Ruthenium complexes are attracting interest in cancer treatment due to their potent cytotoxic activity. However, as their high toxicity may also affect healthy tissues, efficient and selective drug delivery systems to tumour tissues are needed. Our study focuses on the construction of such drug delivery systems for the delivery of cytotoxic Ru(II) complexes upon exposure to a weakly acidic environment of tumours. As nanocarriers, mesoporous silica nanoparticles (MSN) are utilized, whose surface is functionalized with two types of ligands, (2-thienylmethyl)hydrazine hydrochloride (H1) and (5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)hydrazine (H2), which were attached to MSN through a pH-responsive hydrazone linkage. Further coordination to ruthenium(II) center yielded two types of nanomaterials MSN-H1[Ru] and MSN-H2[Ru]. Spectrophotometric measurements of the drug release kinetics at different pH (5.0, 6.0 and 7.4) confirm the enhanced release of Ru(II) complexes at lower pH values, which is further supported by inductively coupled plasma optical emission spectrometry (ICP-OES) measurements. Furthermore, the cytotoxicity effect of the released metallotherapeutics is evaluated in vitro on metastatic B16F1 melanoma cells and enhanced cancer cell-killing efficacy is demonstrated upon exposure of the nanomaterials to weakly acidic conditions. The obtained results showcase the promising capabilities of the designed MSN nanocarriers for the pH-responsive delivery of metallotherapeutics and targeted treatment of cancer.
", "keywords": ["Ruthenium-based anti-cancer drugs", "ruthenium-based anticancer drugs", "PH-responsive drug delivery", "Mesoporous silica nanoparticles", "pH-responsive drug delivery", "02 engineering and technology", "controlled drug delivery", "01 natural sciences", "Article", "cancer treatment", "ddc:", "3. Good health", "0104 chemical sciences", "RS1-441", "Pharmacy and materia medica", "Cancer treatment", "mesoporous silica nanoparticles", "0210 nano-technology", "Controlled drug delivery"]}, "links": [{"href": "http://www.mdpi.com/1999-4923/13/4/460/pdf"}, {"href": "https://www.mdpi.com/1999-4923/13/4/460/pdf"}, {"href": "https://doi.org/10.5281/zenodo.4655380"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Pharmaceutics", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.5281/zenodo.4655380", "name": "item", "description": "10.5281/zenodo.4655380", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.5281/zenodo.4655380"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2021-03-28T00:00:00Z"}}, {"id": "10.1002/adfm.202112374", "type": "Feature", "geometry": null, "properties": {"updated": "2026-07-27T16:14:17Z", "type": "Journal Article", "created": "2022-02-24", "title": "Differential Bio\u2010Optoelectronic Gating of Semiconducting Carbon Nanotubes by Varying the Covalent Attachment Residue of a Green Fluorescent Protein", "description": "AbstractIntegrating photoactive proteins with synthetic nanomaterials holds great promise in developing optoelectronic devices whereby light, captured by a antenna protein, is converted to a modulated electrical response. The protein\uffe2\uff80\uff93nanomaterial interface is critical to defining optoelectronic properties; successful integration of bionanohybrids requires control over protein attachment site and a detailed understanding of its impact on device performance. Here, the first single\uffe2\uff80\uff90walled carbon nanotube (SWCNT) bio\uffe2\uff80\uff90optoelectronic transistor enabled by the site\uffe2\uff80\uff90specific direct interfacing with a green fluorescent protein (GFP) via genetically encoded phenyl azide photochemistry is reported. The electrical behavior of individual semiconducting SWCNTs depends on the protein residue coupling site and provides the basis to design eco\uffe2\uff80\uff90friendly phototransistors and optoelectronic memory. Attachment at one GFP residue proximal to the chromophore produces a wavelength\uffe2\uff80\uff90specific phototransistor. The bio\uffe2\uff80\uff90transistor can be switched off in less than 38 s with responsivity up to 7 \uffc3\uff97 103 A W\uffe2\uff88\uff921 at 470\uffc2\uffa0nm. Attachment via a second residue distal to the chromophore generates optoelectronic memory that show rapid and reproducible conductivity switching with up to 15\uffe2\uff80\uff90fold modulation that is restored on the application of a gate voltage. Therefore, photoactive proteins, especially GFP, can be realized as a key material for novel single\uffe2\uff80\uff90molecule electronic and photonic devices.Polarization is a fundamental property of electromagnetic waves that plays a key role in many physical phenomena and applications. Schemes to manipulate it are revisited with the emergence of metasurfaces, which have brought multi\uffe2\uff80\uff90functionalities straightforwardly. However, this has come at the expense of design complexity that relies strongly on field theory. Here, an ingenious strategy of modular design is proposed to construct subwavelength multifunctional polarization control devices. Chiral metasurfaces with different handedness are first proposed and regarded as modules. The versatile polarization controller can thus be obtained with the combination of different modules. These experiments demonstrate that the well\uffe2\uff80\uff90designed polarization controller possesses reconfigurable functionality, and various broadband polarization and amplitude regulation functions with high efficiency including arbitrary linear polarization rotation, asymmetric transmission effect, neutral\uffe2\uff80\uff90density\uffe2\uff80\uff90like filter, polarization beam splitter, etc., can be readily realized just by changing the cascaded modules. The physical mechanisms of the versatile polarization controller and chiral metasurface modules are both guaranteed by the Fabry\uffe2\uff80\uff93P\uffc3\uffa9rot\uffe2\uff80\uff90like resonances, which are theoretically verified via the transfer matrix method. It is envisioned that the modular concept will be of great benefit to designing compact multifunctional polarization controllers.This study explores a novel approach that combines soil recovery with biofuel production, presenting a strategy that addresses the increasing demand for biofuels while sidestepping the food\uffe2\uff80\uff93fuel debate. It also introduces an innovative method for recovering heavy metals from soils through their translocation into the solid product of the conversion process. Phytoremediation trials were conducted under real field conditions, and the thermochemical conversion of the harvested biomass was carried out at lab scale. Field trials took place in 2021\uffe2\uff80\uff932023 in Lithuania and Serbia. In Serbia, the contamination primarily involved heavy metals, whereas the Lithuanian site was predominantly contaminated with hydrocarbons from petroleum products. The harvested biomass underwent pretreatment and was then used as feedstock for conversion into high\uffe2\uff80\uff90energy carriers. The conversion products were evaluated for their potential to substitute fossil fuels. Finally, the value chain, encompassing key stakeholders and factors impacting the profitability of this approach, was established, and initial estimates were made regarding the size of individual cost components.More diverse crop rotations have been promoted for their potential to remediate the range of ecosystem services compromised by biologically simplified grain\uffe2\uff80\uff90based agroecosystems, including increasing soil organic carbon (SOC). We hypothesized that functional diversity offers a more predictive means of characterizing the impact of crop rotations on SOC concentrations than species diversity per se. Furthermore, we hypothesized that functional diversity can either increase or decrease SOC depending on its associated carbon (C) input to soil. We compiled a database of 27 cropping system sites and 169 cropping systems, recorded the species and functional diversity of crop rotations, SOC concentrations (g C kg/soil), nitrogen (N) fertilizer applications (kg\uffc2\uffa0N\uffc2\uffb7ha\uffe2\uff88\uff921\uffc2\uffb7yr\uffe2\uff88\uff921), and estimated C input to soil (Mg\uffc2\uffa0C\uffc2\uffb7ha\uffe2\uff88\uff921\uffc2\uffb7yr\uffe2\uff88\uff921). We categorized crop rotations into three broad categories: grain\uffe2\uff80\uff90only rotations, grain rotations with cover crops, and grain rotations with perennial crops. We divided the grain\uffe2\uff80\uff90only rotations into two sub\uffe2\uff80\uff90categories: cereal\uffe2\uff80\uff90only rotations and those that included both cereals and a legume grain. We compared changes in SOC and C input using mean effect sizes and 95% bootstrapped confidence intervals. Cover cropped and perennial cropped rotations, relative to grain\uffe2\uff80\uff90only rotations, increased C input by 42% and 23% and SOC concentrations by 6.3% and 12.5%, respectively. Within grain\uffe2\uff80\uff90only rotations, cereal\uffc2\uffa0+\uffc2\uffa0legume grain rotations decreased total C input (\uffe2\uff88\uff9216%), root C input (\uffe2\uff88\uff9212%), and SOC (\uffe2\uff88\uff925.3%) relative to cereal\uffe2\uff80\uff90only rotations. We found no effect of species diversity on SOC within grain\uffe2\uff80\uff90only rotations. N fertilizer rates mediated the effect of functional diversity on SOC within grain\uffe2\uff80\uff90only crop rotations: at low N fertilizer rates (\uffe2\uff89\uffa475\uffc2\uffa0kg N\uffc2\uffb7ha\uffe2\uff88\uff921\uffc2\uffb7yr\uffe2\uff88\uff921), the decrease in SOC with cereal\uffc2\uffa0+\uffc2\uffa0legume grain rotations was less than at high N fertilizer rates. Our results show that increasing the functional diversity of crop rotations is more likely to increase SOC concentrations if it is accompanied by an increase in C input. Functionally diverse perennial and cover cropped rotations increased both C input and SOC concentrations, potentially by exploiting niches in time that would otherwise be unproductive, that is, increasing the \uffe2\uff80\uff9cperenniality\uffe2\uff80\uff9d of crop rotations.
