{"type": "FeatureCollection", "features": [{"id": "10.1002/sae2.12006", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T06:55:10Z", "type": "Journal Article", "created": "2021-11-15", "title": "Effects of microplastics on crop nutrition in fertile soils and interaction with arbuscular mycorrhizal fungi", "description": "AbstractIntroduction

Soil microplastic (MP) pollution has emerged as a main factor of global change, but its effects on soil nutrient availability and uptake by crops (macro and micronutrients) are largely unknown. Arbuscular mycorrhizal fungi (AMF) are regulators of nutrient availability and uptake and can interact with soil MP.

Materials and Methods

Building on previous studies, here we explored in a 50\uffe2\uff80\uff90days pot experiment the influence and interaction of MP fibres (0.4%) and commercial AMF in soil and onion chemistry, that is, in elemental composition of onion shoots and soils (C, N, Ca, Mg, K, P, S, Cu, Fe, Mn and Zn) and micronutrient soil availability (Cu, Fe, Mn and Zn).

Results

MP had detrimental effects on K, Mg and S, but increased the soil availability of Zn and shoot uptake. AMF inoculation buffered the effects of MP by balancing/enhancing nutrient availability and plant uptake. Particularly, the commercial AMF inoculum remarkably enhanced Mn uptake by onion.

Conclusion

Our results support the use of AMF to sustainably manage agricultural ecosystems contaminated with MP, buffering and counteracting the effects of MP by balancing nutrient availability and plant uptake.

", "keywords": ["2. Zero hunger", "570", "microplastics", "Agriculture (General)", "Microplastics", "macronutrients", "Qu\u00edmica", "500 Naturwissenschaften und Mathematik::570 Biowissenschaften; Biologie::570 Biowissenschaften; Biologie", "04 agricultural and veterinary sciences", "15. Life on land", "6. Clean water", "S1-972", "soil", "Environmental sciences", "Soil", "13. Climate action", "micronutrients", "0401 agriculture", " forestry", " and fisheries", "GE1-350", "Macronutrients", "Micronutrients", "Onion", "onion"]}, "links": [{"href": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/sae2.12006"}, {"href": "https://doi.org/10.1002/sae2.12006"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Sustainable%20Agriculture%20and%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1002/sae2.12006", "name": "item", "description": "10.1002/sae2.12006", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1002/sae2.12006"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-11-15T00:00:00Z"}}, {"id": "10.1016/j.still.2005.10.006", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T06:57:54Z", "type": "Journal Article", "created": "2006-05-09", "title": "Tillage And Crop Rotation Effects On Barley Yield And Soil Nutrients On A Calciortidic Haploxeralf", "description": "Reduced tillage with appropriate crop rotation could increase the viability of dry land agriculture in semiarid zones. The effects of tillage and crop rotation on soil physico-chemical properties, soil organic carbon (SOC) and N have been studied widely in long and short-term experiments. However, their effects on nutrient levels and fertility losses have not been extensively studied in Mediterranean soils. We determined SOC, N, P, K, Fe, Mn, Cu and Zn distribution in the soil profile and in plant uptake, on a Calciortidic Haploxeralf in Spain. Three tillage systems [CT, conventional tillage (mouldboard plow); MT, minimum tillage and NT, no tillage] and three crop rotations [BB, continuous barley (Hordeum vulgare v. Tipper), FB, fallow-barley and VB, vetch (Vicia sativa v. Muza)-barley] were compared. SOC and N were higher for CT than for MT and NT in the first year, but higher for NT and MT than CT in the next years. In the 0-15 cm depth, SOC and N in NT also became higher than in MT for the fourth crop season. In the 15-30 depths, NT and MT had also higher SOC than CT since the second year. However, NT had only higher N than MT after three crop seasons. The increase in SOC was 75% for NT and MT while CT had a decrease of 17% in the 0-15 cm layer. The increase in N was 154% for NT, 108% for MT and 30% for CT in the upper 15 cm. NT had higher P, K and Cu than MT and higher P, K, Fe, Mn, Cu and Zn than CT in the upper layers due to the higher SOC level and to the fact that these systems maintain surface-applied K and P fertilizer. On the other hand, neither SOC nor N were affected by crop rotation. Tillage and rotation interactions were not significant for SOC, N and, in general, nutrient levels in the different soil depths. In general, the main factor that affected SOC, N and nutrients was tillage, which had reduced influence with depth. Highest yield was for CT-FB and CT-VB, but not different from NT-FB and NT-VB, meanwhile highest nutrient levels were obtained for interactions that included NT. These results suggest that NT, and to a lesser extend MT, preserved SOC and nutrient levels in the upper layers and, with NT-VB and NT-FB interaction, could also obtain high yields and keep