Residual concentrations of glyphosate and its main transformation product aminomethylphosphonic acid (AMPA) are often observed in soils. The factors controlling their biodegradation are currently not well understood. We analyzed sorption\uffe2\uff80\uff90limited biodegradation of glyphosate and AMPA in soil with a set of microcosm experiments. A mechanistic model that accounts for equilibrium and kinetic sorption facilitated interpretation of the experimental results. Both compounds showed a biphasic dissipation with an initial fast (up to Days 7\uffe2\uff80\uff9310) and subsequent slower transformation rate, pointing to sorption\uffe2\uff80\uff90limited degradation. Glyphosate transformation was well described by considering only equilibrium sorption. Model simulations suggested that only 0.02\uffe2\uff80\uff930.13% of total glyphosate was present in the soil solution and thus bioavailable. Glyphosate transformation was rapid in solution (time required for 50 % dissipation of the total initially added chemical [DT50]\uffc2\uffa0=\uffc2\uffa03.9\uffc2\uffa0min), and, despite strong equilibrium sorption, total glyphosate in soil dissipated quickly (DT50\uffc2\uffa0=\uffc2\uffa02.4\uffc2\uffa0d). Aminomethylphosphonic acid dissipation kinetics could only be described when considering both equilibrium and kinetic sorption. In comparison to glyphosate, the model simulations showed that a higher proportion of total AMPA was dissolved and directly bioavailable (0.27\uffe2\uff80\uff933.32%), but biodegradation of dissolved AMPA was slower (DT50\uffc2\uffa0=\uffc2\uffa01.9\uffc2\uffa0h). The model\uffe2\uff80\uff90based data interpretation suggests that kinetic sorption strongly reduces AMPA bioavailability, leading to increased AMPA persistence in soil (DT50\uffc2\uffa0=\uffc2\uffa012\uffc2\uffa0d). Thus, strong sorption combined with rapid degradation points to low risks of glyphosate leaching by vertical transport through soil in the absence of preferential flow. Ecotoxicological effects on soil microorganisms might be reduced. In contrast, AMPA persists, rendering these risks more likely.Natural products present an environmentally attractive alternative to synthetic pesticides which have been implicated in the off\uffe2\uff80\uff90target effect. Currently, the assessment of pesticide toxicity on soil microorganisms relies on the OECD 216 N transformation assay (OECD stands for the Organisation Economic Co\uffe2\uff80\uff90operation and Development, which is a key international standard\uffe2\uff80\uff90setting organisation). We tested the hypotheses that (i) the OECD 216 assay fails to identify unacceptable effects of pesticides on soil microbiota compared to more advanced molecular and standardized tests, and (ii) the natural products tested (dihydrochalcone, isoflavone, aliphatic phenol, and spinosad) are less toxic to soil microbiota compared to a synthetic pesticide compound (3,5\uffe2\uff80\uff90dichloraniline). We determined the following in three different soils: (i) ammonium (NH4+) and nitrate (NO3\uffe2\uff88\uff92) soil concentrations, as dictated by the OECD 216 test, and (ii) the abundance of phylogenetically (bacteria and fungi) and functionally distinct microbial groups [ammonia\uffe2\uff80\uff90oxidizing archaea (AOA) and bacteria (AOB)] using quantitative polymerase chain reaction (q\uffe2\uff80\uff90PCR).
RESULTSAll pesticides tested exhibited limited persistence, with spinosad demonstrating the highest persistence. None of the pesticides tested showed clear dose\uffe2\uff80\uff90dependent effects on NH4+ and NO3\uffe2\uff88\uff92 levels and the observed effects were <25% of the control, suggesting no unacceptable impacts on soil microorganisms. In contrast, q\uffe2\uff80\uff90PCR measurements revealed (i) distinct negative effects on the abundance of total bacteria and fungi, which were though limited to one of the studied soils, and (ii) a significant reduction in the abundance of both AOA and AOB across soils. This reduction was attributed to both natural products and 3,5\uffe2\uff80\uff90dichloraniline.
CONCLUSIONOur findings strongly advocate for a revision of the current regulatory framework regarding the toxicity of pesticides to soil microbiota, which should integrate advanced and well\uffe2\uff80\uff90standardized tools. \uffc2\uffa9 2024 The Authors. Pest Management Science published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.The combination of plant residues with inorganic fertiliser\uffe2\uff80\uff90N provides the potential to increase N\uffe2\uff80\uff90use efficiency in agricultural fruit production systems, such as olive orchards. The development of weeds in the inter\uffe2\uff80\uff90canopy area of olive orchards is encouraged as a novel strategy to reduce soil erosion. However, little is known about soil N retention or N2O production following the combined application of inorganic\uffe2\uff80\uff90N with the mulched weed residues.
METHODSEmissions of 15N\uffe2\uff80\uff90N2O and soil mineral 15N retention were measured following combined applications of 15N\uffe2\uff80\uff90labelled fertiliser and a range of olive crop weed residues to a silty loam soil under controlled conditions. These plant residues differed in their C:N ratios, lignin and polyphenol contents.
RESULTSThe magnitude of soil 15N\uffe2\uff80\uff90NO3\uffe2\uff80\uff93 retention from combining plant residues and fertiliser\uffe2\uff80\uff90N was highly dependent on potential N mineralisation (r\uffe2\uff80\uff89=\uffe2\uff80\uff89\uffe2\uff88\uff920.96) and the (lignin\uffe2\uff80\uff89+\uffe2\uff80\uff89polyphenol)\uffe2\uff80\uff90to\uffe2\uff80\uff90N ratio (r\uffe2\uff80\uff89=\uffe2\uff80\uff890.98) of the residues. Fertiliser\uffe2\uff80\uff90N\uffe2\uff80\uff90derived retention was zero for a legume\uffe2\uff80\uff90based mulch but up to 80% in the treatment containing plant residues with a high (lignin\uffe2\uff80\uff89+\uffe2\uff80\uff89polyphenol)\uffe2\uff80\uff90to\uffe2\uff80\uff90N ratio. N2O emissions increased after the addition of residues, and increased further (up to 128%) following the combined application of inorganic fertiliser and residues. Fertiliser\uffe2\uff80\uff90derived 15N\uffe2\uff80\uff90N2O was <1.4% of the total 14+15N\uffe2\uff80\uff90N2O emission and <0.01% of the applied 15N\uffe2\uff80\uff90NO3\uffe2\uff80\uff93. Enhanced N2O emissions following the application of residues and the fertiliser\uffe2\uff80\uff90N values were positively correlated with the C:N ratio of the residue. Thus, combining organic\uffe2\uff80\uff90 and inorganic\uffe2\uff80\uff90N immobilised a significant proportion of the inorganic N with little increase in N2O, especially in low C:N ratio residues.
CONCLUSIONSThe results demonstrate that whilst there is potential for N2O emissions to be controlled by combining weed residues and inorganic fertilisers, this is not easy to achieve as the magnitude and direction of interactions vary between different species due to their varying substrate qualities. Copyright \uffc2\uffa9 2012 John Wiley & Sons, Ltd.
", "keywords": ["2. Zero hunger", "Nitrogen", "Chemistry", " Analytical", "Nitrous Oxide", "04 agricultural and veterinary sciences", "15. Life on land", "Plants", "01 natural sciences", "6. Clean water", "Biochemical Research Methods", "0104 chemical sciences", "Soil", "13. Climate action", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Fertilizers", "Spectroscopy", "Environmental Monitoring"]}, "links": [{"href": "https://doi.org/10.1002/rcm.6254"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Rapid%20Communications%20in%20Mass%20Spectrometry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1002/rcm.6254", "name": "item", "description": "10.1002/rcm.6254", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1002/rcm.6254"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2012-09-10T00:00:00Z"}}, {"id": "10.1016/j.envpol.2020.115097", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:16:06Z", "type": "Journal Article", "created": "2020-06-30", "title": "Impact of plastic mulch film debris on soil physicochemical and hydrological properties", "description": "The plastic mulch films used in agriculture are considered to be a major source of the plastic residues found in soil. Mulching with low-density polyethylene (LDPE) is widely practiced and the resulting macro- and microscopic plastic residues in agricultural soil have aroused concerns for years. Over the past decades, a variety of biodegradable (Bio) plastics have been developed in the hope of reducing plastic contamination of the terrestrial ecosystem. However, the impact of these Bio plastics in agroecosystems have not been sufficiently studied. Therefore, we investigated the impact of macro (around 5\u00a0mm) and micro (<1\u00a0mm) sized plastic debris from LDPE and one type of starch-based Bio mulch film on soil physicochemical and hydrological properties. We used environmentally relevant concentrations of plastics, ranging from 0 to 2% (w/w), identified by field studies and literature review. We studied the effects of the plastic residue on a sandy soil for one month in a laboratory experiment. The bulk density, porosity, saturated hydraulic conductivity, field capacity and soil water repellency were altered significantly in the presence of the four kinds of plastic debris, while pH, electrical conductivity and aggregate stability were not substantially affected. Overall, our research provides clear experimental evidence that microplastics affect soil properties. The type, size and content of plastic debris as well as the interactions between these three factors played complex roles in the variations of the measured soil parameters. Living in a plastic era, it is crucial to conduct further interdisciplinary studies in order to have a comprehensive understanding of plastic debris in soil and agroecosystems.", "keywords": ["2. Zero hunger", "Microplastics", "0211 other engineering and technologies", "Agriculture", "02 engineering and technology", "15. Life on land", "Biodegradable plastic", "Agricultural soil", "01 natural sciences", "Soil quality", "Soil", "13. Climate action", "Plastic pollution", "international", "Soil Pollutants", "Hydrology", "Plastics", "Plan_S-Compliant_TA", "Ecosystem", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.envpol.2020.115097"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envpol.2020.115097", "name": "item", "description": "10.1016/j.envpol.2020.115097", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envpol.2020.115097"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-11-01T00:00:00Z"}}, {"id": "10.1007/s00128-012-0523-0", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:22Z", "type": "Journal Article", "created": "2012-01-25", "title": "Effect Of Long-Term Zinc Pollution On Soil Microbial Community Resistance To Repeated Contamination", "description": "The aim of the study was to compare the effects of stress (contamination trials) on the microorganisms in zinc-polluted soil (5,018\u00a0mg Zn\u00a0kg(-1) soil dry weight) and unpolluted soil (141\u00a0mg Zn kg(-1) soil\u00a0dw), measured as soil respiration rate. In the laboratory, soils were subjected to copper contamination (0, 500, 1,500 and 4,500\u00a0mg\u00a0kg(-1) soil\u00a0dw), and then a bactericide (oxytetracycline) combined with a fungicide (captan) along with glucose (10\u00a0mg\u00a0g(-1) soil\u00a0dw each) were added. There was a highly significant effect of soil type, copper treatment and oxytetracycline/captan treatment. The initial respiration rate of chronically zinc-polluted soil was higher than that of unpolluted soil, but in the copper treatment it showed a greater decline. Microorganisms in copper-treated soil were more susceptible to oxytetracycline/captan contamination. After the successive soil contamination trials the decline of soil respiration was greater in zinc-polluted soil than in unpolluted soil.", "keywords": ["Health", " Toxicology and Mutagenesis", "trace metals", "Oxytetracycline", "Toxicology", "01 natural sciences", "Article", "Captan", "Soil", "Stress", " Physiological", "Soil Pollutants", "Soil Microbiology", "combined stressors", "0105 earth and related environmental sciences", "soil pollution", "Drug Resistance", " Microbial", "04 agricultural and veterinary sciences", "Pollution", "Adaptation", " Physiological", "soil respiration rate", "6. Clean water", "Anti-Bacterial Agents", "Fungicides", " Industrial", "Zinc", "13. Climate action", "0401 agriculture", " forestry", " and fisheries", "Copper"], "contacts": [{"organization": "Klimek, Beata", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1007/s00128-012-0523-0"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Bulletin%20of%20Environmental%20Contamination%20and%20Toxicology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00128-012-0523-0", "name": "item", "description": "10.1007/s00128-012-0523-0", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00128-012-0523-0"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2012-01-26T00:00:00Z"}}, {"id": "10.1007/s00128-007-9045-6", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:22Z", "type": "Journal Article", "created": "2007-04-04", "title": "Zinc And Copper Toxicity To Soil Bacteria And Fungi From Zinc Polluted And Unpolluted Soils: A Comparative Study With Different Types Of Biolog Plates", "keywords": ["Microbiological Techniques", "Zinc", "Bacteria", "Fungi", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Poland", "04 agricultural and veterinary sciences", "01 natural sciences", "Copper", "Soil Microbiology", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1007/s00128-007-9045-6"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Bulletin%20of%20Environmental%20Contamination%20and%20Toxicology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00128-007-9045-6", "name": "item", "description": "10.1007/s00128-007-9045-6", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00128-007-9045-6"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2007-04-05T00:00:00Z"}}, {"id": "10.1007/s00128-020-02834-9", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:22Z", "type": "Journal Article", "created": "2020-03-31", "title": "Accumulation and Transformation of 2,2',4,4'-Tetrabrominated Diphenyl Ether (BDE47) by the Earthworm Metaphire vulgaris in Soil", "description": "The accumulation and transformation of 2,2',4,4'-tetrabrominated diphenyl ether (BDE47), one congener of the flame retardants polybrominated diphenyl ethers (PBDEs), in soil-feeding fauna are still unknown. Using radioactivity tracer, we incubated 14C-labelled BDE47 in soil for 21 days in the presence and absence of the geophagous earthworm Metaphire vulgaris. BDE47 accumulated in the earthworm predominantly via oral ingestion of soil, giving a biota-soil accumulation factor (BSAF) value of 1.3 for radioactivity at the end of incubation, and was mostly located in intestine, followed by clitellum (organs region) and skin of earthworms. Accumulation was accompanied by significant decrease of BDE47 concentration in soil porewater and BDE47 mineralization in soil. BDE47 was transformed in the earthworm gut into two metabolites with higher polarities than BDE47. The results provide for the first time insights into accumulation and transformation of lower-brominated congeners of PBDEs in geophagous earthworms, being helpful for environmental risk assessment of PBDEs.", "keywords": ["Soil", "Halogenated Diphenyl Ethers", "Animals", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "04 agricultural and veterinary sciences", "Oligochaeta", "Bioaccumulation", "01 natural sciences", "Flame Retardants", "0105 earth and related environmental