{"type": "FeatureCollection", "features": [{"id": "10.3390/ma11040557", "type": "Feature", "geometry": null, "properties": {"updated": "2026-06-23T16:21:46Z", "type": "Journal Article", "created": "2018-04-04", "title": "Hydroxyapatite and Other Calcium Phosphates for the Conservation of Cultural Heritage: A Review", "description": "<p>The present paper reviews the methods and the performance of in situ formation of calcium phosphates (CaP) for the conservation of materials belonging to cultural heritage. The core idea is to form CaP (ideally hydroxyapatite, HAP, the most stable CaP at pH &gt; 4) by reaction between the substrate and an aqueous solution of a phosphate salt. Initially proposed for the conservation of marble and limestone, the treatment has been explored for a variety of different substrates, including sandstones, sulphated stones, gypsum stuccoes, concrete, wall paintings, archaeological bones and paper. First, the studies aimed at identifying the best treatment conditions (e.g., nature and concentration of the phosphate precursor, solution pH, treatment duration, ionic and organic additions to the phosphate solution, mineralogical composition of the new CaP phases) are summarized. Then, the treatment performance on marble and limestone is reviewed, in terms of protective and consolidating effectiveness, compatibility (aesthetic, microstructural and physical) and durability. Some pilot applications in real case studies are also reported. Recent research aimed at extending the phosphate treatment to other substrates is then illustrated. Finally, the strengths of the phosphate treatment are summarized, in comparison with alternative products, and some aspects needing future research are outlined.</p>", "keywords": ["Ammonium oxalate; Ammonium phosphate; Calcium phosphates; Consolidation; Durability; Hydroxyapatite; Limestone; Marble; Octacalcium phosphate; Protection; Materials Science", "2. Zero hunger", "11. Sustainability", "Review", "02 engineering and technology", "ING-IND/22 Scienza e tecnologia dei materiali", "0210 nano-technology", "6. Clean water", "marble limestone consolidation protection durability calcium phosphates hydroxyapatite octacalcium phosphate ammonium phosphate ammonium oxalate", "12. Responsible consumption"], "contacts": [{"organization": "Sassoni, Enrico", "roles": ["creator"]}]}, "links": [{"href": "https://cris.unibo.it/bitstream/11585/643011/1/Sassoni%20%282018%29%20Review%20HAP%20for%20CH.pdf"}, {"href": "http://www.mdpi.com/1996-1944/11/4/557/pdf"}, {"href": "https://doi.org/10.3390/ma11040557"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Materials", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.3390/ma11040557", "name": "item", "description": "10.3390/ma11040557", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.3390/ma11040557"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2018-04-04T00:00:00Z"}}, {"id": "10.6092/unibo/amsacta/5712", "type": "Feature", "geometry": null, "properties": {"license": "Open Access", "updated": "2026-06-23T16:25:26Z", "type": "Journal Article", "title": "Mineral consolidants", "description": "Inorganic consolidants, such as ethyl silicate, nanolime and ammonium oxalate, have proven to be effective for certain materials, but each has its drawbacks. This has recently led to the investigation of hydroxyapatite (HAP) as a novel inorganic consolidant, which demonstrated excellent performance on carbonate stones. Considering that a mineral that matched calcite crystal lattice parameters even more closely than HAP would be expected to provide a consolidating action even greater than HAP, in this study aluminum phosphate (AP) was investigated as a potential new consolidant. Indeed, AP has lattice parameters differing from those of calcite by only 1%. The consolidating ability of AP was preliminarily investigated here in comparison with HAP. Both treatments were tested on artificially weathered marble samples, in the view of their application for conservation of sugaring marble. A novel method is also proposed for producing samples with near-surface damage similar to that of sugaring marble in the field. The results of the study point out that the novel weathering method is able to provide samples with tailored gradient in dynamic elastic modulus, closely resembling naturally sugaring marble. The AP treatment was found to significantly improve the dynamic elastic modulus of weathered marble, at least as efficiently as the HAP treatment investigated in this study. This confirmed the high potential of AP as a new inorganic consolidant.", "keywords": ["Marble; Inorganic consolidants", " Hydroxyapatite; Calcium phosphates", "ING-IND/22 Scienza e tecnologia dei