soil fertility in the upper depths during the first 4 years. \u00a9 2006 Elsevier B.V. All rights reserved.", "keywords": ["2. Zero hunger", "Crop rotation", "Soil organic carbon", "Nitrogen", "Potassium", "0401 agriculture", " forestry", " and fisheries", "Phosphorus", "Micronutrients", "04 agricultural and veterinary sciences", "15. Life on land", "6. Clean water", "Tillage"]}, "links": [{"href": "https://doi.org/10.1016/j.still.2005.10.006"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Soil%20and%20Tillage%20Research", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.still.2005.10.006", "name": "item", "description": "10.1016/j.still.2005.10.006", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.still.2005.10.006"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2007-01-01T00:00:00Z"}}, {"id": "10.1007/s11104-009-0234-4", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T06:55:54Z", "type": "Journal Article", "created": "2009-12-01", "title": "Selenium Biofortification Of High-Yielding Winter Wheat (Triticum Aestivum L.) By Liquid Or Granular Se Fertilisation", "description": "Selenium (Se) is an essential trace element for humans and livestock. In the UK, human Se intake and status has declined since the 1980s. This is primarily due to the increased use of wheat (Triticum aestivum L.) grown in UK soils which are naturally low in Se. The aim of this study was to determine the potential for increasing grain Se concentration in a high-yielding UK wheat crop using fertilisers. The crop response of winter-wheat to Se fertilisation was determined under standard field conditions in two consecutive years at up to 10 sites. Selenium fertilisers were applied as high-volume drenches of sodium selenate solution, or as granular Se-containing products. Yield and harvest index were unaffected by Se fertilisation. Under all treatments, grain Se concentration increased by 16\u201326\u00a0ng Se g\u22121 fresh weight (FW) per gram Se ha\u22121 applied. An application of 10\u00a0g Se ha\u22121 would thereby increase the Se concentration of most UK wheat grain 10-fold from current ambient levels and agronomic biofortification of UK-grown wheat is feasible. Total recovery (grain and straw) of applied Se was 20\u201335%. The fate of Se in the food-chain and in the soil must be determined in order to optimize the efficiency of this process.", "keywords": ["0106 biological sciences", "2. Zero hunger", "1110 Plant Science", "Cereals", "500", "0401 agriculture", " forestry", " and fisheries", "Selenium fertilisers", "Agronomic biofortification", "Micronutrients", "04 agricultural and veterinary sciences", "01 natural sciences", "1111 Soil Science", "Diet"]}, "links": [{"href": "https://doi.org/10.1007/s11104-009-0234-4"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Plant%20and%20Soil", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s11104-009-0234-4", "name": "item", "description": "10.1007/s11104-009-0234-4", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s11104-009-0234-4"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-12-02T00:00:00Z"}}, {"id": "10.1016/j.aca.2023.341718", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T06:56:13Z", "type": "Journal Article", "created": "2023-08-15", "title": "Surveying the mugineic acid family: Ion mobility \u2013 quadrupole time-of-flight mass spectrometry (IM-QTOFMS) characterization and tandem mass spectrometry (LC-ESI-MS/MS) quantification of all eight naturally occurring phytosiderophores", "description": "Phytosiderophores (PS) are root exudates released by grass species (Poaceae) that play a pivotal role in iron (Fe) plant nutrition. A direct determination of PS in biological samples is of paramount importance in understanding micronutrient acquisition mediated by PS. To date, eight plant-born PS have been identified; however, no analytical procedure is currently available to quantify all eight PS simultaneously with high analytical confidence. With access to the full set of PS standards for the first time, we report comprehensive methods to both fully characterize (IM-QTOFMS) and quantify (LC-ESI-MS/MS) all eight naturally occurring PS belonging to the mugineic acid family. The quantitative method was fully validated, yielding linear results for all eight analytes, and no unwanted interferences with soil and plant matrices were observed. LOD and LOQ values determined for each PS were below 11 and 35\u00a0nmol\u00a0L-1, respectively. The method's precision under reproducibility conditions (intra- and inter-day) of measurement was less than 2.5% RSD for all analytes. Additionally, all PS were annotated with high-resolution mass spectrometric fragment spectra and further characterized via drift tube ion mobility-mass spectrometry. The collision cross-sections obtained for primary ion species yielded a valuable database for future research focused on in-depth PS studies. The new quantitative method was applied to analyse root exudates from Fe-controlled and deficient barley, oat, rye, and sorghum plants. All