", "keywords": ["Crops", " Agricultural", "2. Zero hunger", "Science", "Ecology and Evolutionary Biology", "Agriculture", "Fabaceae", "cropping systems", "04 agricultural and veterinary sciences", "15. Life on land", "functional diversity", "Poaceae", "sustainable agriculture", "Soil", "meta\u2010analysis", "soil organic matter", "0401 agriculture", " forestry", " and fisheries", "cover crops", "soil carbon", "Organic Chemicals", "perennials", "Fertilizers", "nitrogen fertilizer", "biodiversity"]}, "links": [{"href": "https://doi.org/10.1002/eap.1648"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Ecological%20Applications", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1002/eap.1648", "name": "item", "description": "10.1002/eap.1648", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1002/eap.1648"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-12-27T00:00:00Z"}}, {"id": "10.1007/s00216-022-03943-6", "type": "Feature", "geometry": null, "properties": {"updated": "2026-07-27T16:14:39Z", "type": "Journal Article", "created": "2022-02-09", "title": "Systematic identification of trimethoprim metabolites in lettuce", "description": "AbstractAntibiotics are some of the most widely used drugs. Their release in the environment is of great concern since their consumption is a major factor for antibiotic resistance, one of the most important threats to human health. Their occurrence and fate in agricultural systems have been extensively investigated in recent years. Yet whilst their biotic and abiotic degradation pathways have been thoroughly researched, their biotransformation pathways in plants are less understood, such as in case of trimethoprim. Although trimethoprim has been reported in the environment, its fate in higher plants still remains unknown. A bench-scale experiment was performed and 30 trimethoprim metabolites were identified in lettuce (Lactuca sativa L.), of which 5 belong to phase I and 25 to phase II. Data mining yielded a list of 1018 ions as possible metabolite candidates, which was filtered to a final list of 87 candidates. Molecular structures were assigned for 19 compounds, including 14 TMP metabolites reported for the first time. Alongside well-known biotransformation pathways in plants, additional novel pathways were suggested, namely, conjugation with sesquiterpene lactones, and abscisic acid as a part of phase II of plant metabolism. The results obtained offer insight into the variety of phase II conjugates and may serve as a guideline for studying the metabolization of other chemicals that share a similar molecular structure or functional groups with trimethoprim. Finally, the toxicity and potential contribution of the identified metabolites to the selective pressure on antibiotic resistance genes and bacterial communities via residual antimicrobial activity were evaluated.
", "keywords": ["2. Zero hunger", "High-resolution mass spectrometry", "Phytochemicals", "0211 other engineering and technologies", "02 engineering and technology", "01 natural sciences", "Trimethoprim", "Anti-Bacterial Agents", "3. Good health", "Conjugates", "Antibiotics", "Non-target screening", "Humans", "Plant metabolites", "Biotransformation", "Research Paper", "Lactuca", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Tadi\u0107, \u0110or\u0111e, Gramblicka, Michal, Mistrik, Robert, Bayona, Josep Maria,", "roles": ["creator"]}]}, "links": [{"href": "https://link.springer.com/content/pdf/10.1007/s00216-022-03943-6.pdf"}, {"href": "https://doi.org/10.1007/s00216-022-03943-6"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Analytical%20and%20Bioanalytical%20Chemistry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00216-022-03943-6", "name": "item", "description": "10.1007/s00216-022-03943-6", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00216-022-03943-6"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-02-09T00:00:00Z"}}, {"id": "0c6c5bbc-20a7-4011-8585-7befb511a4b4", "type": "Feature", "geometry": null, "properties": {"updated": "2024-09-24T14:57:55", "type": "Dataset", "language": "en", "title": "GSI GEMAS European Geochemical Data", "description": "The GEMAS Dataset is based on low density geochemical sampling of agriculture (Ap) and Grassland (Gr) Soils across 34 European countries. Sample density covering an area of 5.6 million km\u00b2 of 1 site each, arable land (0-20\u00a0cm) and land under permanent grass cover (0-10\u00a0cm), per 2\u00a0500\u00a0km\u00b2. The Geochemical Mapping of Agricultural and GRAZING Land Soil comprises more than 70 chemical elements and parameters determined on more than 4000 soil samples. The geochemistry of European agriculture and grazing Soils are depicted graphically on maps of the GEMAS geochemical atlas. In 2016 the Geological Survey of Ireland as a European partner contributes to GEMAS and EGDI (European Geological Data Infrastructure) with provision of a GIS Spatial data classification and publication of WMS geochemical web mapping services to support European data interoperability of EGDI web portal. The GIS GEMAS sample classification was constructed in ArcGIS 10.1 and the original GEMAS Dataset is available as ESRI shapefile format.", "formats": [{"name": "ESRI REST"}], "keywords": ["agricultural-soil", "analysis", "arable-land", "arable-land-groundwater", "chemical", "chemistry", "continental-scale", "earth-science", "egdi", "environment", "europe", "european-soil-analysis", "forensic-chemistry", "gemas", "geochemical", "geochemical-analysis", "geochemical-mapping", "geology", "geoscientificinformation", "grazing-land", "groundwater", "heavy-metals", "ie", "ireland", "land", "lithosphere", "mapping", "metal", "micka", "pedosphere", "science", "soil", "soil-nutrient", "toxic-element", "trace-element"], "contacts": [{"organization": "https://data.gov.ie/organization/geological-survey-of-ireland", "roles": ["publisher"]}]}, "links": [{"href": "https://data.geus.dk/egdi/?mapname=egdi_new_structure#baslay=baseMapGEUS&optlay=&extent=1237790%2C1796730%2C4849410%2C4619780&%20target=_blank"}, {"href": "https://gemas.eurogeosurveys.org/"}, {"href": "https://gsi.geodata.gov.ie/downloads/Geochemistry/Data/IE_GSI_GEMAS_Geochemistry_Agricultural_Grazing_Land_Soil_EU_WGS84.zip"}, {"href": "https://gsi.geodata.gov.ie/server/rest/services/Geochemistry/IE_GSI_GEMAS_Geochemistry_Agricultural_Grazing_Land_Soil_EU_WGS84/MapServer"}, {"href": "https://gsi.geodata.gov.ie/server/rest/services/Geochemistry/IE_GSI_GEMAS_Geochemistry_Agricultural_Grazing_Land_Soil_EU_WGS84/MapServer?f=pjson"}, {"href": "https://gsi.geodata.gov.ie/server/services/Geochemistry/IE_GSI_GEMAS_Geochemistry_Agricultural_Grazing_Land_Soil_EU_WGS84/MapServer/WMSServer?request=GetCapabilities&service=WMS"}, {"href": "http://data.europa.eu/88u/dataset/0c6c5bbc-20a7-4011-8585-7befb511a4b4"}, {"rel": "self", "type": "application/geo+json", "title": "0c6c5bbc-20a7-4011-8585-7befb511a4b4", "name": "item", "description": "0c6c5bbc-20a7-4011-8585-7befb511a4b4", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/0c6c5bbc-20a7-4011-8585-7befb511a4b4"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"null": "date"}}, {"id": "10.1002/2014jg002635", "type": "Feature", "geometry": null, "properties": {"updated": "2026-07-27T16:14:16Z", "type": "Journal Article", "created": "2014-11-18", "title": "Woody Plant Encroachment Into Grasslands Leads To Accelerated Erosion Of Previously Stable Organic Carbon From Dryland Soils", "description": "AbstractDrylands worldwide are experiencing rapid and extensive environmental change, concomitant with the encroachment of woody vegetation into grasslands. Woody encroachment leads to changes in both the structure and function of dryland ecosystems and has been shown to result in accelerated soil erosion and loss of soil nutrients. Covering 40% of the terrestrial land surface, dryland environments are of global importance, both as a habitat and a soil carbon store. Relationships between environmental change, soil erosion, and the carbon cycle are uncertain. There is a clear need to further our understanding of dryland vegetation change and impacts on carbon dynamics. Here two grass\uffe2\uff80\uff90to\uffe2\uff80\uff90woody ecotones that occur across large areas of the southwestern United States are investigated. This study takes a multidisciplinary approach, combining ecohydrological monitoring of structure and function and a dual\uffe2\uff80\uff90proxy biogeochemical tracing approach using the unique natural biochemical signatures of the vegetation. Results show that following woody encroachment, not only do these drylands lose significantly more soil and organic carbon via erosion but that this includes significant amounts of legacy organic carbon which would previously have been stable under grass cover. Results suggest that these dryland soils may not act as a stable organic carbon pool, following encroachment and that accelerated erosion of carbon, driven by vegetation change, has important implications for carbon dynamics.
