residual Effects Of De-Oiled Two-Phase Olive Mill Waste Application To Soil On Diuron Sorption, Leaching, Degradation, And Persistence", "description": "Laboratory and field experiments were conducted to evaluate the influence of de-oiled two-phase olive mill waste (DTPOMW) amendments on the sorption-desorption, degradation, leaching, and persistence of the herbicide diuron in a representative olive grove soil. The soil was amended in the laboratory with DTPOMW at the rates of 5% and 10% (w/w), and in the field with 27 and 54 Mg ha(-1) of DTPOMW for 7 years. Cumulative and residual effects were evaluated in the last year and 2 years after the last DTPOMW field application (2005 and 2007, respectively). The results showed that the adsorption of diuron to the soil significantly increased in the presence of DTPOMW in the laboratory and field-amended soils, and that humic acid content was mainly responsible for this increase. The DTPOMW soil application only significantly increased the half-life of diuron in the laboratory-amended soils, ranging from 8.6d for the original soil to 51 d at the greater application rate. The DTPOMW amendments significantly reduced the downward mobility of diuron, and reduced the amount of herbicide leached in the laboratory and field-amended soils, and no residues of diuron were detected in the leacheate of the residual-amended columns. In the field study, DTPOMW addition increased the persistence of diuron in the upper 10 and 5 cm of the soils in the cumulative and residual years, respectively, decreasing the herbicide's vertical movement through the amended soils with increasing DTPOMW rate. This study has shown that in olive grove soils DTPOMW amendment may be an effective management practice for controlling ground water contamination by diuron.", "keywords": ["2. Zero hunger", "Lixiviaci\u00f3n", "3103", "Herbicides", "04 agricultural and veterinary sciences", "Waste Disposal", " Fluid", "01 natural sciences", "6. Clean water", "Soil", "Diuron", "Residuos de almazara bif\u00e1sicos desaceitados", "Plant Oils", "0401 agriculture", " forestry", " and fisheries", "Adsorption", "De-oiled two-phase olive mill waste", "Olive Oil", "Humic Substances", "Water Pollutants", " Chemical", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2009.09.070"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2009.09.070", "name": "item", "description": "10.1016/j.chemosphere.2009.09.070", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2009.09.070"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2010-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2010.01.009", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2010-01-28", "title": "Agronomic Properties Of Wastewater Sludge Biochar And Bioavailability Of Metals In Production Of Cherry Tomato (Lycopersicon Esculentum)", "description": "This work presents agronomic values of a biochar produced from wastewater sludge through pyrolysis at a temperature of 550 degrees C. In order to investigate and quantify effects of wastewater sludge biochar on soil quality, growth, yield and bioavailability of metals in cherry tomatoes, pot experiments were carried out in a temperature controlled environment and under four different treatments consisting of control soil, soil with biochar; soil with biochar and fertiliser, and soil with fertiliser only. The soil used was chromosol and the applied wastewater sludge biochar was 10tha(-1). The results showed that the application of biochar improves the production of cherry tomatoes by 64% above the control soil conditions. The ability of biochar to increase the yield was attributed to the combined effect of increased nutrient availability (P and N) and improved soil chemical conditions upon amendment. The yield of cherry tomato production was found to be at its maximum when biochar was applied in combination with the fertiliser. Application of biochar was also found to significantly increase the soil electrical conductivity as well as phosphorus and nitrogen contents. Bioavailability of metals present in the biochar was found to be below the Australian maximum permitted concentrations for food.", "keywords": ["Sewage", "Nitrogen", "Biological Availability", "Agriculture", "Phosphorus", "Waste Disposal", " Fluid", "01 natural sciences", "6. Clean water", "Soil", "Solanum lycopersicum", "Metals", "Charcoal", "Fruit", "Fertilizers", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2010.01.009"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2010.01.009", "name": "item", "description": "10.1016/j.chemosphere.2010.01.009", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2010.01.009"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2010-02-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2009.11.015", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2009-12-17", "title": "Selenium Accumulation By Forage And Grain Crops And Volatilization From Seleniferous Soils Amended With Different Organic Materials", "description": "Greenhouse and field experiments were conducted to study the direct and residual effect of applying different organic materials on Se accumulation by crops and volatilization from seleniferous soils of northwestern India. Among organic manures, press mud and poultry manures proved 4-5 times more effective in reducing Se accumulation by different crops than farmyard manure. Efficiency of organic manures increased with increase in application rates. Application of both press mud and poultry manures reduced Se accumulation by 44-97% in wheat (Triticum aestivum) and rapeseed (Brassica napus) shoots in the greenhouse; 85-92% in wheat straw, 45-74% in wheat grains, 45-74% in rapeseed straw and 76-92% in rapeseed grains under field conditions. Both the manures remained highly effective in reducing Se accumulation by the crops following wheat and rapeseed and the extent of reduction varied from 50% to 87% in maize (Zea mays) and cowpeas (Vigna sinensis) in the greenhouse and 40-89% in maize and rice (Oryza sativa) crops under field situation. Rate of Se volatilization by wheat and rapeseed crops increased by 1.8-4.0 times; the greatest increase was observed with press mud followed by poultry manure, arhar (Cajanus cajan) leaves and farmyard manure. After 134d of incubation of 500g soil amended with 2% of plant tissues, the maximum amount of Se was volatilized with cowpea leaves (385ng) followed by wheat grains, leaves of maize, sugarcane (Saccharum officcinarum), arhar, poplar (Populus deltoides) and the control (91ng). The results of this study convincingly prove the usefulness of applying press mud and poultry manure in enhancing volatilization and retarding the transfer of Se from soil to plant in seleniferous soils.", "keywords": ["Crops", " Agricultural", "2. Zero hunger", "04 agricultural and veterinary sciences", "15. Life on land", "Zea mays", "01 natural sciences", "6. Clean water", "Manure", "Plant Leaves", "Selenium", "Seeds", "Animals", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Volatilization", "Plant Shoots", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2009.11.015"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2009.11.015", "name": "item", "description": "10.1016/j.chemosphere.2009.11.015", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2009.11.015"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2010-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2010.06.047", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2010-07-06", "title": "Trace Element Availability In A Sewage Sludge-Amended Cotton Grown Mediterranean Soil", "description": "Long-term field investigations on the use of biosolids are scarce in the Mediterranean region, especially on non-food high-profit crops. Thus we studied the effects of repeated sludge application for 4 yr on trace element (both essential and non-essential) availability to cotton, by applying sludge at four increasing rates up to 50 Mg ha(-1). Although sludge had low metal concentrations, sludge-added trace element availability (assessed with soil-to-plant transfer coefficient) was higher in the first year compared to those in the subsequent years of experiment, but it decreased with time to the value of the unamended control. This shows that trace element mobility can be reduced within a time-scale of a few years, provided soils have a relatively sufficient retention capacity (high CEC, clay, and non-acidic pH) and applied sludge has low heavy metal content. We also found that sludge-borne organic matter greatly affected metal availability, since metal transfer coefficients decreased with elevated organic matter content.", "keywords": ["2. Zero hunger", "Gossypium", "Manganese", "Greece", "Sewage", "Climate", "04 agricultural and veterinary sciences", "01 natural sciences", "6. Clean water", "Trace Elements", "12. Responsible consumption", "Plant Leaves", "Zinc", "Biodegradation", " Environmental", "Lead", "Nickel", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Copper", "Cadmium", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2010.06.047"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2010.06.047", "name": "item", "description": "10.1016/j.chemosphere.2010.06.047", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2010.06.047"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2010-09-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2011.05.052", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:22Z", "type": "Journal Article", "created": "2011-06-26", "title": "Poor Efficacy Of