{"type": "FeatureCollection", "features": [{"id": "10.5194/egusphere-2022-1414", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-06-27T16:24:40Z", "type": "Journal Article", "created": "2023-02-20", "title": "Modeling dust mineralogical composition: sensitivity to soil mineralogy atlases and their expected climate impacts", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>Abstract. Soil dust aerosols are a key component of the climate system, as they interact with short- and long-wave radiation, alter cloud formation processes, affect atmospheric chemistry and play a role in biogeochemical cycles by providing nutrient inputs such as iron and phosphorus. The influence of dust on these processes depends on its physico-chemical properties, which far from being homogeneous, are shaped by its regionally varying mineral composition. The relative amount of minerals in dust depends on the source region and shows a large geographical variability. However, many state-of-the-art Earth System Models (ESMs), upon which climate analyses and projections rely, still consider dust mineralogy as invariant. The explicit representation of minerals in ESMs is more hindered by our limited knowledge of the global soil composition along with the resulting size-resolved airborne mineralogy than by computational constraints. In this work, we introduce an explicit mineralogy representation within the state-of-the-art atmosphere-chemistry model MONARCH. We review and compare two existing soil mineralogy datasets, which remain a source of uncertainty for dust mineralogy modelling, and provide an evaluation of multi-annual simulations against available mineralogy observations. Soil mineralogy datasets are based on measurements performed after wet sieving, which breaks the aggregates found in the parent soil. Our model predicts the emitted particle size distribution (PSD) in terms of its constituent minerals based on Brittle Fragmentation Theory (BFT), which reconstructs the emitted mineral aggregates destroyed by wet sieving. Our simulations broadly reproduce the most abundant mineral fractions, independently of the soil composition data used. Feldspars and calcite are highly sensitive to the soil mineralogy map, mainly due to the different assumptions made in each soil dataset to extrapolate a handful of soil measurements to arid and semiarid regions worldwide. For the least abundant or more difficult to determine minerals, such as the iron oxides, uncertainties in soil mineralogy yield differences in annual mean aerosol mass fractions of up to \u223c100 %. Although BFT restores coarse aggregates including phyllosilicates that usually break during soil analysis, we still identify an overestimation of coarse quartz mass fractions (above 2 \u00b5m in diameter). In a dedicated experiment, we estimate the fraction of dust with undetermined composition as given by a soil map, which makes a \u223c10 % of the emitted dust mass at the global scale, and can be regionally larger. Changes in the underlying soil mineralogy impact our estimates of climate-relevant variables, particularly affecting the regional variability of the single scattering albedo at solar wavelengths, or the total iron deposited over oceans. All in all, this assessment represents a baseline for future model experiments including new mineralogical maps constrained by high quality spaceborne hyperspectral measurements, such as those arising from the NASA EMIT mission.                         </p></article>", "keywords": ["Mineral dusts", "[SDU.OCEAN]Sciences of the Universe [physics]/Ocean", "info:eu-repo/classification/ddc/550", "550", "Atmosphere", "ddc:550", "[SDU.OCEAN] Sciences of the Universe [physics]/Ocean", " Atmosphere", "Physics", "QC1-999", "Climatologia -- Models matem\u00e0tics", "Aerosols atmosf\u00e8rics", "15. Life on land", "Atmospheric aerosols", "[SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces", " environment", "Climatology -- Mathematical models", "\u00c0rees tem\u00e0tiques de la UPC::Desenvolupament hum\u00e0 i sostenible::Enginyeria ambiental", "Earth sciences", "Chemistry", "13. Climate action", "[SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces", "Pols minerals", "environment", "QD1-999"]}, "links": [{"href": "https://acp.copernicus.org/articles/23/8623/2023/acp-23-8623-2023.pdf"}, {"href": "https://doi.org/10.5194/egusphere-2022-1414"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Atmospheric%20Chemistry%20and%20Physics", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.5194/egusphere-2022-1414", "name": "item", "description": "10.5194/egusphere-2022-1414", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.5194/egusphere-2022-1414"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-02-20T00:00:00Z"}}, {"id": "2117/410005", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-06-27T16:30:04Z", "type": "Journal Article", "created": "2024-06-04", "title": "Improved constraints on hematite refractive index for estimating climatic effects of dust aerosols", "description": "Abstract<p>Uncertainty in desert dust composition poses a big challenge to understanding Earth\uffe2\uff80\uff99s climate across different epochs. Of particular concern is hematite, an iron-oxide mineral dominating the solar absorption by dust particles, for which current estimates of absorption capacity vary by over two orders of magnitude. Here, we show that laboratory measurements of dust composition, absorption, and scattering provide valuable constraints on the absorption potential of hematite, substantially narrowing its range of plausible values. The success of this constraint is supported by results from an atmospheric transport model compared with station-based measurements. Additionally, we identify substantial bias in simulating hematite abundance in dust aerosols with current soil mineralogy descriptions, underscoring the necessity for improved data sources. Encouragingly, the next-generation imaging spectroscopy remote sensing data hold promise for capturing the spatial variability of hematite. These insights have implications for enhancing dust modeling, thus contributing to efforts in climate change mitigation and adaptation.</p", "keywords": ["Aerosols", "Mineral dusts", "QE1-996.5", "\u00c0rees tem\u00e0tiques de la UPC::Desenvolupament hum\u00e0 i sostenible::Degradaci\u00f3 ambiental::Canvi clim\u00e0tic", "550", "500", "Geology", "Climatic changes", "15. Life on land", "01 natural sciences", "Environmental sciences", "[SDE.MCG] Environmental Sciences/Global Changes", "13. Climate action", "\u00c0rees tem\u00e0tiques de la UPC::Enginyeria civil::Geologia::Mineralogia", "GE1-350", "Pols minerals", "Canvis clim\u00e0tics", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://www.nature.com/articles/s43247-024-01441-4.pdf"}, {"href": "https://doi.org/2117/410005"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Communications%20Earth%20%26amp%3B%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2117/410005", "name": "item", "description": "2117/410005", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2117/410005"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-06-04T00:00:00Z"}}, {"id": "2117/407828", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-06-27T16:30:04Z", "type": "Journal Article", "created": "2024-05-07", "title": "Observationally constrained regional variations of shortwave absorption by iron oxides emphasize the cooling effect of dust", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>Abstract. The composition of soil dust aerosols derives from the mineral abundances in the parent soils that vary across dust source regions. Nonetheless, Earth system models (ESMs) have traditionally represented mineral dust as a globally homogeneous species. The growing interest in modeling dust mineralogy, facilitated by the recognized sensitivity of the dust climate impacts to composition, has motivated state-of-the-art ESMs to incorporate the mineral speciation of dust along with its effect upon the dust direct radiative effect (DRE). In this work, we enable the NASA Goddard Institute for Space Studies ModelE2.1 to calculate the shortwave (SW) DRE accounting for the regionally varying soil mineralogy. Mineral\u2013radiation interaction at solar wavelengths is calculated according to two alternative coupling schemes: (1)\u00a0external mixing of three mineral components that are optically distinguished, one of which contains embedded iron oxides; (2)\u00a0a single internal mixture of all dust minerals with a dynamic fraction of iron oxides that varies regionally and temporally. We link dust absorption to the fractional mass of iron oxides based on recent chamber measurements using natural dust aerosol samples. We show that coupled mineralogy overall enhances the scattering by dust, and thus the global cooling, compared to our control run with globally uniform composition. According to the external mixing scheme, the SW DRE at the top of atmosphere (TOA) changes from \u22120.25 to -0.30Wm-2, corresponding to a change in the net DRE, including the longwave effect, from \u22120.08 to -0.12Wm-2. The cooling increase is accentuated when the internal mixing scheme is configured: the SW DRE at the TOA becomes -0.34Wm-2 with a net DRE of -0.15Wm-2. The varying composition modifies the regional distribution of single scattering albedo (SSA), whose variations in specific regions can be remarkable (above 0.03) and significantly modify the regional SW DRE. Evaluation against the AErosol RObotic NETwork (AERONET) shows that explicit representation of soil mineralogy and its regional variations reduces the low bias of model dust SSA while improving the range of variability across stations and calendar months. Despite these improvements, the moderate spatiotemporal correlation with AERONET reveals remaining modeling challenges and the need for more accurate measurements of mineral fractions in soils.