eight PS, including mugineic acid (MA), 3'-hydroxymugineic acid (HMA), 3'-epi-hydroxymugineic acid (epi-HMA), hydroxyavenic acid (HAVA), deoxymugineic acid (DMA), 3'-hydroxydeoxymugineic acid (HDMA), 3'-epi-hydroxydeoxymugineic acid (epi-HDMA) and avenic acid (AVA) were for the first time successfully identified and quantified in root exudates of various graminaceous plants using a single analytical procedure. These newly developed methods can be applied to studies aimed at improving crop yield and micronutrient grain content for food consumption via plant-based biofortification.", "keywords": ["Tandem Mass Spectrometry", "Reproducibility of Results", "Micronutrients", "Poaceae", "Edible Grain"]}, "links": [{"href": "https://doi.org/10.1016/j.aca.2023.341718"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Analytica%20Chimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.aca.2023.341718", "name": "item", "description": "10.1016/j.aca.2023.341718", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.aca.2023.341718"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-10-01T00:00:00Z"}}, {"id": "10.1016/j.plantsci.2022.111537", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T06:57:29Z", "type": "Journal Article", "created": "2022-11-16", "title": "Deficient copper availability on organoleptic and nutritional quality of tomato fruit", "description": "Copper (Cu) is an essential micronutrient for plants because it functions as a redox-active cofactor in vital processes inside the cells. Arable lands are often deficient in micronutrient contents and require the application of enriched fertilisers, whose overuse poses a high risk for human health, the environment and the food safety. Here, we aimed to decipher the effects of Cu deficiency during fruit growth on Cu and other micronutrients contents and on the fruit nutritional value and quality of tomato, the most consumed fruit worldwide, throughout the maturation process. Changes in the contents of important micronutrients for fruit physiology and human health, such as Fe and Mn, occurred in response to Cu deficient growing conditions at different fruit ripening stages, while lower Cu levels were detected in those fruit along the whole maturation process. Cu deficiency delayed changes in lycopene content and fruit colour, but increased acidity, and advanced the rise in antioxidant capacity and vitamin C content during fruit colour change from green to light red in the Moneymaker tomato; although this time lag eventually caught up in the most mature fruit stage. Cu deficiency also increased total phenolic and flavonoid contents only in green fruit.", "keywords": ["2. Zero hunger", "0301 basic medicine", "0303 health sciences", "Ripening", "15. Life on land", "3. Good health", "Copper stress", "03 medical and health sciences", "Lycopene", "Solanum lycopersicum", "Fruit", "Ascorbic acid", "Humans", "Micronutrients", "Phenolics", "Nutritive Value", "Copper"]}, "links": [{"href": "https://doi.org/10.1016/j.plantsci.2022.111537"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Plant%20Science", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.plantsci.2022.111537", "name": "item", "description": "10.1016/j.plantsci.2022.111537", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.plantsci.2022.111537"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-01-01T00:00:00Z"}}, {"id": "10.1016/j.plantsci.2023.111919", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T06:57:30Z", "type": "Journal Article", "created": "2023-11-20", "title": "Phytosiderophore pathway response in barley exposed to iron, zinc or copper starvation", "description": "Efficient micronutrient acquisition is a critical factor in selecting micronutrient dense crops for human consumption. Enhanced exudation and re-uptake of metal chelators, so-called phytosiderophores, by roots of graminaceous plants has been implicated in efficient micronutrient acquisition. We compared PS biosynthesis and exudation as a response mechanism to either Fe, Zn or Cu starvation. Two barley (Hordeum vulgare L.) lines with contrasting micronutrient grain yields were grown hydroponically and PS exudation (LC-MS) and root gene expression (RNAseq) were determined after either Fe, Zn, or Cu starvation. The response strength of the PS pathway was micronutrient dependent and decreased in the order Fe >\u00a0Zn >\u00a0Cu deficiency. We observed a stronger expression of PS pathway genes and greater PS exudation in the barley line with large micronutrient grain yield suggesting that a highly expressed PS pathway might be an important trait involved in high micronutrient accumulation. In addition to several metal specific transporters, we also found that the expression of IRO2 and bHLH156 transcription factors was not only induced under Fe but also under Zn and Cu deficiency. Our study delivers important insights into the role of the PS pathway in the acquisition of different micronutrients.", "keywords": ["2. Zero