Herbicides In Biochar-Amended Soils As Affected By Their Chemistry And Mode Of Action", "description": "We evaluated wheat straw biochar produced at 450\u00b0C for its ability to influence bioavailability and persistence of two commonly used herbicides (atrazine and trifluralin) with different modes of action (photosynthesis versus root tip mitosis inhibitors) in two contrasting soils. The biochar was added to soils at 0%, 0.5% and 1.0% (w/w) and the herbicides were applied to those soil-biochar mixes at nil, half, full, two times, and four times, the recommended dosage (H(4)). Annual ryegrass (Lolium rigidum) was grown in biochar amended soils for 1 month. Biochar had a positive impact on ryegrass survival rate and above-ground biomass at most of the application rates, and particularly at H(4). Within any given biochar treatment, increasing herbicide application decreased the survival rate and fresh weight of above-ground biomass. Biomass production across the biochar treatment gradient significantly differed (p<0.01) and was more pronounced in the case of atrazine than trifluralin. For example, the dose-response analysis showed that in the presence of 1% biochar in soil, the value of GR(50) (i.e. the dose required to reduce weed biomass by 50%) for atrazine increased by 3.5 times, whereas it increased only by a factor of 1.6 in the case of trifluralin. The combination of the chemical properties and the mode of action governed the extent of biochar-induced reduction in bioavailability of herbicides. The greater biomass of ryegrass in the soil containing the highest biochar (despite having the highest herbicide residues) demonstrates decreased bioavailability of the chemicals caused by the wheat straw biochar. This work clearly demonstrates decreased efficacy of herbicides in biochar amended soils. The role played by herbicide chemistry and mode of action will have major implications in choosing the appropriate application rates for biochar amended soils.", "keywords": ["Carbon sequestration", "2. Zero hunger", "Bioavailability", "Herbicides", "Bound residue", "Weed control", "01 natural sciences", "630", "Gas Chromatography-Mass Spectrometry", "6. Clean water", "Trifluralin", "Persistence", "Biochar", "Soil", "Charcoal", "Lolium", "Atrazine", "Biomass", "Environmental Restoration and Remediation", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2011.05.052"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2011.05.052", "name": "item", "description": "10.1016/j.chemosphere.2011.05.052", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2011.05.052"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2011-09-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2012.05.092", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2012-06-23", "title": "Effects Of Sewage Sludge Biochar On Plant Metal Availability After Application To A Mediterranean Soil", "description": "Pyrolytic conversion of sewage sludge into biochar could be a sustainable management option for Mediterranean agricultural soils. The aim of this work is to evaluate the effects of biochar from sewage sludge pyrolysis on soil properties; heavy metals solubility and bioavailability in a Mediterranean agricultural soil and compared with those of raw sewage sludge. Biochar (B) was prepared by pyrolysis of selected sewage sludge (SL) at 500\u00b0C. The pyrolysis process decreased the plant-available of Cu, Ni, Zn and Pb, the mobile forms of Cu, Ni, Zn, Cd and Pb and also the risk of leaching of Cu, Ni, Zn and Cd. A selected Mediterranean soil was amended with SL and B at two different rates in mass: 4% and 8%. The incubation experiment (200 d) was conducted in order to study carbon mineralization and trace metal solubility and bioavailability of these treatments. Both types of amendments increased soil respiration with respect to the control soil. The increase was lower in the case of B than when SL was directly added. Metals mobility was studied in soil after the incubation and it can be established that the risk of leaching of Cu, Ni and Zn were lower in the soil treated with biochar that in sewage sludge treatment. Biochar amended samples also reduced plant availability of Ni, Zn, Cd and Pb when compared to sewage sludge amended samples.", "keywords": ["Sewage", "Mediterranean Region", "Agriculture", "04 agricultural and veterinary sciences", "Plants", "Risk Assessment", "Waste Disposal", " Fluid", "01 natural sciences", "6. Clean water", "12. Responsible consumption", "Soil", "Metals", "Charcoal", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2012.05.092"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2012.05.092", "name": "item", "description": "10.1016/j.chemosphere.2012.05.092", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2012.05.092"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2012-11-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2013.12.024", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2014-01-04", "title": "Carbon Mineralization In Two Ultisols Amended With Different Sources And Particle Sizes Of Pyrolyzed Biochar", "description": "Biochar produced during pyrolysis has the potential to enhance soil fertility and reduce greenhouse gas emissions. The influence of biochar properties (e.g., particle size) on both short- and long-term carbon (C) mineralization of biochar remains unclear. There is minimal information on the potential effects of biochar particle sizes on their breakdowns by soil microorganism, so it is unknown if the particle size of biochar influences C mineralization rate and/or stability in soils. In order to evaluate the effect of different sources (BS) and particle sizes (BF) of biochar on C loss and/or stability in soils, an incubation study on C mineralization of different biochar sources and particle sizes was established using two soils (ST): Norfolk soil (fine loamy, kaolinitic, thermic, typic Kandiudults) and Coxville soil (fine loamy kaolinitic, thermic, Paleaquults). In separate incubation vessels, these soils were amended with one of two manure-based biochars (poultry litters, PL; swine solids, SS) or one of two lignocellulosic-based biochars (switchgrass, SG; pine chips, PC) which were processed into two particle sizes (dust, <0.42 mm; pellet, >2 mm). The amount of CO2 evolved varied significantly between soils (p\u22640.0001); particle sizes (p\u22640.0001) and the interactions of biochar source (p\u22640.001) and forms of biochars (p\u22640.0001) with soil types. Averaged across soils and sources of biochar, CO2-C evolved from dust-sized biochar (281 mg kg(-1)) was significantly higher than pellet-sized biochar (226 mg kg(-1)). Coxville soils with SS biochar produced the greatest average CO2-C of 428 mg kg(-1) and Norfolk soils with PC had the lowest CO2-C production (93 mg kg(-1)). Measured rates of carbon mineralization also varied with soils and sources of biochar (Norfolk: PL>SS>SG\u2265PC; Coxville: PC>SG>SS>PL). The average net CO2-C evolved from the Coxville soils (385 mg kg(-1)) was about threefold more than the CO2-C evolved from the Norfolk soils (123 mg kg(-1)). Our results suggest different particle sizes and sources of biochar as well as soil type influence biochar stability.", "keywords": ["2. Zero hunger", "Minerals", "Hot Temperature", "Swine", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "Carbon", "Poultry", "6. Clean water", "Manure", "Soil", "13. Climate action", "Charcoal", "11. Sustainability", "Animals", "0401 agriculture", " forestry", " and fisheries", "Particle Size", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2013.12.024"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2013.12.024", "name": "item", "description": "10.1016/j.chemosphere.2013.12.024", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2013.12.024"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2014-05-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2014.06.094", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2014-08-13", "title": "Influence of tetracycline on the microbial community composition and activity of nitrifying biofilms", "description": "The present work aims to evaluate the bacterial composition and activity (carbon and nitrogen removal) of nitrifying biofilms exposed to 50 \u03bcg L(-1) of tetracycline. The tetracycline removal efficiency and the occurrence of tetracycline resistance (tet) genes were also studied. Two sequencing batch biofilm reactors (SBBRs) fed with synthetic wastewater were operated without (SBBR1) and with (SBBR2) the antibiotic. Both SBBRs showed similar organic matter biodegradation and nitrification activity. Tetracycline removal was about 28% and biodegradation was probably the principal removal mechanism of the antibiotic. Polymerase chain reaction-denaturing gradient gel electrophoresis analysis of the bacterial community showed shifts leading to not only the fading of some ribotypes, but also the emergence of new ones in the biofilm with tetracycline. The study of the tet genes showed that tet(S) was only detected in the biofilm with tetracycline, suggesting a relationship between its occurrence and the presence of the antibiotic.", "keywords": ["Science & Technology", "Polymers", "Microbiota", "Molecular Sequence Data", "Tetracycline Resistance", "0211 other engineering and technologies", "Resistance genes", "Sequence Analysis", " DNA", "02 engineering and technology", "Tetracycline", "Nitrification", "01 natural sciences", "6. Clean water", "Anti-Bacterial Agents", "Tetracycline removal", "Nitrifying