{"type": "FeatureCollection", "features": [{"id": "10.1016/j.epsl.2017.04.002", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:16:22Z", "type": "Journal Article", "created": "2017-04-14", "title": "The origin of volatile element depletion in early solar system material: Clues from Zn isotopes in chondrules", "description": "Abstract   Volatile lithophile elements are depleted in the different planetary materials to various degrees, but the origin of these depletions is still debated. Stable isotopes of moderately volatile elements such as Zn can be used to understand the origin of volatile element depletions. Samples with significant volatile element depletions, including the Moon and terrestrial tektites, display heavy Zn isotope compositions (i.e. enrichment of 66Zn vs. 64Zn), consistent with kinetic Zn isotope fractionation during evaporation. However,  Luck et al. (2005)  found a negative correlation between      \u03b4    66     Zn and 1/[Zn] between CI, CM, CO, and CV chondrites, opposite to what would be expected if evaporation caused the Zn abundance variations among chondrite groups.  We have analyzed the Zn isotope composition of multiple samples of the major carbonaceous chondrite classes: CI (1), CM (4), CV (2), CO (4), CB (2), CH (2), CK (4), and CK/CR (1). The bulk chondrites define a negative correlation in a plot of      \u03b4    66     Zn vs 1/[Zn], confirming earlier results that Zn abundance variations among carbonaceous chondrites cannot be explained by evaporation. Exceptions are CB and CH chondrites, which display Zn systematics consistent with a collisional formation mechanism that created enrichment in heavy Zn isotopes relative to the trend defined by CI\u2013CK.  We further report Zn isotope analyses of chondrite components, including chondrules from Allende (CV3) and Mokoia (CV3), as well as an aliquot of Allende matrix. All chondrules are enriched in light Zn isotopes (\u223c500 ppm on 66Zn/64Zn) relative to the bulk, contrary to what would be expected if Zn were depleted during evaporation, on the other hand the matrix has a complementary heavy isotope composition. We report sequential leaching experiments in un-equilibrated ordinary chondrites, which show sulfides are isotopically heavy compared to silicates and the bulk meteorite by ca. +0.65 per mil on 66Zn/64Zn. We suggest isotopically heavy sulfides were removed from either chondrules or their precursors, thereby producing the light Zn isotope enrichments in chondrules.", "keywords": ["chondrules", "550", "protoplanetary disk", "551", "carbonaceous chondrites", "01 natural sciences", "volatiles", "[SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology", "[SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "13. Climate action", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "[SDU.STU.PL] Sciences of the Universe [physics]/Earth Sciences/Planetology", "zinc isotopes", "0105 earth and related environmental sciences"]}, "links": [{"href": "https://doi.org/10.1016/j.epsl.2017.04.002"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Earth%20and%20Planetary%20Science%20Letters", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1016/j.epsl.2017.04.002", "name": "item", "description": "10.1016/j.epsl.2017.04.002", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1016/j.epsl.2017.04.002"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-06-01T00:00:00Z"}}, {"id": "10.1021/acs.est.7b02944", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:17:50Z", "type": "Journal Article", "created": "2017-10-11", "title": "Novel Multi-isotope Tracer Approach To Test ZnO Nanoparticle and Soluble Zn Bioavailability in Joint Soil Exposures", "description": "Here we use two enriched stable isotopes, 68Znen and 64Znen (>99%), to prepare 68ZnO nanoparticles (NPs) and soluble 64ZnCl2. The standard LUFA 2.2 test soil was dosed with 68ZnO NPs and soluble 64ZnCl2 to 5 mg kg-1 each, plus between 0 and 95 mg kg-1 of soluble ZnCl2 with a natural isotope composition. After 0, 1, 3, 6, and 12 months of soil incubation, earthworms (Eisenia andrei) were introduced for 72 h exposures. Analyses of soils, pore waters, and earthworm tissues using multiple collector inductively coupled plasma mass spectrometry allowed the simultaneous measurement of the diagnostic 68Zn/66Zn, 64Zn/66Zn, and 68Zn/64Zn ratios, from which the three different isotopic forms of Zn were quantified. Eisenia andrei was able to regulate Zn body concentrations with no difference observed between the different total dosing concentrations. The accumulation of labeled Zn by the earthworms showed a direct relationship with the proportion of labeled to total Zn in the pore water, which increased with longer soil incubation times and decreasing soil pH. The 68Znen/64Znen ratios determined for earthworms (1.09 \u00b1 0.04), soils (1.09 \u00b1 0.02), and pore waters (1.08 \u00b1 0.02) indicate indistinguishable environmental distribution and uptake of the Zn forms, most likely due to rapid dissolution of the ZnO NPs.", "keywords": ["104002 Analytische Chemie", "550", "TRANSFORMATIONS", "FATE", "0211 other engineering and technologies", "Biological Availability", "02 engineering and technology", "01 natural sciences", "Soil", "104002 Analytical chemistry", "104023 Umweltchemie", "ENGINEERED NANOMATERIALS", "MD Multidisciplinary", "Animals", "Soil Pollutants", "105906 Environmental geosciences", "210004 Nanomaterials", "Oligochaeta", "EARTHWORM EISENIA-ANDREI", "0105 earth and related environmental sciences", "ENVIRONMENT", "104023 Environmental chemistry", "KNOWLEDGE GAPS", "[SDU.ENVI] Sciences of the Universe [physics]/Continental interfaces", " environment", "6. Clean water", "Zinc", "Nanoparticles", "Zinc Isotopes", "Zinc Oxide", "210004 Nanomaterialien", "Environmental Sciences", "105906 Umweltgeowissenschaften"]}, "links": [{"href": "https://pubs.acs.org/doi/pdf/10.1021/acs.est.7b02944"}, {"href": "https://doi.org/10.1021/acs.est.7b02944"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Environmental%20Science%20%26amp%3B%20Technology", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1021/acs.est.7b02944", "name": "item", "description": "10.1021/acs.est.7b02944", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1021/acs.est.7b02944"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-10-26T00:00:00Z"}}, {"id": "10.1111/maps.12922", "type": "Feature", "geometry": null, "properties": {"updated": "2026-04-13T16:19:47Z", "type": "Journal Article", "created": "2017-07-27", "title": "Implications for behavior of volatile elements during impacts-Zinc and copper systematics in sediments from the Ries impact structure and central European tektites", "description": "Abstract<p>Moldavites are tektites genetically related to the Ries impact structure, located in Central Europe, but the source materials and the processes related to the chemical fractionation of moldavites are not fully constrained. To further understand moldavite genesis, the Cu and Zn abundances and isotope compositions were measured in a suite of tektites from four different substrewn fields (South Bohemia, Moravia, Cheb Basin, Lusatia) and chemically diverse sediments from the surroundings of the Ries impact structure. Moldavites are slightly depleted in Zn (~10\uffe2\uff80\uff9320%) and distinctly depleted in Cu (&gt;90%) relative to supposed sedimentary precursors. Moreover, the moldavites show a wide range in \uffce\uffb466Zn values between 1.7 and 3.7\uffe2\uff80\uffb0 (relative to JMC 3\uffe2\uff80\uff900749 Lyon) and \uffce\uffb465Cu values between 1.6 and 12.5\uffe2\uff80\uffb0 (relative to NIST SRM 976) and are thus enriched in heavy isotopes relative to their possible parent sedimentary sources (\uffce\uffb466Zn\uffc2\uffa0=\uffc2\uffa0\uffe2\uff88\uff920.07 to +0.64\uffe2\uff80\uffb0; \uffce\uffb465Cu\uffc2\uffa0=\uffc2\uffa0\uffe2\uff88\uff920.4 to +0.7\uffe2\uff80\uffb0). In particular, the Cheb Basin moldavites show some of the highest \uffce\uffb465Cu values (up to 12.5\uffe2\uff80\uffb0) ever observed in natural samples. The relative magnitude of isotope fractionation for Cu and Zn seen here is opposite to oxygen\uffe2\uff80\uff90poor environments such as the Moon where Zn is significantly more isotopically fractionated than Cu. One possibility is that monovalent Cu diffuses faster than divalent Zn in the reduced melt and diffusion will not affect the extent of Zn isotope fractionation. These observations imply that the capability of forming a redox environment may aid in volatilizing some elements, accompanied by isotope fractionation, during the impact process. The greater extent of elemental depletion, coupled with isotope fractionation of more refractory Cu relative to Zn, may also hinge on the presence of carbonyl species of transition metals and electromagnetic charge, which could exist in the impact\uffe2\uff80\uff90induced high\uffe2\uff80\uff90velocity jet of vapor and melts.</p>", "keywords": ["550", "GRANITES", "NDAS", "Ries crater", "01 natural sciences", "Tektites", "ZINC", "[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry", "QE", "14. Life underwater", "STABLE-ISOTOPE GEOCHEMISTRY", "QC", "0105 earth and related environmental sciences", "Copper isotopes", "ORIGIN", "AUSTRALASIAN TEKTITES", "FRACTIONATION", "IRON", "500", "LACHLAN FOLD BELT", "Ries area sediments", "QE Geology", "Impact", "QC Physics", "13. Climate action", "Volatile loss", "ZN", "Isotope fractionation", "Zinc isotopes", "CU"]}, "links": [{"href": "http://onlinelibrary.wiley.com/wol1/doi/10.1111/maps.12922/fullpdf"}, {"href": "https://doi.org/10.1111/maps.12922"}, {"rel": "related", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/Meteoritics%20%26amp%3B%20Planetary%20Science", "name": "related record", "description": "related record", "type": "application/json"}, {"rel": "self", "type": "application/geo+json", "title": "10.1111/maps.12922", "name": "item", "description": "10.1111/maps.12922", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items/10.1111/maps.12922"}, {"rel": "collection", "type": "application/json", "title": "Collection", "name": "collection", "description": "Collection", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main"}], "time": {"date": "2017-07-27T00:00:00Z"}}], "links": [{"rel": "self", "type": "application/geo+json", "title": "This document as GeoJSON", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=zinc+isotopes&f=json", "hreflang": "en-US"}, {"rel": "alternate", "type": "text/html", "title": "This document as HTML", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=zinc+isotopes&f=html", "hreflang": "en-US"}, {"rel": "collection", "type": "application/json", "title": "Collection URL", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main", "hreflang": "en-US"}, {"type": "application/geo+json", "rel": "first", "title": "items (first)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=zinc+isotopes&", "hreflang": "en-US"}, {"rel": "last", "type": "application/geo+json", "title": "items (last)", "href": "https://repository.soilwise-he.eu/cat/collections/metadata:main/items?keywords=zinc+isotopes&offset=3", "hreflang": "en-US"}], "numberMatched": 3, "numberReturned": 3, "distributedFeatures": [], "timeStamp": "2026-04-16T12:36:02.802248Z"}