{"type": "FeatureCollection", "features": [{"id": "10.1007/978-3-031-12786-1_33", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:14:20Z", "type": "Report", "created": "2023-01-01", "title": "MONARCH Regional Reanalysis of\u00a0Desert Dust Aerosols: An Initial Assessment", "description": "Open AccessWe acknowledge the DustClim project which is part of ERA4CS, an ERA-NET initiated by JPI Climate, and funded by FORMAS (SE), DLR (DE), BMWFW (AT), IFD (DK), MINECO (ES), ANR (FR) with co-funding by the European Union\u2019s Horizon 2020 research and innovation programme (Grant n. 690462). BSC co-authors also acknowledge support from the European Research Council under the European Union\u2019s Horizon 2020 research and innovation programme (grant n. 773051; FRAGMENT), the AXA Research Fund, the 60 Spanish Ministry of Science, Innovation and Universities (grant n. RYC-2015-18690 and CGL2017-88911-R), the European Union\u2019s Horizon 2020 research and innovation programme (grant n. 792103; SOLWARIS). This work has been partially funded by the contribution agreement between AEMET and BSC to carry out development and improvement activities of the products and services supplied by the WMO Sand and Dust Storm Regional Centres. Jer\u00f3nimo Escribano and Martina Klose have received funding from the European Union\u2019s Horizon 2020 research and innovation programme, respectively, under the Marie Sk\u0142odowska-Curie grant agreements H2020-MSCA-COFUND-2016- 65 754433 and H2020-MSCA-IF-2017-789630. Martina Klose further acknowledges support through the Helmholtz Association\u2019s Initiative and Networking Fund (grant agreement n. VH-NG-1533). We acknowledge PRACE (eDUST, eFRAGMENT1, and eFRAGMENT2) and RES (AECT-2019-3-0001, AECT-2020-1-0007, AECT-2020-3-0013) for awarding access to MareNostrum at the BSC and for providing technical support.", "keywords": ["\u00c0rees tem\u00e0tiques de la UPC::Enginyeria mec\u00e0nica::Mec\u00e0nica de fluids", "info:eu-repo/classification/ddc/550", "Aerosol speciation", "550", "ddc:550", "Aerosol data assimilation", "Dust", "Aerosols atmosf\u00e8rics", "Atmospheric aerosols", "\u00c0rees tem\u00e0tiques de la UPC::Desenvolupament hum\u00e0 i sostenible::Enginyeria ambiental", "Earth sciences", "Aerosol regional reanalysis", "Pols -- Control", "13. Climate action", "2023 OA procedure", "Modis deep blue", "Dust control"]}, "links": [{"href": "https://link.springer.com/content/pdf/10.1007/978-3-031-12786-1"}, {"href": "https://link.springer.com/content/pdf/10.1007/978-3-031-12786-1_33"}, {"href": "https://doi.org/10.1007/978-3-031-12786-1_33"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/978-3-031-12786-1_33", "name": "item", "description": "10.1007/978-3-031-12786-1_33", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/978-3-031-12786-1_33"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-01-01T00:00:00Z"}}, {"id": "10.1007/s11104-009-0229-1", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:14:50Z", "type": "Journal Article", "created": "2009-12-01", "title": "Soil Factors Affecting Selenium Concentration In Wheat Grain And The Fate And Speciation Of Se Fertilisers Applied To Soil", "description": "UK crops have a low selenium (Se) status, therefore Se fertilisation of wheat (Triticum aestivum L.) at 10 field sites was investigated and the effect on the content and speciation of Se in soils determined. Soil characterisation was carried out at each field site to determine the soil factors that may influence wheat grain Se concentrations in unfertilised plots. Soil samples were taken after harvest from each treatment to determine the fate and speciation of selenate fertiliser applied to soil. Wheat grain Se concentrations could be predicted from soil Se concentration and soil extractable sulphur (S) using the following regression model: Grain Se = a + b(total soil Se) + c(extractable soil Se) - d(extractable soil S), with 86 % of the variance being accounted for, suggesting that these properties control Se concentrations in grain from unfertilised plots. Extractable soil Se concentrations were low (2.4 \u2013 12.4 \u00b5g kg\u22121) and predominantly consisted of selenite (up to 70 % of extractable Se) and soluble organic forms, whereas selenate was below the detection limit. Little of the added Se, in either liquid or granular form was left in the soil after crop harvest. Se fertilisation up to 20 g ha\u22121 did not lead to a significant Se accumulation in the soil, suggesting losses of Se unutilised by the crop.", "keywords": ["2. Zero hunger", "550", "Selenium speciation", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "630", "Residual effect", "Selenium", "Soil", "Wheat", "1110 Plant Science", "0401 agriculture", " forestry", " and fisheries", "Biofortification", "1111 Soil Science", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1007/s11104-009-0229-1"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Plant%20and%20Soil", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s11104-009-0229-1", "name": "item", "description": "10.1007/s11104-009-0229-1", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s11104-009-0229-1"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-12-02T00:00:00Z"}}, {"id": "10.1007/s11104-009-0230-8", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:14:50Z", "type": "Journal Article", "created": "2009-11-24", "title": "Impact Of Sulphur Fertilisation On Crop Response To Selenium Fertilisation", "description": "UK wheat (Triticum aestivum L.) has a low selenium (Se) concentration and agronomic biofortification with Se is a proposed solution. A possible limitation is that UK wheat is routinely fertilised with sulphur (S), which may affect uptake of Se by the crop. The response of wheat to Se and S fertilisation and residual effects of Se were determined in field trials over 2 consecutive years. Selenium fertilisation at 20\u00a0g\u00a0ha\u22121 as sodium selenate increased grain Se by four to seven fold, up to 374\u00a0\u00b5g\u00a0Se\u00a0kg\u22121. Sulphur fertilisation produced contrasting effects in 2\u00a0years; in year 1 when the crop was not deficient in S, grain Se concentration was significantly enhanced by S, whereas in year 2 when crop yield responded significantly to S