</p></article>", "keywords": ["[SDE] Environmental Sciences", "Mineral dusts", "Radiation", "Physics", "QC1-999", "Cicle hidrol\u00f2gic", "15. Life on land", "Aerosols atmosf\u00e8rics", "01 natural sciences", "Radiaci\u00f3", "Chemistry", "13. Climate action", "\u00c0rees tem\u00e0tiques de la UPC::Enginyeria civil::Geologia::Mineralogia", "Pols minerals", "QD1-999", "Atmospheric aerosol", "\u00c0rees tem\u00e0tiques de la UPC::Desenvolupament hum\u00e0 i sostenible::Degradaci\u00f3 ambiental", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://acp.copernicus.org/articles/24/5337/2024/acp-24-5337-2024.pdf"}, {"href": "https://doi.org/2117/407828"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Atmospheric%20Chemistry%20and%20Physics", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2117/407828", "name": "item", "description": "2117/407828", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2117/407828"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-06-05T00:00:00Z"}}, {"id": "2117/411014", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-06-27T16:30:04Z", "type": "Journal Article", "created": "2024-06-28", "title": "Modeling impacts of dust mineralogy on fast climate response", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>Abstract. Mineralogical composition drives dust impacts on Earth's climate systems. However, most climate models still use homogeneous dust, without accounting for the temporal and spatial variation in mineralogy. To quantify the radiative impact of resolving dust mineralogy on Earth's climate, we implement and simulate the distribution of dust minerals (i.e., illite, kaolinite, smectite, hematite, calcite, feldspar, quartz, and gypsum) from Claquin et\u00a0al. (1999) (C1999) and activate their interaction with radiation in the GFDL AM4.0 model. Resolving mineralogy reduces dust absorption compared to the homogeneous dust used in the standard GFDL AM4.0 model that assumes a globally uniform hematite volume content of 2.7\u2009% (HD27). The reduction in dust absorption results in improved agreement with observation-based single-scattering albedo (SSA), radiative fluxes from CERES (the Clouds and the Earth's Radiant Energy System), and land surface temperature from the CRU (Climatic Research Unit) compared to the baseline HD27 model version. It also results in distinct radiative impacts on Earth's climate over North Africa. Over the 19-year (from 2001 to 2019) modeled period during JJA (June\u2013July\u2013August), the reduction in dust absorption in AM4.0 leads to a reduction of over 50\u2009% in net downward radiation across the Sahara and approximately 20\u2009% over the Sahel at the top of the atmosphere (TOA) compared to the baseline HD27 model version. The reduced dust absorption weakens the atmospheric warming effect of dust aerosols and leads to an alteration in land surface temperature, resulting in a decrease of 0.66\u2009K over the Sahara and an increase of 0.7\u2009K over the Sahel. The less warming in the atmosphere suppresses ascent and weakens the monsoon inflow from the Gulf of Guinea. This brings less moisture to the Sahel, which combined with decreased ascent induces a reduction of precipitation. To isolate the effect of reduced absorption compared to resolving spatial and temporal mineralogy, we carry out a simulation where the hematite volume content of homogeneous dust is reduced from 2.7\u2009% to 0.9\u2009% (HD09). The dust absorption (e.g., single-scattering albedo) of HD09 is comparable to that of the mineralogically speciated model on a global mean scale, albeit with a lower spatial variation that arises solely from particle size. Comparison of the two\u00a0models indicates that the spatial inhomogeneity in dust absorption resulting from resolving mineralogy does not have significant impacts on Earth's radiation and climate, provided there is a similar level of dust absorption on a global mean scale before and after resolving dust mineralogy. However, uncertainties related to emission and distribution of minerals may blur the advantages of resolving minerals to study their impact on radiation, cloud properties, ocean biogeochemistry, air quality, and photochemistry. On the other hand, lumping together clay minerals (i.e., illite, kaolinite, and smectite), but excluding externally mixed hematite and gypsum, appears to provide both computational efficiency and relative accuracy. Nevertheless, for specific research, it may be necessary to fully resolve mineralogy to achieve accuracy.</p></article>", "keywords": ["Mineral dusts", "Climatology", "Physics", "QC1-999", "\u00c0rees tem\u00e0tiques de la UPC::F\u00edsica", "15. Life on land", "01 natural sciences", "Chemistry", "13. Climate action", "Climatologia", "Radiative transfer", "\u00c0rees tem\u00e0tiques de la UPC::Enginyeria civil::Geologia::Mineralogia", "Pols minerals", "QD1-999", "Transfer\u00e8ncia radiativa", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://acp.copernicus.org/articles/24/7421/2024/acp-24-7421-2024.pdf"}, {"href": "https://doi.org/2117/411014"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Atmospheric%20Chemistry%20and%20Physics", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2117/411014", "name": "item", "description": "2117/411014", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2117/411014"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-06-28T00:00:00Z"}}, {"id": "10067/1897670151162165141", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:28:46Z", "type": "Journal Article", "created": "2022-07-01", "title": "Global stocks and capacity of mineral-associated soil organic carbon", "description": "Abstract<p>Soil is the largest terrestrial reservoir of organic carbon and is central for climate change mitigation and carbon-climate feedbacks. Chemical and physical associations of soil carbon with minerals play a critical role in carbon storage, but the amount and global capacity for storage in this form remain unquantified. Here, we produce spatially-resolved global estimates of mineral-associated organic carbon stocks and carbon-storage capacity by analyzing 1144 globally-distributed soil profiles. We show that current stocks total 899 Pg C to a depth of 1\uffe2\uff80\uff89m in non-permafrost mineral soils. Although this constitutes 66% and 70% of soil carbon in surface and deeper layers, respectively, it is only 42% and 21% of the mineralogical capacity. Regions under agricultural management and deeper soil layers show the largest undersaturation of mineral-associated carbon. Critically, the degree of undersaturation indicates sequestration efficiency over years to decades. We show that, across 103 carbon-accrual measurements spanning management interventions globally, soils furthest from their mineralogical capacity are more effective at accruing carbon; sequestration rates average 3-times higher in soils at one tenth of their capacity compared to soils at one half of their capacity. Our findings provide insights into the world\uffe2\uff80\uff99s soils, their capacity to store carbon, and priority regions and actions for soil carbon management.</p", "keywords": ["Carbon sequestration", "550", "Permafrost", "/704/106/47/4113", "Carbon Dynamics in Peatland Ecosystems", "Digital Soil Mapping Techniques", "Oceanography", "01 natural sciences", "Agricultural and Biological Sciences", "Soil", "Soil water", "Carbon fibers", "Climate change", "2. Zero hunger", "Minerals", "Ecology", "Forestry Sciences", "Q", "Total organic carbon", "article", "Life Sciences", "Composite number", "Geology", "Agriculture", "/704/106/694/682", "Soil carbon", "Chemistry", "/704/47/4113", "CESD-Soil Quality", "Physical Sciences", "Environmental chemistry", "Engineering sciences. Technology", "Composite material", "/141", "Carbon Sequestration", "Environmental Engineering", "Life on Land", "Science", "[SDU.STU]Sciences of the Universe [physics]/Earth Sciences", "Veterinary and Food Sciences", "Soil Science", "/704/106/694/1108", "Environmental science", "Article", "Digital Soil Mapping", "[SDU] Sciences of the Universe [physics]", "Global Soil Information", "Soil Carbon Sequestration", "Biology", "0105 earth and related environmental sciences", "Soil science", "Agricultural", "Soil organic matter", "FOS: Environmental engineering", "Soil Properties", "FOS: Earth and related environmental sciences", "15. Life on land", "Materials science", "Carbon", "Carbon dioxide", "[SDU]Sciences of the Universe [physics]", "13. Climate action", "FOS: Biological sciences", "Environmental Science", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "Soil Carbon Dynamics and Nutrient Cycling in Ecosystems", "/119", "Climate Change Impacts and Adaptation", "Environmental Sciences"]}, "links": [{"href": "https://www.nature.com/articles/s41467-022-31540-9.pdf"}, {"href": "https://escholarship.org/content/qt2vm0b30s/qt2vm0b30s.pdf"}, {"href": "https://doi.org/10067/1897670151162165141"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Nature%20Communications", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10067/1897670151162165141", "name": "item", "description": "10067/1897670151162165141", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10067/1897670151162165141"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-07-01T00:00:00Z"}}, {"id": "10259/7423", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:28:49Z", "type": "Journal Article", "created": "2022-05-28", "title": "Evaluation of Biostimulation, Bioaugmentation, and Organic Amendments Application on the Bioremediation of Recalcitrant Hydrocarbons of Soil", "description": "In the present work, the operational conditions for improving the degradation rates of Total Petroleum Hydrocarbons (TPHs) in contaminated soil from a machinery park were optimized at a microcosms scale along a 90- days incubation period. In this study, bioremediation strategies and an organic amendment have been tested to verify the remediation of soil contaminated with different hydrocarbons, mineral oils, and heavy metals. Specifically, designed biostimulation and bioaugmentation strategies were compared with and without adding vermicompost. The polluted soil harboring multiple contaminants, partially attenuated for years, was used. The initial profile showed enrichment in heavy linear alkanes, suggesting a previous moderate weathering. The application of vermicompost increased five and two times the amounts of available phosphorus (P) and exchangeable potassium (K), respectively, as a direct consequence of the organic amendment addition. The microbial activity increased due to soil acidification, which influenced the solubility of P and other micronutrients. It also impacted the predominance and variability of the different microbial groups and the incubation, as reflected by phospholipid fatty acid (PLFA) results. An increase in the alkaline phosphatases and proteases linked to bacterial growth was displayed. This stimulation of microbial metabolism correlated with the degradation rates since TPHs degradation\u2019 efficiency after vermicompost addition reached 32.5% and 34.4% of the initial hydrocarbon