hunger", "Phytosiderophore", "/dk/atira/pure/subjectarea/asjc/1300/1311", "/dk/atira/pure/subjectarea/asjc/1100/1102", "Root exudation", "name=Genetics", "Iron", "/dk/atira/pure/subjectarea/asjc/1100/1110", "Hordeum", "Copper deficiency", "Plant Roots", "630", "Mugineic acid", "name=Agronomy and Crop Science", "Zinc", "Barley", "Humans", "Micronutrients", "name=Plant Science", "Biofortification", "Copper"]}, "links": [{"href": "https://doi.org/10.1016/j.plantsci.2023.111919"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Plant%20Science", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.plantsci.2023.111919", "name": "item", "description": "10.1016/j.plantsci.2023.111919", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.plantsci.2023.111919"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-02-01T00:00:00Z"}}, {"id": "10.1111/gcb.16478", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T06:59:30Z", "type": "Journal Article", "created": "2022-10-28", "title": "Soils in warmer and less developed countries have less micronutrients globally", "description": "Abstract

Soil micronutrients are capital for the delivery of ecosystem functioning and food provision worldwide. Yet, despite their importance, the global biogeography and ecological drivers of soil micronutrients remain virtually unknown, limiting our capacity to anticipate abrupt unexpected changes in soil micronutrients in the face of climate change. Here, we analyzed >1300 topsoil samples to examine the global distribution of six metallic micronutrients (Cu, Fe, Mn, Zn, Co and Ni) across all continents, climates and vegetation types. We found that warmer arid and tropical ecosystems, present in the least developed countries, sustain the lowest contents of multiple soil micronutrients. We further provide evidence that temperature increases may potentially result in abrupt and simultaneous reductions in the content of multiple soil micronutrients when a temperature threshold of 12\uffe2\uff80\uff9314\uffc2\uffb0C is crossed, which may be occurring on 3% of the planet over the next century. Altogether, our findings provide fundamental understanding of the global distribution of soil micronutrients, with direct implications for the maintenance of ecosystem functioning, rangeland management and food production in the warmest and poorest regions of the planet.Citrate (Cit) and Deferoxamine B (DFOB) are two important organic ligands coexisting in soils with distinct different affinities for metal ions. It has been theorized that siderophores and weak organic ligands play a synergistic role during the transport of micronutrients in the rhizosphere, but the geochemical controls of this process remain unknown. Here we test the hypothesis that gradients in pH and ion strength regulate and enable the cooperation. To this end, first we use potentiometric titrations to identify the dominant Zn(II)\uffe2\uff80\uff93Cit and Zn(II)\uffe2\uff80\uff93DFOB complexes and to determine their ionic strength dependent stability constants between 0 and 1\uffc2\uffa0mol\uffc2\uffa0dm\uffe2\uff88\uff923. We parametrise the Extended Debye-H\uffc3\uffbcckel (EDH) equation and determine accurate intrinsic association constants (log\uffce\uffb20) for the formation of the complexes present. The speciation model developed confirms the presence of [Zn(Cit)]\uffe2\uff88\uff92, [Zn(HCit)], [Zn2(Cit)2(OH)2]4\uffe2\uff88\uff92, and [Zn(Cit)2]4\uffe2\uff88\uff92, with [Zn(Cit)]\uffe2\uff88\uff92 and [Zn2(Cit)2(OH)2]4\uffe2\uff88\uff92 the dominant species in the pH range relevant to rhizosphere. We propose the existence of a\uffc2\uffa0new [Zn(Cit)(OH)3]4\uffe2\uff88\uff92 complex above pH 10. We also verify the existence of two hexadentate Zn(II)\uffe2\uff80\uff93DFOB species, i.e., [Zn(DFOB)]\uffe2\uff88\uff92 and [Zn(HDFOB)], and of one tetradentate species [Zn(H2DFOB)]+. Second, we identify the pH and ionic strength dependent ligand exchange points (LEP) of Zn with citrate and DFOB and the stability windows for Zn(II)\uffe2\uff80\uff93Cit and Zn(II)\uffe2\uff80\uff93DFOB complexes in NaCl and rice soil solutions. We find that the LEPs fall within the pH and ionic strength gradients expected in rhizospheres and that the stability windows for Zn(II)\uffe2\uff80\uff93citrate and Zn(II)\uffe2\uff80\uff93DFOB, i.e., low and high affinity ligands, can be distinctly set off. This suggests that pH and ion strength gradients allow for Zn(II) complexes with citrate and DFOB to dominate in different parts of the rhizosphere and this explains why mixtures of low and high affinity ligands increase leaching of micronutrients in soils. Speciation models of soil solutions using newly determined association constants demonstrate that the presence of dissolved organic matter and inorganic ligands (i.e., bicarbonate, phosphate, sulphate, or chlorides) do neither affect the position of the LEP nor the width of the stability windows significantly. In conclusion, we demonstrate that cooperative and synergistic ligand interaction between low and high affinity ligands is a valid mechanism for\uffc2\uffa0controlling