fertilisation, grain Se concentration was decreased significantly in the S-fertilised plots. An incubation experiment showed that addition of sulphate enhanced the recovery of selenate added to soils, probably through a suppression of selenate transformation to other unavailable forms in soils. Our results demonstrate complex interactions between S and Se involving both soil and plant physiological processes; S can enhance Se availability in soil but inhibit selenate uptake by plants. Furthermore, no residual effect of Se fertiliser applied in year 1 was found on the following crop.", "keywords": ["0106 biological sciences", "2. Zero hunger", "571", "Selenium speciation", "500", "04 agricultural and veterinary sciences", "Sulphate", "15. Life on land", "01 natural sciences", "630", "Selenium", "Sulphur", "Wheat", "1110 Plant Science", "0401 agriculture", " forestry", " and fisheries", "Selenium biofortification", "1111 Soil Science"]}, "links": [{"href": "https://doi.org/10.1007/s11104-009-0230-8"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Plant%20and%20Soil", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s11104-009-0230-8", "name": "item", "description": "10.1007/s11104-009-0230-8", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s11104-009-0230-8"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-11-25T00:00:00Z"}}, {"id": "10.1016/j.envpol.2008.11.050", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:15:36Z", "type": "Journal Article", "created": "2009-01-19", "title": "Ion Activity And Distribution Of Heavy Metals In Acid Mine Drainage Polluted Subtropical Soils", "description": "The oxidative dissolution of mine wastes gives rise to acidic, metal-enriched mine drainage (AMD) and has typically posed an additional risk to the environment. The poly-metallic mine Dabaoshan in South China is an excellent test site to understand the processes affecting the surrounding polluted agricultural fields. Our objectives were firstly to investigate metal ion activity in soil solution, distribution in solid constituents, and spatial distribution in samples, secondly to determine dominant environment factors controlling metal activity in the long-term AMD-polluted subtropical soils. Soil Column Donnan Membrane Technology (SC-DMT) combined with sequential extraction shows that unusually large proportion of the metal ions are present as free ion in the soil solutions. The narrow range of low pH values prevents any pH effects during the binding onto oxides or organic matter. The differences in speciation of the soil solutions may explain the different soil degradation observed between paddy and non-paddy soils.", "keywords": ["China", "Time Factors", "550", "Speciation", "0211 other engineering and technologies", "Industrial Waste", "02 engineering and technology", "Chemical Fractionation", "01 natural sciences", "Mining", "Soil", "Acid mine drainage", "X-Ray Diffraction", "Metals", " Heavy", "Soil Pollutants", "Humic Substances", "0105 earth and related environmental sciences", "Ions", "Hydrogen-Ion Concentration", "15. Life on land", "6. Clean water", "Tropical soils", "13. Climate action", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "Sorption", "Free ion", "Environmental Monitoring"]}, "links": [{"href": "https://doi.org/10.1016/j.envpol.2008.11.050"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envpol.2008.11.050", "name": "item", "description": "10.1016/j.envpol.2008.11.050", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envpol.2008.11.050"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2009-04-01T00:00:00Z"}}, {"id": "10.1016/j.envpol.2021.116897", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:15:37Z", "type": "Journal Article", "created": "2021-03-13", "title": "X-ray absorption spectroscopy evidence of sulfur-bound cadmium in the Cd-hyperaccumulator Solanum nigrum and the non-accumulator Solanum melongena", "description": "It has been proposed that non-protein thiols and organic acids play a major role in cadmium phytoavailability and distribution in plants. In the Cd-hyperaccumulator Solanum nigrum and non-accumulator Solanum melongena, the role of these organic ligands in the accumulation and detoxification mechanisms of Cd are debated. In this study, we used X-ray absorption spectroscopy to investigate Cd speciation in these plants (roots, stem, leaves) and in the soils used for their culture to unravel the plants responses to Cd exposure. The results show that Cd in the 100\u00a0mg\u00a0kg-1 Cd-doped clayey loam soil is sorbed onto iron oxyhydroxides. In both S.\u00a0nigrum and S.\u00a0melongena, Cd in roots and fresh leaves is mainly bound to thiol ligands, with a small contribution of inorganic S ligands in S.\u00a0nigrum leaves. We interpret the Cd binding to sulfur ligands as detoxification mechanisms, possibly involving the sequestration of Cd complexed with glutathione or phytochelatins in the plant vacuoles. In the stems, results show an increase binding of Cd to -O ligands (>50% for S.\u00a0nigrum). We suggest that Cd is partly complexed by organic acids for transportation in the sap.", "keywords": ["[SDE] Environmental Sciences", "0106 biological sciences", "570", "[CHIM.ANAL] Chemical Sciences/Analytical chemistry", "Speciation", "Plant Roots", "01 natural sciences", "[SDV.BV.BOT] Life Sciences [q-bio]/Vegetal Biology/Botanics", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDE.ES] Environmental Sciences/Environment and Society", "Soil Pollutants", "Solanum melongena", "Solanaceae", "Solanum nigrum", "0105 earth and related environmental sciences", "580", "Toxicity", "X-Ray absorption spectroscopy", "[SDV.BV.BOT]Life Sciences [q-bio]/Vegetal Biology/Botanics", "3. Good health", "Biodegradation", " Environmental", "X-Ray Absorption Spectroscopy", "13. Climate action", "[SDE]Environmental Sciences", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "Sulfur", "Cadmium"]}, "links": [{"href": "https://doi.org/10.1016/j.envpol.2021.116897"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.envpol.2021.116897", "name": "item", "description": "10.1016/j.envpol.2021.116897", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.envpol.2021.116897"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-01-01T00:00:00Z"}}, {"id": "10.1016/j.jenvman.2019.02.120", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:15:56Z", "type": "Journal