", "keywords": ["2. Zero hunger", "soil erosion", "info:eu-repo/classification/ddc/550", "550", "04 agricultural and veterinary sciences", "15. Life on land", "01 natural sciences", "soil carbon pool", "13. Climate action", "biogeochemical tracing", "woody encroachment", "0401 agriculture", " forestry", " and fisheries", "Geosciences", " Multidisciplinary", "dryland vegetation change", "Environmental Sciences", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1002/2014jg002635"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Geophysical%20Research%3A%20Biogeosciences", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1002/2014jg002635", "name": "item", "description": "10.1002/2014jg002635", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1002/2014jg002635"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2014-12-01T00:00:00Z"}}, {"id": "10.1002/adma.200304005", "type": "Feature", "geometry": null, "properties": {"updated": "2026-07-27T16:14:17Z", "type": "Journal Article", "created": "2003-04-25", "title": "Effect of Molecular Orientation of Epitaxially Grown Platinum(II) Octaethyl Porphyrin Films on the Performance of Field\u2010Effect Transistors", "description": "The molecular alignment of platinum(II) octaethyl porphyrin (PtOEP) crystals evaporated on KBr (see atomic force microscopy image, Figure) can be readily changed from perpendicular to parallel by changing the substrate temperature. The field\uffe2\uff80\uff90effect mobility of transisitors prepared using epitaxially grown PtOEP films aligned perpendicularly to a substrate is 100 times higher than that of those of parallel alignment.Insights into the fascinating molecular world of biological processes are crucial for understanding diseases, developing diagnostics, and effective therapeutics. These processes are complex as they involve interactions between four major classes of biomolecules, i.e., proteins, nucleic acids, carbohydrates, and lipids, which makes it important to be able to discriminate between all these different biomolecular species. In this work, a deep learning\uffe2\uff80\uff90augmented, chemically\uffe2\uff80\uff90specific nanoplasmonic technique that enables such a feat in a label\uffe2\uff80\uff90free manner to not disrupt native processes is presented. The method uses a highly sensitive multiresonant plasmonic metasurface in a microfluidic device, which enhances infrared absorption across a broadband mid\uffe2\uff80\uff90IR spectrum and in water, despite its strongly overlapping absorption bands. The real\uffe2\uff80\uff90time format of the optofluidic method enables the collection of a vast amount of spectrotemporal data, which allows the construction of a deep neural network to discriminate accurately between all major classes of biomolecules. The capabilities of the new method are demonstrated by monitoring of a multistep bioassay containing sucrose\uffe2\uff80\uff90 and nucleotides\uffe2\uff80\uff90loaded liposomes interacting with a small, lipid membrane\uffe2\uff80\uff90perforating peptide. It is envisioned that the presented technology will impact the fields of biology, bioanalytics, and pharmacology from fundamental research and disease diagnostics to drug development.Whole\uffe2\uff80\uff90cell inorganic\uffe2\uff80\uff90biohybrid systems, integrating inorganic photosensitizers with intact living cells, have shown great potential for solar hydrogen production. However, the typical whole cell biohybrid system often suffers from the sluggish kinetics of electron transfer in the transmembrane diffusion process, which severely restrict their photocatalytic activity. Here, a unique periplasmic photosensitized biohybrid system is constructed by translocating CuInS2/ZnS quantum dots (QDs) into the Shewanella oneidensis MR\uffe2\uff80\uff901 (SW) cells that express periplasmic hydrogenases. The photoexcitation and electron transfer processes of QDs photosensitizers occur simultaneously in the periplasm of SW cells, which reduces the distance for electron transport and avoids the extra energy loss involved in the transmembrane process. As expected, the photocatalytic H2 generation of the fabricated biohybrid system is 8.6 times higher than that of bare QDs under visible light irradiation. Moreover, the good viability and stability of this biohybrid system endow it with an excellent sustained hydrogen production within 45 h, representing the most stable biohybrid among the reported whole\uffe2\uff80\uff90cell biohybrid H2 production systems. This work provides a novel insight into the construction of a robust whole\uffe2\uff80\uff90cell biohybrid system for solar hydrogen production.Es wurden die Bedingungen der Erythrochinreaktion mit Chinin systematisch variiert, und es wurde eine neue Vorschrift erarbeitet, die eine maximale F\uffc3\uffa4rbung ergibt. Aus der Modellsubstanz 6\uffe2\uff80\uff90Methoxychinolin wurde die f\uffc3\uffbcr die Farbreaktion verantwortliche Substanz rein isoliert und auf ihre Konstitution hin untersucht. Alle Befunde sprechen daf\uffc3\uffbcr, da\uffc3\uff9f der Substanz die dimere Parachinonstruktur II zukommt. \uffe2\uff80\uff93 Es ist wahrscheinlich, da\uffc3\uff9f die Farbreaktion mit Chinin zu einem analogen Produkt f\uffc3\uffbchrt, das seiner Labilit\uffc3\uffa4t wegen nur nicht in reiner Form gewonnen werden konnte.The radical polymerization of styrene (St) initiated by a trifluoromethyl radical generated from a perfluorinated highly branched persistent radical (PPFR) is presented with an isolated yield above 70\uffe2\uff80\uff89%. The release of .CF3 radical occurred from a temperature above 85\uffe2\uff80\uff89\uffc2\uffb0C. Deeper 1H and 19F\uffe2\uff80\uff85NMR spectroscopies of the resulting fluorinated polystyrenes (CF3\uffe2\uff80\uff90PSts) evidenced the presence of both CF3 end\uffe2\uff80\uff90group of the PSt chain and the trifluoromethylation of the phenyl ring (in meta\uffe2\uff80\uff90position mainly). [PPFR]0/[St]0 initial molar ratios of 3:1, 3:10 and 3:100 led to various molar masses ranging from 1750 to 5400\uffe2\uff80\uff85g\uffe2\uff80\uff89mol\uffe2\uff88\uff921 in 70\uffe2\uff80\uff9386\uffe2\uff80\uff89% yields. MALDI\uffe2\uff80\uff90TOF spectrometry of such CF3\uffe2\uff80\uff90PSts highlighted polymeric distributions which evidenced differences between m/z fragments of 104 and 172 corresponding to styrene and trifluoromethyl styrene units, respectively. Such CF3\uffe2\uff80\uff90PSt polymers were also compared to conventional PSts produced from the radical polymerization