biofilms", "Bacterial Proteins", "Antibiotics", "Biofilms", "11. Sustainability", "Bacterial community", "Adsorption", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2014.06.094"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2014.06.094", "name": "item", "description": "10.1016/j.chemosphere.2014.06.094", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2014.06.094"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2014-12-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2012.08.042", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2012-09-16", "title": "Role Of Edta In Arsenic Mobilization And Its Uptake By Maize Grown On An As-Polluted Soil", "description": "EDTA amendments are widely used for micronutrient fertilization in arid soils, besides their effectiveness in the remediation process of heavy metal from contaminated soils. However, the persistence of EDTA in arsenic contaminated soil may have further negative effects on the grown plants. To investigate the influences of EDTA on soil As, a pot experiment was conducted using a sandy clay loam As-polluted soil treated with gradual rates of EDTA (0, 1.0, 2.5 and 5 mmol kg(-1)) and planted with maize for two months. The key findings reveal that EDTA applications increased AB-DTPA extractable and water soluble As significantly. Such increases seemed to be the main reasons behind the increase in As uptake by maize plants as the addition of EDTA at the rates of 1.0, 2.5 and 5.0 mmol kg(-1) increased significantly As uptake by shoots 1.5, 2.4 and 3.0 folds, respectively compared to the untreated soil. On the other hand, As uptake by roots did not increase significantly except with the highest application rates of 2.5 and 5.0 mmol kg(-1). The results also show that arsenic translocation factor (TF) values were too low to attain successful phytoextraction. In conclusion, the bioavailable fraction of As is important to investigate the phytoextraction and phytotoxicity of As.", "keywords": ["2. Zero hunger", "04 agricultural and veterinary sciences", "Zea mays", "01 natural sciences", "6. Clean water", "Arsenic", "Soil", "Biodegradation", " Environmental", "13. Climate action", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Edetic Acid", "Environmental Restoration and Remediation", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2012.08.042"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2012.08.042", "name": "item", "description": "10.1016/j.chemosphere.2012.08.042", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2012.08.042"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2013-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2014.06.024", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2014-07-08", "title": "Combining Phytoextraction And Biochar Addition Improves Soil Biochemical Properties In A Soil Contaminated With Cd", "description": "The main goal of phytoremediation is to improve ecosystem functioning. Soil biochemical properties are considered as effective indicators of soil quality and are sensitive to various environmental stresses, including heavy metal contamination. The biochemical response in a soil contaminated with cadmium was tested after several treatments aimed to reduce heavy metal availability including liming, biochar addition and phytoextraction using Amaranthus tricolor L. Two biochars were added to the soil: eucalyptus pyrolysed at 600 \u00b0C (EB) and poultry litter at 400 \u00b0C (PLB). Two liming treatments were chosen with the aim of bringing soil pH to the same values as in the treatments EB and PLB. The properties studied included soil microbial biomass C, soil respiration and the activities of invertase, \u03b2-glucosidase, \u03b2-glucosaminidase, urease and phosphomonoesterase. Both phytoremediation and biochar addition improved soil biochemical properties, although results were enzyme specific. For biochar addition these changes were partly, but not exclusively, mediated by alterations in soil pH. A careful choice of biochar must be undertaken to optimize the remediation process from the point of view of metal phytoextraction and soil biological activity.", "keywords": ["China", "Eucalyptus", "Amaranthus", "Oxides", "04 agricultural and veterinary sciences", "Calcium Compounds", "15. Life on land", "01 natural sciences", "Gas Chromatography-Mass Spectrometry", "Mass Spectrometry", "6. Clean water", "3. Good health", "Soil", "Biodegradation", " Environmental", "Charcoal", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Cadmium", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2014.06.024"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2014.06.024", "name": "item", "description": "10.1016/j.chemosphere.2014.06.024", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2014.06.024"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2015-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2015.04.088", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2015-05-07", "title": "Biochar Helps Enhance Maize Productivity And Reduce Greenhouse Gas Emissions Under Balanced Fertilization In A Rainfed Low Fertility Inceptisol", "description": "Maize production plays an important role in global food security, especially in arid and poor-soil regions. Its production is also increasing in China in terms of both planting area and yield. However, maize productivity in rainfed croplands is constrained by low soil fertility and moisture insufficiency. To increase the maize yield, local farmers use NPK fertilizer. However, the fertilization regime (CF) they practice is unbalanced with too much nitrogen in proportion to both phosphorus and potassium, which has led to low fertilizer use efficiency and excessive greenhouse gases emissions. A two-year field experiment was conducted to assess whether a high yielding but low greenhouse gases emission system could be developed by the combination of balanced fertilization (BF) and biochar amendment in a rainfed farmland located in the Northern region of China. Biochar was applied at rates of 0, 20, and 40 t/ha. Results show that BF and biochar increased maize yield and partial nutrient productivity and decreased nitrous oxide (N2O) emission. Under BF the maize yield was 23.7% greater than under CF. N2O emissions under BF were less than half that under CF due to a reduced N fertilizer application rate. Biochar amendment decreased N2O by more than 31% under CF, while it had no effect on N2O emissions under BF. Thus BF was effective at maintaining a high maize yield and reducing greenhouse gases emissions. If combined with biochar amendment, BF would be a good way of sustaining low carbon agriculture in rainfed areas.", "keywords": ["Greenhouse Effect", "330", "Rain", "Balanced fertilization", "Zea mays", "01 natural sciences", "630", "12. Responsible consumption", "Soil", "11. Sustainability", "Crop yield", "Fertilizers", "0105 earth and related environmental sciences", "2. Zero hunger", "Agriculture", "04 agricultural and veterinary sciences", "15. Life on land", "6. Clean water", "Biochar", "Greenhouse gases", "Fertility", "13. Climate action", "Charcoal", "0401 agriculture", " forestry", " and fisheries", "Gases", "Rainfed agriculture"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2015.04.088"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2015.04.088", "name": "item", "description": "10.1016/j.chemosphere.2015.04.088", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2015.04.088"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2015.07.063", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2015-08-03", "title": "Changes In The Chemical Composition Of An Acidic Soil Treated With Marble Quarry And Marble Cutting Wastes", "description": "Soil acidity greatly affects the availability of plant nutrients. The level of soil acidity can be adjusted by treating the soil with certain additives. The objective of this study was to determine the effect of marble quarry waste (MQW) and marble cutting waste (MCW) on the chemical composition and the acidity of a soil. Marble wastes at different rates were applied to an acid soil. Their effectiveness in neutralizing the soil pH was compared with that of agricultural lime. The changes in the chemical composition of the soil were also evaluated with column test at the end of a 75-day incubation period. The results indicated that the MQW and MCW applications significantly increased the soil pH (from 4.71 up to 6.54), the CaCO3 content (from 0.33% up to 0.75%), and the exchangeable Ca (from 14.79 cmol kg(-1) up to 21.18 cmol kg(-1)) and Na (from 0.57 cmol kg(-1) up to 1.07 cmol kg(-1)) contents, but decreased the exchangeable K (from 0.46 cmol kg(-1) down to 0.28 cmol kg(-1)), the plant-available P (from 25.56 mg L(-1) down to 16.62 mg L(-1)), and the extractable Fe (from 259.43 mg L(-1) down to 55.4 mg L(-1)), Cu (from 1.97 mg L(-1) down to 1.42 mg L(-1)), Mn (from 17.89 mg L(-1) down to 4.61 mg L(-1)) and Zn (from 7.88 mg L(-1) down to 1.56 mg L(-1)) contents. In addition, the Cd (from 0.060 mg L(-1) down to 0.046 mg L(-1)), Ni (from 0.337 mg L(-1) down to 0.092 mg L(-1)) and Pb (from 28.00 mg L(-1) down to 20.08 mg L(-1)) concentrations decreased upon the treatment of the soil with marble wastes.", "keywords": ["Soil", "13. Climate action", "Industrial Waste", "0401 agriculture", " forestry", " and fisheries", "Agriculture", "04 agricultural and veterinary sciences", "Hydrogen-Ion Concentration", "01 natural sciences", "6. Clean water", "Calcium Carbonate", "0105 earth and related environmental sciences"], "contacts": [{"organization": "\u00d6ZTA\u015e, Ta\u015fk\u0131n, AROL, AL\u0130 \u0130HSAN, KALKAN, Ekrem, Tozsin, G\u00fcl\u015fen,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2015.07.063"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2015.07.063", "name": "item", "description": "10.1016/j.chemosphere.2015.07.063", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2015.07.063"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2015-11-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2017.06.060", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2017-06-15", "title": "Effects Of Short-Term Invasion Of Spartina Alterniflora And The Subsequent Restoration Of Native Mangroves On The Soil Organic Carbon, Nitrogen And Phosphorus Stock", "description": "The exotic cordgrass Spartina alterniflora has severely invaded the mangrove wetlands in southern China and ecological restoration using native mangroves was conducted in an attempt to control this invasive species. In this study, the contents and pools of soil organic carbon (SOC), total nitrogen (TN) and total phosphorus (TP) were quantified to investigate the invasive effects of S.