zinc transport in the rhizosphere and possibly in other environmental reservoirs such as in the phycosphere. Multiple production of weak and strong ligands is therefore a valid strategy of plants and other soil organisms to improve access to micronutrients.To explore the importance of 12 elements in litter production and decomposition, we fertilized 36 1600\uffe2\uff80\uff83m2\uffe2\uff80\uff90plots with combinations of N, P, K, or micronutrients (i.e. B, Ca, Cu, Fe, Mg, Mn, Mo, S, Zn) for 6\uffe2\uff80\uff83years in a lowland Panamanian forest. The 90% of litter falling as leaves and twigs failed to increase with fertilization, but reproductive litter (fruits and flowers) increased by 43% with N. K enhanced cellulose decomposition; one or more micronutrients enhanced leaf\uffe2\uff80\uff90litter decomposition; P enhanced both. Our results suggest tropical forests are a non\uffe2\uff80\uff90Liebig world of multiple nutrient limitations, with at least four elements shaping rates of litterfall and decomposition. Multiple metallomic enzymes and cofactors likely create gradients in the break down of leaf litter. Selection favours individuals that make more propagules, and even in an N\uffe2\uff80\uff90rich forest, N is a non\uffe2\uff80\uff90substitutable resource for reproduction.

", "keywords": ["0106 biological sciences", "Tropical Climate", "Nitrogen", "Potassium", "Phosphorus", "Micronutrients", "15. Life on land", "Cellulose", "Fertilizers", "01 natural sciences", "Ecosystem", "Trees"]}, "links": [{"href": "https://doi.org/10.1111/j.1461-0248.2007.01124.x"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Ecology%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1111/j.1461-0248.2007.01124.x", "name": "item", "description": "10.1111/j.1461-0248.2007.01124.x", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1111/j.1461-0248.2007.01124.x"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2007-11-16T00:00:00Z"}}, {"id": "10.2139/ssrn.4106102", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T07:01:12Z", "type": "Journal Article", "created": "2022-05-28", "title": "Evaluation of Biostimulation, Bioaugmentation, and Organic Amendments Application on the Bioremediation of Recalcitrant Hydrocarbons of Soil", "description": "In the present work, the operational conditions for improving the degradation rates of Total Petroleum Hydrocarbons (TPHs) in contaminated soil from a machinery park were optimized at a microcosms scale along a 90- days incubation period. In this study, bioremediation strategies and an organic amendment have been tested to verify the remediation of soil contaminated with different hydrocarbons, mineral oils, and heavy metals. Specifically, designed biostimulation and bioaugmentation strategies were compared with and without adding vermicompost. The polluted soil harboring multiple contaminants, partially attenuated for years, was used. The initial profile showed enrichment in heavy linear alkanes, suggesting a previous moderate weathering. The application of vermicompost increased five and two times the amounts of available phosphorus (P) and exchangeable potassium (K), respectively, as a direct consequence of the organic amendment addition. The microbial activity increased due to soil acidification, which influenced the solubility of P and other micronutrients. It also impacted the predominance and variability of the different microbial groups and the incubation, as reflected by phospholipid fatty acid (PLFA) results. An increase in the alkaline phosphatases and proteases linked to bacterial growth was displayed. This stimulation of microbial metabolism correlated with the degradation rates since TPHs degradation\u2019 efficiency after vermicompost addition reached 32.5% and 34.4% of the initial hydrocarbon levels for biostimulation and bioaugmentation, respectively. Although Polycyclic Aromatic", "keywords": ["Soil enzymes", "01 natural sciences", "Total petroleum hydrocarbons polluted soils", "Soil", "Bioaugmentation", "Alkanes", "Soil Pollutants", "Micronutrients", "Polycyclic Aromatic Hydrocarbons", "Materials", "Phospholipids", "Soil Microbiology", "0105 earth and related environmental sciences", "2. Zero hunger", "Minerals", "Materiales", "Biostimulation", " Bioaugmentation", " Phospholipid fatty acids", " Total petroleum hydrocarbons polluted soils", " Soil enzymes", "Fatty Acids", "Phosphorus", "Phenanthrenes", "Hydrocarbons", "Phosphoric Monoester Hydrolases", "6. Clean water", "Biostimulation", "Biodegradation", " Environmental", "Petroleum", "13. Climate action", "Phospholipid fatty acids", "Potassium", "Oils", "Biostimulation Bioaugmentation Phospholipid fatty acids Total petroleum hydrocarbons polluted soils Soil enzymes", "Peptide Hydrolases"]}, "links": [{"href": "https://doi.org/10.2139/ssrn.4106102"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/SSRN%20Electronic%20Journal", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.2139/ssrn.4106102", "name": "item", "description": "10.2139/ssrn.4106102", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.2139/ssrn.4106102"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-01-01T00:00:00Z"}}, {"id": "10.3390/agronomy10101463", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T07:01:36Z", "type": "Journal Article", "created": "2020-09-24", "title": "The Mineral Composition of Wild-Type and Cultivated Varieties of Pasture Species", "description": "