of St initiated by a peroxydicarbonate initiator. A mechanism of the polymerization is presented showing the formation of a trifluoromethyl styrene first, followed by its radical (co)polymerization with styrene. The thermal properties (thermal stability and glass transition temperature, Tg) of these polymers were also compared and revealed a much better thermal stability of the CF3\uffe2\uff80\uff90PSt (10\uffe2\uff80\uff89% weight loss at 356\uffe2\uff80\uff93376\uffe2\uff80\uff89\uffc2\uffb0C) and a Tg of around 70\uffe2\uff80\uff89\uffc2\uffb0C.This work reports on the concise total synthesis of eight natural products of the mugineic acid and avenic acid families (phytosiderophores). An innovative \uffe2\uff80\uff9eeast\uffe2\uff80\uff90to\uffe2\uff80\uff90west\uffe2\uff80\uff9c assembly of the trimeric products resulted in a high degree of divergence enabling the formation of the final products in just 10 or 11\uffe2\uff80\uff85steps each with a minimum of overall synthetic effort. Chiral pool starting materials (l\uffe2\uff80\uff90malic acid, threonines) were employed for the outer building blocks while the middle building blocks were accessed by diastereo\uffe2\uff80\uff90 and enantioselective methods. A highlight of this work consists in the straightforward preparation of epimeric hydroxyazetidine amino acids, useful building blocks on their own, enabling the first synthesis of 3\uffe2\uff80\uff99\uffe2\uff80\uff99\uffe2\uff80\uff90hydroxymugineic acid and 3\uffe2\uff80\uff99\uffe2\uff80\uff99\uffe2\uff80\uff90hydroxy\uffe2\uff80\uff902\uffe2\uff80\uff99\uffe2\uff80\uff90deoxymugineic acid.Benzoylessigs\uffc3\uffa4ureester (I) reagiert mit Dimethylhydrazin (II) \uffc3\uffbcber das Hydrazon (III) zu den Betainen (IV).ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a \uffe2\uff80\uff9cFull Text\uffe2\uff80\uff9d option. The original article is trackable via the \uffe2\uff80\uff9cReferences\uffe2\uff80\uff9d option.The functionalization of aliphatic C\uffe2\uff80\uff94H bonds is achieved by direct photolytic cyanation with TosCN.The title chromenoquinolines are prepared by a novel copper\uffe2\uff80\uff90catalyzed oxidative ring closure \uffe2\uff80\uff90arylation concept utilizing arylpropynyloxy\uffe2\uff80\uff90benzonitriles and diaryliodinium salts.The photoRAFT (RAFT=reversible addition\uffe2\uff80\uff90fragmentation radical transfer) polymerization of vinylidene fluoride (VDF) mediated by O\uffe2\uff80\uff90ethyl\uffe2\uff80\uff90S\uffe2\uff80\uff90(1\uffe2\uff80\uff90methoxycarbonyl)ethyl dithiocarbonate using a household white LED as light source at room temperature is presented. PVDFs with molar masses up to ca. 8000\uffe2\uff80\uff85g\uffe2\uff80\uff89mol\uffe2\uff88\uff921 and low dispersities (1.11\uffe2\uff80\uff931.49) were obtained. Kinetic experiments revealed that the use of Ir(ppy)3 as photoredox catalyst lead to faster polymerization. A slowdown of the chain equilibration process was observed during the polymerization, attributed to the accumulation of the less reactivatable CF2\uffe2\uff88\uff92CH2\uffe2\uff88\uff92Xa terminated chains.In the present study, leaves from 13 sweet potato cultivars were collected as raw materials. The nutritional and functional composition, antioxidant activity, and sunscreen activity of different sweet potato leaf samples were determined, and the comprehensive nutritional quality was calculated by gray relational analysis. Results showed that the nutritional and functional components are significantly different between different cultivars. Tainong71 showed the highest comprehensive nutritional quality, followed by Fu22, Ningcai, Fu23, Ecai10, Zhecai726, Ecai1, Fu18, Pushu53, Guangcai5, Shulv1, Guangcai2, and Zhecai1. The antioxidant activity varied from 3.94 to 16.75\uffc2\uffa0g Trolox equivalent/100\uffc2\uffa0g dry weight. Pushu53 showed the highest sunscreen activity, with the sun protection factor 24.65. There was a positive correlation between antioxidant activity and sunscreen activity (r\uffc2\uffa0=\uffc2\uffa0.737, p\uffc2\uffa0=\uffc2\uffa0.004). In conclusion, sweet potato leaves possess high nutritional and functional properties, and have the huge potential to be used as green leafy vegetables and sunscreen agent.
", "keywords": ["2. Zero hunger", "0404 agricultural biotechnology", "chemical/nutritional characterization ; antioxidant activity ; correlation analysis ; sunscreen acitvity ; gray relational analysis ; sweet potato leaves", "04 agricultural and veterinary sciences", "0405 other agricultural sciences", "Original Research"]}, "links": [{"href": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/fsn3.1675"}, {"href": "https://doi.org/10.1002/fsn3.1675"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Food%20Science%20%26amp%3B%20Nutrition", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1002/fsn3.1675", "name": "item", "description": "10.1002/fsn3.1675", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1002/fsn3.1675"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2020-07-14T00:00:00Z"}}, {"id": "10.1002/jctb.6409", "type": "Feature", "geometry": null, "properties": {"license": "Closed Access", "updated": "2026-07-27T16:14:22Z", "type": "Journal Article", "created": "2020-03-13", "title": "Self\u2010assembling of Shewanella@rGO@Pd bionanohybrid for synergistic bio\u2010abiotic removal of Cr(VI)", "description": "AbstractBACKGROUNDBacterial cells can biosynthesize palladium nanoparticles (Pd NPs) and utilize those in situ assembled nanoparticles for synergistic bio\uffe2\uff80\uff90abiotic catalysis, which is promising for pollutant remediation. However, such synergistic catalysis is restricted due to the low cell viability and inefficient palladium immobilization.
RESULTSIn this study, conductive and two\uffe2\uff80\uff90dimensional reduced graphene oxide (rGO) was explored for nanocoating of Shewanella oneidensis cells and the construction of a self\uffe2\uff80\uff90assembled Shewanella@rGO bionanohybrid. Impressively, after in situ biosynthesis of Pd NPs on the Shewanella@rGO bionanohybrid, a Shewanella@rGO@Pd bionanohybrid was assembled, which showed about 10 times higher cell viability and 2.4 times more immobilized palladium content than the bionanohybrid without rGO. More importantly, the improved cell viability and enhanced Pd immobilization synergistically promoted Cr(VI) removal using the Shewanella@rGO@Pd bionanohybrid, which was 10 times that of native cells and five times that of the bionanohybrid without rGO.