\u00a0alterniflora and then to evaluate whether the ecological restoration of native mangrove could reverse those effects. S.\u00a0alterniflora only showed significantly higher organic carbon content in the surface 0-10\u00a0cm of soil than in the uninvaded mudflat. The high \u03b413C values in the surface soil of the invaded habitat demonstrated that S.\u00a0alterniflora contributed 42.6-62.2% of the organic carbon. The SOC for invasive S.\u00a0alterniflora and newly restored mangroves (4 years and 14 years) was not enhanced in comparison to the unvegetated mudflat. S.\u00a0alterniflora significantly increased the surface soil TN content, but decreased the available phosphorus content and TP density. The TN densities increased gradually with the mangrove restoration, while the TP densities were only slightly influenced. The results suggested that short-term invasion of S.\u00a0alterniflora and subsequent mangrove restoration did not alter SOC or TN pool sizes, but S.\u00a0alterniflora was shown to affect the potential carbon storage capacity produced by the mangroves in the Zhangjiang Estuary.", "keywords": ["China", "Nitrogen", "Phosphorus", "15. Life on land", "Poaceae", "01 natural sciences", "Carbon", "6. Clean water", "Soil", "Wetlands", "Estuaries", "Introduced Species", "Ecosystem", "Environmental Restoration and Remediation", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2017.06.060"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2017.06.060", "name": "item", "description": "10.1016/j.chemosphere.2017.06.060", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2017.06.060"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-10-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2019.03.190", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2019-04-01", "title": "Dissolution and aggregation kinetics of zero valent copper nanoparticles in (simulated) natural surface waters: Simultaneous effects of pH, NOM and ionic strength", "description": "The combined effects of pH, dissolved organic carbon (DOC) and Ca2+/Mg2+ on the dissolution and aggregation kinetics of zero valent copper engineered nanoparticles (Cu0 ENPs) were investigated. The dissolution and aggregation of the particles were studied in (a) synthetic aqueous media, similar in chemistry to natural surface waters, and (b) natural surface waters samples, for up to 32 or 24\u202fh. The DOC stabilized the particles and prevented aggregation, and thus increased the available surface area. The higher available surface area in turn accelerated the dissolution of the particles. The presence of Ca2+/Mg2+, however, changed the aggregation and the dissolution of the DOC-stabilized particles. The influence of Ca2+/Mg2+ on DOC-stabilized particles was different at different pH's. In the absence of DOC, 10\u202fmM of Ca2+/Mg2+ induced charge reversal on the particles and caused particle stability against aggregation. This subsequently increased particles dissolution. The results obtained with regard to dissolution and aggregation of the particles in natural surface waters were compared with those determined for the synthetic waters. This comparison showed that the behavior of the particles in the natural surface waters was mostly similar to the behavior determined for media at pH 9. Overall, the current study provides some novel insights into the simultaneous effects of physicochemical parameters of water on particle stability against aggregation and dissolution, and provides data about how the processes of aggregation and dissolution of Cu0 ENPs interact and jointly determine the overall particle fate.", "keywords": ["Cations", " Divalent", "Environmental fate", "Osmolar Concentration", "0211 other engineering and technologies", "Metal Nanoparticles", "Fresh Water", "02 engineering and technology", "Hydrogen-Ion Concentration", "01 natural sciences", "Physico-chemical parameters", "6. Clean water", "Aggregation", "Kinetics", "Solubility", "Aggregation; Complexation; Copper nanoparticles; Dissolution; Environmental fate; Natural water; Physico-chemical parameters", "Complexation", "Natural water", "Calcium", "Magnesium", "Copper nanoparticles", "Organic Chemicals", "Dissolution", "Copper", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2019.03.190"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2019.03.190", "name": "item", "description": "10.1016/j.chemosphere.2019.03.190", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2019.03.190"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-07-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2022.136146", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2022-08-26", "title": "Phytoextraction of Cu, Cd, Zn and As in four shrubs and trees growing on soil contaminated with mining waste", "description": "Mining activity has degraded large extensions of soil and its waste is composed of metals, anthropogenic chemicals, and sterile rocks. The use of native species in the recovery of polluted soils improves the conditions for the emergence of other species, tending to a process of ecosystem restoration. The objective of this study was to evaluate the bioaccumulation of metal(loid)s in four species of native plants and the effect of their distribution and bioavailability in soil with waste from an abandoned gold mine. Soil samples were taken from two sites in La Planta, San Juan, Argentina: Site 1 and Site 2 (mining waste and reference soil, respectively). In Site 1, vegetative organ samples were taken from Larrea cuneifolia, Bulnesia retama, Plectrocarpa tetracantha, and Prosopis flexuosa. The concentration of metal(loid)s in soil from Site 1 were Zn\u00a0>\u00a0As\u00a0>\u00a0Cu\u00a0>\u00a0Cd, reaching values of 7123, 6516, 240 and 76\u00a0mg\u00a0kg-1, respectively. The contamination indices were among the highest categories of contamination for all four metal(loid)s. The spatial interpolation analysis showed the effect of the vegetation as the lowest concentration of metal(loid)s were found in rhizospheric soil. The maximum concentrations of As, Cu, Cd and Zn found in vegetative organs were 371, 461, 28, and 1331\u00a0mg\u00a0kg-1, respectively. L. cuneifolia and B. retama presented high concentrations of Cu and Zn. The most concentrated metal(loid)s in P. tetracantha and P. flexuosa were Zn, As and Cu. Cd was the least concentrated metal in all four species. The values of BAF and TF were greater than one for all four species. In conclusion, the different phytoextraction capacities and the adaptations to arid environments of these four species are an advantage for future phytoremediation strategies. Their application contributes to the ecological restoration and risk reduction, allowing the recovery of ecosystem services.", "keywords": ["Biodisponibilidad", "Bioavailability", "BIOAVAILABILITY", "Soil pollution", "01 natural sciences", "Mining", "Trees", "Bioacumulaci\u00f3n", "SOIL POLLUTION", "Soil", "https://purl.org/becyt/ford/1.5", "Metals", " Heavy", "Poluci\u00f3n del Suelo", "Metales", "Soil Pollutants", "https://purl.org/becyt/ford/1", "Ecosystem", "0105 earth and related environmental sciences", "2. Zero hunger", "Metal", "Abandoned mine", "ABANDONED MINE", "PHYTOREMEDIATION", "BIOACCUMULATION", "15. Life on land", "Bioaccumulation", "6. Clean water", "Phytoremediation", "Zinc", "Biodegradation", " Environmental", "Metals", "13. Climate action", "METAL", "Miner\u00eda", "Fitodecontaminaci\u00f3n", "Gold", "Soil Pollution", "Cadmium", "Environmental Monitoring"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2022.136146"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2022.136146", "name": "item", "description": "10.1016/j.chemosphere.2022.136146", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2022.136146"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-12-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2017.07.035", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2017-07-08", "title": "Assessment and prediction of joint algal toxicity of binary mixtures of graphene and ionic liquids", "description": "Graphene and ionic liquids (ILs) released into the environment will interact with each other. So far however, the risks associated with the concurrent exposure of biota to graphene and ILs in the environment have received little attention. The research reported here focused on observing and predicting