Mineral deficiencies in livestock are often prevented by using prophylactic supplementation, which is imprecise and inefficient. Instead, the trend for increased species diversity in swards is an opportunity to improve mineral concentrations in the basal diet. Currently, there are limited data on the mineral concentrations of different species and botanical groups, particularly for I and Se, which are among the most deficient minerals in livestock diets. We grew 21 pasture species, including some cultivar/wild type comparisons, of grasses, legumes and forbs, as single species stands in a pot study in a standard growth medium. Herbage concentrations of Co, Cu, I, Mn, Se, Zn, S, Mo and Fe showed no consistent differences between the wild and cultivated types. There were significant differences between botanical groups for many minerals tested. Forbs were highest in I and Se, grasses in Mn and legumes in Cu, Co, Zn and Fe. Comparing species concentrations to recommended livestock intakes, the forbs Achillea millefolium, Cichorium intybus and Plantago lanceolata, and the legumes Medicago lupulina, Trifolium hybridum and Lotus corniculatus, appear to be good sources of Co, Cu, I, Se and Zn. Further work is required to ensure these results are consistent in multispecies mixtures, in different soil types and in field trials.

", "keywords": ["forb", "0106 biological sciences", "grass", "trace elements", "01 natural sciences", "Sward", "Forb", "Multifunctional", "Micronutrients", "multifunctional", "Antagonism", "2. Zero hunger", "Trace elements", "S", "Multispecies", "Grass", "Livestock intake", "Agriculture", "legume", "04 agricultural and veterinary sciences", "15. Life on land", "antagonism", "Legume", "multispecies", "micronutrients", "livestock intake", "0401 agriculture", " forestry", " and fisheries", "sward"]}, "links": [{"href": "http://www.mdpi.com/2073-4395/10/10/1463/pdf"}, {"href": "https://www.mdpi.com/2073-4395/10/10/1463/pdf"}, {"href": "https://doi.org/10.3390/agronomy10101463"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Agronomy", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.3390/agronomy10101463", "name": "item", "description": "10.3390/agronomy10101463", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.3390/agronomy10101463"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-09-24T00:00:00Z"}}, {"id": "10.5281/zenodo.15310473", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T07:03:35Z", "type": "Dataset", "title": "Water Analysis Data", "description": "It\u00a0 a comprehensive examination of various types of wastewater with the aim of establishing a comprehensive database on the presence of both micronutrients and micropollutants. The sources of agricultural wastewater are from UNIDEB (Hungary; fermented sludge wastewater and irrigation channel wastewater), UNIBO (Italy; surface irrigation water and agricultural drainage water) and UPWr (Poland; agricultural runoff and ditch).", "keywords": ["Water Analysis", "Micronutrients", "Wastewater", "Pesticides"], "contacts": [{"organization": "Eden Tech", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.5281/zenodo.15310473"}, {"rel": "self", "type": "application/geo+json", "title": "10.5281/zenodo.15310473", "name": "item", "description": "10.5281/zenodo.15310473", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.5281/zenodo.15310473"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2025-04-30T00:00:00Z"}}, {"id": "10486/714786", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T07:05:21Z", "type": "Journal Article", "created": "2019-04-01", "title": "Aridity and reduced soil micronutrient availability in global drylands", "description": "Drylands cover more than 40% of terrestrial surface, and their global extent and socio-ecological importance will increase in the future due to the forecasted increases in aridity driven by climate change. Despite the essential role of metallic micronutrients in life chemistry and ecosystem functioning, it is virtually unknown how their bioavailability changes along aridity gradients at the global scale. Here we analysed soil total and available Cu, Fe, Mn, and Zn in 143 drylands from all continents, except Antarctica, covering a broad range of aridity and soil conditions. We found that total and available micronutrient concentrations in dryland soils were low compared to averages commonly found in soils of natural and agricultural ecosystems globally. Aridity negatively affected the availability of all micronutrients evaluated, mainly indirectly by increasing soil pH and decreasing soil organic matter. Remarkably, the available Fe:Zn ratio decreased exponentially