sciences"]}, "links": [{"href": "http://link.springer.com/content/pdf/10.1007/s00128-020-02834-9.pdf"}, {"href": "https://doi.org/10.1007/s00128-020-02834-9"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Bulletin%20of%20Environmental%20Contamination%20and%20Toxicology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00128-020-02834-9", "name": "item", "description": "10.1007/s00128-020-02834-9", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00128-020-02834-9"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-03-31T00:00:00Z"}}, {"id": "10.1007/s00128-020-02835-8", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:22Z", "type": "Journal Article", "created": "2020-03-28", "title": "Fate of 2,4,6-tribromophenol in soil under different redox conditions.", "description": "Fate of 2,4,6-tribromophenol (TBP) in environmental matrices is obscure. We used 14C-tracer to investigated mineralization, transformation, and non-extractable residue (NER)-formation of TBP in a soil under continuously oxic, continuously anoxic, and anoxic-oxic alteration conditions. In all cases, TBP rapidly dissipated, mineralized to CO2, and formed NERs in the soil. Considerable amounts of transformation products (2-12%) were detected during the incubation. Marked mineralization (13-26%) indicated that soil microorganisms used TBP as their energy source. About 62-70% of the initial radioactivity was transformed into NERs, being mainly attributed to binding to humic and fulvic acid fractions. TBP transformation was significantly faster under oxic conditions than under anoxic conditions, and was boosted when the soil redox changed from anoxic to oxic state. The results provide new insights into fate of TBP in soil and suggest the importance to evaluate the stability of NERs for risk assessment of TBP in soil.", "keywords": ["Minerals", "Soil", "Phenols", "0211 other engineering and technologies", "Soil Pollutants", "Benzopyrans", "02 engineering and technology", "Oxidation-Reduction", "01 natural sciences", "Humic Substances", "6. Clean water", "0105 earth and related environmental sciences"]}, "links": [{"href": "http://link.springer.com/content/pdf/10.1007/s00128-020-02835-8.pdf"}, {"href": "https://doi.org/10.1007/s00128-020-02835-8"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Bulletin%20of%20Environmental%20Contamination%20and%20Toxicology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00128-020-02835-8", "name": "item", "description": "10.1007/s00128-020-02835-8", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00128-020-02835-8"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-03-28T00:00:00Z"}}, {"id": "10.1007/s00248-008-9467-7", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:23Z", "type": "Journal Article", "created": "2008-11-21", "title": "Molecular And Functional Assessment Of Bacterial Community Convergence In Metal-Amended Soils", "description": "Species diversity and the structure of microbial communities in soils are thought to be a function of the cumulative selective pressures within the local environment. Shifts in microbial community structure, as a result of metal stress, may have lasting negative effects on soil ecosystem dynamics if critical microbial community functions are compromised. Three soils in the vicinity of a copper smelter, previously contaminated with background, low and high levels of aerially deposited metals, were amended with metal-salts to determine the potential for metal contamination to shape the structural and functional diversity of microbial communities in soils. We hypothesized that the microbial communities native to the three soils would initially be unique to each site, but would converge on a microbial community with similar structure and function, as a result of metal stress. Initially, the three different sites supported microbial communities with unique structural and functional diversity, and the nonimpacted site supported inherently higher levels of microbial activity and biomass, relative to the metal-contaminated sites. Amendment of the soils with metal-salts resulted in a decrease in microbial activity and biomass, as well as shifts in microbial community structure and function at each site. Soil microbial communities from each site were also observed to be sensitive to changes in soil pH as a result of metal-salt amendment; however, the magnitude of these pH-associated effects varied between soils. Microbial communities from each site did not converge on a structurally or functionally similar community following metal-salt amendment, indicating that other factors may be equally important in shaping microbial communities in soils. Among these factors, soil physiochemical parameters like organic matter and soil pH, which can both influence the bioavailability and toxicity of metals in soils, may be critical.", "keywords": ["DNA", " Bacterial", "0301 basic medicine", "0303 health sciences", "Bacteria", "Biodiversity", "Hydrogen-Ion Concentration", "15. Life on land", "Soil", "03 medical and health sciences", "13. Climate action", "Metals", " Heavy", "Soil Pollutants", "Biomass", "Ecosystem", "Soil Microbiology"]}, "links": [{"href": "https://doi.org/10.1007/s00248-008-9467-7"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Microbial%20Ecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00248-008-9467-7", "name": "item", "description": "10.1007/s00248-008-9467-7", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00248-008-9467-7"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2008-11-22T00:00:00Z"}}, {"id": "10.1016/j.envpol.2021.116827", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:16:06Z", "type": "Journal Article", "created": "2021-03-09", "title": "Cocktails of pesticide residues in conventional and organic farming systems in Europe \u2013 Legacy of the past and turning point for the future", "description": "<p>Considering that pesticides have been used in Europe for over 70 years, a system for monitoring pesticide residues in EU soils and their effects on soil health is long overdue. In an attempt to address this problem, we tested 340 EU agricultural topsoil samples for multiple pesticide residues. These samples originated from 4 representative EU case study sites (CSS), which covered 3 countries and four of the main EU crops: vegetable and orange production in Spain (S-V and S-O, respectively), grape production in Portugal (P-G), and potato production in the Netherlands (N-P). Soil samples were collected between 2015 and 2018 after harvest or before the start of the growing season, depending on the CSS. Conventional and organic farming results were compared in S-V, S-O and N-P. Soils from conventional farms presented mostly mixtures of pesticide residues, with a maximum of 16 residues/sample. Soils from organic farms had significantly fewer residues, with a maximum of 5 residues/sample. The residues with the highest frequency of detection and the highest content in soil were herbicides: glyphosate and its main metabolite AMPA (P-G, N-P, S-O), and pendimethalin (S-V). Total residue content in soil reached values of 0.8 mg kg-1 for S-V, 2 mg kg-1 for S-O and N-P, and 12 mg kg-1 for P-G. Organic soils presented 70-90% lower residue concentrations than the corresponding conventional soils. There is a severe knowledge gap concerning the effects of the accumulated and complex mixtures of pesticide residues found in soil on soil biota and soil health. Safety benchmarks should be defined and introduced into (soil) legislation as soon as possible. Soil remediation techniques should be developed to keep the levels of pesticide residues below such benchmarks. Furthermore, the process of transitioning to organic farming should take into consideration the residue mixtures and their residence time in soil. &#160;</p>
", "keywords": ["2. Zero hunger", "Organic Agriculture", "Portugal", "Pesticide Residues", "Agriculture", "04 agricultural and veterinary sciences", "15. Life on land", "EU agricultural soils", "Europe", "Soil", "Mixtures of pesticide residues", "Spain", "13. Climate action", "Mixtures of pesticide residues; EU agricultural soils Organic", " conventional farming", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Organic and conventional farming", "Netherlands"]}, "links": [{"href": "https://doi.org/10.1016/j.envpol.2021.116827"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envpol.2021.116827", "name": "item", "description": "10.1016/j.envpol.2021.116827", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envpol.2021.116827"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-03-03T00:00:00Z"}}, {"id": "10.1016/j.envpol.2021.118128", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:16:06Z", "type": "Journal Article", "created": "2021-09-09", "title": "Diagnosis of cadmium contamination in urban and suburban soils using visible-to-near-infrared spectroscopy", "description": "Previous studies have mostly focused on using visible-to-near-infrared spectral technique to quantitatively estimate soil cadmium (Cd) content, whereas little attention has been paid to identifying soil Cd contamination from a perspective of spectral classification. Here, we developed a framework to compare the potential of two spectral transformations (i.e., raw reflectance and continuum removal [CR]), three optimization strategies (i.e., full-spectrum, Boruta feature selection, and synthetic minority over-sampling technique [SMOTE]), and three classification algorithms (i.e., partial least squares discriminant analysis, random forest [RF], and support vector machine) for diagnosing soil Cd contamination. A total of 536 soil samples were collected from urban and suburban areas located in Wuhan City, China. Specifically, Boruta and SMOTE strategies were aimed at selecting the most informative predictors and obtaining balanced training datasets, respectively. Results indicated that soils contaminated by Cd induced decrease in spectral reflectance magnitude. Classification models developed after Boruta and SMOTE strategies out-performed to those from full-spectrum. A diagnose model combining CR preprocessing, SMOTE strategy, and RF algorithm achieved the highest validation accuracy for soil Cd (Kappa = 0.74). This study provides a theoretical reference for rapid identification of and monitoring of soil Cd contamination in urban and suburban areas.", "keywords": ["DIFFUSE-REFLECTANCE SPECTROSCOPY", "HUMAN HEALTH", "PREDICTION", "POTENTIALLY TOXIC ELEMENTS", "Boruta algorithm", "01 natural sciences", "Visible-to-near-infrared spectroscopy", "NIR SPECTROSCOPY", "Soil", "ORGANIC-CARBON", "Machine learning", "11. Sustainability", "Soil Pollutants", "Least-Squares Analysis", "0105 earth and related environmental sciences", "Spectroscopy", " Near-Infrared", "RANDOM FOREST", "Urban and suburban soil Cd contamination", "04 agricultural and veterinary sciences", "15. Life on land", "QUANTITATIVE-ANALYSIS", "6. Clean water", "RIVER DELTA", "13. Climate action", "Earth and Environmental Sciences", "Synthetic minority over-sampling technique", "0401 agriculture", " forestry", " and fisheries", "HEAVY-METAL CONCENTRATIONS", "Cadmium"]}, "links": [{"href": "https://doi.org/10.1016/j.envpol.2021.118128"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envpol.2021.118128", "name": "item", "description": "10.1016/j.envpol.2021.118128", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envpol.2021.118128"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-12-01T00:00:00Z"}}, {"id": "10.1007/s00572-016-0694-3", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:34Z", "type": "Journal Article", "created": "2016-04-14", "title": "Organic Amendments Increase Phylogenetic Diversity Of Arbuscular Mycorrhizal Fungi In Acid Soil Contaminated By Trace Elements", "description": "In 1998, a toxic mine spill polluted a 55-km(2) area in a basin southward to Do\u00f1ana National Park (Spain). Subsequent attempts to restore those trace element-contaminated soils have involved physical, chemical, or biological methodologies. In this study, the restoration approach included application of different types and doses of organic amendments: biosolid compost (BC) and leonardite (LEO). Twelve years after the last addition, molecular analyses of arbuscular mycorrhizal (AM) fungal communities associated with target plants (Lamarckia aurea and Chrysanthemum coronarium) as well as analyses of trace element concentrations both in soil and in plants were performed. The results showed an improved soil quality reflected by an increase in soil pH and a decrease in trace element availability as a result of the amendments and dosages. Additionally, the phylogenetic diversity of the AM fungal community increased, reaching the maximum diversity at the highest dose of BC. Trace element concentration was considered the predominant soil factor determining the AM fungal community composition. Thereby, the studied AM fungal community reflects a community adapted to different levels of contamination as a result of the amendments. The study highlights the long-term effect of the amendments in stabilizing the soil system.", "keywords": ["2. Zero hunger", "0301 basic medicine", "Minerals", "0303 health sciences", "Bioindicator", "Chrysanthemum", "Genetic Variation", "Hydrogen-Ion Concentration", "15. Life on land", "Poaceae", "Soil biodiversity", "Trace element contaminated soils", "Ecosystem restoration", "Mining", "Soil fungal community", "Trace Elements", "Soil", "03 medical and health sciences", "Biodegradation", " Environmental", "13. Climate action", "Mycorrhizae", "Mine spill", "Bioindicators", "Soil Pollutants", "Phylogeny"]}, "links": [{"href": "https://doi.org/10.1007/s00572-016-0694-3"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Mycorrhiza", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00572-016-0694-3", "name": "item", "description": "10.1007/s00572-016-0694-3", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00572-016-0694-3"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-04-12T00:00:00Z"}}, {"id": "10.1007/s10646-011-0619-z", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:46Z", "type": "Journal Article", "created": "2011-03-04", "title": "Investigations Of Responses To Metal Pollution In Land Snail Populations (Cantareus Aspersus And Cepaea Nemoralis) From A Smelter-Impacted Area", "description": "A cross-transplantation field experiment was performed to investigate about possible adaptation/acclimatization to metal pollution in common garden snail Cantareus aspersus (ex-Helix aspersa) and brown-lipped grove snail Cepaea nemoralis populations. Adults were collected from an area surrounding a former smelter (ME), highly polluted by trace metals (TMs) for decades, and from an unpolluted site (BE). Subadults of first generation (F1) were exposed in microcosms in a 28-day kinetic study. Four exposure sites were chosen around the smelter along a soil pollution gradient (vegetation and soil otherwise comparable). Bioaccumulation in snail soft tissues globally increased with soil contamination, with Cd, Pb and Zn concentrations reaching 271, 187, 5527\u00a0\u03bcg\u00a0g(-1), respectively. Accumulation kinetic patterns were similar between snail species but C. nemoralis showed greater TM levels than C. aspersus. Some inter-population differences were revealed in TM accumulation (bioaccumulation factors, accumulation kinetics) but did not suggest consistent adaptive responses. We did not detect negative effects of TM exposure on snail condition (body weight, shell size, shell weight). ME C. aspersus snails produced heavier shells than BE snails under exposure to TMs at the highest level, suggesting an adaptive response. The protocol used in this study, however, did