the joint toxicity effects in the green alga Scenedesmus obliquus exposed to binary mixtures of intrinsic graphene (iG)/graphene oxide (GO) and five ILs of varying anionic and cationic types. The isolated ILs in the binary mixtures were the main contributors to toxicity. The binary GO-IL mixtures resulted in more severe joint toxicity than the binary iG-IL mixtures, irrespective of mixture ratios. The mechanism of the joint toxicity may be associated with the adsorption capability of the graphenes for the ILs, the dispersion stability of the graphenes in aquatic media, and modulation of the binary mixtures-induced oxidative stress. A toxic unit assessment showed that the graphene and IL toxicities were additive at low concentration of the mixtures but antagonistic at high concentration of the mixtures. Predictions made using the concentration addition and independent action models were close to the observed joint toxicities regardless of mixture types and mixture ratios. These findings provide new insights that are of use in the risk assessment of mixtures of engineered nanoparticles and other environmentally relevant contaminants.", "keywords": ["Anions", "Chlorophyta", "13. Climate action", "Toxicity Tests", "Ionic Liquids", "Graphite", "02 engineering and technology", "Organic Chemicals", "0210 nano-technology", "01 natural sciences", "Water Pollutants", " Chemical", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2017.07.035"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2017.07.035", "name": "item", "description": "10.1016/j.chemosphere.2017.07.035", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2017.07.035"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-10-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2018.01.019", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2018-01-08", "title": "Toxicokinetics of Zn and Cd in the earthworm Eisenia andrei exposed to metal-contaminated soils under different combinations of air temperature and soil moisture content", "description": "This study evaluated how different combinations of air temperature (20\u202f\u00b0C and 25\u202f\u00b0C) and soil moisture content (50% and 30% of the soil water holding capacity, WHC), reflecting realistic climate change scenarios, affect the bioaccumulation kinetics of Zn and Cd in the earthworm Eisenia andrei. Earthworms were exposed for 21\u202fd to two metal-contaminated soils (uptake phase), followed by 21\u202fd incubation in non-contaminated soil (elimination phase). Body Zn and Cd concentrations were checked in time and metal uptake (k1) and elimination (k2) rate constants determined; metal bioaccumulation factor (BAF) was calculated as k1/k2. Earthworms showed extremely fast uptake and elimination of Zn, regardless of the exposure level. Climate conditions had no major impacts on the bioaccumulation kinetics of Zn, although a tendency towards lower k1 and k2 values was observed at 25\u00a0\u00b0C\u00a0+\u00a030% WHC. Earthworm Cd concentrations gradually increased with time upon exposure to metal-contaminated soils, especially at 50% WHC, and remained constant or slowly decreased following transfer to non-contaminated soil. Different combinations of air temperature and soil moisture content changed the bioaccumulation kinetics of Cd, leading to higher k1 and k2 values for earthworms incubated at 25\u00a0\u00b0C\u00a0+\u00a050% WHC and slower Cd kinetics at 25\u00a0\u00b0C\u00a0+\u00a030% WHC. This resulted in greater BAFs for Cd at warmer and drier environments which could imply higher toxicity risks but also of transfer of Cd within the food chain under the current global warming perspective.", "keywords": ["Soil invertebrates", "Bioavailability", "Climate Change", "0211 other engineering and technologies", "02 engineering and technology", "Global Warming", "01 natural sciences", "Soil", "Metals", " Heavy", "SDG 13 - Climate Action", "Climate change", "Animals", "Soil Pollutants", "Oligochaeta", "0105 earth and related environmental sciences", "2. Zero hunger", "Triazines", "Temperature", "Water", "Bioaccumulation", "Mining wastes", "Toxicokinetics", "Zinc", "Heavy metals", "Metals", "13. Climate action", "Environmental Pollution", "Cadmium"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2018.01.019"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2018.01.019", "name": "item", "description": "10.1016/j.chemosphere.2018.01.019", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2018.01.019"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-04-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2019.02.158", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2019-02-25", "title": "Bioreduction of selenate in an anaerobic biotrickling filter using methanol as electron donor", "description": "The anaerobic bioreduction of selenate, fed in step (up to 60\u202fmg.L-1) or continuous (\u223c7\u202fmg.L-1) trickling mode, in the presence of gas-phase methanol (4.3-50\u202fg\u202fm-3.h-1) was evaluated in a biotrickling filter (BTF). During the 48\u202fd of step-feed and 41\u202fd of continuous-feed operations, average selenate removal efficiencies (RE)\u202f>\u202f90% and \u223c68% was achieved, corresponding to a selenate reduction rate of, respectively, 7.3 and 4.5\u202fmg.L-1.d-1. During the entire period of BTF operation, 65.6% of the total Se fed as SeO42- was recovered. Concerning gas-phase methanol, the maximum elimination capacity (ECmax) was 46.4\u202fg\u202fm-3.h-1, with a RE\u202f>\u202f80%. Methanol was mainly utilized for acetogenesis and converted to volatile fatty acids (VFA) in the liquid-phase. Up to 5000\u202fmg.L-1 of methanol and 800\u202fmg.L-1 of acetate accumulated in the trickling liquid of the BTF.", "keywords": ["Bacteria", "Sewage", "Methanol", "0211 other engineering and technologies", "02 engineering and technology", "Selenic Acid", "Fatty Acids", " Volatile", "Archaea", "01 natural sciences", "6. Clean water", "Biodegradation", " Environmental", "Bioreactors", "Oxidation-Reduction", "Filtration", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2019.02.158"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2019.02.158", "name": "item", "description": "10.1016/j.chemosphere.2019.02.158", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2019.02.158"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-06-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2020.128102", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2020-09-12", "title": "Effect of high hydrostatic pressure-assisted pectinase modification on the Pb2+ adsorption capacity of pectin isolated from sweet potato residue", "description": "Novel pectin derived from sweet potato residue was modified by high hydrostatic pressure (HHP)-assisted pectinase and then used for Pb2+ removal from aqueous solutions. The removal characteristics and mechanisms were also investigated. Results showed that modified sweet potato pectin exhibited greater adsorption performances for Pb2+ than that of natural ones, and showed excellent eco-friendly properties and good potential for adsorption of some other heavy metals (such as Cu2+). The adsorption curves were much more conformed to Langmuir model, and the highest capacity for Pb2+ adsorption was 263.15\u00a0mg/g with 1.00% pectin at pH 7. Chemical adsorption process of pectin for Pb2+ absorption involved O-containing functional groups (O-H, COO-), cation exchange, and along with electrostatic interactions. Overall, the results in this study indicated that sweet potato pectin modified with HHP-assisted pectinase had the potential to become an environmentally friendly coagulant-flocculant agent for the heavy metal adsorption, especially for Pb2+.", "keywords": ["02 engineering and technology", "Hydrogen-Ion Concentration", "Wastewater", "01 natural sciences", "Water Purification", "Kinetics", "Polygalacturonase", "Lead", "Hydrostatic Pressure", "Pectins", "Adsorption", "Ipomoea batatas", "0210 nano-technology", "Water Pollutants", " Chemical", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Mudugamuwa Arachchige, Melani Purnika, Mu, Taihua, Ma, Mengmei,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2020.128102"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2020.128102", "name": "item", "description": "10.1016/j.chemosphere.2020.128102", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2020.128102"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2022.137472", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:23Z", "type": "Journal Article", "created": "2022-12-07", "title": "Assembled mixed co-cultures for emerging pollutant removal using native microorganisms from sewage sludge", "description": "The global pharmaceutical pollution caused by drug consumption (>100,000 tonnes) and its disposal into the environment is an issue which is currently being addressed by bioremediation techniques, using single or multiple microorganisms. Nevertheless, the low efficiency and the selection of non-compatible species interfere with the success of this methodology. This paper proposes a novel way of obtaining an effective multi-domain co-culture, with the capacity to degrade multi-pharmaceutical compounds simultaneously. To this end, seven microorganisms (fungi and bacteria) previously isolated from sewage sludge were investigated to enhance their degradation performance. All seven strains were factorially mixed and used to assemble different artificial co-cultures. Consequently, 127 artificial co-cultures were established and ranked, based on their