CONCLUSIONSThis work provides a promising strategy for biosynthesis and in situ assembly of Pd NPs with living bacterial cells, which is promising for synergistic bio\uffe2\uff80\uff90abiotic removal of Cr(VI) and should extend the application of Pd NPs in pollutant remediation. \uffc2\uffa9 2020 Society of Chemical IndustryDissolved organic matter (DOM) composition exerts a direct control on its degradation and subsequent persistence in aquatic ecosystems. Yet, under certain conditions, the degradation patterns of DOM cannot be solely explained by its composition, highlighting the relevance of environmental conditions for DOM degradation. Here, we experimentally assessed the relative influence of composition vs. environment on DOM degradation by performing degradation bioassays using three contrasting DOM sources inoculated with a standardized bacterial inoculum under five distinct environments. The DOM degradation kinetics modeled using reactivity continuum models showed that composition was more important than environment in determining the bulk DOM decay patterns. Changes in DOM composition resulted from the interaction between DOM source and environment. The role of environment was stronger on shaping the bacterial community composition, but the intrinsic nature of the DOM source exerted stronger control on the DOM degradation function.High\uffe2\uff80\uff90resolution mass spectrometry (HRMS) has become a vital tool for dissolved organic matter (DOM) characterization. The upward trend in HRMS analysis of DOM presents challenges in data comparison and interpretation among laboratories operating instruments with differing performance and user operating conditions. It is therefore essential that the community establishes metric ranges and compositional trends for data comparison with reference samples so that data can be robustly compared among research groups. To this end, four identically prepared DOM samples were each measured by 16 laboratories, using 17 commercially purchased instruments, using positive\uffe2\uff80\uff90ion and negative\uffe2\uff80\uff90ion mode electrospray ionization (ESI) HRMS analyses. The instruments identified ~1000 common ions in both negative\uffe2\uff80\uff90 and positive\uffe2\uff80\uff90ion modes over a wide range of m/z values and chemical space, as determined by van Krevelen diagrams. Calculated metrics of abundance\uffe2\uff80\uff90weighted average indices (H/C, O/C, aromaticity, and m/z) of the commonly detected ions showed that hydrogen saturation and aromaticity were consistent for each reference sample across the instruments, while average mass and oxygenation were more affected by differences in instrument type and settings. In this paper we present 32 metric values for future benchmarking. The metric values were obtained for the four different parameters from four samples in two ionization modes and can be used in future work to evaluate the performance of HRMS instruments.The combination of plant residues with inorganic fertiliser\uffe2\uff80\uff90N provides the potential to increase N\uffe2\uff80\uff90use efficiency in agricultural fruit production systems, such as olive orchards. The development of weeds in the inter\uffe2\uff80\uff90canopy area of olive orchards is encouraged as a novel strategy to reduce soil erosion. However, little is known about soil N retention or N2O production following the combined application of inorganic\uffe2\uff80\uff90N with the mulched weed residues.
METHODSEmissions of 15N\uffe2\uff80\uff90N2O and soil mineral 15N retention were measured following combined applications of 15N\uffe2\uff80\uff90labelled fertiliser and a range of olive crop weed residues to a silty loam soil under controlled conditions. These plant residues differed in their C:N ratios, lignin and polyphenol contents.
RESULTSThe magnitude of soil 15N\uffe2\uff80\uff90NO3\uffe2\uff80\uff93 retention from combining plant residues and fertiliser\uffe2\uff80\uff90N was highly dependent on potential N mineralisation (r\uffe2\uff80\uff89=\uffe2\uff80\uff89\uffe2\uff88\uff920.96) and the (lignin\uffe2\uff80\uff89+\uffe2\uff80\uff89polyphenol)\uffe2\uff80\uff90to\uffe2\uff80\uff90N ratio (r\uffe2\uff80\uff89=\uffe2\uff80\uff890.98) of the residues. Fertiliser\uffe2\uff80\uff90N\uffe2\uff80\uff90derived retention was zero for a legume\uffe2\uff80\uff90based mulch but up to 80% in the treatment containing plant residues with a high (lignin\uffe2\uff80\uff89+\uffe2\uff80\uff89polyphenol)\uffe2\uff80\uff90to\uffe2\uff80\uff90N ratio. N2O emissions increased after the addition of residues, and increased further (up to 128%) following the combined application of inorganic fertiliser and residues. Fertiliser\uffe2\uff80\uff90derived 15N\uffe2\uff80\uff90N2O was <1.4% of the total 14+15N\uffe2\uff80\uff90N2O emission and <0.01% of the applied 15N\uffe2\uff80\uff90NO3\uffe2\uff80\uff93. Enhanced N2O emissions following the application of residues and the fertiliser\uffe2\uff80\uff90N values were positively correlated with the C:N ratio of the residue. Thus, combining organic\uffe2\uff80\uff90 and inorganic\uffe2\uff80\uff90N immobilised a significant proportion of the inorganic N with little increase in N2O, especially in low C:N ratio residues.
CONCLUSIONSThe results demonstrate that whilst there is potential for N2O emissions to be controlled by combining weed residues and inorganic fertilisers, this is not easy to achieve as the magnitude and direction of interactions vary between different species due to their varying substrate qualities. Copyright \uffc2\uffa9 2012 John Wiley & Sons, Ltd.
", "keywords": ["2. Zero hunger", "Nitrogen", "Chemistry", " Analytical", "Nitrous Oxide", "04 agricultural and veterinary sciences", "15. Life on land", "Plants", "01 natural sciences", "6. Clean water", "Biochemical Research Methods", "0104 chemical sciences", "Soil", "13. Climate action", "Soil Pollutants", "0401 agriculture", " forestry", " and fisheries", "Fertilizers", "Spectroscopy", "Environmental Monitoring"]}, "links": [{"href": "https://doi.org/10.1002/rcm.6254"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Rapid%20Communications%20in%20Mass%20Spectrometry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1002/rcm.6254", "name": "item", "description": "10.1002/rcm.6254", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1002/rcm.6254"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2012-09-10T00:00:00Z"}}, {"id": "10.1002/macp.201900573", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-07-27T16:14:27Z", "type": "Journal Article", "created": "2020-03-26", "title": "The Promising Future of Fluoropolymers", "description": "AbstractThis article aims at showing the usefulness of fluoropolymers (FPs), supplying an overview of their synthesis, applications, and recycling. FPs are currently prepared by conventional radical polymerization of fluoromonomers. These specialty polymers, produced in low tonnage compared to that of commodity ones, display outstanding properties, such as chemical, oxidative, and thermal resistances, low refractive index, dissipation factor, permittivity, and water absorptivity, and excellent weatherability and durability. More recent routes for their preparations are suggested, controlled or not, leading to random, alternated, block, graft, dendrimers, or multiarm copolymers, as well as their applications ranging from coatings to high performance (thermoplastic) elastomers, energy related\uffe2\uff80\uff90materials (e.g., fuel cell membranes, components for lithium\uffe2\uff80\uff90ion batteries, electroactive devices, and photovoltaics) to original and surfactants, optical devices, organic electronics, composites, and shape memory polymers.Determination of \uffce\uffb417O values directly from CO2 with traditional gas source isotope ratio mass spectrometry is not possible due to isobaric interference of 13C16O16O on 12C17O16O. The methods developed so far use either chemical conversion or isotope equilibration to determine the \uffce\uffb417O value of CO2. In addition, \uffce\uffb413C measurements require correction for the interference from 12C17O16O on 13C16O16O since it is not possible to resolve the two isotopologues.
MethodsWe present a technique to determine the \uffce\uffb417O, \uffce\uffb418O and \uffce\uffb413C values of CO2 from the fragment ions that are formed upon electron ionization in the ion source of the Thermo Scientific 253 Ultra high\uffe2\uff80\uff90resolution isotope ratio mass spectrometer (hereafter 253 Ultra). The new technique is compared with the CO2\uffe2\uff80\uff90O2 exchange method and the 17O\uffe2\uff80\uff90correction algorithm for \uffce\uffb417O and \uffce\uffb413C values, respectively.
ResultsThe scale contractions for \uffce\uffb413C and \uffce\uffb418O values are slightly larger for fragment ion measurements than for molecular ion measurements. The \uffce\uffb417O and \uffce\uff9417O values of CO2 can be measured on the 17O+ fragment with an internal error that is a factor 1\uffe2\uff80\uff932 above the counting statistics limit. The ultimate precision depends on the signal intensity and on the total time that the 17O+ beam is monitored; a precision of 14\uffe2\uff80\uff89ppm (parts per million) (standard error of the mean) was achieved in 20\uffe2\uff80\uff89hours at the University of G\uffc3\uffb6ttingen. The \uffce\uff9417O measurements with the O\uffe2\uff80\uff90fragment method agree with the CO2\uffe2\uff80\uff90O2 exchange method over a range of \uffce\uff9417O values of \uffe2\uff88\uff920.3 to +0.7\uffe2\uff80\uffb0.
ConclusionsIsotope measurements on atom fragment ions of CO2 can be used as an alternative method to determine the carbon and oxygen isotopic composition of CO2 without chemical processing or corrections for mass interferences.