as aridity increased, pointing to stoichiometric alterations. Our findings suggest that increased aridity conditions due to climate change will limit the availability of essential micronutrients for organisms, particularly that of Fe and Zn, which together with other adverse effects (e.g., reduced water availability) may pose serious threats to key ecological processes and services, such as food production, in drylands worldwide.", "keywords": ["0301 basic medicine", "2. Zero hunger", "drylands", "03 medical and health sciences", "aridity", "13. Climate action", "micronutrients", "0401 agriculture", " forestry", " and fisheries", "Qu\u00edmica", "04 agricultural and veterinary sciences", "15. Life on land"]}, "links": [{"href": "https://www.nature.com/articles/s41893-019-0262-x.pdf"}, {"href": "https://doi.org/10486/714786"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Nature%20Sustainability", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10486/714786", "name": "item", "description": "10486/714786", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10486/714786"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-04-01T00:00:00Z"}}, {"id": "10.7910/DVN/GXUNAZ", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T07:05:01Z", "type": "Dataset", "title": "Non-responsiveness of crops to fertilizers under some soils in sub-Saharan Africa", "description": "Open AccessLow productivity of agriculture observed in different parts of sub-Saharan Africa is threatening food security in the region. Decades of production with mostly application of small amounts of inorganic fertilizers (mostly macronutrients) and scarce organic resources in the context of integrated soil fertility management (ISFM) result in nutrient mining of secondary and micronutrients in majority of smallholder farms. With the last decade, crop non-responsiveness to nutrient application has become an important issue requiring scientific understanding. We provide data focused on identifying the extent of non-responsiveness of crops to nutrient application and the associated factors. Data contains crop yield response to secondary and micronutrient (SMN), manure and lime application relative to yields of only NP/K application.", "keywords": ["Nutrient response", "carbono organico del suelo", "Agricultural Sciences", "Soil organic carbon", "CGIAR Research Program on Water", " Land and Ecosystems", "Inorganic fertilisers", "abonos inorganicos", "Multifunctional Landscapes", "micronutrients fertilizers", "Soil fertility", "Micronutrient fertilizers", "soil organic carbon", "Manure", "Earth and Environmental Sciences", "Africa", "inorganic fertilizers", "fertilizantes de oligoelementos"], "contacts": [{"organization": "Kihara, Job Maguta, Okeyo, Jeremiah, Bolo, Peter Omondi, Kinyua, Michael,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.7910/DVN/GXUNAZ"}, {"rel": "self", "type": "application/geo+json", "title": "10.7910/DVN/GXUNAZ", "name": "item", "description": "10.7910/DVN/GXUNAZ", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.7910/DVN/GXUNAZ"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-01-01T00:00:00Z"}}, {"id": "10044/1/96781", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-31T07:05:05Z", "type": "Journal Article", "created": "2022-04-26", "title": "Synergistic use of siderophores and weak organic ligands during zinc transport in the rhizosphere controlled by pH and ion strength gradients", "description": "Abstract

Citrate (Cit) and Deferoxamine B (DFOB) are two important organic ligands coexisting in soils with distinct different affinities for metal ions. It has been theorized that siderophores and weak organic ligands play a synergistic role during the transport of micronutrients in the rhizosphere, but the geochemical controls of this process remain unknown. Here we test the hypothesis that gradients in pH and ion strength regulate and enable the cooperation. To this end, first we use potentiometric titrations to identify the dominant Zn(II)\uffe2\uff80\uff93Cit and Zn(II)\uffe2\uff80\uff93DFOB complexes and to determine their ionic strength dependent stability constants between 0 and 1\uffc2\uffa0mol\uffc2\uffa0dm\uffe2\uff88\uff923. We parametrise the Extended Debye-H\uffc3\uffbcckel (EDH) equation and determine accurate intrinsic association constants (log\uffce\uffb20) for the formation of the complexes present. The speciation model developed confirms the presence of [Zn(Cit)]\uffe2\uff88\uff92, [Zn(HCit)], [Zn2(Cit)2(OH)2]4\uffe2\uff88\uff92, and [Zn(Cit)2]4\uffe2\uff88\uff92, with [Zn(Cit)]\uffe2\uff88\uff92 and [Zn2(Cit)2(OH)2]4\uffe2\uff88\uff92 the dominant species in the pH range relevant to rhizosphere. We propose the existence of a\uffc2\uffa0new [Zn(Cit)(OH)3]4\uffe2\uff88\uff92 complex above pH 10. We also verify the existence of two hexadentate Zn(II)\uffe2\uff80\uff93DFOB species, i.e., [Zn(DFOB)]\uffe2\uff88\uff92 and [Zn(HDFOB)], and of one tetradentate species [Zn(H2DFOB)]+. Second, we identify the pH and ionic strength dependent ligand exchange