fitness performance, by using the BSocial analysis web tool. The individual strains were categorized according to their social behaviour, whose net effect over the remaining strains was defined as 'Positive', 'Negative' or 'Neutral'. To evaluate the emerging-pollutant degradation rate, the best 10 co-cultures, and those which contained the social strains were then challenged with three different Pharmaceutical Active compounds (PhACs): diclofenac, carbamazepine and ketoprofen. The co-cultures with the fungi Penicillium oxalicum XD-3.1 and Penicillium rastrickii were able to degrade PhACs. However, the highest performance (>80% degradation) was obtained by the minimal active microbial consortia consisting of both Penicillium spp., Cladosporium cladosporoides and co-existing bacteria. These consortia transformed the PhACs to derivate molecules through hydroxylation and were released to the media, resulting in a low ecotoxicity effect. High-throughput screening of co-cultures provides a quick, reliable and efficient method to narrow down suitable degradation co-cultures for emerging PhAC contaminants while avoiding toxic metabolic derivatives.", "keywords": ["Sewage", "Bacteria", "Fungi", "HTGrowth", "Waste Disposal", " Fluid", "01 natural sciences", "Coculture Techniques", "6. Clean water", "12. Responsible consumption", "Biodegradation", " Environmental", "Pharmaceutical Preparations", "13. Climate action", "Environmental Pollutants", "BSocial", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2022.137472"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2022.137472", "name": "item", "description": "10.1016/j.chemosphere.2022.137472", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2022.137472"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-02-01T00:00:00Z"}}, {"id": "10.1016/j.chnaes.2017.02.007", "type": "Feature", "geometry": null, "properties": {"license": "Closed Access", "updated": "2026-04-03T16:16:24Z", "type": "Journal Article", "created": "2017-07-11", "title": "Effects Of Simulated Climate Change On Soil Microbial Biomass And Enzyme Activities In Young Chinese Fir ( Cunninghamia Lanceolata ) In Subtropical China", "description": "Global warming and nitrogen deposition have been responsible for numerous environmental disturbances, and have attracted much attention from researchers, government agencies and international community. Recent studies indicate that the trend of global warming and nitrogen deposition will continue over the next few decades. These changes not only affect the growth of aboveground vegetation, but also change the belowground soil environment, and thus directly or indirectly affect the microbial process. The microbial biomass and soil enzymes play significant roles in terrestrial environments, particularly through the decomposition of soil organic matter, dynamic fluctuation between carbon sink and source, and the transformation of soil nutrient. However, little is known about that how global warming and nitrogen deposition will affect the soil microbial and soil enzymes in the subtropical zone.    In the present study, we aim to evaluate the responses of the microbial biomass and soil enzyme activity to short-term simulated warming and nitrogen deposition in young Chinese fir (Cunninghamia lanceolata) in Sanming Fujian province in subtropical China. The results showed that soil warming increased microbial biomass carbon content and improved the activity of acid phosphatase and lignin enzymes significantly (P < 0.05). Additionally, microbial biomass carbon content was significantly higher than that of the control after the application of nitrogen fertilizer. Besides, nitrogen addition also significantly raised the C/N ratio of microbial biomass. It also reduced the activity of lignin and cellulose hydrolysis. The combination of warming and nitrogen treatment was more effective than individual warming and nitrogen treatments, increasing the content of soil microbial biomass carbon and nitrogen, decreasing the activity of lignin hydrolytic enzymes and chitinase, and leading to further acidification of the soil. Redundancy analysis (RDA) showed that moisture and pH are the major determinants of soil enzyme activity at the 0\u201310 cm depth. However, at the 10\u201320 cm depth, the major determiner is microbial biomass. In summary, the simulated warming and nitrogen deposition affected soil microbial biomass and enzyme activity significantly in the short-term, and the interaction of the two factors was significant. That suggests that the climate change could have a profound effect on soil microbial processes. Therefore, the effects of simulated warming and nitrogen deposition on microbial biomass and soil enzyme activity and the mechanism of their interaction with soil, microorganisms and plants need to be studied further, in order to reveal the responses and feedback mechanisms of Chinese fir plantations to global climate change in subtropical China.", "keywords": ["0301 basic medicine", "0303 health sciences", "03 medical and health sciences", "13. Climate action", "15. Life on land", "6. Clean water"]}, "links": [{"href": "https://doi.org/10.1016/j.chnaes.2017.02.007"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Acta%20Ecologica%20Sinica", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chnaes.2017.02.007", "name": "item", "description": "10.1016/j.chnaes.2017.02.007", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chnaes.2017.02.007"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-08-01T00:00:00Z"}}, {"id": "10.1016/j.cofs.2020.11.012", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:24Z", "type": "Journal Article", "created": "2020-12-09", "title": "Environmental microbiome mapping as a strategy to improve quality and safety in the food industry", "description": "In food industries, an environmentally-adapted microbiome can colonize the surfaces of equipment and tools and be transferred to the food product or intermediates of production. These complex microbial consortia may include microbial spoilers, pathogens, as well as beneficial microbes.  Advances in sequencing technologies and metagenomics provide the opportunity to map the environmental microbiome in food industries at an unprecedented depth, highlighting the importance of the resident microbial communities in influencing food quality and safety, as well as the main factors shaping its composition and activities. However, specific technical issues must be considered. Although microbiome mapping in the food industry has the potential to revolutionize food safety and quality management systems, its application as routine practice is still challenging and technical issues limit the exploitation of the powerful information that can be obtained by the application of such state-of-the-art approaches.", "keywords": ["Aurora Universities Network", "0301 basic medicine", "2. Zero hunger", "0303 health sciences", "EC", "food industry", "H2020", "food quality", "Applied Microbiology and Biotechnology", "Horizon 2020 Framework Programme", "Innovation action", "food safety", "03 medical and health sciences", "contamination", "13. Climate action", "Metagenomics", "European Commission", "Knowmad Institut", "environmental microbiome", "Food Science"]}, "links": [{"href": "https://www.iris.unina.it/bitstream/11588/828326/1/COFS%2c2021_EnvMapping.pdf"}, {"href": "https://doi.org/10.1016/j.cofs.2020.11.012"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Current%20Opinion%20in%20Food%20Science", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.cofs.2020.11.012", "name": "item", "description": "10.1016/j.cofs.2020.11.012", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.cofs.2020.11.012"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-04-01T00:00:00Z"}}, {"id": "10.1016/j.coisb.2021.100379", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:24Z", "type": "Journal Article", "created": "2021-09-09", "title": "Approaches for completing metabolic networks through metabolite damage and repair discovery", "description": "Metabolites are prone to damage, either via enzymatic side reactions, which collectively form the underground metabolism, or via spontaneous chemical reactions. The resulting non-canonical metabolites that can be toxic, are mended by dedicated 'metabolite repair enzymes.' Deficiencies in the latter can cause severe disease in humans, whereas inclusion of repair enzymes in metabolically engineered systems can improve the production yield of value-added chemicals. The metabolite damage and repair loops are typically not yet included in metabolic reconstructions and it is likely that many remain to be discovered. Here, we review strategies and associated challenges for unveiling non-canonical metabolites and metabolite repair enzymes, including systematic approaches based on high-resolution mass spectrometry, metabolome-wide side-activity prediction, as well as high-throughput substrate and phenotypic screens.", "keywords": ["0301 basic medicine", "0303 health sciences", "03 medical and health sciences", ": Biochemistry", " biophysics & molecular biology [F05] [Life sciences]", ": Biochimie", " biophysique & biologie mol\u00e9culaire [F05] [Sciences du vivant]", "Article"]}, "links": [{"href": "https://doi.org/10.1016/j.coisb.2021.100379"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Current%20Opinion%20in%20Systems%20Biology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.coisb.2021.100379", "name": "item", "description": "10.1016/j.coisb.2021.100379", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.coisb.2021.100379"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-12-01T00:00:00Z"}}, {"id": "10.1016/j.colsurfa.2018.05.091", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:24Z", "type": "Journal