not allow unambiguously distinguishing whether this response was due to genetic adaptation or to maternal effects. Abnormal but reversible shell development of adult ME C. nemoralis suggested physiological acclimatization. Differences in responses to TMs between populations are observed for conchological parameters, not for bioaccumulation, with different strategies according to the species (acclimatization or adaptation/maternal effects).", "keywords": ["550", "invertebrate", "Snails", "590", "0211 other engineering and technologies", "02 engineering and technology", "heavy metal", "Adaptation", " Physiological", "01 natural sciences", "Kinetics", "bioaccumulation", "Models", " Chemical", "Metals", "13. Climate action", "adaptive response", "Metallurgy", "Animals", "Body Size", "Soil Pollutants", "[SDE.ES]Environmental Sciences/Environment and Society", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1007/s10646-011-0619-z"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Ecotoxicology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10646-011-0619-z", "name": "item", "description": "10.1007/s10646-011-0619-z", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10646-011-0619-z"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2011-03-03T00:00:00Z"}}, {"id": "10.1007/s10646-009-0329-y", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:46Z", "type": "Journal Article", "created": "2009-06-06", "title": "Trace Elements And Activity Of Antioxidative Enzymes In Cistus Ladanifer L. Growing On An Abandoned Mine Area", "description": "The Mediterranean shrub Cistus ladanifer grows naturally in S\u00e3o Domingos (Portugal), an abandoned copper mine. High levels of trace elements in plants can generate oxidative stress increasing the activity of antioxidant enzymes. The aim of this work was to evaluate and compare As, Cu, Pb and Zn concentrations and the activity of the soluble and cell wall ionically bounded forms of the enzymes catalase, peroxidase and superoxide dismutase in leaves of C. ladanifer, collected in spring and summer, growing on S\u00e3o Domingos mine and on a non-contaminated area (Pomar\u00e3o). S\u00e3o Domingos soils showed high total concentrations of As (2.6 g kg(-1)) and Pb (7.3 g kg(-1)) however the available fraction represented less than 1.5% of the total. C. ladanifer population from mine showed tolerance to Pb and Zn, which attain in leaves concentrations considered toxic for plants. The enzymatic activity of catalase, peroxidise and superoxide dismutase varied with plant populations and seasons, although with no particular trend, being specific to each trace element and enzyme cell localization. Catalase activity was evenly distributed between the soluble and ionically bounded forms, whereas the ionically bounded form of peroxidase predominated relatively to total activity, and the opposite was observed for superoxide dismutase. Spring and summer leaves from the two areas presented enzymatic activities in both fractions except to peroxidase soluble activities in leaves collected in summer. C. ladanifer enzymatic activity seems to be related with the co-existence of different stress factors (trace elements concentration, temperature, UV radiation and drought). The survival and growth of this species on contaminated mining soils is due to the presence of effective antioxidant enzyme-based defence systems.", "keywords": ["0106 biological sciences", "trace elements", "Industrial Waste", "antioxidative enzymes", "Antioxidative enzymes", "01 natural sciences", "Mining", "Soil", "Cell Wall", "Soil Pollutants", "adaptative capacity", "0105 earth and related environmental sciences", "Trace elements", "Portugal", "Cistus", "Adaptative capacity", "15. Life on land", "Sulphide abandoned mine", "cistus ladanifer L.", "Trace Elements", "Plant Leaves", "Oxidative Stress", "sulphide abandoned mine", "Cistus ladanifer L.", "Oxidoreductases", "Copper"]}, "links": [{"href": "https://doi.org/10.1007/s10646-009-0329-y"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Ecotoxicology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10646-009-0329-y", "name": "item", "description": "10.1007/s10646-009-0329-y", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10646-009-0329-y"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-06-05T00:00:00Z"}}, {"id": "10.1007/s10646-012-0988-y", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:46Z", "type": "Journal Article", "created": "2012-08-25", "title": "Nematodes As Bioindicators Of Soil Degradation Due To Heavy Metals", "description": "The effect of distance from a heavy metal pollution source on the soil nematode community was investigated on four sampling sites along an 4 km transect originating at the Kovohuty a.s. Krompachy (pollution source). The soil nematode communities were exposed to heavy metal influence directly and through soil properties changes. We quantified the relative effects of total and mobile fraction of metals (As, Cd, Cr, Cu, Pb, and Zn) on soil ecosystem using the nematode community structure (trophic and c-p groups,) and ecological indices (Richness of genera, H', MI2-5, etc.). Pollution effects on the community structure of soil free living nematodes was found to be the highest near the pollution source, with relatively low population density and domination of insensitive taxa. A decrease in heavy metals contents along the transect was linked with an increase in complexity of nematode community. The majority of used indices (MI2-5, SI, H') negatively correlated (P < 0.05 or P < 0.01) with heavy metals content and were sensitive to soil ecosystem disturbance. Contamination by heavy metals has negatively affected the soil environment, which resulted in nematode community structure and ecological indices changes. Results showed that the free-living nematodes are useful tools for bioindication of contamination and could be used as an alternative to the common approaches based on chemical methods.", "keywords": ["Population Density", "Slovakia", "Nematoda", "Industrial Waste", "Environmental Exposure", "04 agricultural and veterinary sciences", "15. Life on land", "Biota", "01 natural sciences", "Mass Spectrometry", "13. Climate action", "Metals", " Heavy", "Metallurgy", "Animals", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1007/s10646-012-0988-y"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Ecotoxicology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10646-012-0988-y", "name": "item", "description": "10.1007/s10646-012-0988-y", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10646-012-0988-y"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2012-08-26T00:00:00Z"}}, {"id": "10.1007/s10646-013-1139-9", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:46Z", "type": "Journal Article", "created": "2013-10-11", "title": "Soil Biological Attributes In Arsenic-Contaminated Gold Mining Sites After Revegetation", "description": "Recovery of arsenic contaminated areas is a challenge society faces throughout the world. Revegetation associated with microbial activity can play an essential role in this process. This work investigated biological attributes in a gold mining area with different arsenic contents at different sites under two types of extant revegetation associated with cover layers of the soil: BS, Brachiaria sp. and Stizolobium sp., and LEGS, Acacia crassicarpa, A. holosericea, A. mangium, Sesbania virgata, Albizia lebbeck and Pseudosamanea guachapele. References were also evaluated, comprising the following three sites: B1, weathered sulfide substrate without revegetation; BM, barren material after gold extraction and PRNH (private reserve of natural heritage), an uncontaminated forest site near the mining area. The organic and microbial biomass carbon contents and substrate-induced respiration rates for these sites from highest to lowest were: PRNH > LEGS > BS > B1 and BM. These attributes were negatively correlated with soluble and total arsenic concentration in the soil. The sites that have undergone revegetation (LEGS and BS) had higher densities of bacteria, fungi, phosphate solubilizers and ammonium oxidizers than the sites without vegetation. Principal component analysis showed that the LEGS site grouped with PRNH, indicating that the use of leguminous species associated with an uncontaminated soil cover layer contributed to the improvement of the biological attributes. With the exception of acid phosphatase, all the biological attributes were indicators of soil recovery, particularly the following: microbial carbon, substrate-induced respiration, density of culturable bacteria, fungi and actinobacteria, phosphate solubilizers and metabolic quotient.", "keywords": ["Arsenic - Contamination", "Microbial biomass", "Quociente microbial", "01 natural sciences", "Mining", "Arsenic", "Photometry", "Respira\u00e7\u00e3o induzida por substrato", "Soil", "Substrate-induced respiration", "Soil Pollutants", "Biomass", "Microbial quotient", "Soil Microbiology", "0105 earth and related environmental sciences", "Ars\u00eanico - Contamina\u00e7\u00e3o", "Spectrophotometry", " Atomic", "Biomassa microbiana", "Phosphate solubilizers", "Solubilizantes de fosfato", "04 agricultural and veterinary sciences", "15. Life on land", "Biodegradation", " Environmental", "13. Climate action", "0401 agriculture", " forestry", " and fisheries", "Brazil", "Environmental Monitoring"]}, "links": [{"href": "https://doi.org/10.1007/s10646-013-1139-9"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Ecotoxicology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10646-013-1139-9", "name": "item", "description": "10.1007/s10646-013-1139-9", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10646-013-1139-9"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2013-10-11T00:00:00Z"}}, {"id": "10.1007/s10653-008-9150-4", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:46Z", "type": "Journal Article", "created": "2008-02-01", "title": "Relationship Between Plant Biodiversity And Heavy Metal Bioavailability In Grasslands Overlying An Abandoned Mine", "description": "Abandoned metal mines in the Sierra de Guadarrama, Madrid, Spain, are often located in areas of high ecological value. This is true of an abandoned barium mine situated in the heart of a bird sanctuary. Today the area sustains grasslands, interspersed with oakwood formations of Quercus ilex and heywood scrub (Retama sphaerocarpa L.), used by cattle, sheep and wild animals. Our study was designed to establish a relationship between the plant biodiversity of these grasslands and the bioavailability of heavy metals in the topsoil layer of this abandoned mine. We conducted soil chemical analyses and performed a greenhouse evaluation of the effects of different soil heavy metal concentrations on biodiversity. The greenhouse bioassays were run for 6 months using soil samples obtained from the mine polluted with heavy metals (Cu, Zn, Pb and Cd) and from a control pasture. Soil heavy metal and Na concentrations, along with the pH, had intense negative effects on plant biodiversity, as determined through changes in the Shannon index and species richness. Numbers of grasses, legumes, and composites were reduced, whilst other species (including ruderals) were affected to a lesser extent. Zinc had the greatest effect on biodiversity, followed by Cd and Cu. When we compared the sensitivity of the biodiversity indicators to the different metal content variables, pseudototal metal concentrations determined by X-ray fluorescence (XRF) were the most sensitive, followed by available and soluble metal contents. Worse correlations between biodiversity variables and metal variables were shown by pseudototal contents obtained by plasma emission spectroscopy (ICP-OES). Our results highlight the importance of using as many different indicators as possible to reliably assess the response shown by plants to heavy metal soil pollution.", "keywords": ["Polluted soils", "2. Zero hunger", "Sodium", "Biodiversity", "04 agricultural and veterinary sciences", "Plants", "15. Life on land", "Ba", "01 natural sciences", "Mining", "Cd", "Spain", "13. Climate action", "Grasslands", "Metals", " Heavy", "Zn", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Alfa diversity", "Shannon index", "Pb", "Cu", "Environmental Monitoring", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Hern\u00e1ndez, Ana Jes\u00fas, Pastor Pi\u00f1eiro, Jes\u00fas,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1007/s10653-008-9150-4"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Geochemistry%20and%20Health", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10653-008-9150-4", "name": "item", "description": "10.1007/s10653-008-9150-4", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10653-008-9150-4"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2008-02-02T00:00:00Z"}}, {"id": "10.1007/s10661-007-9685-3", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:46Z", "type": "Journal Article", "created": "2007-03-16", "title": "Effect Of Heavy Metals On Microbial Biomass And Activities In Century Old Landfill Soil", "description": "A study was conducted to determine the effect of metals on soil microbial biomass and activities in landfill soils as well as normal background soil. The microbial biomass and activities were consistently higher in the landfill soils than in the background soil. Significant positive correlations existed between the microbial parameters and soil organic carbon. The landfill soils contained higher concentrations of metals (iron, manganese, copper, cadmium, lead and zinc) than did the background soil. Microbial parameters were negatively correlated with the metals, with inhibition increasing with the bioavailability of the metals. It is suggested that the metals affected microbial biomass and activities by behaving synergistically or additively with each other. Although the landfill soils had higher microbial biomass and activities than the background soil, due to higher organic matter content, the ratios of microbial parameters/organic carbon indicated that inhibition of microbial growth and activities had occurred due to metal stress.", "keywords": ["Time Factors", "India", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "Carbon", "6. Clean water", "Refuse Disposal", "Soil", "Biodegradation", " Environmental", "13. Climate action", "Metals", " Heavy", "Humans", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Biomass", "Soil Microbiology", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1007/s10661-007-9685-3"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Monitoring%20and%20Assessment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10661-007-9685-3", "name": "item", "description": "10.1007/s10661-007-9685-3", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10661-007-9685-3"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2007-03-17T00:00:00Z"}}, {"id": "10.1007/s10661-009-0774-3", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:47Z", "type": "Journal Article", "created": "2009-02-19", "title": "Lead Contamination Of An Agricultural Soil In The Vicinity Of A Shooting Range", "description": "In this study, coupled Pb concentration/Pb isotope data were used to evaluate the effect of a shooting range (operational for over 30 years) on Pb contamination of adjacent agricultural soils and the associated environmental risks. Lead was mainly concentrated in the arable layer of the contaminated agricultural soils at total concentrations ranging from 573 to 694 mg kg(-1). Isotopic analyses ((206)Pb/(207)Pb) proved that Pb originated predominantly from the currently used pellets. Chemical fractionation analyses showed that Pb was