Article", "created": "2019-03-06", "title": "Distribution trend of trace elements in digestate exposed to air: Laboratory-scale investigations using DGT-based fractionation", "description": "The use of digestate as amendment for agricultural soils has already been proposed as an alternative to mineral fertilizers or undigested organic matter. However, little information is available concerning the effect of digestate atmospheric exposure on trace elements speciation and, consequently, on their mobility and bio-accessibility when digestate is stored in open tanks or handled before land spreading. In this study, we investigated at laboratory-scale the effect of digestate aeration on the distribution of Al, As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Se and W using the diffusive gradients in thin films technique (DGT)-based fractionation. For this purpose, experiments were performed to assess the variation in distribution between the labile, soluble and particulate fractions over time in digested sewage sludge during passive and forced aeration. Results showed that aeration promoted a dissolution of Al, As, Co, Cr, Cu, Fe, Mn, Mo and Pb, suggesting a possible increase in their mobility that may likely occur during storage in open tanks or handling before land spreading. Labile elements' fraction increased only during forced aeration (except for Fe and Mn), suggesting that their short-term bio-accessibility can increase only after significant aeration as the one assumed to occur when land spreading takes place.", "keywords": ["550", "[SPI.GPROC] Engineering Sciences [physics]/Chemical and Process Engineering", "Speciation", "[SDU.STU]Sciences of the Universe [physics]/Earth Sciences", "Diffusive gradients in thin films (DGT)", "Chemical Fractionation", "01 natural sciences", "630", "Soil", "Digested sewage sludge", "[SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering", "Fractionation", "Diffusive gradients in thin films (DGT); Digested sewage sludge; Fractionation; Metalloids; Metals; Speciation; Chemical Fractionation; Environmental Monitoring; Sewage; Soil; Trace Elements", "Metalloids", "0105 earth and related environmental sciences", "2. Zero hunger", "Sewage", "04 agricultural and veterinary sciences", "15. Life on land", "6. Clean water", "Trace Elements", "Metals", "13. Climate action", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "0401 agriculture", " forestry", " and fisheries", "Environmental Monitoring"]}, "links": [{"href": "https://doi.org/10.1016/j.jenvman.2019.02.120"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Environmental%20Management", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.jenvman.2019.02.120", "name": "item", "description": "10.1016/j.jenvman.2019.02.120", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.jenvman.2019.02.120"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-05-01T00:00:00Z"}}, {"id": "10.1016/j.talanta.2018.09.033", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:16:26Z", "type": "Journal Article", "created": "2018-09-12", "title": "Assessment of the DGT technique in digestate to fraction twelve trace elements", "description": "This study proposes an evaluation of the diffusive gradients in thin films technique (DGT) for studying trace elements in digested sewage sludge samples. Twelve elements were monitored by Chelex (Al, Cd, Co, Cr (III), Cu, Fe, Mn, Ni, Pb) and zirconia-DGT (As, Mo, Se) samplers exposed from 4\u202fh to 9 days. Twenty-four hours' deployment time was suitable for most of the studied elements. However, short deployment led to insufficient element accumulation or non-establishment of steady state while long deployment (from 18 to 144\u202fh depending on the element) led to saturation of the binding gels and/or competing effects with other major elements. In addition, this study showed that the matrix of the digested sewage sludge lowers the accumulation of some trace elements in the DGT samplers, leading to labile concentrations underestimation of roughly 10-30% (depending on the element). Moreover, compared to the conventional total dissolved elements measurement, DGT technique allowed to quantify 7 out of 12 labile elements whereas only 3 out of 12 dissolved elements were quantified. These results highlight the potential of DGT technique to assess labile trace elements in digestate samples, provided a careful adaptation of the deployment time as well as an evaluation of the matrix effect is performed.", "keywords": ["550", "[SDE.IE]Environmental Sciences/Environmental Engineering", "Matrix interferences", "Speciation", "Metalloids Speciation", "Chemistry (all)", "Biochemistry", "01 natural sciences", "6. Clean water", "Analytical Chemistry", "0104 chemical sciences", "Passive sampling", "[CHIM.ANAL]Chemical Sciences/Analytical chemistry", "Digested sewage sludge", "Metals", "628", "Digested sewage sludge; Matrix interferences; Metalloids; Metals; Passive sampling; Speciation; Analytical Chemistry; Chemistry (all); Biochemistry; Spectroscopy", "Spectroscopy", "Metalloids", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.talanta.2018.09.033"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Talanta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.talanta.2018.09.033", "name": "item", "description": "10.1016/j.talanta.2018.09.033", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.talanta.2018.09.033"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-01-01T00:00:00Z"}}, {"id": "10.1021/acs.est.4c09261", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:16:32Z", "type": "Journal Article", "created": "2024-11-04", "title": "Geochemical Decoupling of Iron and Zinc during Transformation of Zn-Bearing Ferrihydrite in Reducing Sediments", "description": "Open AccessISSN:0013-936X", "keywords": ["Geologic Sediments", "zinc carbonate", "Iron", "Mossbauer spectroscopy", "X-ray absorption spectroscopy", "mineral transformation; Mossbauer spectroscopy; X-ray absorption spectroscopy; environmental speciation; green rust; zinc sulfide; zinc carbonate", "Ferric Compounds", "Zinc", "Spectroscopy", " Mossbauer", "green rust", "X-Ray Absorption