", "keywords": ["550", "NITROUS-OXIDE", "O-17/O-16", "ANALYTICAL SYSTEM", "01 natural sciences", "O-2", "0104 chemical sciences", "O-17 CORRECTION", "HIGH-PRECISION MEASUREMENTS", "13. Climate action", "Life Science", "ABUNDANCE", "DELTA-O-17", "EXCHANGE", "DIOXIDE", "Research Articles", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/rcm.8478"}, {"href": "https://doi.org/10.1002/rcm.8478"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Rapid%20Communications%20in%20Mass%20Spectrometry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1002/rcm.8478", "name": "item", "description": "10.1002/rcm.8478", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1002/rcm.8478"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-08-05T00:00:00Z"}}, {"id": "10.1002/ps.4546", "type": "Feature", "geometry": null, "properties": {"updated": "2026-07-27T16:14:28Z", "type": "Journal Article", "created": "2017-02-03", "title": "Behaviour Of Bentazon As Influenced By Water And Tillage Management In Rice-Growing Conditions", "description": "AbstractBentazon is a widely used herbicide in rice agroecosystems that has commonly been found in water resources. To assess how tillage and water regimes affect sorption/desorption, dissipation and leaching of bentazon in Mediterranean rice\uffe2\uff80\uff90growing conditions, field experiments were carried out using tillage and flooding (TF), tillage and sprinkler irrigation (TS), no\uffe2\uff80\uff90tillage and sprinkler irrigation (NTS) and long\uffe2\uff80\uff90term no\uffe2\uff80\uff90tillage and sprinkler irrigation (NTS7). After 3 years, the Kd values in TS were 2.3, 1.6 and 1.7 times lower than the values in NTS7, NTS and TF respectively. Greater sorption of bentazon was related to higher contents in total organic carbon and, although to a lesser extent, in humic acids and dissolved organic carbon. The persistence of bentazon was significantly greater under anaerobic (half\uffe2\uff80\uff90life DT50 = 94.1\uffe2\uff80\uff93135 days) than under aerobic (DT50 = 42.4\uffe2\uff80\uff9391.3\uffe2\uff80\uff89days) incubation conditions for all management regimes. Leaching losses of bentazon were reduced from 78 and 74% in TS and TF to 61 and 62% in NTS7 and NTS respectively. The mid\uffe2\uff80\uff90 and long\uffe2\uff80\uff90term implementation of sprinkler irrigation in combination with no\uffe2\uff80\uff90tillage could be considered a management system that is effective at reducing water contamination by bentazon in Mediterranean rice\uffe2\uff80\uff90growing agroecosystems. \uffc2\uffa9 2017 Society of Chemical Industry
", "keywords": ["2. Zero hunger", "0106 biological sciences", "Agricultural Irrigation", "3103", "Herbicides", "Water Pollution", "Bentazona", "Oryza", "04 agricultural and veterinary sciences", "15. Life on land", "Benzothiadiazines", "01 natural sciences", "6. Clean water", "Crop Production", "Bentazon", "Sorption", "Sorci\u00f3n", "0401 agriculture", " forestry", " and fisheries", "Laboreo", "Water Pollutants", " Chemical", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1002/ps.4546"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Pest%20Management%20Science", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1002/ps.4546", "name": "item", "description": "10.1002/ps.4546", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1002/ps.4546"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-03-17T00:00:00Z"}}, {"id": "10.1006/jare.1998.0475", "type": "Feature", "geometry": null, "properties": {"updated": "2026-07-27T16:14:29Z", "type": "Journal Article", "created": "2002-10-07", "title": "Effects Of Livestock Grazing On Physical And Chemical Properties Of Sandy Soils In Sahelian Rangelands", "description": "The effects of grazing by livestock on soil surface features, bulk density and chemical properties were studied at the completion of a 4-year grazing experiment carried out in SadoreH, Niger. Grazing treatments were a factorial arrangement of two stocking rates (62\u00b75 and 125 kg live weight ha~1) and four sheep:goat ratios (0:6, 2:4, 4:2 and 6:0 animals per pasture), with two pastures per treatment and two ungrazed controls. Observations were also made in a fallow subjected to 9 years of intense and uncontrolled mixed grazing, and in a site that had been protected from grazing for 15 years. The topsoil was sampled (at depths of 0\u20132, 2\u20136, 6\u201314 and 14\u201330 cm) below shrub canopy in herbaceous vegetation and in bare soil patches within each of 20 paddocks for determination of pH, organic C, and total N and P concentrations. Soil bulk density was measured in a subset of soil profiles. The areal extent of different types of soil crusts and other soil surface features was assessed in one-half of the paddocks. Grazing resulted in a reduction (p(0\u00b701) and fragmentation of the area of crusted soils. However, this trend was partially compensated for by an increase of newly formed crusts. As a result, the soil infiltration index slightly increased with moderate grazing, but decreased at higher stocking rates. Compaction due to trampling was observed in the topsoil beneath the shrub canopy and also in vegetated patches, but only under intense grazing pressure. Soil bulk density was not affected by grazing except for an increase observed below 10 cm depth at the understorey of shrubs which is therefore unlikely due to trampling. When compared to the ungrazed control, pH, organic C and N concentrations, and to lesser extent P concentration, decreased after 4 years of grazing. Soil P and pH further decreased after 9 years of very high grazing pressure. However, neither N nor organic C decreased further.", "keywords": ["Technology", "570", "Economics", "PH", "630", "PROPRIETE CHIMIQUE", "AZOTE", "sandy soils", "grazing", "2. Zero hunger", "DENSITE", "SURFACE DU SOL", "MATIERE ORGANIQUE", "PATURAGE", "PHOSPHORE", "Production", "ETUDE D'IMPACT", "Agriculture-Farming", "CYCLE D'ELEMENT", "04 agricultural and veterinary sciences", "15. Life on land", "GRANULOMETRIE", "rangelands", "CARBONE ORGANIQUE", "livestock", "soil chemical properties", "BILAN HYDROLOGIQUE", "soil physical properties", "ETUDE EXPERIMENTALE", "0401 agriculture", " forestry", " and fisheries", "soil types", "CROUTE D'ALTERATION"]}, "links": [{"href": "https://doi.org/10.1006/jare.1998.0475"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Arid%20Environments", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1006/jare.1998.0475", "name": "item", "description": "10.1006/jare.1998.0475", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1006/jare.1998.0475"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "1999-03-01T00:00:00Z"}}, {"id": "10.1007/978-3-030-13068-8_80", "type": "Feature", "geometry": null, "properties": {"updated": "2026-07-27T16:14:30Z", "type": "Report", "created": "2019-09-18", "title": "CO2 Biofixation by Chlamydomonas reinhardtii Using Different CO2 Dosing Strategies", "description": "The CO2 sequestration potential of the green microalga Chlamydomonas reinhardtii was investigated with different CO2 dosing strategies. A gas mixture containing 30% CO2 and 70% N2 was used in these experiments in order to simulate the treatment of flue gases from various industries containing high concentrations of CO2. Alongside the CO2 sequestration, the results suggest that the microalgal biomass was rich in carbohydrates and lipids, and thus suitable to be used for biofuel production.", "keywords": ["Periodic CO2 dosing", "CO2 sequestration", "biochemical profiles", "Periodic CO2 dosing", " CO2 sequestration", " biochemical profiles", " chlorophyll", " Chlamydomonas reinhardtii", "chlorophyll", "7. Clean energy", "Chlamydomonas reinhardtii", "6. Clean water"]}, "links": [{"href": "https://www.iris.unina.it/bitstream/11588/726038/2/Version%20submitted%20for%20IRIS.pdf"}, {"href": "http://link.springer.com/content/pdf/10.1007/978-3-030-13068-8"}, {"href": "http://link.springer.com/content/pdf/10.1007/978-3-030-13068-8_80"}, {"href": "https://doi.org/10.1007/978-3-030-13068-8_80"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/978-3-030-13068-8_80", "name": "item", "description": "10.1007/978-3-030-13068-8_80", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/978-3-030-13068-8_80"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-09-19T00:00:00Z"}}, {"id": "10.1007/s13201-024-02101-w", "type": "Feature", "geometry": null, "properties": {"updated": "2026-07-27T16:15:33Z", "type": "Journal Article", "created": "2024-02-20", "title": "Exploration of cephalexin adsorption mechanisms onto bauxite and palygorskite and regeneration of spent adsorbents with cold plasma bubbling", "description": "AbstractThe aim of the present study was the direct comparison of two popular minerals, bauxite and palygorskite, as adsorbents for the removal of cephalexin (CPX) from aqueous solutions and the regeneration of