Article", "created": "2018-05-30", "title": "Protein affinity for TiO2 and CeO2 manufactured nanoparticles. From ultra-pure water to biological media", "description": "Abstract   In this study, we investigated the Bovine Serum Albumin (BSA) protein affinity for manufactured metal oxide nanoparticles (NPs), respectively TiO2 and CeO2. Changes in the NPs surface charge property and resulting stability were investigated by considering pH-dependent electrostatic scenarios and contrasting solution conditions from ultra-pure water to more complex biological mixtures regarding the ionic and protein composition. After careful characterization of NPs and BSA as a function of pH, we used variable BSA concentrations to study the impact of BSA adsorption and we found that protein affinity for NPs was largely controlled by electrostatic interactions. We demonstrated that in ultra-pure water increasing gradually the BSA concentration results in aggregation when BSA and NPs charges are opposite (charge neutralization). On the other hand, when NPs were added in a solution containing BSA, aggregation was prevented due to corona formation. Then, the ultrapure water was replaced by Dulbecco\u2019s phosphate-buffered saline (DPBS) to mimic the blood composition and ionic strength. BSA was then replaced by fetal calf serum (FCS) to mimic the great variety of proteins and other biomolecules found in the blood. Our findings indicate that, in all cases, initially dispersed TiO2 or CeO2 NPs are stabilized by the presence of proteins and that protein adsorption is fast regarding NPs homoaggregation. Proteins are found to improve NPs dispersion even at high ionic strength with overarching consequences on the fate, transport and related risk of NPs in living systems.", "keywords": ["Aggregation", "info:eu-repo/classification/ddc/550", "TiO2 and CeO2", "ddc:550", "0211 other engineering and technologies", "Nanoparticles", "Protein adsorption", "02 engineering and technology", "01 natural sciences", "Protein affinity", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.colsurfa.2018.05.091"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Colloids%20and%20Surfaces%20A%3A%20Physicochemical%20and%20Engineering%20Aspects", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.colsurfa.2018.05.091", "name": "item", "description": "10.1016/j.colsurfa.2018.05.091", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.colsurfa.2018.05.091"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-09-01T00:00:00Z"}}, {"id": "10.1016/j.combustflame.2019.07.046", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:24Z", "type": "Journal Article", "created": "2019-08-21", "title": "Experimental study of moisture content effects on the transient gas and particle emissions from peat fires", "description": "Abstract   Peat fires are a global-scale source of carbon emissions and a leading cause of regional air quality deterioration, especially in Southeast Asia. The ignition and spread of peat fires are strongly affected by moisture, which acts as an energy sink. However, moisture effects on peat fire emissions are poorly understood in the literature. Here we present the first experimental work to investigate transient gas and particle emissions for a wide range of peat moisture contents (MCs). We include drying, ignition, smouldering spread, and even flaming stages. Peat samples conditioned to different MCs were burnt in the laboratory where a suite of diagnostics simultaneously measured mass loss rate, temperature profiles, real-time concentration of 20 gas species, and size-fractioned particle mass. It was found that MC affects emissions, in addition to peat burning dynamics. An increase in MC below a smouldering threshold of 160% in dry basis leads to a decrease in NH3 and greenhouse gas emissions, including CO2 and CH4. The burning of wet peat emits more coarse particles (between 1 and 10\u00a0\u00b5m) than dry peat, especially during the ignition stage. In contrast, flaming stage emits mostly soot particles less than 1\u00a0\u00b5m, and releases 100% more fully oxidised gas species including CO2, NO2 and SO2 than smouldering. The examination of the resulting modified combustion efficiency (MCE) reveals that it fails to recongnise smouldering combustion with sufficient accuracy, especially for wet peat with MC\u00a0>\u00a0120%. MCE confuses drying and flaming, and has significant variations during the ignition stage. As a result, MCE is not valid as a universal fire mode indicator used in the field. This work fills the knowledge gap between moisture and emissions, and provides a better understanding which can help mitigate peat fires.", "keywords": ["Energy", "biomass", "0904 Chemical Engineering", "02 engineering and technology", "624", "Wildfire", "15. Life on land", "0902 Automotive Engineering", "01 natural sciences", "13. Climate action", "moisture", "11. Sustainability", "pollution", "0204 chemical engineering", "fire", "0913 Mechanical Engineering", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.combustflame.2019.07.046"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Combustion%20and%20Flame", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.combustflame.2019.07.046", "name": "item", "description": "10.1016/j.combustflame.2019.07.046", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.combustflame.2019.07.046"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-11-01T00:00:00Z"}}, {"id": "10.1016/j.combustflame.2020.06.039", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:24Z", "type": "Journal Article", "created": "2020-07-19", "title": "Spatially resolved horizontal spread in smouldering peat combining infrared and visual diagnostics", "description": "Abstract   Smouldering wildfires in peatlands can last for weeks, resulting in the release of large amount of soil carbon and harmful emissions with detrimental effects on human health and the environment. Despite their importance, smouldering fires are poorly understood. An experimental study was carried out here to measure the spread rate of peat fire in detail, using infrared (IR) imaging. Peat samples with different moisture contents were prepared and burned in an open reactor of 20\u00a0\u00d7\u00a020\u00a0cm2 cross section and 10\u00a0cm depth, under laboratory-controlled conditions. In total, twelve experiments were studied, each lasting for 8\u00a0h on average. Infrared and visual cameras were synchronised, and images were acquired at a frequency of 1/min, for the duration of the experiment. Profiles of smouldering spread on the free surface of peat were tracked using an image intensity threshold and then used to calculate the horizontal spread rate. Temporally and spatially resolved spread rates are presented and analysed. Increasing the moisture content of the peat resulted in a decrease in spread rate and the smouldering front became increasingly irregular. At high moisture contents, spread at the lower layers of peat is faster compared to top surfaces which leads to formation of overhang, and IR is able to measure the formation of the overhang and its collapse as a step increase in horizontal spread. The overhang becomes more prominent when moisture content is increased. The new tool allows the study of unprecedented details in the spread of peat fires and can be adopted in future experimental studies.", "keywords": ["Energy", "550", "13. Climate action", "0904 Chemical Engineering", "02 engineering and technology", "0204 chemical engineering", "15. Life on land", "0902 Automotive Engineering", "01 natural sciences", "630", "0913 Mechanical Engineering", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Amin, HMF, Hu, Y, Rein, G,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.combustflame.2020.06.039"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Combustion%20and%20Flame", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.combustflame.2020.06.039", "name": "item", "description": "10.1016/j.combustflame.2020.06.039", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.combustflame.2020.06.039"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-10-01T00:00:00Z"}}, {"id": "10.1016/j.compgeo.2019.04.013", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-04-03T16:16:24Z", "type": "Journal Article", "created": "2019-05-21", "title": "Numerical simulations of triaxial compression tests of cemented sandstone", "description": "Abstract   Three-dimensional DEM simulations of triaxial compression tests of cemented sandstone samples have been performed at different values of confining pressure, initial density and bond strength. The results show that with increase in bond strength, initial density and confining pressure both the initial stiffness and peak strength increase. For a higher bond strength and initial density the samples exhibit a higher rate of dilation. Bond breakage was found to increase with confining pressure and decrease with bond strength and initial density. The Mohr-Coulomb strength parameters c' and \u03c6' were obtained for the numerical samples and correlations between the shear strength parameters and the bond strength were established. The correlations were then used to find the value of the bond strength to be used for comparisons with results of experimental triaxial tests. The