Spectroscopy", "zinc sulfide", "Oxidation-Reduction", "mineral transformation", "environmental speciation"], "contacts": [{"organization": "Lefebvre, Pierre, Grigg, Andrew R. C., Kretzschmar, Ruben,", "roles": ["creator"]}]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.4c09261"}, {"href": "https://doi.org/10.1021/acs.est.4c09261"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.4c09261", "name": "item", "description": "10.1021/acs.est.4c09261", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.4c09261"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-11-04T00:00:00Z"}}, {"id": "10.1111/mec.14358", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-09-21T16:17:53Z", "type": "Journal Article", "created": "2017-09-19", "title": "Speciation below ground: Tempo and mode of diversification in a radiation of endogean ground beetles", "description": "Abstract<p>Dispersal is a critical factor determining the spatial scale of speciation, which is constrained by the ecological characteristics and distribution of a species\uffe2\uff80\uff99 habitat and the intrinsic traits of species. Endogean taxa are strongly affected by the unique qualities of the below\uffe2\uff80\uff90ground environment and its effect on dispersal, and contrasting reports indicate either high dispersal capabilities favoured by small body size and mediated by passive mechanisms, or low dispersal due to restricted movement and confinement inside the soil. We studied a species\uffe2\uff80\uff90rich endogean ground beetle lineage, Typhlocharina, including three genera and more than 60 species, as a model for the evolutionary biology of dispersal and speciation in the deep soil. A time\uffe2\uff80\uff90calibrated molecular phylogeny generated from &gt;400 individuals was used to delimit candidate species, to study the accumulation of lineages through space and time by species\uffe2\uff80\uff93area\uffe2\uff80\uff93age relationships and to determine the geographical structure of the diversification using the relationship between phylogenetic and geographic distances across the phylogeny. Our results indicated a small spatial scale of speciation in Typhlocharina and low dispersal capacity combined with sporadic long distance, presumably passive dispersal events that fuelled the speciation process. Analysis of lineage growth within Typhlocharina revealed a richness plateau correlated with the range of distribution of lineages, suggesting a long\uffe2\uff80\uff90term species richness equilibrium mediated by density dependence through limits of habitat availability. The interplay of area\uffe2\uff80\uff90 and age\uffe2\uff80\uff90dependent processes ruling the lineage diversification in Typhlocharina may serve as a general model for the evolution of high species diversity in endogean mesofauna.</p", "keywords": ["0106 biological sciences", "2. Zero hunger", "Geography", "Genetic Speciation", "Geographic speciation", "Endogean", "Density dependence", "15. Life on land", "Anillini", "01 natural sciences", "Coleoptera", "Long\u2010distance dispersal (LDD)", "Animals", "Microendemism", "Typhlocharina", "Ecosystem", "Phylogeny"]}, "links": [{"href": "https://doi.org/10.1111/mec.14358"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Molecular%20Ecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1111/mec.14358", "name": "item", "description": "10.1111/mec.14358", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1111/mec.14358"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-10-16T00:00:00Z"}}, {"id": "10.2139/ssrn.4249963", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:19:02Z", "type": "Journal Article", "created": "2022-10-19", "title": "A New NMVOC Speciated Inventory for a Reactivity-Based Approach to Support Ozone Control Strategies in Spain", "description": "Ozone (O3) pollution is a persistent problem in many regions of Spain, so understanding O3 precursor emissions and trends is essential to design effective control strategies. We estimated the impact of Non-Methane Volatile Organic Compounds (NMVOC) species upon O3 formation potential (OFP) using the maximum incremental reactivity approach. For this, we developed a speciated NMVOC emission inventory for Spain from 2010 to 2019 combining national reported emissions with state-of-the-art speciation profiles, which resulted in a database of emissions for over 900 individual NMVOC species and 153 individual sectors. Additionally, we analysed 2030 emission projections to quantify the expected impact of planned measures on future OFP levels. Overall, the main activities contributing to OFP in Spain are paint manufacturing and applications (20 %), manure management (16 %), and domestic solvent use (6 %). These activities contribute unevenly across regions. The more urbanised areas report a larger contribution from the solvent sector (64 % in Madrid), while in rural areas, manure management and agricultural waste burning gain importance (24 % in Extremadura), indicating that local control measures should be implemented. The top 10 NMVOC species contributing to OFP are ethanol, ethene, xylenes, propene, toluene, formaldehyde, 1,3-butadiene, styrene, n-butane, and cyclopentane, which together are responsible for 54 % of the total OFP. Our trend analysis indicates a reduction of NMVOC emissions and OFP of -5 % and -10 % between 2010 and 2019, respectively. The larger decrease in OFP is driven by a bigger reduction in xylenes (-29 %) and toluene (-28 %) from paint application industries and the road transport sector. By 2030 a significant increase (+37 %) in the OFP from the public electricity sector is expected due to the planned increase in biomass use for power generation. Our results indicate that policies should focus on paint reformulation, limiting aerosol products, and implementing NMVOC control devices in future biomass power plants.", "keywords": ["Anthropogenic emissions", "15. Life on land", "Tropospheric ozone", "01 natural sciences", "7. Clean energy", "Emission control strategies", "Article", "12. Responsible consumption", "\u00c0rees tem\u00e0tiques de la UPC::Desenvolupament hum\u00e0 i sostenible::Enginyeria ambiental", "Atmospheric ozone -- Spain", "OFP Tropospheric ozone", "NMVOC speciation", "OFP", "13. Climate