levels for biostimulation and bioaugmentation, respectively. Although Polycyclic Aromatic", "keywords": ["Soil enzymes", "01 natural sciences", "Total petroleum hydrocarbons polluted soils", "Soil", "Bioaugmentation", "Alkanes", "Soil Pollutants", "Micronutrients", "Polycyclic Aromatic Hydrocarbons", "Materials", "Phospholipids", "Soil Microbiology", "0105 earth and related environmental sciences", "2. Zero hunger", "Minerals", "Materiales", "Fatty Acids", "Phosphorus", "Phenanthrenes", "Hydrocarbons", "Phosphoric Monoester Hydrolases", "6. Clean water", "Biostimulation", "Biodegradation", " Environmental", "Petroleum", "13. Climate action", "Phospholipid fatty acids", "Potassium", "Oils", "Biostimulation Bioaugmentation Phospholipid fatty acids Total petroleum hydrocarbons polluted soils Soil enzymes", "Peptide Hydrolases"]}, "links": [{"href": "https://doi.org/10259/7423"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/SSRN%20Electronic%20Journal", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10259/7423", "name": "item", "description": "10259/7423", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10259/7423"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-01-01T00:00:00Z"}}, {"id": "20.500.11850/529133", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:29:49Z", "type": "Journal Article", "created": "2021-11-08", "title": "Mineral characterization and composition of Fe-rich flocs from wetlands of Iceland: Implications for Fe, C and trace element export", "description": "Open AccessIn freshwater wetlands, redox interfaces characterized by circumneutral pH, steep gradients in O2, and a continual supply of Fe(II) form ecological niches favorable to microaerophilic iron(II) oxidizing bacteria (FeOB) and the formation of flocs; associations of (a)biotic mineral phases, microorganisms, and (microbially-derived) organic matter. On the volcanic island of Iceland, wetlands are replenished with Fe-rich surface-, ground- and springwater. Combined with extensive drainage of lowland wetlands, which forms artificial redox gradients, accumulations of bright orange (a)biotically-derived Fe-rich flocs are common features of Icelandic wetlands. These loosely consolidated flocs are easily mobilized, and, considering the proximity of Iceland's lowland wetlands to the coast, are likely to contribute to the suspended sediment load transported to coastal waters. To date, however, little is known regarding (Fe) mineral and elemental composition of the flocs. In this study, flocs from wetlands (n = 16) across Iceland were analyzed using X-ray diffraction and spectroscopic techniques (X-ray absorption and 57Fe M\u00f6ssbauer) combined with chemical extractions and (electron) microscopy to comprehensively characterize floc mineral, elemental, and structural composition. All flocs were rich in Fe (229\u2013414 mg/g), and floc Fe minerals comprised primarily ferrihydrite and nano-crystalline lepidocrocite, with a single floc sample containing nano-crystalline goethite. Floc mineralogy also included Fe in clay minerals and appreciable poorly-crystalline aluminosilicates, most likely allophane and/or imogolite. Microscopy images revealed that floc (bio)organics largely comprised mineral encrusted microbially-derived components (i.e. sheaths, stalks, and EPS) indicative of common FeOB Leptothrix spp. and Gallionella spp. Trace element contents in the flocs were in the low \u03bcg/g range, however nearly all trace elements were extracted with hydroxylamine hydrochloride. This finding suggests that the (a)biotic reductive dissolution of floc Fe minerals, plausibly driven by exposure to the varied geochemical conditions of coastal waters following floc mobilization, could lead to the release of associated trace elements. Thus, the flocs should be considered vectors for transport of Fe, organic carbon, and trace elements from Icelandic wetlands to coastal waters.", "keywords": ["Minerals", "Iron", "Iceland", "Freshwater flocs", "04 agricultural and veterinary sciences", "15. Life on land", "Ferric Compounds", "01 natural sciences", "6. Clean water", "Trace Elements", "EXAFS", "13. Climate action", "Freshwater flocs; Fe(II)-oxidizing bacteria; Biominerals; Wetlands; EXAFS; 57Fe M\u00f6ssbauer", "Wetlands", "57Fe M\u00f6ssbauer", "Biominerals", "Fe(II)-oxidizing bacteria", "0401 agriculture", " forestry", " and fisheries", "14. Life underwater", "Oxidation-Reduction", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/20.500.11850/529133"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20of%20The%20Total%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.11850/529133", "name": "item", "description": "20.500.11850/529133", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.11850/529133"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-04-01T00:00:00Z"}}, {"id": "1983/ee301c22-7b50-46dd-9d94-2cb7973a0a60", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-06-27T16:29:41Z", "type": "Journal Article", "created": "2023-02-06", "title": "Competitive incorporation of Mn and Mg in vivianite at varying salinity and effects on crystal structure and morphology", "description": "Open AccessVivianite, a ferrous phosphate mineral, can be an important phosphorus (P) sink in non-sulfidic, reducing coastal sediments. The Fe in the crystal structure of vivianite can be substituted by other divalent metal cations such as Mn2+ or Mg2+. Since Mg is much more abundant in coastal porewaters than Mn, the more frequent reports of Mn substitution in vivianites of coastal sediments has been suggested to indicate a preferential incorporation of Mn over Mg into the crystal structure of vivianite. However, although both Mn and Mg substitution in vivianite are environmentally relevant, it is yet unknown whether Mn or Mg is preferentially incorporated and how these isomorphic substitutions alter the crystal structure and morphology of vivianite, parameters which may influence vivianite reactivity. Here, we studied the incorporation of Mn and/or Mg in vivianites formed by co-precipitation at pH 7 in the presence of varying dissolved Mn and/or Mg concentrations and solution salinities resembling an estuarine gradient from 0 to 9 psu. In total, 19 different vivianites were synthesized, with up to 50% of Fe substituted by Mn and Mg. Thermodynamic equilibrium calculations showed that aqueous Mg speciation was altered with increasing salinity, while Mn speciation was less affected, likely explaining the preferential incorporation of Mn in the vivianite structure at higher salinities. 57Fe-M\u00f6ssbauer spectroscopy revealed that both Mn and Mg were preferentially incorporated in the double-octahedral Fe position, at which intervalence charge transfer is possible during the oxidation of vivianite. In contrast to Mg, which is redox inactive, incorporated Mn can participate in heteronuclear intervalence charge transfer with Fe. Thus, incorporation of either cation may impact the reactivity of vivianite under oxidizing conditions in element specific ways. Results of complementary analyses including X-ray diffraction, electron microscopy and Fe K-edge X-ray absorption spectroscopy further showed that incorporation of Mn and/or Mg led to smaller particle size, increased crystal roughness and thinner crystals, as well as systematic changes in unit cell parameters. These observed changes in crystal morphology might impact the reactivity of vivianite in natural environments and thus the effect of cation incorporation in vivianite should be considered when studying Fe and P cycling in coastal sediments.", "keywords": ["M\u00f6ssbauer Spectroscopy", "550", "Isomorphic substitution", "13. Climate action", "Ferrous phosphate minerals", "Electron microscopy", "Ferrous phosphate minerals; Phosphorus burial; Isomorphic substitution; M\u00f6ssbauer Spectroscopy; Electron microscopy", "Phosphorus burial", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/1983/ee301c22-7b50-46dd-9d94-2cb7973a0a60"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "1983/ee301c22-7b50-46dd-9d94-2cb7973a0a60", "name": "item", "description": "1983/ee301c22-7b50-46dd-9d94-2cb7973a0a60", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/1983/ee301c22-7b50-46dd-9d94-2cb7973a0a60"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-04-01T00:00:00Z"}}, {"id": "1983/a88fc0ed-e9c4-447e-b866-fc5384e91e0c", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-06-27T16:29:41Z", "type": "Journal Article", "created": "2023-06-26", "title": "A New Approach for Investigating Iron Mineral Transformations in Soils and Sediments Using 57Fe-Labeled Minerals and 57Fe M\u00f6ssbauer Spectroscopy", "description": "Open AccessIron minerals in soils and sediments play important roles in many biogeochemical processes and therefore influence the cycling of major and trace elements and the fate of pollutants in the environment. However, the kinetics and pathways of Fe mineral recrystallization and transformation processes under environmentally relevant conditions are still elusive. Here, we present a novel approach enabling us to follow the transformations of Fe minerals added to soils or sediments in close spatial association with complex solid matrices including other minerals, organic matter, and microorganisms. Minerals enriched with the stable isotope 57Fe are mixed with soil or sediment, and changes in Fe speciation are subsequently studied by 57Fe M\u00f6ssbauer spectroscopy, which exclusively detects 57Fe. In this study, 57Fe-labeled ferrihydrite was synthesized, mixed with four soils differing in chemical and physical properties, and incubated for 12+ weeks under anoxic conditions. Our results reveal that the formation of crystalline Fe(III)(oxyhydr)oxides such as lepidocrocite and goethite was strongly suppressed, and instead formation of a green rust-like phase was observed in all soils. These results contrast those from Fe(II)-catalyzed ferrihydrite transformation experiments, where formation of lepidocrocite, goethite, and/or magnetite often occurs. The presented approach allows control over the composition and crystallinity of the initial Fe mineral, and it can be easily adapted to other experimental setups or Fe minerals. It thus offers great potential for future investigations of Fe mineral transformations in situ under environmentally relevant conditions, in both the laboratory and the field.", "keywords": ["Minerals", "550", "Iron", "iron reduction", "01 natural sciences", "Ferric Compounds", "ferrihydrite", "microcosm", "Soil", "Spectroscopy", " Mossbauer", "green