the spent adsorbents through cold atmospheric plasma. Batch kinetics and isotherm studies were carried out to evaluate the effect of contact time, initial CPX concentration, adsorbent dosage, pH and temperature. The adsorbents were characterized by ATR-FTIR, N2 sorption, SEM and XRD, while several isotherm, kinetic and thermodynamic models were evaluated attempting to shed light on the adsorption mechanisms. CPX adsorption on both adsorbents was better described by Langmuir model, with an adsorption capacity of 112.36\uffc2\uffa0mg/g for palygorskite and 11.79\uffc2\uffa0mg/g for bauxite. Thermodynamics revealed the endothermic and the spontaneous character of the process, indicating chemisorption as the main adsorption mechanism for both adsorbents. The pseudo-second-order and the Elovich models fitted satisfactorily the adsorption onto bauxite, while adsorption onto palygorskite was well presented by Weber\uffe2\uff80\uff93Morris model, indicating that pore diffusion is also involved in the process. The adsorption capacity of both minerals decreased significantly after being used for several adsorption cycles and then almost completely recovered (regeneration efficiency was 99.6% and 98% for palygorskite and bauxite, respectively) inside a novel cold plasma microbubble reactor energized by high-voltage nanopulses, revealing the potential of these adsorbents to be reused. In addition to the regeneration of the adsorbents, the cold plasma completely eliminated the CPX transferred from the solid to the aqueous phase during the regeneration process.\u200990%), whereas isoelectric precipitation resulted in higher contents of dietary fibre and some minerals (i.e., sodium and phosphorus). Differences in the functional properties between the two ingredients were found as the isoelectric precipitated ingredient showed lower protein solubilities over the investigated pH range (from 3 to 9) which can be linked to the slightly higher hydrophobicity values (2688.7) and total sulfhydryl groups (23.9\u00a0\u00b5M/g) found in this sample. In contrast, the protein ingredient obtained by ultrafiltration was superior with regard to its solubility (48.3%; pH 7), fat-binding capacity (2.24\u00a0g/g), water holding capacity (3.96\u00a0g/g), gelling properties (11%; w/w), and foam-forming capacity (69.6%). The assessment of the environmental performance showed that both LPIs exhibited promising properties and low carbon footprints in comparison to traditional dairy proteins.", "keywords": ["2. Zero hunger", "Isoelectric precipitation", "Life cycle assessment", "0404 agricultural biotechnology", "lentil protein isolate; ultrafltration; isoelectric precipitation; physicochemical properties; protein functionality; life cycle assessment", "Physicochemical properties", "13. Climate action", "Lentil protein isolate", "Ultrafiltration", "04 agricultural and veterinary sciences", "Protein functionality", "0405 other agricultural sciences", "6. Clean water"]}, "links": [{"href": "http://link.springer.com/content/pdf/10.1007/s00217-019-03296-y.pdf"}, {"href": "https://doi.org/10.1007/s00217-019-03296-y"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/European%20Food%20Research%20and%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00217-019-03296-y", "name": "item", "description": "10.1007/s00217-019-03296-y", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00217-019-03296-y"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-05-24T00:00:00Z"}}, {"id": "10.1007/s00248-016-0730-z", "type": "Feature", "geometry": null, "properties": {"updated": "2026-07-27T16:14:40Z", "type": "Journal Article", "created": "2016-02-02", "title": "Responses Of Soil Bacterial Communities To Nitrogen Deposition And Precipitation Increment Are Closely Linked With Aboveground Community Variation", "description": "It has been predicted that precipitation and atmospheric nitrogen (N) deposition will increase in northern China; yet, ecosystem responses to the interactive effects of water and N remain largely unknown. In particular, responses of belowground microbial community to projected global change and their potential linkages to aboveground macro-organisms are rarely studied. In this study, we examined the responses of soil bacterial diversity and community composition to increased precipitation and multi-level N deposition in a temperate steppe in Inner Mongolia, China, and explored the diversity linkages between aboveground and belowground communities. It was observed that N addition caused the significant decrease in bacterial alpha-diversity and dramatic changes in community composition. In addition, we documented strong correlations of alpha- and beta-diversity between plant and bacterial communities in response to N addition. It was found that N enriched the so-called copiotrophic bacteria, but reduced the oligotrophic groups, primarily by increasing the soil inorganic N content and carbon availability and decreasing soil pH. We still highlighted that increased precipitation tended to alleviate the effects of N on bacterial diversity and dampen the plant-microbe connections induced by N. The counteractive effects of N addition and increased precipitation imply that even though the ecosystem diversity and function are predicted to be negatively affected by N deposition in the coming decades; the combination with increased precipitation may partially offset this detrimental effect.", "keywords": ["0301 basic medicine", "2. Zero hunger", "China", "0303 health sciences", "Bacteria", "Nitrogen", "Climate", "Microbial Consortia", "Water", "Biodiversity", "Plants", "15. Life on land", "Carbon", "6. Clean water", "Soil", "03 medical and health sciences", "13. Climate action", "Chemical Precipitation", "Ecosystem", "Phylogeny", "Soil Microbiology"]}, "links": [{"href": "https://doi.org/10.1007/s00248-016-0730-z"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Microbial%20Ecology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00248-016-0730-z", "name": "item", "description": "10.1007/s00248-016-0730-z", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00248-016-0730-z"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-02-02T00:00:00Z"}}, {"id": "10.1007/s00253-019-09689-z", "type": "Feature", "geometry": null, "properties": {"updated": "2026-07-27T16:14:40Z", "type": "Journal Article", "created": "2019-02-20", "title": "Distribution of Oenococcus oeni populations in natural habitats", "description": "Oenococcus oeni is the lactic acid bacteria species most commonly encountered in wine, where it develops after the alcoholic fermentation and achieves the malolactic fermentation that is needed to improve the quality of most wines. O. oeni is abundant in the oenological environment as well as in apple cider and kombucha, whereas it is a minor species in the natural environment. Numerous studies have shown that there is a great diversity of strains in each wine region and in each product or type of wine. Recently, genomic studies have shed new light on the species diversity, population structure, and environmental distribution. They revealed that O. oeni has unique genomic features that have contributed to its fast evolution and adaptation to the enological environment. They have also unveiled the phylogenetic diversity and genomic properties of strains that develop in different regions or different products. This review explores the distribution of O. oeni and the diversity of strains in natural habitats.", "keywords": ["0106 biological sciences", "0301 basic medicine", "570", "Evolution", "[SPI.GPROC] Engineering Sciences [physics]/Chemical and Process Engineering", "590", "Wine", "01 natural sciences", "Domestication", "Evolution", " Molecular", "03 medical and health sciences", "[SDV.IDA]Life Sciences [q-bio]/Food engineering", "MD Multidisciplinary", "[SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering", "Ecosystem", "Oenococcus", "Phylogeny", "0303 health sciences", "Malolactic fermentation", "Genetic Variation", "Genomics", "[SDV.IDA] Life Sciences [q-bio]/Food engineering", "Mini-Review", "Fermentation", "Oenococcus oeni", "Biotechnology"]}, "links": [{"href": "http://link.springer.com/content/pdf/10.1007/s00253-019-09689-z.pdf"}, {"href": "https://doi.org/10.1007/s00253-019-09689-z"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Applied%20Microbiology%20and%20Biotechnology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00253-019-09689-z", "name": "item", "description": "10.1007/s00253-019-09689-z", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00253-019-09689-z"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2019-02-20T00:00:00Z"}}, {"id": "10.1007/s00267-003-9106-5", "type": "Feature", "geometry": null, "properties": {"updated": "2026-07-27T16:14:40Z", "type": "Journal Article", "created": "2004-03-22", "title": "Response Of Organic And Inorganic Carbon