action", "11. Sustainability", "Oz\u00f3 atmosf\u00e8ric -- Espanya", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.2139/ssrn.4249963"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/SSRN%20Electronic%20Journal", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.2139/ssrn.4249963", "name": "item", "description": "10.2139/ssrn.4249963", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.2139/ssrn.4249963"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-01-01T00:00:00Z"}}, {"id": "10.5061/dryad.mf3gd/9", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:19:50Z", "type": "Dataset", "title": "real-model1", "description": "settings and output for migrate-N model 1", "keywords": ["Spitsbergen", "Sweden", "Speciation", "the Netherlands", "Greenland", "population genetics", "SNP", "admixture", "Branta leucopsis", "cultural evolution", "migration modelling", "Russia"], "contacts": [{"organization": "Jonker, Rudy M., Kraus, Robert H. S., Zhang, Qiong, Van Hooft, Pim, Larsson, Kjell, Van Der Jeugd, Henk P., Kurvers, Ralf H. J. M., Van Wieren, Sip E., Loonen, Maarten J. J. E., Crooijmans, Richard P. M. A., Ydenberg, Ronald C., Groenen, Martien A. M., Prins, Herbert H. T.,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.5061/dryad.mf3gd/9"}, {"rel": "self", "type": "application/geo+json", "title": "10.5061/dryad.mf3gd/9", "name": "item", "description": "10.5061/dryad.mf3gd/9", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.5061/dryad.mf3gd/9"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2013-01-01T00:00:00Z"}}, {"id": "20.500.11850/705672", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:22:37Z", "type": "Journal Article", "created": "2024-11-04", "title": "Geochemical Decoupling of Iron and Zinc during Transformation of Zn-Bearing Ferrihydrite in Reducing Sediments", "description": "Open AccessISSN:0013-936X", "keywords": ["Geologic Sediments", "zinc carbonate", "Iron", "Mossbauer spectroscopy", "X-ray absorption spectroscopy", "mineral transformation; Mossbauer spectroscopy; X-ray absorption spectroscopy; environmental speciation; green rust; zinc sulfide; zinc carbonate", "Ferric Compounds", "Zinc", "Spectroscopy", " Mossbauer", "green rust", "X-Ray Absorption Spectroscopy", "zinc sulfide", "Oxidation-Reduction", "mineral transformation", "environmental speciation"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.4c09261"}, {"href": "https://doi.org/20.500.11850/705672"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "20.500.11850/705672", "name": "item", "description": "20.500.11850/705672", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/20.500.11850/705672"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-11-04T00:00:00Z"}}, {"id": "10.5281/zenodo.15024429", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:20:45Z", "type": "Dataset", "title": "Climate change and the transformation of non-toxic sediments into toxic soils", "description": "RestrictedENG: In recent years, the floodplain lakes of the Vistula River in Poland have been drying up and the sediments have been transforming into soils. The data show changes in physical and chemical properties between the sediments and the soils that developed from them. The study included texture, pH, hydrolytic acidity, total alkaline cations, total nitrogen, organic carbon, total content of Al, Ca, Fe, K, Mg, Mn, Na, P as well as heavy metals (Cd, Cr, Cu, Ni, Pb, Zn) and their speciation. In addition, a toxicity assessment of both materials was performed.   PL: W ostatnich latach starorzecza Wis\u0142y wysychaj\u0105, a osady przekszta\u0142caj\u0105 si\u0119 w gleby. Dane pokazuj\u0105 zmiany w\u0142a\u015bciwo\u015bci fizycznych i chemicznych mi\u0119dzy osadami a glebami, kt\u00f3re si\u0119 z nich wykszta\u0142ci\u0142y. Badania obejmowa\u0142y uziarnienie, pH, kwasowo\u015b\u0107 hydrolityczn\u0105, ca\u0142kowit\u0105 zawarto\u015b\u0107 kation\u00f3w zasadowych, azot ca\u0142kowity, w\u0119giel organiczny, ca\u0142kowit\u0105 zawarto\u015b\u0107 Al, Ca, Fe, K, Mg, Mn, Na, P, a tak\u017ce metali ci\u0119\u017ckich (Cd, Cr, Cu, Ni, Pb, Zn) i ich specjacj\u0119. Ponadto przeprowadzono ocen\u0119 toksyczno\u015bci obydwu materia\u0142\u00f3w.", "keywords": ["small lakes", "climate change", "13. Climate action", "sediments", "toxicity assessment", "15. Life on land", "heavy metals", "heavy metal speciation", "6. Clean water", "soil"], "contacts": [{"organization": "Gmitrowicz-Iwan, Joanna", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.5281/zenodo.15024429"}, {"rel": "self", "type": "application/geo+json", "title": "10.5281/zenodo.15024429", "name": "item", "description": "10.5281/zenodo.15024429", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.5281/zenodo.15024429"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2023-09-27T00:00:00Z"}}, {"id": "10261/184998", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:22:02Z", "type": "Journal Article", "created": "2017-09-19", "title": "Speciation below ground: Tempo and mode of diversification in a radiation of endogean ground beetles", "description": "Abstract<p>Dispersal is a critical factor determining the spatial scale of speciation, which is constrained by the ecological characteristics and distribution of a species\uffe2\uff80\uff99 habitat and the intrinsic traits of species. Endogean taxa are strongly affected by the unique qualities of the below\uffe2\uff80\uff90ground environment and its effect on dispersal, and contrasting reports indicate either high dispersal capabilities favoured by small body size and mediated by passive mechanisms, or low dispersal due to restricted movement and confinement inside the soil. We studied a species\uffe2\uff80\uff90rich endogean ground beetle lineage, Typhlocharina, including three genera and more than 60 species, as a model for the evolutionary biology of dispersal and speciation in the deep soil. A time\uffe2\uff80\uff90calibrated molecular phylogeny generated from &gt;400 individuals was used to delimit candidate species, to study the accumulation of lineages through space and time by species\uffe2\uff80\uff93area\uffe2\uff80\uff93age relationships and to determine the geographical structure of the diversification using the relationship between phylogenetic and geographic distances across the phylogeny. Our results indicated a small spatial scale of speciation in Typhlocharina and low dispersal capacity combined with sporadic long distance, presumably passive dispersal events that fuelled the speciation process. Analysis of lineage growth within Typhlocharina revealed a richness plateau correlated with the range of distribution of lineages, suggesting a long\uffe2\uff80\uff90term species richness equilibrium mediated by density dependence through limits of habitat availability. The interplay of area\uffe2\uff80\uff90 and age\uffe2\uff80\uff90dependent processes ruling the lineage diversification in Typhlocharina may serve as a general model for the evolution of high species diversity in endogean mesofauna.