rust", "13. Climate action", "Oxidation-Reduction", "Fe(II)-catalyzed transformation", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/1983/a88fc0ed-e9c4-447e-b866-fc5384e91e0c"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "1983/a88fc0ed-e9c4-447e-b866-fc5384e91e0c", "name": "item", "description": "1983/a88fc0ed-e9c4-447e-b866-fc5384e91e0c", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/1983/a88fc0ed-e9c4-447e-b866-fc5384e91e0c"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-06-26T00:00:00Z"}}, {"id": "20.500.12556/RUNG-8752", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:29:53Z", "type": "Journal Article", "created": "2023-12-22", "title": "Variability in sediment particle size, mineralogy, and Fe mode of occurrence across dust-source inland drainage basins: the case of the lower Dr\u00e2a Valley, Morocco", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>Abstract. The effects of desert dust upon climate and ecosystems depend strongly on its particle size and size-resolved mineralogical composition. However, there is very limited quantitative knowledge on the particle size and composition of the parent sediments along with their variability within dust-source regions, particularly in dust emission hotspots. The lower Dr\u00e2a Valley, an inland drainage basin and dust hotspot region located in the Moroccan Sahara, was chosen for a comprehensive analysis of sediment particle size and mineralogy. Different sediment type samples (n=\u200942) were collected, including paleo-sediments, paved surfaces, crusts, and dunes, and analysed for particle-size distribution (minimally and fully dispersed samples) and mineralogy. Furthermore, Fe sequential wet extraction was carried out to characterise the modes of occurrence of Fe, including Fe in Fe (oxyhydr)oxides, mainly from goethite and hematite, which are key to dust radiative effects; the poorly crystalline pool of Fe (readily exchangeable ionic Fe and Fe in nano-Fe oxides), relevant to dust impacts upon ocean biogeochemistry; and structural Fe. Results yield a conceptual model where both particle size and mineralogy are segregated by transport and deposition of sediments during runoff of water across the basin and by the precipitation of salts, which causes a sedimentary fractionation. The proportion of coarser particles enriched in quartz is higher in the highlands, while that of finer particles rich in clay, carbonates, and Fe oxides is higher in the lowland dust emission hotspots. There, when water ponds and evaporates, secondary carbonates and salts precipitate, and the clays are enriched in readily exchangeable ionic Fe, due to sorption of dissolved Fe by illite. The results differ from currently available mineralogical atlases and highlight the need for observationally constrained global high-resolution mineralogical data for mineral-speciated dust modelling. The dataset obtained represents an important resource for future evaluation of surface mineralogy retrievals from spaceborne spectroscopy.</p></article>", "keywords": ["Mineral dusts", "geology", "550", "QC1-999", "Climate", "01 natural sciences", "\u00c0rees tem\u00e0tiques de la UPC::Desenvolupament hum\u00e0 i sostenible::Enginyeria ambiental", "Pols minerals", "QD1-999", "Sahara", "0105 earth and related environmental sciences", "mineral dust", "S\u00e0hara", "info:eu-repo/classification/ddc/550", "ddc:550", "Physics", "Aire--Contaminaci\u00f3", "15. Life on land", "info:eu-repo/classification/udc/502.3/.7", "6. Clean water", "Earth sciences", "Chemistry", "13. Climate action", "Air--Pollution", "Desert dust", "aerosols"]}, "links": [{"href": "https://acp.copernicus.org/articles/23/15815/2023/acp-23-15815-2023.pdf"}, {"href": "https://doi.org/20.500.12556/RUNG-8752"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Atmospheric%20Chemistry%20and%20Physics", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.12556/RUNG-8752", "name": "item", "description": "20.500.12556/RUNG-8752", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.12556/RUNG-8752"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-12-22T00:00:00Z"}}, {"id": "20.500.11850/572789", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:29:50Z", "type": "Journal Article", "created": "2022-09-22", "title": "Ferrihydrite transformations in flooded paddy soils: rates, pathways, and product spatial distributions", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>The rate and pathway of ferrihydrite transformation in soil depends on the properties of the soil pore water and diffusion processes.</p></article>", "keywords": ["Chemistry", "Soil", "Minerals", "Iron", "Water", "Ferrous Compounds", "Ferric Compounds", "Oxidation-Reduction", "01 natural sciences", "6. Clean water", "0105 earth and related environmental sciences"]}, "links": [{"href": "http://pubs.rsc.org/en/content/articlepdf/2022/EM/D2EM00290F"}, {"href": "https://doi.org/20.500.11850/572789"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%3A%20Processes%20%26amp%3B%20Impacts", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.11850/572789", "name": "item", "description": "20.500.11850/572789", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.11850/572789"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-01-01T00:00:00Z"}}, {"id": "20.500.11850/618141", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:29:50Z", "type": "Journal Article", "created": "2023-06-09", "title": "Coprecipitation with Ferrihydrite Inhibits Mineralization of Glucuronic Acid in an Anoxic Soil", "description": "It is known thatthe association of soil organic matter(SOM) withiron minerals limits carbon mobilization and degradation in aerobicsoils and sediments. However, the efficacy of iron mineral protectionmechanisms under reducing soil conditions, where Fe(III)-bearing mineralsmay be used as terminal electron acceptors, is poorly understood.Here, we quantified the extent to which iron mineral protection inhibitsmineralization of organic carbon in reduced soils by adding dissolved \u00b9\u00b3C-glucuronic acid, a \u2075\u2077Fe-ferrihydrite-\u00b9\u00b3C-glucuronic acid coprecipitate, or pure \u2075\u2077Fe-ferrihydriteto anoxic soil slurries. In tracking the re-partitioning and transformationof \u00b9\u00b3C-glucuronic acid and native SOM, we find that coprecipitationsuppresses mineralization of \u00b9\u00b3C-glucuronic acid by 56%after 2 weeks (at 25 \u00b0C) and decreases to 27% after 6 weeks,owing to ongoing reductive dissolution of the coprecipitated \u2075\u2077Fe-ferrihydrite. Addition of both dissolved and coprecipitated \u00b9\u00b3C-glucuronic acid resulted in increased native SOM mineralization,but the reduced bioavailability of the coprecipitated versus dissolved \u00b9\u00b3C-glucuronic acid decreased the priming effect by 35%. Incontrast, the addition of pure \u2075\u2077Fe-ferrihydrite resultedin negligible changes in native SOM mineralization. Our results showthat iron mineral protection mechanisms are relevant for understandingthe mobilization and degradation of SOM under reducing soil conditions.", "keywords": ["Soil", "Minerals", "Iron", "organic carbon", "anoxic soils", "organic carbon; anoxic soils; mineralization; iron minerals", "mineralization", "Ferric Compounds", "Oxidation-Reduction", "iron minerals", "Carbon"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.3c01336"}, {"href": "https://doi.org/20.500.11850/618141"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.11850/618141", "name": "item", "description": "20.500.11850/618141", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.11850/618141"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-06-09T00:00:00Z"}}, {"id": "20.500.11850/638608", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:29:51Z", "type": "Journal Article", "created": "2023-10-10", "title": "Relating mineral\u2013organic matter stabilization mechanisms to carbon quality and age distributions using ramped thermal analysis", "description": "<p>             Organic carbon (OC) association with soil minerals stabilizes OC on timescales reflecting the strength of mineral\uffe2\uff80\uff93C interactions. We applied ramped thermal oxidation to subsoil B horizons with different mineral\uffe2\uff80\uff93C associations to separate OC according to increasing temperature of oxidation, i.e. thermal activation energy. Generally, OC released at lower temperatures was richer in bioavailable forms like polysaccharides, while OC released at higher temperatures was more aromatic. Organic carbon associated with pedogenic oxides was released at lower temperatures and had a narrow range of             14             C content. By contrast, N-rich compounds were released at higher temperatures from samples with 2\uffe2\uff80\uff89:\uffe2\uff80\uff891 clays and short-range ordered (SRO) amorphous minerals. Temperatures of release overlapped for SRO minerals and crystalline oxides, although the mean age of OC released was older for the SRO. In soils with more mixed mineralogy, the added presence of older OC released at temperatures greater than 450\uffc2\uffb0C from clays resulted in a broader distribution of OC ages within the sample, especially for soils rich in 2\uffe2\uff80\uff89:\uffe2\uff80\uff891 layer expandable clays such as smectite. While pedogenic setting affects mineral stability and absolute OC age, mineralogy controls the structure of OC age distribution within a sample, which may provide insight into model structures and OC dynamics under changing conditions.           </p>           <p>This article is part of the Theo Murphy meeting issue \uffe2\uff80\uff98Radiocarbon in the Anthropocene\uffe2\uff80\uff99.