mainly associated with the reducible fraction of the contaminated soil, which is in accordance with its predominant soil phases (PbO, PbCO(3)). The 0.05 M EDTA extraction showed that up to 62% of total Pb from the contaminated site is potentially mobilizable. Furthermore, Pb concentrations obtained from the synthetic precipitation leaching procedure extraction exceeded the regulatory limit set by the United States Environmental Protection Agency for drinking water. Ion exchange resin bags showed to be inefficient for determining the vertical distribution of free Pb(2 + ) throughout the soil profile. Increased Pb concentrations were found in the biomass of spring barley (Hordeum vulgare L.) sampled at the studied site and two possible pathways of Pb uptake have been identified: (1) through passive diffusion-driven uptake by roots and (2) especially through atmospheric deposition, which was also proved by analyses of a bioindicator species (bryophyte Hypnum cupressiforme Hedw.). This study showed that shooting ranges can present an important source of Pb contamination of agricultural soils located in their close vicinity.", "keywords": ["2. Zero hunger", "Firearms", "Lead", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Agriculture", "Ion Exchange Resins", "04 agricultural and veterinary sciences", "01 natural sciences", "6. Clean water", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1007/s10661-009-0774-3"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Monitoring%20and%20Assessment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10661-009-0774-3", "name": "item", "description": "10.1007/s10661-009-0774-3", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10661-009-0774-3"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-02-20T00:00:00Z"}}, {"id": "10.1007/s10661-010-1531-3", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:47Z", "type": "Journal Article", "created": "2010-06-17", "title": "Soil Chemical And Physical Properties At The Bear Brook Watershed In Maine, Usa", "description": "Acidic deposition leads to the acidification of waters and accelerated leaching and depletion of soil base cations. The Bear Brook Watershed in Maine has used whole-watershed chemical manipulations to study the effects of elevated N and S on forest ecosystem function on a decadal time scale. The objectives of this study were to define the chemical and physical characteristics of soils in both the reference and treated watersheds after 17 years of treatment and assess evidence of change in soil chemistry by comparing soil studies in 1998 and 2006. Results from 1998 confirmed depletion of soil base cation pools and decreased pH due to elevated N and S within the treated watershed. However, between 1998 and 2006, during a period of declining SO4(2-) deposition and continued whole-watershed experimental acidification on the treated watershed, there was little evidence of continued soil exchangeable base cation concentration depletion or recovery. The addition of a pulse of litterfall and accelerating mineralization from a severe ice storm in 1998 may have had significant effects on forest floor nutrient pools and cycling between 1998 and 2006. Our findings suggest that mineralization of additional litter inputs from the ice storm may have obscured temporal trends in soil chemistry. The physical data presented also demonstrate the importance of coarse fragments in the architecture of these soils. This study underscores the importance of long-term, quantitative soil monitoring in determining the trajectories of change in forest soils and ecosystem processes over time.", "keywords": ["Nitrogen", "Fresh Water", "Phosphorus", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "Carbon", "6. Clean water", "Trees", "Soil", "13. Climate action", "Humans", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Calcium", "Magnesium", "Maine", "Acids", "Ecosystem", "Aluminum", "Environmental Monitoring", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Stephen A. Norton, Michael D. SanClements, Ivan J. Fernandez,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1007/s10661-010-1531-3"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Monitoring%20and%20Assessment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10661-010-1531-3", "name": "item", "description": "10.1007/s10661-010-1531-3", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10661-010-1531-3"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2010-06-18T00:00:00Z"}}, {"id": "10.1007/s10661-015-4492-8", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:47Z", "type": "Journal Article", "created": "2015-04-17", "title": "Effects Of Simulated Acid Rain On Soil And Soil Solution Chemistry In A Monsoon Evergreen Broad-Leaved Forest In Southern China", "description": "Acid rain is an environmental problem of increasing concern in China. In this study, a laboratory leaching column experiment with acid forest soil was set up to investigate the responses of soil and soil solution chemistry to simulated acid rain (SAR). Five pH levels of SAR were set: 2.5, 3.0, 3.5, 4.0, and 4.5 (as a control, CK). The results showed that soil acidification would occur when the pH of SAR was \u22643.5. The concentrations of NO\u2083(-)and Ca(2+) in the soil increased significantly when the pH of SAR fell 3.5. The concentration of SO\u2084(2-) in the soil increased significantly when the pH of SAR was <4.0. The effects of SAR on soil solution chemistry became increasingly apparent as the experiment proceeded (except for Na(+) and dissolved organic carbon (DOC)). The net exports of NO\u2083(-), SO\u2084(2-), Mg(2+), and Ca(2+) increased about 42-86% under pH 2.5 treatment as compared to CK. The Ca(2+) was sensitive to SAR, and the soil could release Ca(2+) through mineral weathering to mitigate soil acidification. The concentration of exchangeable Al(3+) in the soil increased with increasing the acidity of SAR. The releases of soluble Al and Fe were SAR pH dependent, and their net exports under pH 2.5 treatment were 19.6 and 5.5 times, respectively, higher than that under CK. The net export of DOC was reduced by 12-29% under SAR treatments as compared to CK. Our results indicate the chemical constituents in the soil are more sensitive to SAR than those in the soil solution, and the effects of SAR on soil solution chemistry depend not only on the intensity of SAR but also on the duration of SAR addition. The soil and soil solution chemistry in this region may not be affected by current precipitation (pH\u22484.5) in short term, but the soil and soil leachate chemistry may change dramatically if the pH of precipitation were below 3.5 and 3.0, respectively.", "keywords": ["China", "Acid Rain", "04 agricultural and veterinary sciences", "Forests", "Hydrogen-Ion Concentration", "15. Life on land", "01 natural sciences", "6. Clean water", "3. Good health", "Soil", "13. Climate action", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Environmental Monitoring", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Juxiu Liu, Guoyi Zhou, Deqiang Zhang, Guowei Chu, Guohua Liang, Qingyan Qiu, Jianping Wu,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1007/s10661-015-4492-8"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Monitoring%20and%20Assessment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10661-015-4492-8", "name": "item", "description": "10.1007/s10661-015-4492-8", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10661-015-4492-8"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2015-04-18T00:00:00Z"}}, {"id": "10.1007/s10661-017-6441-1", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:14:47Z", "type": "Journal Article", "created": "2018-01-12", "title": "A meta-analysis of pesticide loss in runoff under conventional tillage and no-till management", "description": "Global agricultural intensification has led to increased pesticide use (37-fold from 1960 to 2005) and soil erosion (14% since 2000). Conservation tillage, including no-till (NT), has been proposed as an alternative to conventional plow till (PT) to mitigate soil erosion, but past studies have reported mixed results on the effect of conservation tillage on pesticide loss. To explore the underlying factors of these differences, a meta-analysis was conducted using published data on pesticide concentration and load in agricultural runoff from NT and PT fields. Peer-reviewed articles (1985-2016) were compiled to build a database for analysis. Contrary to expectations, results showed greater concentration of atrazine, cyanazine, dicamba, and simazine in runoff from NT than PT fields. Further, we observed greater load of dicamba and metribuzin, but reduced load of alachlor from NT fields. Overall, the concentration and the load of pesticides were greater in runoff from NT fields, especially pesticides with high solubility and low affinity for solids. Thus, NT farming affects soil properties that control pesticide retention and interactions with soils, and ultimately their mobility in the environment. Future research is needed for a more complete understanding of pesticide-soil interactions in NT systems. This research could inform the selection of pesticides by farmers and improve the predictive power of pesticide transport models.", "keywords": ["2. Zero hunger", "Triazines", "solubility", "Agriculture", "04 agricultural and veterinary sciences", "Environment", "15. Life on land", "octanol-water partition coefficient", "01 natural sciences", "6. Clean water", "Soil", "13. Climate action", "Acetamides", "tillage", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Atrazine", "Pesticides", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1007/s10661-017-6441-1"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Monitoring%20and%20Assessment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10661-017-6441-1", "name": "item", "description": "10.1007/s10661-017-6441-1", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10661-017-6441-1"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-01-12T00:00:00Z"}}, {"id": "10.1016/j.scitotenv.2019.03.176", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:16:42Z", "type": "Journal Article", "created": "2019-03-13", "title": "Effect of digestate application on microbial respiration and bacterial communities' diversity during bioremediation of weathered petroleum hydrocarbons contaminated soils", "description": "Digestate is an organic by-product of biogas production via anaerobic digestion processes and has a great potential as soil fertilizer due to concentrated nutrients. In this study, we examined digestate as a potential nutrient and microbial seeding for bioremediation of weathered (aged) petroleum hydrocarbon contaminated soils. We analysed 6 different treatments in microcosm using two industrial soils having different textures: a clay rich soil and a sandy soil. After 30\u202fdays of incubation, the highest total petroleum hydrocarbons (TPH) removal was observed in microcosms containing digestate together with bulking agent (17.8% and 12.7% higher than control in clay rich soil and sandy soil, respectively) or digestate together with immobilized bacteria (13.4% and 9% higher than control in clay rich soil and sandy soil, respectively). After digestate application microbial respiration was enhanced in sandy soil and inhibited in clay rich soil due to aggregates formation. After bulking agent addition to clay rich soil aggregates size was reduced and oxygen uptake was improved. Application of digestate to soil resulted in the development of distinct microbial groups in amended and non-amended soils. Genera containing species able to degrade TPH like Acinetobacter and Mycobacterium were abundant in digestate and in soil amended with digestate. Quantification of alkB genes, encoding alkane monoxygenase, revealed high concentration of these genes in digestate bacterial community. After application of digestate, the level of alkB genes significantly increased in soils and remained high until the end of the treatment. The study revealed great potential of digestate as a nutrient and bacteria source for soil bioremediation.", "keywords": ["[SDE] Environmental Sciences", "TPH removal", "550", "Soil remediation", "0211 other engineering and technologies", "alkB genes; Organic fertilizers; qPCR; Soil remediation; TPH removal; Biodegradation", " Environmental; Environmental Restoration and Remediation; Hydrocarbons; Petroleum; Petroleum Pollution; Soil; Soil Pollutants; Soil Microbiology", "02 engineering and technology", "01 natural sciences", "7. Clean energy", "630", "Organic fertilizers", "Environmental", "Soil", "alkB genes", "Soil Pollutants", "Petroleum Pollution", "Environmental Restoration and Remediation", "Soil Microbiology", "0105 earth and related environmental sciences", "2. Zero hunger", "[SDE.IE]Environmental Sciences/Environmental Engineering", "15. Life on land", "Hydrocarbons", "6. Clean water", "qPCR", "Biodegradation", " Environmental", "Petroleum", "[SDE]Environmental Sciences", "Biodegradation", "[SDE.IE] Environmental Sciences/Environmental Engineering"]}, "links": [{"href": "https://doi.org/10.1016/j.scitotenv.2019.03.176"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20of%20The%20Total%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.scitotenv.2019.03.176", "name": "item", "description": "10.1016/j.scitotenv.2019.03.176", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.scitotenv.2019.03.176"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-06-01T00:00:00Z"}}, {"id": "10.1016/j.scitotenv.2024.173265", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:16:44Z", "type": "Journal Article", "created": "2024-05-15", "title": "Comparing the impact of microplastics derived from a biodegradable and a conventional plastic mulch on plant performance", "description": "Agricultural lands have been identified as plastic sinks. One source is plastic mulches, which are a source of micro- and nano-sized plastics in agricultural soils. Because of their persistence, there is now a push towards developing biodegradable plastics, which are designed to undergo (partial) breakdown after entering the environment. Yet, limited research has investigated the impacts of both conventional and biodegradable plastics on distinct plants. Moreover, comparisons among studies are difficult due to differences in experimental design. This study directly compares the effects of artificially weathered conventional polyethylene (PE) and starch-based biodegradable polybutylene adipate terephthalate (PBAT) on four food crops, including two monocots (barley, Hordeum vulgare, and wheat, Triticum aestivum L.) and two dicots (carrot, Daucus carota, and lettuce, Lactuca sativa L.). We investigated the effects of environmentally relevant low, medium, and high (0.01\u00a0%, 0.1\u00a0%, 1\u00a0% w/w) concentrations of PE and starch-PBAT blend on seed germination (acute toxicity), and subsequently on plant growth and chlorophyll through a pot-plant experiment (chronic toxicity). Germination of all species was not affected by both plastics. However, root length was reduced for lettuce and wheat seedlings. No other effects were recorded on monocots. We observed a reduction in shoot length and bud wet weight of carrot seedlings for the highest concentration of PE and starch-PBAT blend. Chronic exposure resulted in a significant decrease in shoot biomass of barley and lettuce. Additionally, a positive increase in the number of leaves of lettuce was observed for both plastics. Chlorophyll content was increased in lettuce when exposed to PE and starch-PBAT blend. Overall, adverse effects in dicots were more abundant than in monocots. Importantly, we found