stress-strain responses of the numerical samples were found to be in good agreement with the experimental results. The critical state lines (CSL) of triaxial compression tests for both loose and medium dense systems show that the critical void ratio is independent of the initial density but increases with increase in bond strength. Increasing the bond strength increases the dilation, which leads to a\u00a0higher\u00a0critical\u00a0state\u00a0void\u00a0ratio.", "keywords": ["0211 other engineering and technologies", "02 engineering and technology", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.compgeo.2019.04.013"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Computers%20and%20Geotechnics", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.compgeo.2019.04.013", "name": "item", "description": "10.1016/j.compgeo.2019.04.013", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.compgeo.2019.04.013"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-09-01T00:00:00Z"}}, {"id": "10.1016/j.compgeo.2019.103200", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:24Z", "type": "Journal Article", "created": "2019-08-18", "title": "Non-orthogonal elastoplastic constitutive model with the critical state for clay", "description": "<p>A non-orthogonal elastoplastic model for clay is proposed by combining the non-orthogonal plastic flow rule with the critical state concept, and the model framework is presented from the perspective of the magnitude and direction of the plastic strain increment. The magnitude is obtained based on the improved elliptical yield function and the plastic volumetric strain dependent hardening parameter. The direction is determined by ap-plying the non-orthogonal plastic flow rule with the Riemann-Liouville fractional derivative to the yield function without the necessity of additional plastic potential function. The presented approach gives rise to a simple model for soil with five parameters. All parameters have clear physical meaning and can be easily identified by triaxial tests. The model performance is shown by analyzing the evolution process of the yield surface, the hardening rule and the plastic flow direction. The capability of the proposed model to capture the mechanical behaviours of clay with different stiffness is also confirmed by predicting test results from the literature.</p>", "keywords": ["Civil and Environmental Engineering", "bepress|Engineering", "0211 other engineering and technologies", "Aerospace Engineering", "bepress|Engineering|Aerospace Engineering", "02 engineering and technology", "Geotechnical Engineering", "01 natural sciences", "engrXiv|Engineering|Aerospace Engineering", "Engineering", "engrXiv|Engineering", "bepress|Engineering|Civil and Environmental Engineering", "engrXiv|Engineering|Civil and Environmental Engineering|Geotechnical Engineering", "engrXiv|Engineering|Civil and Environmental Engineering", "bepress|Engineering|Civil and Environmental Engineering|Geotechnical Engineering", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.compgeo.2019.103200"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Computers%20and%20Geotechnics", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.compgeo.2019.103200", "name": "item", "description": "10.1016/j.compgeo.2019.103200", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.compgeo.2019.103200"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-12-01T00:00:00Z"}}, {"id": "10.1016/j.compgeo.2020.103486", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:16:25Z", "type": "Journal Article", "created": "2021-03-11", "title": "Extension of a basic hypoplastic model for overconsolidated clays", "description": "<p>This paper presents a new rate-dependent hypoplastic constitutive model for overconsolidated clays. The model is developed based on a basic hypoplastic model proposed recently for sand. New density and stiffness factors are introduced to account for history dependence. The Matsuoka-Nakai failure surface is incorporated for the limit stress criterion. With six constitutive parameters, the model is capable of predicting the hardening/softening, shear dilation/contraction, and asymptotic state for overconsolidated clays. Comparison between numerical predictions and experimental results shows this model can properly describe the main features of both reconstituted and undisturbed clays with different overconsolidation ratios.</p>", "keywords": ["Civil and Environmental Engineering", "Engineering", "engrXiv|Engineering", "bepress|Engineering|Civil and Environmental Engineering", "bepress|Engineering", "engrXiv|Engineering|Civil and Environmental Engineering|Geotechnical Engineering", "engrXiv|Engineering|Civil and Environmental Engineering", "0211 other engineering and technologies", "02 engineering and technology", "Geotechnical Engineering", "bepress|Engineering|Civil and Environmental Engineering|Geotechnical Engineering", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.compgeo.2020.103486"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Computers%20and%20Geotechnics", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.compgeo.2020.103486", "name": "item", "description": "10.1016/j.compgeo.2020.103486", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.compgeo.2020.103486"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-07-01T00:00:00Z"}}, {"id": "10.1029/2020gb006672", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-03T16:18:30Z", "type": "Journal Article", "created": "2020-09-02", "title": "Assessing the Potential for Mobilization of Old Soil Carbon After Permafrost Thaw: A Synthesis of 14C Measurements From the Northern Permafrost Region", "description": "Abstract<p>The magnitude of future emissions of greenhouse gases from the northern permafrost region depends crucially on the mineralization of soil organic carbon (SOC) that has accumulated over millennia in these perennially frozen soils. Many recent studies have used radiocarbon (14C) to quantify the release of this \uffe2\uff80\uff9cold\uffe2\uff80\uff9d SOC as CO2 or CH4 to the atmosphere or as dissolved and particulate organic carbon (DOC and POC) to surface waters. We compiled ~1,900 14C measurements from 51 sites in the northern permafrost region to assess the vulnerability of thawing SOC in tundra, forest, peatland, lake, and river ecosystems. We found that growing season soil 14C\uffe2\uff80\uff90CO2 emissions generally had a modern (post\uffe2\uff80\uff901950s) signature, but that well\uffe2\uff80\uff90drained, oxic soils had increased CO2 emissions derived from older sources following recent thaw. The age of CO2 and CH4 emitted from lakes depended primarily on the age and quantity of SOC in sediments and on the mode of emission, and indicated substantial losses of previously frozen SOC from actively expanding thermokarst lakes. Increased fluvial export of aged DOC and POC occurred from sites where permafrost thaw caused soil thermal erosion. There was limited evidence supporting release of previously frozen SOC as CO2, CH4, and DOC from thawing peatlands with anoxic soils. This synthesis thus suggests widespread but not universal release of permafrost SOC following thaw. We show that different definitions of \uffe2\uff80\uff9cold\uffe2\uff80\uff9d sources among studies hamper the comparison of vulnerability of permafrost SOC across ecosystems and disturbances. We also highlight opportunities for future 14C studies in the permafrost region.</p", "keywords": ["particulate organic carbon", "[SDE] Environmental Sciences", "0301 basic medicine", "551.9", "550", "permafrost thaw", "methane", "500", "carbon dioxide", "15. Life on land", "551", "dissolved organic carbon", "01 natural sciences", "[SDE.MCG] Environmental Sciences/Global Changes", "03 medical and health sciences", "13. Climate action", "radiocarbon", "0105 earth and related environmental sciences"]}, "links": [{"href": "http://livrepository.liverpool.ac.uk/3106184/1/2020%20Estop%E2%80%90Aragon%C3%A9s%20et%20al%2C%20GBC%20-%20Arctic%2014C%20synthesis.pdf"}, {"href": "https://eprints.gla.ac.uk/222767/13/222767.pdf"}, {"href": "https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2020GB006672"}, {"href": "https://doi.org/10.1029/2020gb006672"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Global%20Biogeochemical%20Cycles", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1029/2020gb006672", "name": "item", "description": "10.1029/2020gb006672", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1029/2020gb006672"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-09-01T00:00:00Z"}}], "links": [{"rel": "self", "type": "application/geo+json", "title": "This document as GeoJSON", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=H+&offset=1250&f=json", "hreflang": "en-US"}, {"rel": "alternate", "type": "text/html", "title": "This document as HTML", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=H+&offset=1250&f=html", "hreflang": "en-US"}, {"rel": "collection", "type": "application/json", "title": "Collection URL", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main", "hreflang": "en-US"}, {"type": "application/geo+json", "rel": "prev", "title": "items (prev)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=H+&offset=1200", "hreflang": "en-US"}, {"rel": "next", "type": "application/geo+json", "title": "items (next)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=H+&offset=1300", "hreflang": "en-US"}], "numberMatched": 7616, "numberReturned": 50, "distributedFeatures": [], "timeStamp": "2026-04-04T14:16:58.614380Z"}