</p", "keywords": ["2. Zero hunger", "0106 biological sciences", "Geography", "Genetic Speciation", "Geographic speciation", "Endogean", "Density dependence", "15. Life on land", "Anillini", "01 natural sciences", "Coleoptera", "Long\u2010distance dispersal (LDD)", "Animals", "Microendemism", "Typhlocharina", "Ecosystem", "Phylogeny"]}, "links": [{"href": "https://doi.org/10261/184998"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Molecular%20Ecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10261/184998", "name": "item", "description": "10261/184998", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10261/184998"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-10-16T00:00:00Z"}}, {"id": "2117/383484", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:22:43Z", "type": "Report", "created": "2023-01-01", "title": "MONARCH Regional Reanalysis of\u00a0Desert Dust Aerosols: An Initial Assessment", "description": "Open AccessWe acknowledge the DustClim project which is part of ERA4CS, an ERA-NET initiated by JPI Climate, and funded by FORMAS (SE), DLR (DE), BMWFW (AT), IFD (DK), MINECO (ES), ANR (FR) with co-funding by the European Union\u2019s Horizon 2020 research and innovation programme (Grant n. 690462). BSC co-authors also acknowledge support from the European Research Council under the European Union\u2019s Horizon 2020 research and innovation programme (grant n. 773051; FRAGMENT), the AXA Research Fund, the 60 Spanish Ministry of Science, Innovation and Universities (grant n. RYC-2015-18690 and CGL2017-88911-R), the European Union\u2019s Horizon 2020 research and innovation programme (grant n. 792103; SOLWARIS). This work has been partially funded by the contribution agreement between AEMET and BSC to carry out development and improvement activities of the products and services supplied by the WMO Sand and Dust Storm Regional Centres. Jer\u00f3nimo Escribano and Martina Klose have received funding from the European Union\u2019s Horizon 2020 research and innovation programme, respectively, under the Marie Sk\u0142odowska-Curie grant agreements H2020-MSCA-COFUND-2016- 65 754433 and H2020-MSCA-IF-2017-789630. Martina Klose further acknowledges support through the Helmholtz Association\u2019s Initiative and Networking Fund (grant agreement n. VH-NG-1533). We acknowledge PRACE (eDUST, eFRAGMENT1, and eFRAGMENT2) and RES (AECT-2019-3-0001, AECT-2020-1-0007, AECT-2020-3-0013) for awarding access to MareNostrum at the BSC and for providing technical support.", "keywords": ["\u00c0rees tem\u00e0tiques de la UPC::Enginyeria mec\u00e0nica::Mec\u00e0nica de fluids", "info:eu-repo/classification/ddc/550", "Aerosol speciation", "550", "ddc:550", "Aerosol data assimilation", "Dust", "Aerosols atmosf\u00e8rics", "Atmospheric aerosols", "\u00c0rees tem\u00e0tiques de la UPC::Desenvolupament hum\u00e0 i sostenible::Enginyeria ambiental", "Earth sciences", "Aerosol regional reanalysis", "Pols -- Control", "13. Climate action", "2023 OA procedure", "Modis deep blue", "Dust control"]}, "links": [{"href": "https://link.springer.com/content/pdf/10.1007/978-3-031-12786-1"}, {"href": "https://link.springer.com/content/pdf/10.1007/978-3-031-12786-1_33"}, {"href": "https://doi.org/2117/383484"}, {"rel": "self", "type": "application/geo+json", "title": "2117/383484", "name": "item", "description": "2117/383484", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2117/383484"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-01-01T00:00:00Z"}}, {"id": "2117/385368", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:22:43Z", "type": "Journal Article", "created": "2022-10-19", "title": "A New NMVOC Speciated Inventory for a Reactivity-Based Approach to Support Ozone Control Strategies in Spain", "description": "Ozone (O3) pollution is a persistent problem in many regions of Spain, so understanding O3 precursor emissions and trends is essential to design effective control strategies. We estimated the impact of Non-Methane Volatile Organic Compounds (NMVOC) species upon O3 formation potential (OFP) using the maximum incremental reactivity approach. For this, we developed a speciated NMVOC emission inventory for Spain from 2010 to 2019 combining national reported emissions with state-of-the-art speciation profiles, which resulted in a database of emissions for over 900 individual NMVOC species and 153 individual sectors. Additionally, we analysed 2030 emission projections to quantify the expected impact of planned measures on future OFP levels. Overall, the main activities contributing to OFP in Spain are paint manufacturing and applications (20 %), manure management (16 %), and domestic solvent use (6 %). These activities contribute unevenly across regions. The more urbanised areas report a larger contribution from the solvent sector (64 % in Madrid), while in rural areas, manure management and agricultural waste burning gain importance (24 % in Extremadura), indicating that local control measures should be implemented. The top 10 NMVOC species contributing to OFP are ethanol, ethene, xylenes, propene, toluene, formaldehyde, 1,3-butadiene, styrene, n-butane, and cyclopentane, which together are responsible for 54 % of the total OFP. Our trend analysis indicates a reduction of NMVOC emissions and OFP of -5 % and -10 % between 2010 and 2019, respectively. The larger decrease in OFP is driven by a bigger reduction in xylenes (-29 %) and toluene (-28 %) from paint application industries and the road transport sector. By 2030 a significant increase (+37 %) in the OFP from the public electricity sector is expected due to the planned increase in biomass use for power generation. Our results indicate that policies should focus on paint reformulation, limiting aerosol products, and implementing NMVOC control devices in future biomass power plants.", "keywords": ["Anthropogenic emissions", "15. Life on land", "Tropospheric ozone", "7. Clean energy", "01 natural sciences", "Emission control strategies", "Article", "12. Responsible consumption", "\u00c0rees tem\u00e0tiques de la UPC::Desenvolupament hum\u00e0 i sostenible::Enginyeria ambiental", "Atmospheric ozone -- Spain", "OFP Tropospheric ozone", "NMVOC speciation", "OFP", "13. Climate action", "11. Sustainability", "Oz\u00f3 atmosf\u00e8ric -- Espanya", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/2117/385368"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/SSRN%20Electronic%20Journal", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2117/385368", "name": "item", "description": "2117/385368", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2117/385368"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-01-01T00:00:00Z"}}, {"id": "2753972636", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-09-21T16:22:52Z", "type": "Journal Article", "created": "2017-09-19", "title": "Speciation below ground: Tempo and mode of diversification in a radiation of endogean ground beetles", "description": "Abstract<p>Dispersal is a critical factor determining the spatial scale of speciation, which is constrained by the ecological characteristics and distribution of a species\uffe2\uff80\uff99 habitat and the intrinsic traits of species. Endogean taxa are strongly affected by the unique qualities of the below\uffe2\uff80\uff90ground environment and its effect on dispersal, and contrasting reports indicate either high dispersal capabilities favoured by small body size and mediated by passive mechanisms, or low dispersal due to restricted movement and confinement inside the soil. We studied a species\uffe2\uff80\uff90rich endogean ground beetle lineage, Typhlocharina, including three genera and more than 60 species, as a model for the evolutionary biology of dispersal and speciation in the deep soil. A time\uffe2\uff80\uff90calibrated molecular phylogeny generated from &gt;400 individuals was used to delimit candidate species, to study the accumulation of lineages through space and time by species\uffe2\uff80\uff93area\uffe2\uff80\uff93age relationships and to determine the geographical structure of the diversification using the relationship between phylogenetic and geographic distances across the phylogeny. Our results indicated a small spatial scale of speciation in Typhlocharina and low dispersal capacity combined with sporadic long distance, presumably passive dispersal events that fuelled the speciation process. Analysis of lineage growth within Typhlocharina revealed a richness plateau correlated with the range of distribution of lineages, suggesting a long\uffe2\uff80\uff90term species richness equilibrium mediated by density dependence through limits of habitat availability. The interplay of area\uffe2\uff80\uff90 and age\uffe2\uff80\uff90dependent processes ruling the lineage diversification in Typhlocharina may serve as a general model for the evolution of high species diversity in endogean mesofauna.</p", "keywords": ["0106 biological sciences", "2. Zero hunger", "Geography", "Genetic Speciation", "Geographic speciation", "Endogean", "Density dependence", "15. Life on land", "Anillini", "01 natural sciences", "Coleoptera", "Long\u2010distance dispersal (LDD)", "Animals", "Microendemism", "Typhlocharina", "Ecosystem", "Phylogeny"]}, "links": [{"href": "https://doi.org/2753972636"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Molecular%20Ecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "2753972636", "name": "item", "description": "2753972636", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/2753972636"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-10-16T00:00:00Z"}}, {"id": "3137244153", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:23:09Z", "type": "Journal Article", "created": "2021-03-13", "title": "X-ray absorption spectroscopy evidence of sulfur-bound cadmium in the Cd-hyperaccumulator Solanum nigrum and the non-accumulator Solanum melongena", "description": "It has been proposed that non-protein thiols and organic acids play a major role in cadmium phytoavailability and distribution in plants. In the Cd-hyperaccumulator Solanum nigrum and non-accumulator Solanum melongena, the role of these organic ligands in the accumulation and detoxification mechanisms of Cd are debated. In this study, we used X-ray absorption spectroscopy to investigate Cd speciation in these plants (roots, stem, leaves) and in the soils used for their culture to unravel the plants responses to Cd exposure. The results show that Cd in the 100\u00a0mg\u00a0kg-1 Cd-doped clayey loam soil is sorbed onto iron oxyhydroxides. In both S.\u00a0nigrum and S.\u00a0melongena, Cd in roots and fresh leaves is mainly bound to thiol ligands, with a small contribution of inorganic S ligands in S.\u00a0nigrum leaves. We interpret the Cd binding to sulfur ligands as detoxification mechanisms, possibly involving the sequestration of Cd complexed with glutathione or phytochelatins in the plant vacuoles. In the stems, results show an increase binding of Cd to -O ligands (>50% for S.