that the biodegradable plastic caused more commonly adverse effects on plants compared to conventional plastic, which was confirmed by a mini-review of studies directly comparing the impact of conventional and biodegradable microplastics.", "keywords": ["Microplastics", "0211 other engineering and technologies", "seed germination", "Germination", "Biodegradable Plastics", "02 engineering and technology", "myrkyllisyys", "01 natural sciences", "630", "maatalous", "Soil Pollutants", "Triticum", "agriculture", "Plant growth", "0105 earth and related environmental sciences", "mikromuovi", "580", "2. Zero hunger", "Toxicity", "kasvien kasvu", "Microplastic", "toxicity", "Agriculture", "Hordeum", "it\u00e4minen", "plant growth", "biodegradable plastic", "15. Life on land", "Biodegradable plastic", "Seed germination", "biohajoaminen", "6. Clean water", "Biodegradation", " Environmental", "microplastic", "Plastics"]}, "links": [{"href": "https://doi.org/10.1016/j.scitotenv.2024.173265"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20of%20The%20Total%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.scitotenv.2024.173265", "name": "item", "description": "10.1016/j.scitotenv.2024.173265", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.scitotenv.2024.173265"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-07-01T00:00:00Z"}}, {"id": "10.1016/j.scitotenv.2023.168901", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:16:44Z", "type": "Journal Article", "created": "2023-11-30", "title": "Do contaminants compromise the use of recycled nutrients in organic agriculture? A review and synthesis of current knowledge on contaminant concentrations, fate in the environment and risk assessment", "description": "Use of nutrients recycled from societal waste streams in agriculture is part of the circular economy, and in line with organic farming principles. Nevertheless, diverse contaminants in waste streams create doubts among organic farmers about potential risks for soil health. Here, we gather the current knowledge on contaminant levels in waste streams and recycled nutrient sources, and discuss associated risks. For potentially toxic elements (PTEs), the input of zinc (Zn) and copper (Cu) from mineral feed supplements remains of concern, while concentrations of PTEs in many waste streams have decreased substantially in Europe. The same applies to organic contaminants, although new chemical groups such as flame retardants are of emerging concern and globally contamination levels differ strongly. Compared to inorganic fertilizers, application of organic fertilizers derived from human or animal feces is associated with an increased risk for environmental dissemination of antibiotic resistance. The risk depends on the quality of the organic fertilizers, which varies between geographical regions, but farmland application of sewage sludge appears to be a safe practice as shown by some studies (e.g. from Sweden). Microplastic concentrations in agricultural soils show a wide spread and our understanding of its toxicity is limited, hampering a sound risk assessment. Methods for assessing public health risks for organic contaminants must include emerging contaminants and potential interactions of multiple compounds. Evidence from long-term field experiments suggests that soils may be more resilient and capable to degrade or stabilize pollutants than often assumed. In view of the need to source nutrients for expanding areas under organic farming, we discuss inputs originating from conventional farms vs. non-agricultural (i.e. societal) inputs. Closing nutrient cycles between agriculture and society is feasible in many cases, without being compromised by contaminants, and should be enhanced, aided by improved source control, waste treatment and sound risk assessments.", "keywords": ["Organic farming", "organic agriculture", "Risk Assessment", "630", "Societal wastes", "12. Responsible consumption", "Organic contaminants", "Soil", "Soil biology", "RELACS", "11. Sustainability", "Animals", "Humans", "Soil Pollutants", "recycled nutrients", "FiBL25054", "Fertilizers", "Abacus", "Risk assessment", "2. Zero hunger", "Organic Agriculture", "Sewage", "Nutrient turnover", "Agriculture", "Nutrients", "15. Life on land", "6. Clean water", "13. Climate action", "contaminants", "environment", "Plastics"]}, "links": [{"href": "https://doi.org/10.1016/j.scitotenv.2023.168901"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20of%20The%20Total%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.scitotenv.2023.168901", "name": "item", "description": "10.1016/j.scitotenv.2023.168901", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.scitotenv.2023.168901"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-02-01T00:00:00Z"}}, {"id": "10.1007/s11356-013-1649-2", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:06Z", "type": "Journal Article", "created": "2013-04-22", "title": "A Study On As, Cu, Pb And Zn (Bio)Availability In An Abandoned Mine Area (Sao Domingos, Portugal) Using Chemical And Ecotoxicological Tools", "description": "The aim of this study was to relate the results obtained by chemical methods, used to assess environmental (bio)availability, with the ecotoxic response and bioaccumulation of trace elements (TE) by the earthworm Eisenia fetida exposed to field-contaminated, metal-polluted soils from a sulphide mine. The extracting solution 0.5\u00a0M NH4CH3COO, 0.5\u00a0M CH3COOH and 0.02\u00a0M EDTA (pH\u00a04.7), was able to predict environmental bioavailability of TE to E. fetida. However, the toxicological bioavailability could not be predicted from the results of the chemical extractions or from the bioaccumulation results: E. fetida reproduction was higher in soils where environmental bioavailability of TE and bioaccumulation values were also higher. In this study, the toxic response of the organism seemed to be more influenced by the overall nutritional status of the soil (e.g. pH, organic matter, plant nutrient availability and cation exchange capacity) than by its TE contamination. In the case of anthropogenic multi-contaminated sites, the different soil characteristics exert an important and confounding influence in the toxic response and the relationship between different bioavailable fractions cannot be easily established, emphasising the need to combine results from chemical methods with those from bioassays when evaluating the bioavailability of TE in these soils.", "keywords": ["Bioavailability", "Mine contaminated soils", "Biological Availability", "Ecotoxicology", "01 natural sciences", "Bioassays", "Mining", "Arsenic", "Soil", "Animals", "Soil Pollutants", "Oligochaeta", "0105 earth and related environmental sciences", "Trace elements", "Portugal", "04 agricultural and veterinary sciences", "Bioaccumulation", "Zinc", "Lead", "Metals", "Indexa\u00e7\u00e3o ISI", "0401 agriculture", " forestry", " and fisheries", "Chemical extraction methods", "Copper", "Environmental Monitoring"]}, "links": [{"href": "https://doi.org/10.1007/s11356-013-1649-2"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20and%20Pollution%20Research", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s11356-013-1649-2", "name": "item", "description": "10.1007/s11356-013-1649-2", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s11356-013-1649-2"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2013-04-23T00:00:00Z"}}, {"id": "10.1007/s11356-015-4745-7", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:07Z", "type": "Journal Article", "created": "2015-05-25", "title": "Accumulation, Availability, And Uptake Of Heavy Metals In A Red Soil After 22-Year Fertilization And Cropping", "description": "Fertilization is important to increase crop yields, but long-term application of fertilizers probably aggravated the risk of heavy metals in acidic soils. In this study, the effect of 22-year fertilization and cropping on accumulation, availability, and uptake of heavy metals in red soil was investigated. The results showed that pig manure promoted significantly cadmium (Cd) accumulation (average 1.1 mg kg(-1)), nearly three times higher than national soil standards and, thus, increased metal availability. But the enrichment of heavy metals decreased remarkably by 50.5 % under manure fertilization, compared with CK (control without fertilization). On the contrary, chemical fertilizers increased greatly lead (Pb) availability and Cd activity; in particular, exceeding 85 % of soil Cd became available to plant under N (nitrogen) treatment during 9-16 years of fertilization, which correspondingly increased their enrichment by 29.5 %. Long-term application of chemical fertilizers caused soil acidification and manure fertilization led to the increase in soil pH, soil organic matter (SOM), and available phosphorus (Olsen P), which influenced strongly metal behavior in red soil, and their effect had extended to deeper soil layer (20\u223c40 cm). It is advisable to increase application of manure alone with low content of heavy metals or in combination with chemical fertilizers to acidic soils in order to reduce toxic metal risk.", "keywords": ["Crops", " Agricultural", "2. Zero hunger", "China", "Nitrogen", "Swine", "Phosphorus", "Models", " Theoretical", "15. Life on land", "Zea mays", "01 natural sciences", "6. Clean water", "Manure", "Soil", "13. Climate action", "Metals", " Heavy", "Animals", "Soil Pollutants", "Fertilizers", "Humic Substances", "Cadmium", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Nan Sun, Jialong Lv, Jing Liu, Shiwei Zhou, Minggang Xu,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1007/s11356-015-4745-7"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20and%20Pollution%20Research", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s11356-015-4745-7", "name": "item", "description": "10.1007/s11356-015-4745-7", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s11356-015-4745-7"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2015-05-26T00:00:00Z"}}, {"id": "10.1016/j.scitotenv.2007.07.015", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:16:40Z", "type": "Journal Article", "created": "2007-09-06", "title": "The Effects Of Copper Oxy Chloride Waste Contamination On Selected Soil Biochemical Properties At Disposal Site", "description": "A study was carried out at a sanitary waste disposal site for Kutsaga Tobacco Research Station, Zimbabwe, which uses large amounts of copper oxy chloride for sterilization of recycled float trays in flooded bench tobacco seedling production systems. Soil samples randomly collected from six stream bank zones (bands up the valley slope) varying in their distance ranges from the centre of both the wastewater-free and wastewater-affected paths [0-5 m (B1); 6-10 m (B2); 11-15 m (B3); 16-20 m (B4); 21-25 m (B5) and 26-30 m (B6)] in two sample depths (0-15; 15-30 cm) were analysed for metal copper, organic matter contents, and soil pH and subjected to agarized incubation for microbial counts. Results suggest that the repeated disposals of copper oxy chloride waste from tobacco float tray sanitation sinks into a creek amplify metal copper loads in the soil by 500 fold. The greatest concentrations of copper in both the topsoil and upper subsoil were recorded in the B3, B4 and B5 stream bank zones of the wastewater path. The concentration of copper was significantly lower in the middle of the waste-affected creek than that in the stream bank zones. This trend in the copper concentration coincided with the lowest acidity of the soil. Overloading the soil with copper, surprisingly, enhances the content of soil organic matter. The repeated release of copper oxy chloride waste into a stream causes an accelerated build-up of metal copper and soil acidity in the stream bank on-site while contamination is translocated to either underground water reserve or surface stream water flow in the middle of the wastewater path.", "keywords": ["Nicotiana", "Zimbabwe", "Industrial Waste", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "6. Clean water", "Refuse Disposal", "12. Responsible consumption", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Copper", "Soil Microbiology", "Water Pollutants", " Chemical", "Disinfectants", "Environmental Monitoring", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Johnson Masaka, M. Muunganirwa,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.scitotenv.2007.07.015"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20of%20The%20Total%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.scitotenv.2007.07.015", "name": "item", "description": "10.1016/j.scitotenv.2007.07.015", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.scitotenv.2007.07.015"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2007-11-15T00:00:00Z"}}, {"id": "10.1016/j.scitotenv.2008.07.048", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:16:40Z", "type": "Journal Article", "created": "2008-09-18", "title": "Impact Of Different Tillage Practices On Molecular Characteristics Of Humic Acids In A Long-Term Field Experiment \u2014 An Application Of Three Different Spectroscopic Methods", "description": "The present paper describes changes in soil organic carbon (SOC) and extractable humic acids (HAs) in a long-term field experiment with different tillage treatments (minimum tillage (MT), reduced tillage (RT) and conventional tillage (CT)). This field experiment is located in the east of Vienna in a Pannonian climate and it was started in 1988. The methodological approach included elemental analyses, FT-IR, 13C NMR and fluorimetric measurements. Both MT and RT revealed significant depth gradients of yields of extractable HAs. In CT no depth gradient was observable, neither for HA yields nor for observed molecular characteristics. This indicated a destruction of the gradient by mixing of the soil in CT. Especially MT showed an increase of aromatic moieties with depth, suggesting an increased humification of HAs in the lower soil layers. Gradients with similar trends were indicated for the carbonylic, the amidic and probably the hydroxylic groups in HAs extracted from MT and RT samples. The data revealed with FT-IR and solid-state 13C NMR spectroscopy were convincing, plausible and meaningful, the highly sensitive fluorescence spectroscopy was limited because of strong quenching by inner filter effects, compromising data reliability. However, the fluorescence results based on a defined HAs concentration (and comparing soils from the same site) were in line with results from the other methods (13C NMR and FT-IR). As a consequence, the influence of tillage treatments can be followed by absence or presence of depth gradients of the according molecular characteristics in extracted HAs.", "keywords": ["Magnetic Resonance Spectroscopy", "Agriculture", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "6. Clean water", "13. Climate action", "Austria", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Fluorometry", "Cities", "Humic Substances", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.scitotenv.2008.07.048"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20of%20The%20Total%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.scitotenv.2008.07.048", "name": "item", "description": "10.1016/j.scitotenv.2008.07.048", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.scitotenv.2008.07.048"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2008-11-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2009.01.042", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:52Z", "type": "Journal Article", "created": "2009-02-16", "title": "Effects Of Earthworms On Metal Uptake Of Heavy Metals From Polluted Mine Soils By Different Crop