materiali", "Marble; Limestone; Calcium phosphates; Consolidation"], "contacts": [{"organization": "George W. Scherer, SASSONI, ENRICO,", "roles": ["creator"]}]}, "links": [{"href": "https://cris.unibo.it/bitstream/11585/563450/5/Covegno%20RILEM%20Copenhagen.pdf"}, {"href": "https://doi.org/10.6092/unibo/amsacta/5712"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Proceedings%20of%20the%20International%20RILEM%20Conference%20Materials%2C%20Systems%20and%20Structures%20in%20Civil%20Engineering%202016%20-%20Segment%20on%20Historical%20Masonry", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.6092/unibo/amsacta/5712", "name": "item", "description": "10.6092/unibo/amsacta/5712", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.6092/unibo/amsacta/5712"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2016-01-01T00:00:00Z"}}, {"id": "158864ac-e232-4ce5-9ddc-5f1f8481f89f", "type": "Feature", "geometry": {"type": "Polygon", "coordinates": [[[11.46, 51.51], [11.46, 54.03], [15.24, 54.03], [15.24, 51.51], [11.46, 51.51]]]}, "properties": {"rights": "Restrictions applied to assure the protection of privacy or intellectual property, and any special restrictions or limitations or warnings on using the resource or metadata. Reports, articles, papers, scientific and non-scientific works of any form, including tables, maps, or any other kind of output, in printed or electronic form, based in whole or in part on the data supplied, must contain an acknowledgement of the form: \u201cData reused from the BonaRes Data Centre www.bonares.de.\u201d Although every care has been taken in preparing and testing the soil profile data, the author and BonaRes Data Centre cannot guarantee that the data are correct; neither does the author and BonaRes Data Centre accept any liability whatsoever for any error, missing data or omission in the data, or for any loss or damage arising from its use. 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Concepts, version 2.4"}, {"concepts": [{"id": "opendata"}, {"id": "Soil"}, {"id": "agriculture"}], "scheme": "INSPIRE"}], "rights": "Restrictions applied to assure the protection of privacy or intellectual property, and any special restrictions or limitations or warnings on using the resource or metadata. Reports, articles, papers, scientific and non-scientific works of any form, including tables, maps, or any other kind of output, in printed or electronic form, based in whole or in part on the data supplied, must contain an acknowledgement of the form: \u201cData reused from the BonaRes Data Centre www.bonares.de.\u201d Although every care has been taken in preparing and testing the soil profile data, the author and BonaRes Data Centre cannot guarantee that the data are correct; neither does the author and BonaRes Data Centre accept any liability whatsoever for any error, missing data or omission in the data, or for any loss or damage arising from its use. The author and BonaRes Data Centre will not be responsible for any direct or indirect use which might be made of the data.", "updated": "2023-09-12", "type": "Dataset", "created": "2023-08-29", "language": "eng", "title": "Reference soil samples (pH, soil texture, SOC, TC, TN, P, K, Mg) from the project \"pH-BB: Precision liming in Brandenburg\" - data set 1 (farm 1)", "description": "Within the EIP-AGRI-funded project \u201cpH-BB: Precision liming in Brandenburg\u201d, research was conducted on improving the management of soil acidity on farms in the federal state of Brandenburg (Germany). With the help of mobile proximal soil sensors, the lime-relevant soil parameters pH value, texture and soil organic matter were recorded time-saving, cost-effectively and on a small scale. Regulations for processing the sensor data and deriving fertilization recommendations were developed. An important sub-step in determining the lime requirement is the site-specific calibration of the sensor data in order to obtain high-resolution maps of the lime-relevant soil parameters. For this purpose, soil samples were taken from all mapped plots and analyzed for pH, soil organic carbon and grain size distribution. The analyzed results of the first out of three participating farms in the project are available in this data set. Furthermore, in addition to the analysis of the pH value, a basic soil investigation was carried out determining the plant-availability of phosphorus, potassium and magnesium. To date, the dataset consists of a total of 308 entries for pH, 222 for soil organic carbon, total carbon and total nitrogen content, 274 for P, K and Mg, and 327 for soil texture (clay, fine silt, medium silt, coarse silt, fine sand, medium sand, coarse sand). 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