\u00a0nigrum). We suggest that Cd is partly complexed by organic acids for transportation in the sap.", "keywords": ["[SDE] Environmental Sciences", "0106 biological sciences", "570", "[CHIM.ANAL] Chemical Sciences/Analytical chemistry", "http://aims.fao.org/aos/agrovoc/c_28566", "cadmium", "http://aims.fao.org/aos/agrovoc/c_2219", "Speciation", "Plant Roots", "01 natural sciences", "[SDV.BV.BOT] Life Sciences [q-bio]/Vegetal Biology/Botanics", "d\u00e9toxification", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDE.ES] Environmental Sciences/Environment and Society", "Soil Pollutants", "http://aims.fao.org/aos/agrovoc/c_32389", "Solanum melongena", "http://aims.fao.org/aos/agrovoc/c_5383", "Solanaceae", "Solanum nigrum", "0105 earth and related environmental sciences", "580", "Toxicity", "thiol", "X-Ray absorption spectroscopy", "[SDV.BV.BOT]Life Sciences [q-bio]/Vegetal Biology/Botanics", "3. Good health", "http://aims.fao.org/aos/agrovoc/c_7731", "bioaccumulation", "Biodegradation", " Environmental", "X-Ray Absorption Spectroscopy", "acide organique", "13. Climate action", "http://aims.fao.org/aos/agrovoc/c_7218", "[SDE]Environmental Sciences", "http://aims.fao.org/aos/agrovoc/c_32250", "[SDU.STU] Sciences of the Universe [physics]/Earth Sciences", "spectroscopie aux rayons x", "H50 - Troubles divers des plantes", "P02 - Pollution", "http://aims.fao.org/aos/agrovoc/c_1178", "Sulfur", "Cadmium"]}, "links": [{"href": "https://doi.org/3137244153"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Pollution", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "3137244153", "name": "item", "description": "3137244153", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/3137244153"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-01-01T00:00:00Z"}}, {"id": "33774364", "type": "Feature", "geometry": null, "properties": {"updated": "2026-09-21T16:23:19Z", "type": "Journal Article", "created": "2021-03-13", "title": "X-ray absorption spectroscopy evidence of sulfur-bound cadmium in the Cd-hyperaccumulator Solanum nigrum and the non-accumulator Solanum melongena", "description": "It has been proposed that non-protein thiols and organic acids play a major role in cadmium phytoavailability and distribution in plants. In the Cd-hyperaccumulator Solanum nigrum and non-accumulator Solanum melongena, the role of these organic ligands in the accumulation and detoxification mechanisms of Cd are debated. In this study, we used X-ray absorption spectroscopy to investigate Cd speciation in these plants (roots, stem, leaves) and in the soils used for their culture to unravel the plants responses to Cd exposure. The results show that Cd in the 100\u00a0mg\u00a0kg-1 Cd-doped clayey loam soil is sorbed onto iron oxyhydroxides. In both S.\u00a0nigrum and S.\u00a0melongena, Cd in roots and fresh leaves is mainly bound to thiol ligands, with a small contribution of inorganic S ligands in S.\u00a0nigrum leaves. We interpret the Cd binding to sulfur ligands as detoxification mechanisms, possibly involving the sequestration of Cd complexed with glutathione or phytochelatins in the plant vacuoles. In the stems, results show an increase binding of Cd to -O ligands (>50% for S.\u00a0nigrum). We suggest that Cd is partly complexed by organic acids for transportation in the sap.", "keywords": ["[SDE] Environmental Sciences", "0106 biological sciences", "570", "[CHIM.ANAL] Chemical Sciences/Analytical chemistry", "http://aims.fao.org/aos/agrovoc/c_28566", "cadmium", "http://aims.fao.org/aos/agrovoc/c_2219", "Speciation", "Plant Roots", "01 natural sciences", "[SDV.BV.BOT] Life Sciences [q-bio]/Vegetal Biology/Botanics", "d\u00e9toxification", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDE.ES] Environmental Sciences/Environment and Society", "Soil Pollutants", "http://aims.fao.org/aos/agrovoc/c_32389", "Solanum melongena", "http://aims.fao.org/aos/agrovoc/c_5383", "Solanaceae", "Solanum nigrum", "0105 earth and related environmental sciences", "580", "Toxicity", "thiol", "X-Ray absorption spectroscopy", "[SDV.BV.BOT]Life Sciences [q-bio]/Vegetal Biology/Botanics", "3. 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Desulfitobacterium sp. G1-2, isolated from a bentonite sample, was used to investigate its potential to reduce U(VI) in different background electrolytes: bicarbonate buffer, where a uranyl(VI)\u2011carbonate complex predominates, and synthetic Opalinus Clay pore water, where a uranyl(VI)-lactate complex occurs, as confirmed by time-resolved laser-induced fluorescence spectroscopic measurements. While Desulfitobacterium sp. G1-2 rapidly removed almost all U from the supernatants in bicarbonate buffer, only a low amount of U was removed in Opalinus Clay pore water. UV/Vis measurements suggest a speciation-dependent reduction by the microorganism. Scanning transmission electron microscopy coupled with energy-dispersive X-ray spectroscopy revealed the formation of two different U-containing nanoparticles inside the cells. In a subsequent step, artificial multispecies bio-aggregates were formed using derivatized polyelectrolytes with cells of Desulfitobacterium sp. G1-2 and Cobetia marina DSM 50416 to assess their potential for U(VI) reduction under aerobic and anaerobic conditions. These findings provide new perspectives on microbial U(VI) reduction and contribute to the development of a safety concept for high-level radioactive waste repositories, as well as to new bioremediation strategies.", "keywords": ["Biodegradation", " Environmental", "Iron", "Radioactive Waste", "Microbial uranium(VI) reduction", "Speciation-dependent reduction", "Uranium", "Artificial biofilms", "Desulfitobacterium", "Oxidation-Reduction", "Iron-reducing bacteria"]}, "links": [{"href": "https://doi.org/39471942"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Science%20of%20The%20Total%20Environment", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "39471942", "name": "item", "description": "39471942", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/39471942"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2024-12-01T00:00:00Z"}}], "links": [{"rel": "self", "type": "application/geo+json", "title": "This document as GeoJSON", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Speciation&f=json", "hreflang": "en-US"}, {"rel": "alternate", "type": "text/html", "title": "This document as HTML", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Speciation&f=html", "hreflang": "en-US"}, {"rel": "collection", "type": "application/json", "title": "Collection URL", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main", "hreflang": "en-US"}, {"type": "application/geo+json", "rel": "first", "title": "items (first)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Speciation&", "hreflang": "en-US"}, {"rel": "last", "type": "application/geo+json", "title": "items (last)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=Speciation&offset=20", "hreflang": "en-US"}], "numberMatched": 20, "numberReturned": 20, "distributedFeatures": [], "timeStamp": "2026-09-22T01:46:47.106923Z"}