Plants", "description": "A pot experiment was conducted in order to assess the effect of the earthworm Eisenia fetida on the uptake of Pb, Zn, Cd and Cu from soils polluted by mining activities using maize (Zea mays) and barley (Hordeum vulgare). Results from single and sequential extractions showed that the soil chemical partitioning of heavy metals was significantly changed by E. fetida, leading to a higher concentration of metals in the non-residual fractions of the soil. Earthworm activities significantly increased shoot biomass (65% for maize and 73% for barley) and root metal concentration for all the metals under study in both maize and barley. The total accumulation rate values for Cd, Cu, Pb and Zn were significantly higher in the presence of E. fetida for both crop plants. Those latter effects led to an increase in Zn extraction yields of up to 3.7-fold and 2.3-fold for barley and maize, respectively.", "keywords": ["2. Zero hunger", "Hordeum", "04 agricultural and veterinary sciences", "Chemical Fractionation", "Plant Roots", "Zea mays", "01 natural sciences", "Mining", "Biodegradation", " Environmental", "13. Climate action", "Metals", " Heavy", "Animals", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Biomass", "Oligochaeta", "Plant Shoots", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2009.01.042"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2009.01.042", "name": "item", "description": "10.1016/j.chemosphere.2009.01.042", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2009.01.042"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-05-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2006.03.038", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:52Z", "type": "Journal Article", "created": "2006-05-09", "title": "Decomposition Of Heavy Metal Contaminated Nettles (Urtica Dioica L.) In Soils Subjected To Heavy Metal Pollution By River Sediments", "description": "Two incubation experiments were conducted to evaluate differences in the microbial use of non-contaminated and heavy metal contaminated nettle (Urtica dioica L.) shoot residues in three soils subjected to heavy metal pollution (Zn, Pb, Cu, and Cd) by river sediments. The microbial use of shoot residues was monitored by changes in microbial biomass C, biomass N, biomass P, ergosterol, N mineralisation, CO(2) production and O(2) consumption rates. Microbial biomass C, N, and P were estimated by fumigation extraction. In the non-amended soils, the mean microbial biomass C to soil organic C ratio decreased from 2.3% in the low metal soil to 1.1% in the high metal soils. In the 42-d incubation experiment, the addition of 2% nettle residues resulted in markedly increased contents of microbial biomass P (+240%), biomass C (+270%), biomass N (+310%), and ergosterol (+360%). The relative increase in the four microbial properties was similar for the three soils and did not show any clear heavy metal effect. The contents of microbial biomass C, N and P and ergosterol contents declined approximately by 30% during the incubation as in the non-amended soils. The ratios microbial biomass C to N, microbial biomass C to P, and ergosterol to microbial biomass C remained constant at 5.2, 26, and 0.5%, respectively. In the 6-d incubation experiment, the respiratory quotient CO(2)/O(2) increased from 0.74 in the low metal soil to 1.58 in the high metal soil in the non-amended soils. In the treatments amended with 4% nettle residues, the respiratory quotient was constant at 1.13, without any effects of the three soils or the two nettle treatments. Contaminated nettle residues led generally to significantly lower N mineralisation, CO(2) production and O(2) consumption rates than non-contaminated nettle residues. However, the absolute differences were small.", "keywords": ["2. Zero hunger", "Geologic Sediments", "Minerals", "Time Factors", "Nitrogen", "Urtica dioica", "04 agricultural and veterinary sciences", "Carbon Dioxide", "01 natural sciences", "6. Clean water", "12. Responsible consumption", "Oxygen", "Rivers", "13. Climate action", "Ergosterol", "Metals", " Heavy", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Biomass", "Soil Microbiology", "Environmental Monitoring", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Rainer Georg Joergensen, Khalid Saifullah Khan,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2006.03.038"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2006.03.038", "name": "item", "description": "10.1016/j.chemosphere.2006.03.038", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2006.03.038"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2006-11-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2007.06.085", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:52Z", "type": "Journal Article", "created": "2007-08-21", "title": "Warming And Drought Change Trace Element Bioaccumulation Patterns In A Mediterranean Shrubland", "description": "A field experiment consisting of drought and warming manipulation was conducted in a Mediterranean shrubland dominated by the shrubs Erica multiflora and Globularia alypum. The aim was to investigate the effects of the climatic changes predicted by IPCC models for the coming decades on trace element concentration and accumulation in aboveground biomass, plant litter, and soil. Warming increased concentrations and aboveground accumulation of some trace elements related to plant root uptake, such as Al, As, Cr, Cu, and partially Pb. This effect was more general in E. multiflora than in G. alypum. The stronger effects were increases in Al leaf concentrations (42%) and aboveground accumulation (500gha(-1)) in E. multiflora, in As stem biomass accumulation (0.2gha(-1)) in E. multiflora, and in Cr leaf concentrations (51%) in G. alypum and stem aboveground accumulation in E. multiflora (1.1gha(-1)). These species-specific increases were related to greater retranslocation, photosynthetic capacity and growth in E. multiflora than in G. alypum. Warming decreased the concentrations of some trace elements in leaf litter, implying the existence of an increased leaf retranslocation. Drought increased As (40%) and Cd (55%) in E. multiflora stems, whereas it decreased Cu (50%) in leaves, Ni (28%) in stems and Pb (32%) in leaf litter of G. alypum. The increasing concentrations of some trace elements in E. multiflora and not in G. alypum were related to a greater growth reduction in E. multiflora than in G. alypum. Warming increased As soil solubility (67%) and decreased total soil As (21%). Those changes were related to a greater Fe mobilization in warming plot and to a greater plant capture. Drought increased Hg (350%) concentrations in soils but had no significant effects on trace element accumulation in aboveground biomass. The different response to warming and drought in the two dominant species implies uneven changes in the quality of the plant tissues that may have implications for herbivores. This may be specially important for the performance of the studied Mediterranean ecosystems under the warmer and drier conditions predicted by the next decades by the GCM and ecophysiological models.", "keywords": ["2. Zero hunger", "Trace elements", "Biomass concentrations", "Mediterranean Region", "15. Life on land", "Models", " Biological", "01 natural sciences", "Soil content", "6. Clean water", "Trace Elements", "Disasters", "Mediterranean shrubland", "Heavy metals", "13. Climate action", "Metals", " Heavy", "Climate change", "Soil Pollutants", "Biomass", "Seasons", "Weather", "Ecosystem", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2007.06.085"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2007.06.085", "name": "item", "description": "10.1016/j.chemosphere.2007.06.085", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2007.06.085"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2008-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2007.09.006", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:52Z", "type": "Journal Article", "created": "2007-10-26", "title": "Tillage Management To Mitigate Herbicide Loss In Runoff Under Simulated Rainfall Conditions", "description": "Conservation tillage mitigates soil loss in cropland because plant residues help protect the soil, but effects on pesticide movement in surface runoff are not as straightforward. Effects of soil disturbance on surface runoff loss of chlorimuron and alachlor were evaluated utilizing runoff trays. Soil in the trays was either disturbed (tilled) and kept bare or was not tilled, and existing decomposed plant residue was left on the surface. Rainfall (25mm, 20min) was simulated 1d after alachlor (2.8kg ha(-1)) or chlorimuron (54g ha(-1)) application, and runoff was collected. Runoff fractions were analyzed for herbicide and sediment. Total alachlor loss from bare plots was greater than that in no-tillage plots (4.5% vs. 2.3%, respectively). More than one-third of total alachlor lost from bare plots occurred in the first l of runoff, while no-tillage plots had less runoff volume with a more even distribution of alachlor concentration in the runoff during the rainfall simulation and subsequent runoff period. In contrast, more chlorimuron was lost from no-tillage plots than bare plots (12% vs. 1.5%) even though total runoff volume was lower in the no-tillage plots (10.6mm vs. 13.6mm). This was attributed to dense coverage with partially decomposed plant residue in no-tillage plots (1652kg ha(-1)) that intercepted chlorimuron. It was likely that chlorimuron, a polar compound, was more easily washed off surface plant residues and transported in runoff.", "keywords": ["2. Zero hunger", "Herbicides", "Rain", "04 agricultural and veterinary sciences", "Models", " Theoretical", "15. Life on land", "01 natural sciences", "6. Clean water", "Soil", "Acetamides", "Water Movements", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2007.09.006"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2007.09.006", "name": "item", "description": "10.1016/j.chemosphere.2007.09.006", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2007.09.006"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2008-02-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2008.07.056", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:52Z", "type": "Journal Article", "created": "2008-10-01", "title": "Integration Of Toxicological And Chemical Tools To Assess The Bioavailability Of Metals And Energetic Compounds In Contaminated Soils", "description": "Bioavailability is critical for understanding effects that might result from exposure of biota to contaminated soils. Soils from military range and training areas (RTAs) are contaminated principally by energetic materials (EM) and metals. Their chemical characteristics are relatively well known and toxicity assessment of soils from RTAs are in some cases available. However, bioavailability on these sites needs to be comprehensively characterized. A holistic approach to bioavailability, incorporating both chemical and earthworm toxicological indicators, was applied to soils from an anti-tank firing range at a Canadian Forces Base. Results showed that HMX and the metals Zn, Pb, Bi and Cd, though not consistently the prevailing toxicants, were the most accessible to earthworms. Some metals (notably Cu, Zn, Cr and Bi) were also accumulated in earthworm tissue but those were not necessarily expected given their bioaccessibility (i.e., the chemical availability of contaminants in the environment for the organisms) at the beginning of the exposure. The tested soils impaired earthworm reproduction and reduced adult growth. Measurement of selected sublethal parameters indicated that lysosomal integrity (determined as the neutral red retention time--NRRT) was decreased, while elevated superoxide dismutase (SOD) activity suggested that earthworms experienced oxidative stress. The correspondence between the NRRT and metal contamination pattern suggested that metals may be the main cause of lysosomal disruption in EM-contaminated soils. The approach to bioavailability appraisal adopted in this case appears to be a promising practice for site-specific assessment of contaminated land.", "keywords": ["zinc/metabolism/pharmacokinetics/toxicity", "assessment", "metals", "Biological Availability", "lead/metabolism/pharmacokinetics/toxicity", "01 natural sciences", "biological availability", "soil pollutants/metabolism/pharmacokinetics/toxicity", "Animals", "Soil Pollutants", "bismuth/metabolism/pharmacokinetics/toxicity", "Oligochaeta", "oligochaeta/rug effects/growth & development/metabolism", "soils", "0105 earth and related environmental sciences", "metals/metabolism/pharmacokinetics/ toxicity", "explosives", "04 agricultural and veterinary sciences", "bioaccessibility", "6. Clean water", "Zinc", "Lead", "Metals", "13. Climate action", "0401 agriculture", " forestry", " and fisheries", "cadmium/metabolism/pharmacokinetics/toxicity", "bioavailability", "Bismuth", "Cadmium"], "contacts": [{"organization": "\u00c9meline Valton, Bertin Trottier, Aurelie Auroy, Aurelie Auroy, Yann Berthelot, Pierre Yves Robidoux, Pierre Yves Robidoux,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2008.07.056"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2008.07.056", "name": "item", "description": "10.1016/j.chemosphere.2008.07.056", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2008.07.056"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2008-12-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2009.06.053", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:53Z", "type": "Journal Article", "created": "2009-08-03", "title": "Impacts Of Woodchip Biochar Additions On Greenhouse Gas Production And Sorption/Degradation Of Two Herbicides In A Minnesota Soil", "description": "A potential abatement to increasing levels of carbon dioxide (CO(2)) in the atmosphere is the use of pyrolysis to convert vegetative biomass into a more stable form of carbon (biochar) that could then be applied to the soil. However, the impacts of pyrolysis biochar on the soil system need to be assessed before initiating large scale biochar applications to agricultural fields. We compared CO(2) respiration, nitrous oxide (N(2)O) production, methane (CH(4)) oxidation and herbicide retention and transformation through laboratory incubations at field capacity in a Minnesota soil (Waukegan silt loam) with and without added biochar. CO(2) originating from the biochar needs to be subtracted from the soil-biochar combination in order to elucidate the impact of biochar on soil respiration. After this correction, biochar amendments reduced CO(2) production for all amendment levels tested (2, 5, 10, 20, 40 and 60% w/w; corresponding to 24-720 tha(-1) field application rates). In addition, biochar additions suppressed N(2)O production at all levels. However, these reductions were only significant at biochar amendment levels >20% w/w. Biochar additions also significantly suppressed ambient CH(4) oxidation at all levels compared to unamended soil. The addition of biochar (5% w/w) to soil increased the sorption of atrazine and acetochlor compared to non-amended soils, resulting in decreased dissipation rates of these herbicides. The recalcitrance of the biochar suggests that it could be a viable carbon sequestration strategy, and might provide substantial net greenhouse gas benefits if the reductions in N(2)O production are lasting.", "keywords": ["Greenhouse Effect", "2. Zero hunger", "Toluidines", "Herbicides", "Minnesota", "Nitrous Oxide", "04 agricultural and veterinary sciences", "Carbon Dioxide", "15. Life on land", "01 natural sciences", "6. Clean water", "12. Responsible consumption", "Soil", "13. Climate