</p", "keywords": ["soil minerals", "Soil organic matter", "550", "py-GC/MS", "Articles", "Py-GC/MS", "Radiocarbon", "mineral-associated organic matter", "13. Climate action", "soil organic matter", "radiocarbon", "Mineral-associated organic matter", "radiocarbon; soil organic matter; mineral-associated organic matter; Py-GC/MS; Soil minerals", "Soil minerals"]}, "links": [{"href": "https://escholarship.org/content/qt17101110/qt17101110.pdf"}, {"href": "https://doi.org/20.500.11850/638608"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Philosophical%20Transactions%20of%20the%20Royal%20Society%20A%3A%20Mathematical%2C%20Physical%20and%20Engineering%20Sciences", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.11850/638608", "name": "item", "description": "20.500.11850/638608", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.11850/638608"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-10-09T00:00:00Z"}}, {"id": "20.500.11850/663192", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:29:51Z", "type": "Report", "title": "Vivianite formation and transformation processes in intertidal sediments and the influence of isomorphic substitution", "keywords": ["Earth sciences", "info:eu-repo/classification/ddc/550", "iron minerals; VIVIANITE (MINERALOGY); IRON PHOSPHATES (INORGANIC CHEMISTRY); Coastal biogeochemistry; mineral transformation; Redox geochemistry; M\u00f6ssbauer Spectroscopy; X-ray absorption spectroscopy; Field experiments; Laboratory experiments; iron biogeochemistry; Phosphorus cycling; X-Ray Diffraction"], "contacts": [{"organization": "Kubeneck, Luisa Jo\u00eblle; id_orcid0000-0003-1894-6809", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/20.500.11850/663192"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.11850/663192", "name": "item", "description": "20.500.11850/663192", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.11850/663192"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-01-01T00:00:00Z"}}, {"id": "20.500.11850/648128", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:29:51Z", "type": "Journal Article", "created": "2023-12-11", "title": "Controls on timescales of soil organic carbon persistence across sub\u2010Saharan Africa", "description": "Abstract<p>Given the importance of soil for the global carbon cycle, it is essential to understand not only how much carbon soil stores but also how long this carbon persists. Previous studies have shown that the amount and age of soil carbon are strongly affected by the interaction of climate, vegetation, and mineralogy. However, these findings are primarily based on studies from temperate regions and from fine\uffe2\uff80\uff90scale studies, leaving large knowledge gaps for soils from understudied regions such as sub\uffe2\uff80\uff90Saharan Africa. In addition, there is a lack of data to validate modeled soil C dynamics at broad scales. Here, we present insights into organic carbon cycling, based on a new broad\uffe2\uff80\uff90scale radiocarbon and mineral dataset for sub\uffe2\uff80\uff90Saharan Africa. We found that in moderately weathered soils in seasonal climate zones with poorly crystalline and reactive clay minerals, organic carbon persists longer on average (topsoil: 201\uffe2\uff80\uff89\uffc2\uffb1\uffe2\uff80\uff89130\uffe2\uff80\uff89years; subsoil: 645\uffe2\uff80\uff89\uffc2\uffb1\uffe2\uff80\uff89385\uffe2\uff80\uff89years) than in highly weathered soils in humid regions (topsoil: 140\uffe2\uff80\uff89\uffc2\uffb1\uffe2\uff80\uff8946\uffe2\uff80\uff89years; subsoil: 454\uffe2\uff80\uff89\uffc2\uffb1\uffe2\uff80\uff89247\uffe2\uff80\uff89years) with less reactive minerals. Soils in arid climate zones (topsoil: 396\uffe2\uff80\uff89\uffc2\uffb1\uffe2\uff80\uff89339\uffe2\uff80\uff89years; subsoil: 963\uffe2\uff80\uff89\uffc2\uffb1\uffe2\uff80\uff89669\uffe2\uff80\uff89years) store organic carbon for periods more similar to those in seasonal climate zones, likely reflecting climatic constraints on weathering, carbon inputs and microbial decomposition. These insights into the timescales of organic carbon persistence in soils of sub\uffe2\uff80\uff90Saharan Africa suggest that a process\uffe2\uff80\uff90oriented grouping of soils based on pedo\uffe2\uff80\uff90climatic conditions may be useful to improve predictions of soil responses to climate change at broader scales.</p", "keywords": ["clay mineralogy", "2. Zero hunger", "Minerals", "Carbon Sequestration", "550", "Subtropical", "African Soil Information Service; Afrotropics; clay mineralogy; climate change; mean C age; radiocarbon; subtropical", "mean C age", "15. Life on land", "Clay mineralogy", "Radiocarbon", "Carbon", "African Soil Information Service", "Soil", "climate change", "subtropical", "13. Climate action", "radiocarbon", "Climate change", "Mean C age", "Afrotropics", "Research Articles", "Africa South of the Sahara"]}, "links": [{"href": "https://escholarship.org/content/qt2qk876dq/qt2qk876dq.pdf"}, {"href": "https://doi.org/20.500.11850/648128"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Global%20Change%20Biology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.11850/648128", "name": "item", "description": "20.500.11850/648128", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.11850/648128"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-12-11T00:00:00Z"}}, {"id": "20.500.11850/648810", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:29:51Z", "type": "Journal Article", "title": "Transformation of jarosite and iron oxyhydroxides in acid sulfate paddy soils", "description": "Open AccessMinerals containing Fe are ubiquitous in soils. By providing an abundance of sites for the sorption and incorporation of major and trace elements, Fe minerals can govern the fate and behaviour of numerous pollutants and nutrients in soils. Furthermore, the reactivity of Fe in redox-dynamic soils produces a web of Fe mineral transformation processes with broad consequences for element cycling. The importance of Fe cycling is no exception in acid sulfate soils, although the high sulfur and low pH conditions produce unique Fe mineral transformation processes and compositions. In acid sulfate soils, jarosite, an Fe-K hydroxysulfate mineral, and ferrihydrite, a common short-range-ordered Fe oxyhydroxide mineral, play a central role in the pedological development of active and post-active acid sulfate soils. Soil pH and the dynamics of metals, such as aluminium, are key to understanding the toxicity of acid sulfate soils and can be directly influenced by jarosite and ferrihydrite transformation processes.   Although the transformation of Fe minerals is a key component of biogeochemical processes in redox-active soils, the variables that control the rates and pathways of Fe mineral transformations in soil remain uncertain. The uncertainty arises from the difficulty of tracing molecular processes within a matrix of diverse soil components. Iron minerals are regularly characterised in soils, but the processes that explain the Fe mineral composition of soils cannot be easily resolved. An alternative approach is to perform simplified experiments, such as mixed mineral suspension experiments, under controlled laboratory conditions, to test the effect of individual variables. These systems often use synthetic minerals, although relatively pure jarosite may also be isolated from soils and tested in mixed suspension experiments. While useful to derive mechanistic understanding, the measured outcomes of mixed suspension experiments may not represent the rates and products of transformations that occur in soils.  Therefore, the objective of this thesis was to gain new understanding of the stability and transformation of jarosite and ferrihydrite in acid sulfate soils by developing novel experimental techniques to follow the transformation of synthetic jarosite and ferrihydrite directly in soils. The central theme of the thesis is the comparison of jarosite and aluminium-substituted jarosite transformation in experimental media of increasing complexity. The experiments are performed under conditions that are relevant to rice paddy soils because of the importance of rice in global food production, and the unique management of rice paddies whereby regular flooding during the growing season produces distinct redox cycles. In Thailand, large areas of the Chao Phraya River delta are cultivated as rice paddies despite being acid sulfate soils, providing a suitable site to observe the effects of regular redox cycling on the biogeochemistry of Fe minerals in acid sulfate soils.  The thesis begins with characterisation of synthetic and natural jarosite mineral composition and reactivity. Spectroscopic techniques (Raman spectroscopy, M\u00f6ssbauer spectroscopy and Energy-dispersive X-ray spectrometry) and X-ray diffraction (XRD) were used to assess the element substitution of mineral samples from two jarosite-alunite synthetic solid solution series. The same characterisation techniques were then applied to a sample of jarosite from an acid sulfate soil in Thailand has a natural Al-for-Fe substitution. The mineral characterisation was followed by a transformation experiment in a mixed-suspension system, similar to experimental designs that have been previously used to study mineral transformation processes. The experiment followed the transformation of the natural jarosite sample from an acid sulfate soil in Thailand and three jarosite samples with variable amounts of Al substitution. The reaction solution mimicked the pH (circumneutral) and Fe(II) content (up to 1:1 ratio of Fe(II) in solution to Fe(III) in solids) of flooded acid sulfate soils. Furthermore, using a 57Fe tracer, the simultaneous transformation processes that explained the distribution of mineral products could be resolved from one another. The transformation experiment revealed the relative reactivity of the minerals in the presence of Fe(II), and created a baseline that could be used to compare traditional mixed-suspension experiments with transformations in complex media such as soil.   To advance mineral transformation experiments towards studies in which transformation processes may be followed within a soil matrix, several novel techniques were developed. In a first step, ferrihydrite was incubated for up to twelve weeks in microcosms, each containing 300 g of 5 mM CaCl2 solution and 250 g of one of five paddy soils. The ferrihydrite was buried in the soil within a mesh bag (polyethel terephthalate, 51 \u03bcm pores, 30 mm x 12 mm x 3 mm) that allowed free contact between the synthetic minerals and the pore water, but separated the minerals from direct contact with the soil matrix. The mineral products of the transformation were identified and quantified by Rietveld fitting of XRD patterns. Further, the spatial arrangements of the ferrihydrite and transformation products were measured after two weeks by Raman spectroscopy, which could be used to assess the effects of pore water chemistry and diffusion processes on mineral transformation in the mesh bags. The second step involved measuring jarosite and Al-substituted jarosite transformation in flooded topsoil and subsoils from a rice paddy located on the Bangkok Plain in Central Thailand using an adaptation of the mesh bag method. To test the effect of pore water on the transformation of jarosite in soil, mesh bags were filled with synthetic jarosite and aluminium-jarosite and incubated in topsoils and subsoils, both in laboratory mesocosms and directly in the field. Then, the effect of the soil matrix was tested by completing a parallel experiment using mesh bags containing soil that was pre-enriched with synthetic 57Fe-labelled jarosite and aluminium-substituted jarosite. To facilitate the deployment and collection of small mesh bags in large soil volumes, the mesh bags were inserted into soils using custom-designed 3D-printed sample holders. At three timepoints within twelve weeks, one set of mesh bags were removed from the soil. Transformation products were identified and quantified in the pure jarosite and aluminium-jarosite mesh bags using Rietveld fitting of XRD patterns, while the fate of the 57Fe in enriched soil mesh bags was traced using 57Fe M\u00f6ssbauer spectroscopy.   