points (LEP) of Zn with citrate and DFOB and the stability windows for Zn(II)\uffe2\uff80\uff93Cit and Zn(II)\uffe2\uff80\uff93DFOB complexes in NaCl and rice soil solutions. We find that the LEPs fall within the pH and ionic strength gradients expected in rhizospheres and that the stability windows for Zn(II)\uffe2\uff80\uff93citrate and Zn(II)\uffe2\uff80\uff93DFOB, i.e., low and high affinity ligands, can be distinctly set off. This suggests that pH and ion strength gradients allow for Zn(II) complexes with citrate and DFOB to dominate in different parts of the rhizosphere and this explains why mixtures of low and high affinity ligands increase leaching of micronutrients in soils. Speciation models of soil solutions using newly determined association constants demonstrate that the presence of dissolved organic matter and inorganic ligands (i.e., bicarbonate, phosphate, sulphate, or chlorides) do neither affect the position of the LEP nor the width of the stability windows significantly. In conclusion, we demonstrate that cooperative and synergistic ligand interaction between low and high affinity ligands is a valid mechanism for\uffc2\uffa0controlling zinc transport in the rhizosphere and possibly in other environmental reservoirs such as in the phycosphere. Multiple production of weak and strong ligands is therefore a valid strategy of plants and other soil organisms to improve access to micronutrients.Soil micronutrients are capital for the delivery of ecosystem functioning and food provision worldwide. Yet, despite their importance, the global biogeography and ecological drivers of soil micronutrients remain virtually unknown, limiting our capacity to anticipate abrupt unexpected changes in soil micronutrients in the face of climate change. Here, we analyzed >1300 topsoil samples to examine the global distribution of six metallic micronutrients (Cu, Fe, Mn, Zn, Co and Ni) across all continents, climates and vegetation types. We found that warmer arid and tropical ecosystems, present in the least developed countries, sustain the lowest contents of multiple soil micronutrients. We further provide evidence that temperature increases may potentially result in abrupt and simultaneous reductions in the content of multiple soil micronutrients when a temperature threshold of 12\uffe2\uff80\uff9314\uffc2\uffb0C is crossed, which may be occurring on 3% of the planet over the next century. Altogether, our findings provide fundamental understanding of the global distribution of soil micronutrients, with direct implications for the maintenance of ecosystem functioning, rangeland management and food production in the warmest and poorest regions of the planet.\u00a0Zn >\u00a0Cu deficiency. We observed a stronger expression of PS pathway genes and greater PS exudation in the barley line with large micronutrient grain yield suggesting that a highly expressed PS pathway might be an important trait involved in high micronutrient accumulation. In addition to several metal specific transporters, we also found that the expression of IRO2 and bHLH156 transcription factors was not only induced under Fe but also under Zn and Cu deficiency. Our study delivers important insights into the role of the PS pathway in the acquisition of different micronutrients.", "keywords": ["2. Zero hunger", "Phytosiderophore", "/dk/atira/pure/subjectarea/asjc/1300/1311", "/dk/atira/pure/subjectarea/asjc/1100/1102", "Root exudation", "name=Genetics", "Iron", "/dk/atira/pure/subjectarea/asjc/1100/1110", "Hordeum", "Copper deficiency", "Plant Roots", "630", "Mugineic acid", "name=Agronomy and Crop Science", "Zinc", "Barley", "Humans", "Micronutrients", "name=Plant Science", "Biofortification", "Copper"]}, "links": [{"href": "https://doi.org/37992897"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Plant%20Science", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "37992897", "name": "item", "description": "37992897", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/37992897"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-02-01T00:00:00Z"}}], "links": [{"rel": "self", "type": "application/geo+json", "title": "This document as GeoJSON", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Micronutrients&f=json", "hreflang": "en-US"}, {"rel": "alternate", "type": "text/html", "title": "This document as HTML", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Micronutrients&f=html", "hreflang": "en-US"}, {"rel": "collection", "type": "application/json", "title": "Collection URL", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main", "hreflang": "en-US"}, {"type": "application/geo+json", "rel": "first", "title": "items (first)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Micronutrients&", "hreflang": "en-US"}, {"rel": "last", "type": "application/geo+json", "title": "items (last)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Micronutrients&offset=22", "hreflang": "en-US"}], "numberMatched": 22, "numberReturned": 22, "distributedFeatures": [], "timeStamp": "2026-05-31T08:59:05.960130Z"}