action", "Charcoal", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Atrazine", "Adsorption", "Gases", "Methane", "Oxidation-Reduction", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2009.06.053"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2009.06.053", "name": "item", "description": "10.1016/j.chemosphere.2009.06.053", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2009.06.053"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-10-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2009.11.015", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:53Z", "type": "Journal Article", "created": "2009-12-17", "title": "Selenium Accumulation By Forage And Grain Crops And Volatilization From Seleniferous Soils Amended With Different Organic Materials", "description": "Greenhouse and field experiments were conducted to study the direct and residual effect of applying different organic materials on Se accumulation by crops and volatilization from seleniferous soils of northwestern India. Among organic manures, press mud and poultry manures proved 4-5 times more effective in reducing Se accumulation by different crops than farmyard manure. Efficiency of organic manures increased with increase in application rates. Application of both press mud and poultry manures reduced Se accumulation by 44-97% in wheat (Triticum aestivum) and rapeseed (Brassica napus) shoots in the greenhouse; 85-92% in wheat straw, 45-74% in wheat grains, 45-74% in rapeseed straw and 76-92% in rapeseed grains under field conditions. Both the manures remained highly effective in reducing Se accumulation by the crops following wheat and rapeseed and the extent of reduction varied from 50% to 87% in maize (Zea mays) and cowpeas (Vigna sinensis) in the greenhouse and 40-89% in maize and rice (Oryza sativa) crops under field situation. Rate of Se volatilization by wheat and rapeseed crops increased by 1.8-4.0 times; the greatest increase was observed with press mud followed by poultry manure, arhar (Cajanus cajan) leaves and farmyard manure. After 134d of incubation of 500g soil amended with 2% of plant tissues, the maximum amount of Se was volatilized with cowpea leaves (385ng) followed by wheat grains, leaves of maize, sugarcane (Saccharum officcinarum), arhar, poplar (Populus deltoides) and the control (91ng). The results of this study convincingly prove the usefulness of applying press mud and poultry manure in enhancing volatilization and retarding the transfer of Se from soil to plant in seleniferous soils.", "keywords": ["Crops", " Agricultural", "2. Zero hunger", "04 agricultural and veterinary sciences", "15. Life on land", "Zea mays", "01 natural sciences", "6. Clean water", "Manure", "Plant Leaves", "Selenium", "Seeds", "Animals", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Volatilization", "Plant Shoots", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2009.11.015"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2009.11.015", "name": "item", "description": "10.1016/j.chemosphere.2009.11.015", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2009.11.015"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2010-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2010.06.047", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:53Z", "type": "Journal Article", "created": "2010-07-06", "title": "Trace Element Availability In A Sewage Sludge-Amended Cotton Grown Mediterranean Soil", "description": "Long-term field investigations on the use of biosolids are scarce in the Mediterranean region, especially on non-food high-profit crops. Thus we studied the effects of repeated sludge application for 4 yr on trace element (both essential and non-essential) availability to cotton, by applying sludge at four increasing rates up to 50 Mg ha(-1). Although sludge had low metal concentrations, sludge-added trace element availability (assessed with soil-to-plant transfer coefficient) was higher in the first year compared to those in the subsequent years of experiment, but it decreased with time to the value of the unamended control. This shows that trace element mobility can be reduced within a time-scale of a few years, provided soils have a relatively sufficient retention capacity (high CEC, clay, and non-acidic pH) and applied sludge has low heavy metal content. We also found that sludge-borne organic matter greatly affected metal availability, since metal transfer coefficients decreased with elevated organic matter content.", "keywords": ["2. Zero hunger", "Gossypium", "Manganese", "Greece", "Sewage", "Climate", "04 agricultural and veterinary sciences", "01 natural sciences", "6. Clean water", "Trace Elements", "12. Responsible consumption", "Plant Leaves", "Zinc", "Biodegradation", " Environmental", "Lead", "Nickel", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Copper", "Cadmium", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2010.06.047"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2010.06.047", "name": "item", "description": "10.1016/j.chemosphere.2010.06.047", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2010.06.047"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2010-09-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2010.08.026", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:53Z", "type": "Journal Article", "created": "2010-09-13", "title": "Optimization Of Pig Slurry Application To Heavy Metal Polluted Soils Monitoring Nitrification Processes", "description": "Nitrification is often negatively affected by heavy metal pollution in soils, this limiting land revegetation. Thus, the potential use of pig slurry as a nitrogen-rich organic amendment in different heavy metal contaminated soils has been evaluated; this also being a way of recycling this waste. In order to identify the factors affecting nitrification processes in heavy metal polluted soils (soil pH, heavy metal solubility and the N source), incubation experiments were run using two polluted soils with different pH values (5.0 and 7.1) and a non-contaminated soil (pH 8.2). Ammonium was added as pig slurry or as ammonium sulphate for comparison (both added at 150 mg NH(4)(+)-N kg(-1) of soil). Pig slurry provoked higher nitrification rates and N-immobilisation than ammonium sulphate, especially in the neutral-polluted soil, reflecting an improvement of the microbial activity in the soil. The microbial immobilisation of N led to an inverse relationship between the amount of N added and nitrate conversion in the neutral-polluted soil and in the non-contaminated soil amended with different pig slurry dosages (75, 150 and 225mg NH(4)(+)-N kg(-1) of soil). Low rates of nitrification and N-immobilisation were found in the acidic soil. Pig slurry addition to metal polluted soils enhanced soil nitrification, especially when metals were in low-solubility forms.", "keywords": ["[SDE] Environmental Sciences", "2. Zero hunger", "PIG SLURRY RECYCLING", "SOIL RECLAMATION", "Nitrogen", "Swine", "METAL SOLUBILITY", "04 agricultural and veterinary sciences", "Hydrogen-Ion Concentration", "15. Life on land", "NITRIFICATION", "6. Clean water", "12. Responsible consumption", "Manure", "Quaternary Ammonium Compounds", "MICROBIAL IMMOBILISATION", "Biodegradation", " Environmental", "13. Climate action", "METAL", "Metals", " Heavy", "Animals", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Soil Microbiology"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2010.08.026"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2010.08.026", "name": "item", "description": "10.1016/j.chemosphere.2010.08.026", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2010.08.026"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2010-10-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2012.05.092", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:53Z", "type": "Journal Article", "created": "2012-06-23", "title": "Effects Of Sewage Sludge Biochar On Plant Metal Availability After Application To A Mediterranean Soil", "description": "Pyrolytic conversion of sewage sludge into biochar could be a sustainable management option for Mediterranean agricultural soils. The aim of this work is to evaluate the effects of biochar from sewage sludge pyrolysis on soil properties; heavy metals solubility and bioavailability in a Mediterranean agricultural soil and compared with those of raw sewage sludge. Biochar (B) was prepared by pyrolysis of selected sewage sludge (SL) at 500\u00b0C. The pyrolysis process decreased the plant-available of Cu, Ni, Zn and Pb, the mobile forms of Cu, Ni, Zn, Cd and Pb and also the risk of leaching of Cu, Ni, Zn and Cd. A selected Mediterranean soil was amended with SL and B at two different rates in mass: 4% and 8%. The incubation experiment (200 d) was conducted in order to study carbon mineralization and trace metal solubility and bioavailability of these treatments. Both types of amendments increased soil respiration with respect to the control soil. The increase was lower in the case of B than when SL was directly added. Metals mobility was studied in soil after the incubation and it can be established that the risk of leaching of Cu, Ni and Zn were lower in the soil treated with biochar that in sewage sludge treatment. Biochar amended samples also reduced plant availability of Ni, Zn, Cd and Pb when compared to sewage sludge amended samples.", "keywords": ["Sewage", "Mediterranean Region", "Agriculture", "04 agricultural and veterinary sciences", "Plants", "Risk Assessment", "Waste Disposal", " Fluid", "01 natural sciences", "6. Clean water", "12. Responsible consumption", "Soil", "Metals", "Charcoal", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2012.05.092"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2012.05.092", "name": "item", "description": "10.1016/j.chemosphere.2012.05.092", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2012.05.092"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2012-11-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2012.08.042", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:53Z", "type": "Journal Article", "created": "2012-09-16", "title": "Role Of Edta In Arsenic Mobilization And Its Uptake By Maize Grown On An As-Polluted Soil", "description": "EDTA amendments are widely used for micronutrient fertilization in arid soils, besides their effectiveness in the remediation process of heavy metal from contaminated soils. However, the persistence of EDTA in arsenic contaminated soil may have further negative effects on the grown plants. To investigate the influences of EDTA on soil As, a pot experiment was conducted using a sandy clay loam As-polluted soil treated with gradual rates of EDTA (0, 1.0, 2.5 and 5 mmol kg(-1)) and planted with maize for two months. The key findings reveal that EDTA applications increased AB-DTPA extractable and water soluble As significantly. Such increases seemed to be the main reasons behind the increase in As uptake by maize plants as the addition of EDTA at the rates of 1.0, 2.5 and 5.0 mmol kg(-1) increased significantly As uptake by shoots 1.5, 2.4 and 3.0 folds, respectively compared to the untreated soil. On the other hand, As uptake by roots did not increase significantly except with the highest application rates of 2.5 and 5.0 mmol kg(-1). The results also show that arsenic translocation factor (TF) values were too low to attain successful phytoextraction. In conclusion, the bioavailable fraction of As is important to investigate the phytoextraction and phytotoxicity of As.", "keywords": ["2. Zero hunger", "04 agricultural and veterinary sciences", "Zea mays", "01 natural sciences", "6. Clean water", "Arsenic", "Soil", "Biodegradation", " Environmental", "13. Climate action", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Edetic Acid", "Environmental Restoration and Remediation", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2012.08.042"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2012.08.042", "name": "item", "description": "10.1016/j.chemosphere.2012.08.042", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2012.08.042"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2013-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2014.06.024", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:53Z", "type": "Journal Article", "created": "2014-07-08", "title": "Combining Phytoextraction And Biochar Addition Improves Soil Biochemical Properties In A Soil Contaminated With Cd", "description": "The main goal of phytoremediation is to improve ecosystem functioning. Soil biochemical properties are considered as effective indicators of soil quality and are sensitive to various environmental stresses, including heavy metal contamination. The biochemical response in a soil contaminated with cadmium was tested after several treatments aimed to reduce heavy metal availability including liming, biochar addition and phytoextraction using Amaranthus tricolor L. Two biochars were added to the soil: eucalyptus pyrolysed at 600 \u00b0C (EB) and poultry litter at 400 \u00b0C (PLB). Two liming treatments were chosen with the aim of bringing soil pH to the same values as in the treatments EB and PLB. The properties studied included soil microbial biomass C, soil respiration and the activities of invertase, \u03b2-glucosidase, \u03b2-glucosaminidase, urease and phosphomonoesterase. Both phytoremediation and biochar addition improved soil biochemical properties, although results were enzyme specific. For biochar addition these changes were partly, but not exclusively, mediated by alterations in soil pH. A careful choice of biochar must be undertaken to optimize the remediation process from the point of view of metal phytoextraction and soil biological activity.", "keywords": ["China", "Eucalyptus", "Amaranthus", "Oxides", "04 agricultural and veterinary sciences", "Calcium Compounds", "15. Life on land", "01 natural sciences", "Gas Chromatography-Mass Spectrometry", "Mass Spectrometry", "6. Clean water", "3. Good health", "Soil", "Biodegradation", " Environmental", "Charcoal", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Cadmium", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2014.06.024"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2014.06.024", "name": "item", "description": "10.1016/j.chemosphere.2014.06.024", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2014.06.024"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2015-01-01T00:00:00Z"}}, {"id": "10.1016/j.chemosphere.2022.136146", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:53Z", "type": "Journal Article", "created": "2022-08-26", "title": "Phytoextraction of Cu, Cd, Zn and As in four shrubs and trees growing on soil contaminated with mining waste", "description": "Mining activity has degraded large extensions of soil and its waste is composed of metals, anthropogenic chemicals, and sterile rocks. The use of native species in the recovery of polluted soils improves the conditions for the emergence of other species, tending to a process of ecosystem restoration. The objective of this study was to evaluate the bioaccumulation of metal(loid)s in four species of native plants and the effect of their distribution and bioavailability in soil with waste from an abandoned gold mine. Soil samples were taken from two sites in La Planta, San Juan, Argentina: Site 1 and Site 2 (mining waste and reference soil, respectively). In Site 1, vegetative organ samples were taken from Larrea cuneifolia, Bulnesia retama, Plectrocarpa tetracantha, and Prosopis flexuosa. The concentration of metal(loid)s in soil from Site 1 were Zn\u00a0>\u00a0As\u00a0>\u00a0Cu\u00a0>\u00a0Cd, reaching values of 7123, 6516, 240 and 76\u00a0mg\u00a0kg-1, respectively. The