Performing experiments in increasingly complex media provides an insight into the effect of experimental design on the observation of Fe mineral transformations and provides new information regarding the transformation rates and pathways of jarosite and ferrihydrite within full complexity of soil media. Indeed, this thesis demonstrates that the complex chemistry, biological activity, and physical arrangement of components in the soil have strong effects on the rate and products of jarosite and ferrihydrite transformation processes. The transformation of jarosite and Al-substituted jarosite in mixed-suspension experiments presented in this thesis, in agreement with previous mixed-suspension experiments on both jarosite and ferrihydrite, occurred within a matter of hours. By contrast, the rate of ferrihydrite, jarosite and Al-jarosite transformation in soil pore and in direct contact with the soil matrix occurred over the course of several weeks or months. In the ferrihydrite mesh bags, slow ferrihydrite transformation kinetics on the outer rim of the mesh bag, and deep in the core of the mesh bag, indicated that the sorption of chemical components of soil pore water and diffusion limitations of Fe(II) in pore water could be reasons for the slower rates of transformation in soil. In addition, both Al-for-Fe substitution and Fe(II) concentration in solution were important factors that altered the rate of mineral transformation.  The different incubation conditions for jarosite and Al-jarosite also altered the products of the transformation. Whereas the hydrolysis of jarosite in the absence of Fe(II) resulted primarily in the formation of ferrihydrite, jarosite transformation in the presence of Fe(II) led to ferrihydrite, goethite and lepidocrocite formation. The Fe oxyhydroxide products were consistent with Fe(II)-catalysed transformation, and Fe(II)-catalysed recrystallisation of jarosite may have occurred concurrently. Aluminium-for-iron substitution hindered the formation of lepidocrocite formation in favour of ferrihydrite and goethite. Similar product phases occurred when jarosite and Al-jarosite were reacted with pore water from acid sulfate soils, indicating that similar transformation pathways may define the mineral products of jarosite transformations when the jarosite occurs as accumulations of pure mineral in soil. However, non- or poorly crystalline phases predominated in the transformation products when jarosite or Al-jarosite were incubated in direct contact with the soil matrix, indicating that the transformation of jarosite under these circumstances was governed by different pathways and processes.  The new insights into the transformation of ferrihydrite, jarosite and Al-jarosite in acid sulfate soils demonstrate that phases previously considered meta-stable may participate in the biogeochemistry of soil over period of several months. In the context of rice cultivation, the transformation processes may affect the biogeochemistry of the soils throughout the growing season. The formation of poorly crystalline minerals following the transformation in flooded soils may have positive consequences on the sequestration of other trace and major elements that were associated with the ferrihydrite, jarosite or Al-jarosite prior to the transformation. However, the stabilisation of reduced Fe in the soil matrix may have the opposite effect, promoting the mobility of other ions in solution. The methods used to incubate jarosite and ferrihydrite in soils are easily adaptable to new experimental questions involving the behaviour of Fe-bearing minerals in soil. Therefore, the findings open up a new class of experiments within environmental mineralogy and biogeochemistry, that can help to uncover the processes that occur in the environment and explain the natural variation in the composition of Fe phases in soil.", "keywords": ["jarosite", "iron biogeochemistry", "soil chemistry", "acid sulfate soil", "laboratory study", "ferrihydrite", "soil", "soil incubation", "redox chemistry", "goethite", "iron minerals", "2. Zero hunger", "soil biogeochemistry", "info:eu-repo/classification/ddc/550", "M\u00f6ssbauer spectroscopy", "rice paddy soil", "15. Life on land", "6. Clean water", "Earth sciences", "lepidocrocite", "field study", "13. Climate action", "Raman spectroscopy", "iron oxyhydroxide", "mineral transformation", "iron minerals; mineral transformation; soil; soil chemistry; soil mineralogy; soil biogeochemistry; redox chemistry; iron biogeochemistry; acid sulfate soil; rice paddy soil; jarosite; ferrihydrite; goethite; lepidocrocite; iron oxyhydroxide; M\u00f6ssbauer spectroscopy; Raman spectroscopy; field study; laboratory study; soil incubation", "soil mineralogy"], "contacts": [{"organization": "Grigg, Andrew R.C.", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/20.500.11850/648810"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Thesis/Dissertation", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.11850/648810", "name": "item", "description": "20.500.11850/648810", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.11850/648810"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-01-01T00:00:00Z"}}, {"id": "20.500.11850/693515", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:29:52Z", "type": "Journal Article", "created": "2024-07-27", "title": "Stability and transformation of jarosite and Al-substituted jarosite in an acid sulfate paddy soil under laboratory and field conditions", "description": "Open AccessGeochimica et Cosmochimica Acta, 382", "keywords": ["Redox", "2. Zero hunger", "Soil incubation", "Mossbauer spectroscopy", "Iron minerals; Mossbauer spectroscopy; Redox; Rice paddy; Soil incubation", "Rice paddy", "15. Life on land", "Iron minerals", "6. Clean water"]}, "links": [{"href": "https://doi.org/20.500.11850/693515"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Geochimica%20et%20Cosmochimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.11850/693515", "name": "item", "description": "20.500.11850/693515", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.11850/693515"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-10-01T00:00:00Z"}}, {"id": "20.500.11850/717357", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:29:52Z", "type": "Report", "title": "In Situ Vivianite Formation in Intertidal Sediments: Ferrihydrite-Adsorbed P Triggers Vivianite Formation", "description": "Open AccessISSN:0013-936X", "keywords": ["Mo\u0308ssbauer spectroscopy; phosphorus cycling; coastal sediments; iron minerals"], "contacts": [{"organization": "Kubeneck, Luisa Jo\u00eblle; id_orcid0000-0003-1894-6809, Rothwell, Katherine A., Notini de Andrade, Luiza; id_orcid0000-0003-2972-6588, ThomasArrigo, Laurel K., Schulz, Katrin; id_orcid0000-0001-9608-0882, Fantappi\u00e8, Giulia, Joshi, Prachi; id_orcid0000-0001-5954-0309, Huthwelker, Thomas, Kretzschmar, Ruben; id_orcid0000-0003-2587-2430,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/20.500.11850/717357"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.11850/717357", "name": "item", "description": "20.500.11850/717357", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.11850/717357"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2025-01-14T00:00:00Z"}}, {"id": "20.500.12556/RUNG-9073", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-06-27T16:29:53Z", "type": "Journal Article", "created": "2022-11-07", "title": "Insights into the single particle composition, size, mixing state and aspect ratio of freshly emitted mineral dust from field measurements in the Moroccan Sahara using electron microscopy", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>Abstract. The chemical and morphological properties of mineral dust aerosols emitted by wind erosion from arid and semi-arid regions influence climate, ocean and land ecosystems, air quality, and multiple socio-economic sectors. However, there is an incomplete understanding of the emitted dust particle size distribution (PSD) in terms of its constituent minerals that typically result from the fragmentation of soil aggregates during wind erosion. The emitted dust PSD affects the duration of particle transport and thus each mineral\u2019s global distribution, along with its specific effect upon climate. This lack of understanding is largely due to the scarcity of relevant in situ measurements in dust sources. To advance our understanding of the physicochemical properties of the emitted dust PSD, we present insights into the elemental composition and morphology of individual dust particles collected during the FRontiers in dust minerAloGical coMposition and its Effects upoN climaTe (FRAGMENT) field campaign in the Moroccan Sahara in September 2019. We analyzed more than 300,000 freshly emitted individual particles by performing offline analysis in the laboratory using Scanning Electron Microscopy (SEM) coupled with Energy-Dispersive X-ray Spectrometry (EDX). Eight major particle-type classes were identified where clay minerals make up the majority of the analyzed particles by number, with carbonates and quartz contributing to a lesser extent. We provide an exhaustive analysis of the size distribution and potential mixing state of different particle types, focusing largely on iron-rich (Fe-oxi/hydroxides) and feldspar particles, which are key to the effects of dust upon radiation and clouds. Nearly pure or externally mixed Fe-oxi/hydroxides are present only in diameters smaller than 2 \u00b5m and mainly below 1 \u00b5m. Fe-oxi/hydroxides tend to be increasingly internally mixed with other minerals, especially clays, as particle size increases, i.e., the volume fraction of Fe-oxi/hydroxides in aggregates decreases with particle size. Pure (externally-mixed) feldspar grains represented 3.7 % of all the particles, of which we estimated about a quarter to be K-feldspar. The externally-mixed total feldspar and K-feldspar abundances are relatively invariant with particle size, in contrast to the increasing abundance of feldspar-like (internally-mixed) aggregates with particle size. We also found that overall the median aspect ratio is rather constant across particle size and mineral groups, although we obtain slightly higher aspect ratios for internally-mixed particles. The detailed information on the composition of freshly emitted individual dust particles along with the quantitative analysis of their mixing state presented here can be used to constrain climate models including mineral species in their representation of the dust cycle.