And Nitrogen To Long-Term Grazing Of The Shortgrass Steppe", "description": "We investigated the influence of long-term (56 years) grazing on organic and inorganic carbon (C) and nitrogen (N) contents of the plant-soil system (to 90 cm depth) in shortgrass steppe of northeastern Colorado. Grazing treatments included continuous season-long (May-October) grazing by yearling heifers at heavy (60-75% utilization) and light (20-35% utilization) stocking rates, and nongrazed exclosures. The heavy stocking rate resulted in a plant community that was dominated (75% of biomass production) by the C4 grass blue grama (Bouteloua gracilis), whereas excluding livestock grazing increased the production of C3 grasses and prickly pear cactus (Opuntia polycantha). Soil organic C (SOC) and organic N were not significantly different between the light grazing and nongrazed treatments, whereas the heavy grazing treatment was 7.5 Mg ha(-1) higher in SOC than the nongrazed treatment. Lower ratios of net mineralized N to total organic N in both grazed compared to nongrazed treatments suggest that long-term grazing decreased the readily mineralizable fraction of soil organic matter. Heavy grazing affected soil inorganic C (SIC) more than the SOC. The heavy grazing treatment was 23.8 Mg ha(-1) higher in total soil C (0-90 cm) than the nongrazed treatment, with 68% (16.3 Mg ha(-1)) attributable to higher SIC, and 32% (7.5 Mg ha(-1)) to higher SOC. These results emphasize the importance in semiarid and arid ecosystems of including inorganic C in assessments of the mass and distribution of plant-soil C and in evaluations of the impacts of grazing management on C sequestration.", "keywords": ["Cactaceae", "2. Zero hunger", "Colorado", "Nitrogen", "Feeding Behavior", "04 agricultural and veterinary sciences", "15. Life on land", "Poaceae", "01 natural sciences", "Carbon", "Soil", "Animals", "0401 agriculture", " forestry", " and fisheries", "Cattle", "Biomass", "Desert Climate", "Organic Chemicals", "Plants", " Edible", "Ecosystem", "0105 earth and related environmental sciences"], "contacts": [{"organization": "Jack A. Morgan, Daniel R. LeCain, Gerald E. Schuman, Jean D. Reeder,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1007/s00267-003-9106-5"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Management", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00267-003-9106-5", "name": "item", "description": "10.1007/s00267-003-9106-5", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00267-003-9106-5"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2004-03-23T00:00:00Z"}}, {"id": "10.1007/s00289-022-04193-3", "type": "Feature", "geometry": null, "properties": {"license": "Closed Access", "updated": "2026-07-27T16:14:42Z", "type": "Journal Article", "created": "2022-04-09", "title": "Development of the hydrophilic additive by suspension copolymerisation of methacrylic acid with isodecyl methacrylate for easy-to-clean coatings", "keywords": ["02 engineering and technology", "0210 nano-technology", "01 natural sciences", "0104 chemical sciences"], "contacts": [{"organization": "P. B. Bamane, R. N. Jagtap,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1007/s00289-022-04193-3"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Polymer%20Bulletin", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00289-022-04193-3", "name": "item", "description": "10.1007/s00289-022-04193-3", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00289-022-04193-3"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-04-09T00:00:00Z"}}, {"id": "10.1007/s10853-014-8308-y", "type": "Feature", "geometry": null, "properties": {"updated": "2026-07-27T16:15:09Z", "type": "Journal Article", "created": "2014-05-22", "title": "Review: the characterization of electrospun nanofibrous liquid filtration membranes", "description": "Electrospun nanofibrous membranes (ENMs) are used in a variety of applications, including sensors, tissue engineering, air filtration, energy, and reinforcement in composite materials. Recently, they have gained an interest in the field of liquid filtration. The membranes, surface, bulk, and overall architecture play an important role in the filtration properties and hence the right characterization technique needs to be established, which will pave the way for future developments in the field of filtration. In this article, we have reviewed the recent advances in ENMs for liquid separation application.", "keywords": ["02 engineering and technology", "0210 nano-technology", "01 natural sciences", "3. Good health", "0104 chemical sciences"]}, "links": [{"href": "https://doi.org/10.1007/s10853-014-8308-y"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Materials%20Science", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10853-014-8308-y", "name": "item", "description": "10.1007/s10853-014-8308-y", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10853-014-8308-y"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2014-05-23T00:00:00Z"}}, {"id": "10.1007/s10853-022-07789-2", "type": "Feature", "geometry": null, "properties": {"license": "Closed Access", "updated": "2026-07-27T16:15:09Z", "type": "Journal Article", "created": "2022-11-11", "title": "Tannic acid/ethylenediamine/succinic acid graft modified PVDF anti-pollution membrane and its application in the field of organic pollutant separation", "keywords": ["02 engineering and technology", "0210 nano-technology", "01 natural sciences", "0104 chemical sciences"], "contacts": [{"organization": "Rui Zhang, Jiacheng Jiang, Yi Liu, Yu Li, Chen Zhao, Ze Yang, Lu Cai, Junrong Yu, Ziyin Chen, Zhengwen Hu,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1007/s10853-022-07789-2"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Journal%20of%20Materials%20Science", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s10853-022-07789-2", "name": "item", "description": "10.1007/s10853-022-07789-2", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s10853-022-07789-2"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2022-11-01T00:00:00Z"}}, {"id": "10.1007/s00604-005-0340-9", "type": "Feature", "geometry": null, "properties": {"license": "Closed Access", "updated": "2026-07-27T16:14:51Z", "type": "Journal Article", "created": "2005-04-01", "title": "Determination of La, Eu and Yb in Water Samples by Inductively Coupled Plasma Atomic Emission Spectrometry After Solid Phase Extraction of Their 1-Phenyl-3-Methyl-4-Benzoylpyrazol-5-one Complexes on Silica Gel Column", "description": "A simple preconcentration method has been developed for the determination of trace amounts of rare earth elements (La, Eu, and Yb) in natural water samples by inductively coupled plasma atomic emission spectrometry (ICP-AES). Preconcentration of La, Eu, and Yb was achieved by sorption of their 1-phenyl-3-methyl-4-benzoylpyrazol-5-one (PMBP) complexes on a silica gel column at pH 5 and then eluting with 1.0 mol L\u22121 HNO3. For the preconcentration of 100 mL of aqueous solution, an enrichment of 100 was obtained for all analytes, and the detection limits for La, Eu and Yb were 82, 34 and 45 ng L\u22121, respectively. The accuracy of this method was demonstrated by analyzing a standard reference material. The method has been successfully applied to the determination of La, Eu and Yb in lake water and synthetic seawater.", "keywords": ["01 natural sciences", "6. Clean water", "0104 chemical sciences"], "contacts": [{"organization": "Pei Liang, Wenjun Fa,", "roles": ["creator"]}]}, "links": [{"href": "https://doi.org/10.1007/s00604-005-0340-9"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Microchimica%20Acta", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1007/s00604-005-0340-9", "name": "item", "description": "10.1007/s00604-005-0340-9", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1007/s00604-005-0340-9"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2005-04-04T00:00:00Z"}}], "links": [{"rel": "self", "type": "application/geo+json", "title": "This document as GeoJSON", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=chemical&f=json", "hreflang": "en-US"}, {"rel": "alternate", "type": "text/html", "title": "This document as HTML", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=chemical&f=html", "hreflang": "en-US"}, {"rel": "collection", "type": "application/json", "title": "Collection URL", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main", "hreflang": "en-US"}, {"type": "application/geo+json", "rel": "first", "title": "items (first)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=chemical&", "hreflang": "en-US"}, {"rel": "next", "type": "application/geo+json", "title": "items (next)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=chemical&offset=50", "hreflang": "en-US"}], "numberMatched": 836, "numberReturned": 50, "distributedFeatures": [], "timeStamp": "2026-07-28T10:48:35.198935Z"}