contamination indices were among the highest categories of contamination for all four metal(loid)s. The spatial interpolation analysis showed the effect of the vegetation as the lowest concentration of metal(loid)s were found in rhizospheric soil. The maximum concentrations of As, Cu, Cd and Zn found in vegetative organs were 371, 461, 28, and 1331\u00a0mg\u00a0kg-1, respectively. L. cuneifolia and B. retama presented high concentrations of Cu and Zn. The most concentrated metal(loid)s in P. tetracantha and P. flexuosa were Zn, As and Cu. Cd was the least concentrated metal in all four species. The values of BAF and TF were greater than one for all four species. In conclusion, the different phytoextraction capacities and the adaptations to arid environments of these four species are an advantage for future phytoremediation strategies. Their application contributes to the ecological restoration and risk reduction, allowing the recovery of ecosystem services.", "keywords": ["Biodisponibilidad", "Bioavailability", "BIOAVAILABILITY", "Soil pollution", "01 natural sciences", "Mining", "Trees", "Bioacumulaci\u00f3n", "SOIL POLLUTION", "Soil", "https://purl.org/becyt/ford/1.5", "Metals", " Heavy", "Poluci\u00f3n del Suelo", "Metales", "Soil Pollutants", "https://purl.org/becyt/ford/1", "Ecosystem", "0105 earth and related environmental sciences", "2. Zero hunger", "Metal", "Abandoned mine", "ABANDONED MINE", "PHYTOREMEDIATION", "BIOACCUMULATION", "15. Life on land", "Bioaccumulation", "6. Clean water", "Phytoremediation", "Zinc", "Biodegradation", " Environmental", "Metals", "13. Climate action", "METAL", "Miner\u00eda", "Fitodecontaminaci\u00f3n", "Gold", "Soil Pollution", "Cadmium", "Environmental Monitoring"]}, "links": [{"href": "https://doi.org/10.1016/j.chemosphere.2022.136146"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Chemosphere", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.chemosphere.2022.136146", "name": "item", "description": "10.1016/j.chemosphere.2022.136146", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.chemosphere.2022.136146"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-12-01T00:00:00Z"}}, {"id": "10.1016/j.ecoenv.2003.09.011", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:56Z", "type": "Journal Article", "created": "2003-12-13", "title": "Effects Of Heavy Metals On Earthworms Along Contamination Gradients In Organic Rich Soils", "description": "Earthworm communities and metal (bio)availability to earthworms along contamination gradients was studied in order to support chemical analyses in risk assessment of metal contaminated soils. Earthworms were sampled in three metal contaminated areas with different habitat and soil properties in Finland. Earthworm and soil samples were collected at three distances (1, 2, and 4 km) from the emission sources. Earthworms were identified as to species and analyzed for heavy metals. Total soil metal concentrations were analyzed using an ultrasound-assisted extraction method and bioavailable metal fraction was estimated by acetic acid extraction. In two of the three areas studied, heavy metal concentrations close to the emission sources were high enough to have harmful effects on earthworms and their environments. In general, diversity, total numbers, and biomass of earthworms increased with increasing distance from the emission sources. When individuals were available for analyses close to the emission source, positive correlations between metal concentrations in the earthworms and those in the soils were observed.", "keywords": ["13. Climate action", "Metals", " Heavy", "Population Dynamics", "Animals", "Biological Availability", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Biomass", "04 agricultural and veterinary sciences", "Oligochaeta", "Risk Assessment", "01 natural sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.ecoenv.2003.09.011"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Ecotoxicology%20and%20Environmental%20Safety", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.ecoenv.2003.09.011", "name": "item", "description": "10.1016/j.ecoenv.2003.09.011", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.ecoenv.2003.09.011"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2004-11-01T00:00:00Z"}}, {"id": "10.1016/j.ecoenv.2012.01.003", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:56Z", "type": "Journal Article", "created": "2012-01-28", "title": "Effects Of Soil Dilution And Amendments (Mussel Shell, Cow Bone, And Biochar) On Pb Availability And Phytotoxicity In Military Shooting Range Soil", "description": "Bioavailability and bioaccessibility determine the level of metal toxicity in the soils. Inorganic soil amendments may decrease metal bioavailability and enhance soil quality. This study used mussel shell, cow bone, and biochar to reduce lead (Pb) toxicity in the highly contaminated military shooting range soil in Korea. Water-soluble and 1-M ammonium nitrate extractions, and a modified physiologically based extraction test (PBET) were performed to determine Pb bioavailability and bioaccessibility in the soil, respectively. Active C in the soil was also measured to evaluate the effects of the amendments on biological soil quality. The Pb contaminated soil was diluted in serial with uncontaminated soil for the bioassays. Seed germination and root elongation tests using lettuce (Lactuca sativa) showed increases in germination percentage and root length in soil treated with the amendments. Biochar was most effective and increased seed germination by 360% and root length by 189% compared to the unamended soil. Up to 20% soil dilution resulted in more than 50% seed germination. Bioavailability and bioaccessibility of Pb in the soils were decreased by 92.5% and 48.5% with mussel shell, by 84.8% and 34.5% with cow bone, and by 75.8% and 12.5% with biochar, respectively, compared to the unamended soil. We found that the Pb availability in the military shooting range soil can be reduced effectively by the tested amendments or soil dilution alternately, thereby decreasing the risk of ecotoxicity. Furthermore, the increasing active C from the amendments revitalized the soil contaminated with Pb.", "keywords": ["2. Zero hunger", "Korea", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "Bone and Bones", "6. Clean water", "Soil", "Lead", "Animal Shells", "Charcoal", "Animals", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Environmental Pollution", "Environmental Restoration and Remediation", "Lactuca", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.ecoenv.2012.01.003"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Ecotoxicology%20and%20Environmental%20Safety", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.ecoenv.2012.01.003", "name": "item", "description": "10.1016/j.ecoenv.2012.01.003", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.ecoenv.2012.01.003"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2012-05-01T00:00:00Z"}}, {"id": "10.1016/j.ecoenv.2016.03.019", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:15:56Z", "type": "Journal Article", "created": "2016-04-06", "title": "Assessing Microbial Activities In Metal Contaminated Agricultural Volcanic Soils - An Integrative Approach", "description": "Volcanic soils are unique naturally fertile resources, extensively used for agricultural purposes and with particular physicochemical properties that may result in accumulation of toxic substances, such as trace metals. Trace metal contaminated soils have significant effects on soil microbial activities and hence on soil quality. The aim of this study is to determine the soil microbial responses to metal contamination in volcanic soils under different agricultural land use practices (conventional, traditional and organic), based on a three-tier approach: Tier 1 - assess soil microbial activities, Tier 2 - link the microbial activity to soil trace metal contamination and, Tier 3 - integrate the microbial activity in an effect-based soil index (Integrative Biological Response) to score soil health status in metal contaminated agricultural soils. Our results showed that microbial biomass C levels and soil enzymes activities were decreased in all agricultural soils. Dehydrogenase and \u03b2-glucosidase activities, soil basal respiration and microbial biomass C were the most sensitive responses to trace metal soil contamination. The Integrative Biological Response value indicated that soil health was ranked as: organic>traditional>conventional, highlighting the importance of integrative biomarker-based strategies for the development of the trace metal 'footprint' in Andosols.", "keywords": ["2. Zero hunger", "beta-Glucosidase", "Agriculture", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "6. Clean water", "Soil", "Metals", "13. Climate action", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Biomass", "Oxidoreductases", "Soil Microbiology", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://orca.cardiff.ac.uk/id/eprint/102750/1/Parelho%202016.pdf"}, {"href": "https://doi.org/10.1016/j.ecoenv.2016.03.019"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Ecotoxicology%20and%20Environmental%20Safety", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.ecoenv.2016.03.019", "name": "item", "description": "10.1016/j.ecoenv.2016.03.019", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.ecoenv.2016.03.019"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-07-01T00:00:00Z"}}, {"id": "10.1016/j.scitotenv.2016.03.226", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:16:41Z", "type": "Journal Article", "created": "2016-04-22", "title": "Biosolids Applied To Agricultural Land: Influence On Structural And Functional Endpoints Of Soil Fauna On A Short- And Long-Term Scale", "description": "Biosolids have well-documented crop and soil benefits similar to other sources of organic amendment, but there is environmental concern due to biosolids-associated pollutants. The present study investigated two field sites that had received biosolids at commercial-scale rates in parallel to associated field sections which were managed similarly but without receiving biosolids (controls). The investigated endpoints were abundance and diversity of soil organisms (nematodes, enchytraeids and earthworms) and soil fauna feeding activity as measured by the bait lamina assay. Repeated sampling of one of the field sites following the only biosolids application demonstrated an enrichment effect typical for organic amendments, which was mostly exhausted after 44months. After an initial suppression, the proportion of free-living plant-parasitic nematodes tended to increase in the biosolids-amended soil over time. Yet, none of the endpoints at this site indicated significant negative effects resulting from the biosolids until 44months post application. In contrast to the repeatedly tilled first field site, the second one was left fallow after three biosolids applications, and was sampled 96months post last application. It was only at this field site that potential evidence for a long-term impact of biosolids was detected with regard to two endpoints: earthworm abundance and structure of the nematode assemblage. Agricultural management and correlation with abiotic soil parameters explained the observed difference in earthworm abundance. Yet, the development of a highly structured and mature nematode assemblage at the control but not at the biosolids-amended section of this fallow field could not be explained by such correlations nor by soil metal concentrations. Overall, the present study found only weak evidence for negative long-term impacts of biosolids applied at commercial rates on soil fauna. High-level community parameters such as the nematode structure index (SI) appeared more suitable to detect deleterious effects on soil fauna than simple abundance measurements.", "keywords": ["2. Zero hunger", "Agriculture", "04 agricultural and veterinary sciences", "15. Life on land", "Waste Disposal", " Fluid", "01 natural sciences", "13. Climate action", "Animals", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Oligochaeta", "Fertilizers", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.scitotenv.2016.03.226"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20of%20The%20Total%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.scitotenv.2016.03.226", "name": "item", "description": "10.1016/j.scitotenv.2016.03.226", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.scitotenv.2016.03.226"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-08-01T00:00:00Z"}}, {"id": "10.1016/j.envpol.2005.01.007", "type": "Feature", "geometry": null, "properties": {"updated": "2026-05-24T16:16:04Z", "type": "Journal Article", "created": "2005-03-15", "title": "Organochlorine Compounds In Soils And Sediments Of The Mountain Andean Lakes", "description": "Semi-volatile organochlorine compounds (OC) were analyzed in remote Andean soils and lake sediments. The sampling sites covered a wide latitudinal gradient from 18 degrees S to 46 degrees S along Chile and an altitudinal gradient (10-4500 m). The concentrations were in the order of background levels, involving absence of major pollution sources in the high mountain areas. Significant correlations were found between log-transformed concentrations of hexachlorobenzene, alpha- and gamma-hexachlorocyclohexane in soils and total organic content (TOC). In addition, TOC-normalized concentrations of the most volatile OC showed a significant linear dependence with air temperature. This good agreement points to temperature as a significant factor for the retention of long range transported OC in remote ecosystems such as the Andean mountains, although other variables should not be totally excluded. The highest concentrations of OCs were achieved in the sites located at highest altitude and lowest temperature of the dataset.", "keywords": ["Geologic Sediments", "Altitude", "lake sediments", "Temperature", "organochlorine compounds; Andean range; long range transport; soil; lake sediments", "Fresh Water", "Organochlorine compounds", "15. Life on land", "01 natural sciences", "Lake sediments", "soil", "organochlorine compound", "Andean range", "Long range transport", "Soil", "13. Climate action", "Hydrocarbons", " Chlorinated", "Soil Pollutants", "Chile", "long range transport", "Environmental Monitoring", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.envpol.2005.01.007"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envpol.2005.01.007", "name": "item", "description": "10.1016/j.envpol.2005.01.007", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envpol.2005.01.007"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2005-07-01T00:00:00Z"}}], "links": [{"rel": "self", "type": "application/geo+json", "title": "This document as GeoJSON", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Soil+Pollutants&f=json", "hreflang": "en-US"}, {"rel": "alternate", "type": "text/html", "title": "This document as HTML", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Soil+Pollutants&f=html", "hreflang": "en-US"}, {"rel": "collection", "type": "application/json", "title": "Collection URL", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main", "hreflang": "en-US"}, {"type": "application/geo+json", "rel": "first", "title": "items (first)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Soil+Pollutants&", "hreflang": "en-US"}, {"rel": "next", "type": "application/geo+json", "title": "items (next)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Soil+Pollutants&offset=50", "hreflang": "en-US"}], "numberMatched": 243, "numberReturned": 50, "distributedFeatures": [], "timeStamp": "2026-05-25T07:18:07.714913Z"}