</p></article>", "keywords": ["Atmospheric chemistry", "550", "QC1-999", "http://metadata.un.org/sdg/3", "Mineral dust", "01 natural sciences", "Climate models", "\u00c0rees tem\u00e0tiques de la UPC::Enginyeria agroaliment\u00e0ria::Ci\u00e8ncies de la terra i de la vida::Climatologia i meteorologia", "Aerosols Measurement", "Pols minerals", "QD1-999", "Ensure healthy lives and promote well-being for all at all ages", "0105 earth and related environmental sciences", "mineral dust", "info:eu-repo/classification/ddc/550", "electron microscopy", "ddc:550", "Physics", "15. Life on land", "info:eu-repo/classification/udc/502.3/.7", "Pollution", "Moroccan Sahara", "Earth sciences", "Chemistry", "13. Climate action", "Mineral dust particles", "Air quality", "Desert dust"]}, "links": [{"href": "https://acp.copernicus.org/articles/23/3861/2023/acp-23-3861-2023.pdf"}, {"href": "https://acp.copernicus.org/articles/23/3861/2023/acp-23-3861-2023-supplement.pdf"}, {"href": "https://doi.org/20.500.12556/RUNG-9073"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Atmospheric%20Chemistry%20and%20Physics", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.12556/RUNG-9073", "name": "item", "description": "20.500.12556/RUNG-9073", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.12556/RUNG-9073"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-11-07T00:00:00Z"}}, {"id": "2078.1/235031", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-06-27T16:29:58Z", "type": "Journal Article", "created": "2020-06-08", "title": "The next generation of climate model should account for the evolution of mineral-organic interactions with permafrost thaw", "description": "The Earth\u2019s high latitude regions are warming twice as fast as the global average which enhances the thawing of permafrost, i.e. the perennially frozen ground which underlies about 25% of the exposed land surface in the Northern Hemisphere (Brown et al 1998). Permafrost thaw exposes previously frozen organic carbon (OC) to microbial decomposition with subsequent emission of the greenhouse gases carbon dioxide (CO2) and methane (CH4) into the atmosphere, creating positive feedback on global warming, i.e. the permafrost carbon feedback (Schuur et al 2015). Permafrost contains 1460\u20131600 GtC, almost twice the C in the atmosphere (IPCC 2019), and 15 \u00b1 3% of that OC stock could be emitted as greenhouse gases by 2100 (Schuur et al 2015). On an annual basis, this would represent 22%\u201331% of the current anthropogenic C emissions (considering anthropogenic C emissions from IPCC 2019). Most of that C would be emitted as CO2 but it is estimated that 2.3% of the permafrost C emissions will be released as CH4 (Schuur et al 2015). This has implications for the Earth\u2019s radiative balance, given the larger global warming potential of CH4 at the century time scale. Therefore, evidence is mounting that permafrost thaw represents a tipping element in the Earth climate system (Lenton et al 2019). Yet uncertainties are associated with how this will unfold.", "keywords": ["organic", "Science", "QC1-999", "Environmental technology. Sanitary engineering", "01 natural sciences", "7. Clean energy", "arctic", "GE1-350", "Renewable Energy", "TD1-1066", "General Environmental Science", "0105 earth and related environmental sciences", "Sustainability and the Environment", "carbon", "organic carbon", "Physics", "Environmental and Occupational Health", "Q", "minerals", "15. Life on land", "artic", "Environmental sciences", "13. Climate action", "Public Health", "thaw", "carbon emissions", "permafrost"], "contacts": [{"organization": "Sophie Opfergelt", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/2078.1/235031"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Research%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2078.1/235031", "name": "item", "description": "2078.1/235031", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2078.1/235031"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-08-21T00:00:00Z"}}, {"id": "21.11116/0000-0009-94BE-A", "type": "Feature", "geometry": null, "properties": {"license": "Closed Access", "updated": "2026-06-27T16:30:00Z", "type": "Journal Article", "created": "2021-12-04", "title": "Beyond bulk: Density fractions explain heterogeneity in global soil carbon abundance and persistence", "description": "Abstract<p>Understanding the controls on the amount and persistence of soil organic carbon (C) is essential for predicting its sensitivity to global change. The response may depend on whether C is unprotected, isolated within aggregates, or protected from decomposition by mineral associations. Here, we present a global synthesis of the relative influence of environmental factors on soil organic C partitioning among pools, abundance in each pool (mg C g\uffe2\uff88\uff921\uffc2\uffa0soil), and persistence (as approximated by radiocarbon abundance) in relatively unprotected particulate and protected mineral\uffe2\uff80\uff90bound pools. We show that C within particulate and mineral\uffe2\uff80\uff90associated pools consistently differed from one another in degree of persistence and relationship to environmental factors. Soil depth was the best predictor of C abundance and persistence, though it accounted for more variance in persistence. Persistence of all C pools decreased with increasing mean annual temperature (MAT) throughout the soil profile, whereas persistence increased with increasing wetness index (MAP/PET) in subsurface soils (30\uffe2\uff80\uff93176\uffc2\uffa0cm). The relationship of C abundance (mg C g\uffe2\uff88\uff921\uffc2\uffa0soil) to climate varied among pools and with depth. Mineral\uffe2\uff80\uff90associated C in surface soils (&lt;30\uffc2\uffa0cm) increased more strongly with increasing wetness index than the free particulate C, but both pools showed attenuated responses to the wetness index at depth. Overall, these relationships suggest a strong influence of climate on soil C properties, and a potential loss of soil C from protected pools in areas with decreasing wetness. Relative persistence and abundance of C pools varied significantly among land cover types and soil parent material lithologies. This variability in each pool's relationship to environmental factors suggests that not all soil organic C is equally vulnerable to global change. Therefore, projections of future soil organic C based on patterns and responses of bulk soil organic C may be misleading.</p", "keywords": ["2. Zero hunger", "Minerals", "Soil", "13. Climate action", "Climate", "Temperature", "0401 agriculture", " forestry", " and fisheries", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "Carbon", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/21.11116/0000-0009-94BE-A"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Global%20Change%20Biology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "21.11116/0000-0009-94BE-A", "name": "item", "description": "21.11116/0000-0009-94BE-A", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/21.11116/0000-0009-94BE-A"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-12-16T00:00:00Z"}}, {"id": "2117/393811", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:30:03Z", "type": "Journal Article", "created": "2023-02-20", "title": "Modeling dust mineralogical composition: sensitivity to soil mineralogy atlases and their expected climate impacts", "description": "<?xml version='1.0' encoding='UTF-8'?><article><p>Abstract. Soil dust aerosols are a key component of the climate system, as they interact with short- and long-wave radiation, alter cloud formation processes, affect atmospheric chemistry and play a role in biogeochemical cycles by providing nutrient inputs such as iron and phosphorus. The influence of dust on these processes depends on its physico-chemical properties, which far from being homogeneous, are shaped by its regionally varying mineral composition. The relative amount of minerals in dust depends on the source region and shows a large geographical variability. However, many state-of-the-art Earth System Models (ESMs), upon which climate analyses and projections rely, still consider dust mineralogy as invariant. The explicit representation of minerals in ESMs is more hindered by our limited knowledge of the global soil composition along with the resulting size-resolved airborne mineralogy than by computational constraints. In this work, we introduce an explicit mineralogy representation within the state-of-the-art atmosphere-chemistry model MONARCH. We review and compare two existing soil mineralogy datasets, which remain a source of uncertainty for dust mineralogy modelling, and provide an evaluation of multi-annual simulations against available mineralogy observations. Soil mineralogy datasets are based on measurements performed after wet sieving, which breaks the aggregates found in the parent soil. Our model predicts the emitted particle size distribution (PSD) in terms of its constituent minerals based on Brittle Fragmentation Theory (BFT), which reconstructs the emitted mineral aggregates destroyed by wet sieving. Our simulations broadly reproduce the most abundant mineral fractions, independently of the soil composition data used. Feldspars and calcite are highly sensitive to the soil mineralogy map, mainly due to the different assumptions made in each soil dataset to extrapolate a handful of soil measurements to arid and semiarid regions worldwide. For the least abundant or more difficult to determine minerals, such as the iron oxides, uncertainties in soil mineralogy yield differences in annual mean aerosol mass fractions of up to \u223c100 %. Although BFT restores coarse aggregates including phyllosilicates that usually break during soil analysis, we still identify an overestimation of coarse quartz mass fractions (above 2 \u00b5m in diameter). In a dedicated experiment, we estimate the fraction of dust with undetermined composition as given by a soil map, which makes a \u223c10 % of the emitted dust mass at the global scale, and can be regionally larger. Changes in the underlying soil mineralogy impact our estimates of climate-relevant variables, particularly affecting the regional variability of the single scattering albedo at solar wavelengths, or the total iron deposited over oceans. All in all, this assessment represents a baseline for future model experiments including new mineralogical maps constrained by high quality spaceborne hyperspectral measurements, such as those arising from the NASA EMIT mission.</p></article>", "keywords": ["Mineral dusts", "[SDU.OCEAN]Sciences of the Universe [physics]/Ocean", "info:eu-repo/classification/ddc/550", "550", "Atmosphere", "ddc:550", "[SDU.OCEAN] Sciences of the Universe [physics]/Ocean", " Atmosphere", "Physics", "QC1-999", "Climatologia -- Models matem\u00e0tics", "Aerosols atmosf\u00e8rics", "15. Life on land", "Atmospheric aerosols", "[SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces", " environment", "Climatology -- Mathematical models", "\u00c0rees tem\u00e0tiques de la UPC::Desenvolupament hum\u00e0 i sostenible::Enginyeria ambiental", "Earth sciences", "Chemistry", "13. Climate action", "[SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces", "Pols minerals", "environment", "QD1-999"]}, "links": [{"href": "https://acp.copernicus.org/articles/23/8623/2023/acp-23-8623-2023.pdf"}, {"href": "https://doi.org/2117/393811"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Atmospheric%20Chemistry%20and%20Physics", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2117/393811", "name": "item", "description": "2117/393811", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2117/393811"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-02-20T00:00:00Z"}}, {"id": "2117/400337", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:30:03Z", "type": "Journal Article", "created": "2024-01-21", "title": "On-orbit calibration and performance of the EMIT imaging spectrometer", "description": "Open AccessArticle signat per 56 autors: David R. Thompson, Robert O. Green, Christine Bradley, Philip G. Brodrick, Natalie Mahowald, Eyal Ben Dor, Matthew Bennett, Michael Bernas, Nimrod Carmon, K. Dana Chadwick, Roger N. Clark, Red Willow Coleman, Evan Cox, Ernesto Diaz, Michael L. Eastwood, Regina Eckert, Bethany L. Ehlmann, Paul Ginoux, Mar\u00eda Gon\u00e7alves Ageitos, Kathleen Grant, Luis Guanter, Daniela Heller Pearlshtien, Mark Helmlinger, Harrison Herzog, Todd Hoefen, Yue Huang, Abigail Keebler, Olga Kalashnikova, Didier Keymeulen, Raymond Kokaly, Martina Klose, Longlei Li, Sarah R. Lundeen, John Meyer, Elizabeth Middleton, Ron L. Miller, Pantazis Mouroulis, Bogdan Oaida, Vincenzo Obiso, Francisco Ochoa, Winston Olson-Duvall, Gregory S. Okin, Thomas H. Painter, Carlos P\u00e9rez Garc\u00eda-Pando, Randy Pollock, Vincent Realmuto, Lucas Shaw, Peter Sullivan, Gregg Swayze, Erik Thingvold, Andrew K. Thorpe, Suresh Vannan, Catalina Villarreal, Charlene Ung, Daniel W. Wilson, Sander Zandbergen.", "keywords": ["Mineral dusts", "Teledetecci\u00f3", "550", "Radiative forcing", "7. Clean energy", "Validation", "\u00c0rees tem\u00e0tiques de la UPC::F\u00edsica::Astronomia i astrof\u00edsica", "Spectrometer--Calibration", "Pols minerals", "Visible-shortwave infrared spectroscopy", "info:eu-repo/classification/ddc/550", "ddc:550", "International space station", "Remote sensing", "Mineralogy", "Espect\u00f2metres--Calibratge", "Imaging spectroscopy", "EMIT", "Earth sciences", "Atmospheric correction", "\u00c0rees tem\u00e0tiques de la UPC::Enginyeria de la telecomunicaci\u00f3::Radiocomunicaci\u00f3 i exploraci\u00f3 electromagn\u00e8tica::Teledetecci\u00f3", "13. Climate action", "Hyperspectral imagery", "Calibration", "Mineral dust cycle", "NASA"]}, "links": [{"href": "https://doi.org/2117/400337"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Remote%20Sensing%20of%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2117/400337", "name": "item", "description": "2117/400337", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2117/400337"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-03-01T00:00:00Z"}}, {"id": "2117/401602", "type": "Feature", "geometry": null, "properties": {"license": "Restricted", "updated": "2026-06-27T16:30:03Z", "type": "Journal Article", "created": "2023-05-15", "title": "Performance and Early Results from the Earth Surface Mineral Dust Source Investigation (EMIT) Imaging Spectroscopy Mission", "description": "RestrictedThe authors gratefully acknowledge all the elements of the National Aeronautics and Space Administration, our partners, and the science community who have contributed to the development of the EMIT mission. EMIT is supported by the National Aeronautics and Space Administration Earth Venture Instrument Program under the Earth Science Division of the Science Mission Directorate. This research was performed at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration.", "keywords": ["Mineral dusts", "550", "500", "15. Life on land", "7. Clean energy", "Spectrometer", "3. Good health", "Earth (Planet)--Surface", "Espect\u00f2metres", "13. Climate action", "Terra (Planeta)--Superf\u00edcie", "11. Sustainability", "\u00c0rees tem\u00e0tiques de la UPC::F\u00edsica::Astronomia i astrof\u00edsica", "14. Life underwater", "Pols minerals"]}, "links": [{"href": "http://xplorestaging.ieee.org/ielx7/10115529/10115530/10115851.pdf?arnumber=10115851"}, {"href": "https://doi.org/2117/401602"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2023%20IEEE%20Aerospace%20Conference", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2117/401602", "name": "item", "description": "2117/401602", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2117/401602"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-03-04T00:00:00Z"}}, {"id": "3017990436", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-06-27T16:30:39Z", "type": "Journal Article", "title": "the splash action group towards standardized sampling strategies in permafrost science", "description": "The Action Group called \u2018Standardized methods across Permafrost Landscapes: from Arctic Soils to Hydrosystems\u2019 (SPLASH) is a community-driven effort aiming to provide a suite of standardized field strategies for sampling mineral and organic components in soils, sediments, and water across permafrost landscapes. This unified approach will allow data from different landscape interfaces, field locations and seasons to be shared and compared, thus improving our understanding of the processes occurring during lateral transport in circumpolar Arctic watersheds.    Citation: Bouchard F, Agnan Y, Broder L, et al. The SPLASH Action Group \u2013 Towards standardized sampling strategies in permafrost science. Adv Polar Sci, 2020, 31 (3): 153-155, doi: 10.13679/j.advps.2020.0009    Note: Queries and discussions on this article should be made by E-mail directly with the corresponding author.", "keywords": ["Aquatic systems", "Minerals", "[SDU.STU]Sciences of the Universe [physics]/Earth Sciences", "lateral transport", "Terrestrial", "[SDV.SA.SDS]Life Sciences [q-bio]/Agricultural sciences/Soil study", "Biogeochemistry", "15. Life on land", "minerals", "Lateral transport", "13. Climate action", "biogeochemistry", "aquatic systems", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "Soils", "Organic matter", "Cryosphere", "[SDV.SA.SDS] Life Sciences [q-bio]/Agricultural sciences/Soil study", "soils", "organic matter"]}, "links": [{"href": "https://doi.org/3017990436"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Advances%20in%20Polar%20Science", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "3017990436", "name": "item", "description": "3017990436", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/3017990436"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-01-01T00:00:00Z"}}, {"id": "37271832", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-27T16:31:12Z", "type": "Journal Article", "created": "2023-06-07", "title": "No detectable upper limit of mineral\u2010associated organic carbon in temperate agricultural soils", "description": "Abstract<p>Soil organic carbon (SOC) sequestration is a promising climate change mitigation option. In this context, the formation of the relatively long\uffe2\uff80\uff90lived mineral\uffe2\uff80\uff90associated organic carbon (MAOC) is key. To date, soils are considered to be limited in their ability to accumulate MAOC, mainly by the amount of clay and silt particles present. Using the comprehensive German Agricultural Soil Inventory, we selected 189 samples with a wide range of SOC (5\uffe2\uff80\uff93118\uffe2\uff80\uff89g\uffe2\uff80\uff89kg\uffe2\uff88\uff921) and clay contents (30\uffe2\uff80\uff93770\uffe2\uff80\uff89g\uffe2\uff80\uff89kg\uffe2\uff88\uff921) to test whether there is a detectable upper limit of MAOC content. We found that the proportion of MAOC was surprisingly stable for soils under cropland and grassland use across the whole range of bulk SOC contents. Soil texture influenced the slope of the relationship between bulk SOC and MAOC, but no upper limit was observed in any texture class. Also, C content in the fine fraction (g\uffe2\uff80\uff89C\uffe2\uff80\uff89kg\uffe2\uff88\uff921 fraction) was negatively correlated to fine fraction content (g\uffe2\uff80\uff89kg\uffe2\uff88\uff921 bulk soil). Both findings challenge the notion that MAOC accumulation is limited by soil fine fraction content per se.</p", "keywords": ["2. Zero hunger", "Soil", "Carbon Sequestration", "Minerals", "13. Climate action", "Clay", "0401 agriculture", " forestry", " and fisheries", "Agriculture", "04 agricultural and veterinary sciences", "15. 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(2023)\u201d", "description": "In this response to a letter to the editor, we provide evidence that the findings regarding a non-detectable limit of mineral-associated organic carbon as published in Begill et al. (2023) are robust. This is mainly done by showing that no methodological bias was present and that the main correlation was not driven by a few exceptional soils.", "keywords": ["Soil", "Minerals", "Carbon Sequestration", "15. 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